JPS59157311A - Melt spinning of synthetic yarn - Google Patents

Melt spinning of synthetic yarn

Info

Publication number
JPS59157311A
JPS59157311A JP2777083A JP2777083A JPS59157311A JP S59157311 A JPS59157311 A JP S59157311A JP 2777083 A JP2777083 A JP 2777083A JP 2777083 A JP2777083 A JP 2777083A JP S59157311 A JPS59157311 A JP S59157311A
Authority
JP
Japan
Prior art keywords
yarn
titanium oxide
contact
running
bar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2777083A
Other languages
Japanese (ja)
Inventor
Kazumi Kondo
近藤 和美
Mitsuo Yamazaki
山崎 満夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to JP2777083A priority Critical patent/JPS59157311A/en
Publication of JPS59157311A publication Critical patent/JPS59157311A/en
Pending legal-status Critical Current

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Landscapes

  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

PURPOSE:To prevent overlapping of filaments constituting yarn, to improve extremely quality and grade, by solidifying yarn under cooling, by bringing it into contact with a specific bar of carbon-containing titanium oxide, running it on the bar. CONSTITUTION:The yarn Y extruded from the spinneret 1' of the spinning part 1 is passed through the cooling and solidifying zone I , cooled, the yarn Y running in a range 250mm. from the oiling agent providing zone II, between the solidifying zone I and the oiling agent providing zone II, is made to intersect perpendicularly to the bar 3 of carbon-containing titanium oxide rotating at circumferential speed 2X10<-5>-45X10<-4> the speed of the yarn, set in an opposing way in the oiling agent providing zone, the yarn is run in contact with the bar for 0.5-2.5mm., so that the yarn is provided with the oiling agent uniformly, and quality and grade of the yarn are extremely improved.

Description

【発明の詳細な説明】 本発明は、合成繊維の紡糸方法に関するものである。[Detailed description of the invention] The present invention relates to a method for spinning synthetic fibers.

従来、溶融紡糸された合成繊維への油剤付与は冷却後直
ちに行なわれるが、糸ゆCなどを防止するすこめに例え
ば特開昭57−95306号公報に記載された技術が知
られている。前記技術は、油剤付与ロールの下流側に糸
条走行方向と直交する方向に伸びた電極に2乃至15K
Vの電圧を印加させ、該電極に前記合成繊維を開繊する
ものである。
Conventionally, the application of oil to melt-spun synthetic fibers is carried out immediately after cooling, but a technique described in Japanese Patent Application Laid-Open No. 57-95306, for example, is known for adding a lubricant to prevent thread C and the like. In the above technology, a voltage of 2 to 15 K is applied to an electrode extending in a direction perpendicular to the yarn running direction on the downstream side of the oil application roll.
A voltage of V is applied to open the synthetic fibers to the electrode.

