JPS59161449A - Heat-insulation material - Google Patents

Heat-insulation material

Info

Publication number
JPS59161449A
JPS59161449A JP3449183A JP3449183A JPS59161449A JP S59161449 A JPS59161449 A JP S59161449A JP 3449183 A JP3449183 A JP 3449183A JP 3449183 A JP3449183 A JP 3449183A JP S59161449 A JPS59161449 A JP S59161449A
Authority
JP
Japan
Prior art keywords
plastic material
heat
hollow glass
insulation
microns
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3449183A
Other languages
Japanese (ja)
Inventor
Shunichi Hayashi
俊一 林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP3449183A priority Critical patent/JPS59161449A/en
Publication of JPS59161449A publication Critical patent/JPS59161449A/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B1/00Engines characterised by fuel-air mixture compression
    • F02B1/02Engines characterised by fuel-air mixture compression with positive ignition
    • F02B1/04Engines characterised by fuel-air mixture compression with positive ignition with fuel-air mixture admission into cylinder

Abstract

PURPOSE:To provide a heat-insulation material having improved heat-insulation property keeping the original mechanical properties of the base resin, and suitable as a heat-insulation packing between the cylinder and the carburetter, etc. of a gasoline engine, by mixing a plastic material with hollow glass spheres. CONSTITUTION:A plastic material is compounded with >=5wt%, preferably 10- 50wt% of hollow glass spheres. The plastic material is e.g. phenolic resin, epoxy resin, etc., and a plastic material requiring a static pressure of 100-300kg/cm<2> for molding is to be avoided. The hollow glass sphere is preferably those having an average particle diameter of 50-100 microns, a particle size distribution wherein the fraction finer than 250 microns accounts for 100% of the particles, and a specific gravity of 0.15-0.4.

Description

【発明の詳細な説明】 本発明は、プラスチック材料製の断熱材に関し、特に機
械的性質を低下させることな(、断熱効果を向上させ得
る上記断熱材に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a heat insulating material made of plastic material, and particularly to the above heat insulating material that can improve the heat insulating effect without deteriorating the mechanical properties.

一般に、プラスチック材料そのものは金属材料に比較し
て、熱伝導率は−〜−と低く、10    10G 充分な断°熱性を有するが、より以上の断熱性を必要と
する場合には、空気、不活性ガス等圧より発泡させる方
法が従来よ(行なわれている。
In general, plastic materials themselves have a low thermal conductivity of 10 to 10 G compared to metal materials, and have sufficient heat insulation properties, but if higher heat insulation properties are required, air, Conventionally, a method of foaming using equal pressure of active gas has been used.

しかし、この方法では、曲げ強度、曲げ剛性率等の機械
的性質が発泡による密度の低下にともない低下するのが
欠点である。
However, this method has the disadvantage that mechanical properties such as bending strength and bending rigidity decrease as the density decreases due to foaming.

本発明は、上記欠点を解消するためになされたもので、
機械的性質を保持したまま1断熱特性を向上させる断熱
材を提供するものである。
The present invention has been made to solve the above-mentioned drawbacks.
The present invention provides a heat insulating material that improves thermal insulation properties while maintaining mechanical properties.

すなわち本発明は、プラスチック材料に中空ガラス球体
(以下ガラスバルーンと称す)を混入してなる断熱材に
関するもので、本発明断熱材によれば、機械的性質を低
下させることなく、熱伝導率を低下させることができる
That is, the present invention relates to a heat insulating material made by mixing hollow glass spheres (hereinafter referred to as glass balloons) into a plastic material. can be lowered.

本発明断熱材は、ガソリンエンジンのシリンダ、気化器
間の断熱パツキン等圧適用することができる。
The heat insulating material of the present invention can be applied to a heat insulating gasket between the cylinder and carburetor of a gasoline engine.

以下に本発明に適するプラスチック材料の種類、ガラス
バルーンの性状を説明する。
The types of plastic materials suitable for the present invention and the properties of the glass balloon will be explained below.

本発明に適するプラスチック材料は、次のようにして選
定される。すなわちグラスチック材料に混入するガラス
バルーンは材質や中空度によっても異なるが大部分は1
00〜500 kf/(7M”の静水圧下で破壊する。
Plastic materials suitable for the present invention are selected as follows. In other words, the glass balloons mixed into the glass material vary depending on the material and degree of hollowness, but most of them are 1.
Destruction under hydrostatic pressure of 00-500 kf/(7M").