しかしながら、前記従来技術は、電極として銅、鉄、真
ちゅうなどからなる導電性金属からなる棒状体を用い、
前記電極には電源から積極的に帯電させるものであり、
特に高電圧であるが故に作業員が糸かけ時、糸切り替え
時、操業中の機械清掃時などにおいて触れることがあり
、ショックを受け、そのはずみに回動するローラへの接
触などを生じ大惨事の原因となることがあった。また、
銅、鉄、真ちゅうなどの金属からなる電極の近傍を合成
繊維が通過する以t+iJに合成繊維にオイリング付与
を施すとともに溶融紡糸されたのちオイリング付与まで
の間合成繊維は冷却されるが、この冷却時における糸通
は一定でなく、前記電極によって合成繊維は開繊さイす
るもののオイリングローラ上での合成Namの・6単糸
の走行路は一定とならなく、開繊作用lζよってオイリ
ングローラと前記単糸とが離脱することがあり、糸切れ
の原因となるなど品質上の問題を1了シていた。さらに
まtこ、前記金属からなる電極と合成繊維とが接触する
ことによって前記電極は合成繊維が著しく接触する部分
だけ摩耗し、表面に凹凸が生じる。該凹凸における四部
は数ミクロンの幅であったり11こ及ぶこともあり、深
さは数2藺となり特に銅、真ちゅうの場合、数分間、鉄
の場合でも8時間も接触すると1期に達してしまい、凸
部の縁と走行糸条との接触による単糸切れが著しくなり
、電極の交換を頻繁tこ行なわざるを得なくなるととも
に、これらの合成繊維を巻き取った糸巻ボビンの品質品
位は極めて悪いものがあった。
However, the prior art uses a rod-shaped body made of a conductive metal such as copper, iron, or brass as an electrode,
The electrode is positively charged from a power source,
In particular, because the voltage is high, workers may come into contact with it when threading, switching threads, or cleaning the machine during operation, resulting in shock and contact with the rotating rollers, resulting in a catastrophe. It could be the cause of. Also,
After the synthetic fiber passes near an electrode made of metal such as copper, iron, or brass, the synthetic fiber is given oiling at t+iJ, and after being melt-spun, the synthetic fiber is cooled until the oiling is given. The threading is not constant at the time, and although the synthetic fiber is opened by the electrode, the running path of the synthetic Nam 6 single yarn on the oiling roller is not constant, and due to the opening action The single yarn may separate from the yarn, causing quality problems such as yarn breakage. Furthermore, due to the contact between the metal electrode and the synthetic fibers, the electrodes are worn at the portions where the synthetic fibers come into significant contact, resulting in unevenness on the surface. The four parts of the unevenness may be several microns wide or even as wide as 11 microns, and the depth may be several micrometers, reaching stage 1 after contact for several minutes with copper and brass, and for 8 hours even with iron. In addition, single yarn breakage due to contact between the edge of the convex portion and the running yarn becomes significant, and electrodes must be replaced frequently, and the quality of the bobbin wound with these synthetic fibers is extremely poor. There was something bad.

したがって、前記従来技術は、電極と合成繊維とを非接
触とした場合単糸同志の反才灸によって一部の単糸がオ
イリングローラに接触しなくなることがあり、゛電極と
合成繊維とが接触する場合は′It極の4耗による単糸
切れ、電極の監視作業才jよび電極の交換作業が増大す
るとともに得られる糸巻きボビンの品質品位を損なうと
いう欠点を有していた。
Therefore, in the prior art, when the electrode and the synthetic fiber are not in contact with each other, some of the single threads may not come into contact with the oiling roller due to anti-moxibustion between the single threads, In this case, there are disadvantages such as single thread breakage due to wear of the electrode, increased electrode monitoring work and electrode replacement work, and a loss of quality of the obtained thread-wound bobbin.

さらに大きな欠点として得られた糸条をボビンに巻取っ
た際、ねずみ色の横縞が多発し、品質・品位を著しく低
下させ製品の収率を減少し苦慮していtこ。
Another major drawback is that when the obtained yarn is wound onto a bobbin, many gray horizontal stripes occur, which significantly reduces the quality and quality and reduces the yield of the product.

本発明の目的は、前記の従来技術の欠点を解消し、得ら
れる糸巻ボビンの品質・品位を向上するとともに合成繊
維の紡糸工程における操業を安定して行なう方法を提供
することにある。
An object of the present invention is to provide a method that eliminates the drawbacks of the prior art described above, improves the quality and quality of the obtained thread-wound bobbin, and stably operates the synthetic fiber spinning process.

本発明の目的は、紡糸口金から紡出されtコ糸条を冷却
固化しtコのち油剤を付与するに際し、前記糸条の冷却
固化域と油剤付与域との間であって前記油剤付与域から
250 rrmの範囲内に走行する光条速度に対して2
Xi O’乃至45×10〜“倍の表面速度で回動し、
前記糸条と直交し、AiJ記糸条をはさんで油剤付与域
に対向して設けられtコ炭素含有酸化チタンイく−に0
5〜2゜5締接触走行させることによって達成される。
It is an object of the present invention to provide a space between a cooling solidification area of the yarn and an oil application area, when the yarn spun from a spinneret is cooled and solidified, and then an oil agent is applied thereto. 2 for a ray speed running within the range of 250 rrm from
Xi O'~45×10~"Rotates at twice the surface speed,
A carbon-containing titanium oxide film is provided perpendicularly to the yarn and facing the oil application area across the AiJ yarn.
This is achieved by running in contact at a 5 to 2 degree angle.

本発明法を図面を用いて詳述する。The method of the present invention will be explained in detail using the drawings.