従って、成形時に、この静水圧力がかかる圧縮圧力以上
の圧力を加えなければならないプラスチック材料は適当
ではない。例えば、射出成形法を用いる大部分の熱・可
塑性樹脂は不適当である。適当なものとじては、圧縮成
形・注型成形が可能なプラスチック材料があげられ、例
えば、フェノール樹脂、エポキシ樹脂、不飽和ポリエス
テル樹脂、ポリ塩化ビニルゾル等がある。
Therefore, plastic materials are not suitable because they require a pressure higher than the compression pressure applied by this hydrostatic pressure during molding. For example, most thermoplastic resins using injection molding methods are unsuitable. Suitable materials include compression moldable/cast moldable plastic materials, such as phenolic resins, epoxy resins, unsaturated polyester resins, polyvinyl chloride sols, and the like.

また混入するガラスバルーンの好ましい性状を表1に示
す。
Further, Table 1 shows preferable properties of the glass balloon to be mixed.

更に、本発明断熱材は、上述したプラスチック材料に上
述したガラスバルーンを5重量−以上混入する。これは
、5重量%より少ないと後述の実施例に示すように熱伝
導率の低下効果が余り得られないからである。また、ガ
ラスバルーンの量が余り多過ぎると、ガラスバルーン同
志が付着してしまい好ましい機械的性質が得られた(な
るので、好ましい混入量は10〜50重量−である。
Furthermore, in the heat insulating material of the present invention, the above-mentioned glass balloon is mixed in the above-mentioned plastic material in an amount of 5 weight or more. This is because if it is less than 5% by weight, the effect of lowering the thermal conductivity cannot be obtained much as shown in the examples below. In addition, if the amount of glass balloons is too large, the glass balloons will stick to each other and preferable mechanical properties will not be obtained (therefore, the preferable amount to be mixed is 10 to 50% by weight).

次に、実施例をあげ本発明を具体的に説明する。Next, the present invention will be specifically explained with reference to Examples.

実施例 供試材料:■ フェノール樹脂成形材料■ 平均粒径8
0ミクロン、粒度 分布100%250ミクロン以 下、比重α28のガラスノくルー ン 成形法: 粉状にしたフェノール樹脂成形材料とガラス
バルーンを所定量混 入し、型内に充填後、通常の圧縮 成形(加圧か150 kl/”l” %硬化時間10分
、硬化温厩150°0)を 行なう。
Example sample material: ■ Phenolic resin molding material ■ Average particle size 8
Glass balloon molding method: 0 micron, particle size distribution 100%, 250 micron or less, specific gravity α28: Mix a predetermined amount of powdered phenolic resin molding material and glass balloons, fill it in a mold, and then perform normal compression molding (pressure molding). 150 kl/"l"% curing time 10 minutes, curing temperature 150°0).

成形品特性: 所定の混合比ごとの熱伝導率と圧縮強さ
を表2に示す。
Molded product properties: Table 2 shows the thermal conductivity and compressive strength for each predetermined mixing ratio.

表2 表2の結果より、ガラス/<ルー7を混入することによ
り、圧縮強さが低下することなく、熱伝導率が著しく低
下し、本発明断熱材力を工業上極めて有益であることが
明らかである。
Table 2 From the results in Table 2, it can be seen that by mixing glass/<Rue 7, the thermal conductivity decreases significantly without decreasing the compressive strength, making the heat insulating material of the present invention extremely useful industrially. it is obvious.

復代理人  内 1)  明 復代理人  萩 原 亮 −Sub-agent: 1) Akira Sub-agent Ryo Hagi Hara -

Claims (1)

【特許請求の範囲】[Claims] プラスチック材料に中空ガラス球体を5重量−以上混入
してなる断熱材。
A heat insulating material made by mixing 5 or more weight of hollow glass spheres into a plastic material.
JP3449183A 1983-03-04 1983-03-04 Heat-insulation material Pending JPS59161449A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3449183A JPS59161449A (en) 1983-03-04 1983-03-04 Heat-insulation material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3449183A JPS59161449A (en) 1983-03-04 1983-03-04 Heat-insulation material

Publications (1)

Publication Number Publication Date
JPS59161449A true JPS59161449A (en) 1984-09-12

Family

ID=12415710

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3449183A Pending JPS59161449A (en) 1983-03-04 1983-03-04 Heat-insulation material

Country Status (1)

Country Link
JP (1) JPS59161449A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0291134A (en) * 1988-09-28 1990-03-30 Chisso Corp Thermoplastic resin composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0291134A (en) * 1988-09-28 1990-03-30 Chisso Corp Thermoplastic resin composition
JPH0611866B2 (en) * 1988-09-28 1994-02-16 チッソ株式会社 Thermoplastic resin composition

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