第1図は本発明に係る合成繊維紡糸装置の概略正面図で
ある。第2図は第1図のa′細部分拡大正面図であり、
第3図は第2図のl+[−Ill’矢視部分の側面図で
ある。
FIG. 1 is a schematic front view of a synthetic fiber spinning apparatus according to the present invention. Figure 2 is an enlarged front view of detail a' in Figure 1;
FIG. 3 is a side view of the l+[-Ill' arrow section in FIG. 2.

紡出部1の紡糸口金1′から紡出された糸条Yは冷却固
化域1を通って冷却され、油剤付与域■において油剤付
与され、巻取機2によって巻取られる。糸条Yは冷却固
化域Iと油剤付与域■との間であって、油剤付与域1に
入る直前油剤付与域11、更に詳しくは糸条Yが油剤付
与手段と接触する位置と酸化チタンパー5に接触する位
置との開館−りは25ow1の範囲内であって、油剤付
与手段例えば給油ローラ4とは接触し・よいようにする
必要がある。距離りが250藺を越えると糸条Yと給油
ローラ4との接触状態が不安定となり、実質的に酸化チ
タンパー6を設けることの効果がなくなる。また、酸化
チタン°バー6は回動するものとする。この回動速度は
、糸条Yの走行速度に対し、2×101乃至45X10
’倍の範囲とするのが望ましい。すなわら糸条速度が1
0ΩOm7m1nの場合、酸化チタンパー5の表面速度
が0.02 m/min乃至4.50m/m″−nの範
囲内であって糸条Yとの接触部分が糸条Yの走行方向と
同じ方向になるよう回動させる。酸化チタンパー5の回
転速度が糸条Yの走行速度に対し2x+D”より遅いか
停止していると糸条Yが急激に広がったり酸化チタンパ
ー5上を離脱し、その部分がオイリングローラ4から離
れることになり糸条に給油が行えない部分が生じる。ま
た糸条Yとの摩擦によって酸化チタンパー3に傷がつき
易く糸条Yを形成する単糸の切断を生じやすくなり、糸
条Yの走行速度に対し45x10 ’より速すぎると酸
化チタンパー3と糸条Yとの接触が円滑に行えなくなる
ことがある。
The yarn Y spun from the spinneret 1' of the spinning section 1 is cooled through the cooling and solidifying zone 1, is coated with an oil agent in the oil agent applying zone (2), and is wound up by the winder 2. The yarn Y is located between the cooling and solidifying zone I and the oil application area (2), and is just before entering the oil application area 1, the oil application area 11, more specifically, the position where the yarn Y contacts the oil application means and the titanium oxide par 5. It is necessary that the opening distance between the opening distance and the position where it contacts is within the range of 25ow1, and it is necessary to make contact with the lubricant applying means, for example, the lubricating roller 4. If the distance exceeds 250 mm, the contact state between the yarn Y and the oil supply roller 4 becomes unstable, and the effect of providing the titanium oxide par 6 is essentially lost. It is also assumed that the titanium oxide bar 6 is rotatable. This rotation speed is 2×101 to 45×10 with respect to the running speed of the yarn Y.
'It is preferable to double the range. In other words, the yarn speed is 1
In the case of 0ΩOm7m1n, the surface speed of the titanium oxide par 5 is within the range of 0.02 m/min to 4.50 m/m''-n, and the contact portion with the yarn Y is in the same direction as the running direction of the yarn Y. If the rotational speed of the titanium oxide spar 5 is slower than 2x+D'' with respect to the running speed of the thread Y, or if the rotation speed is stopped, the thread Y will spread rapidly or separate from the titanium oxide spar 5, causing that part to Since the yarn is separated from the oiling roller 4, there are parts where the yarn cannot be oiled. Furthermore, the titanium oxide perforator 3 is easily damaged by friction with the yarn Y, and single yarns forming the yarn Y are likely to be cut. Contact with the strip Y may not be made smoothly.

酸化チタンパー5は給油ローラ4の軸5をベルト6によ
って連結することによって容易に回動するが、必要によ
り、他の回動手段を用いてもよい。
The titanium oxide perforator 5 can be easily rotated by connecting the shaft 5 of the oil supply roller 4 with a belt 6, but other rotation means may be used if necessary.

酸化チタンバー5は第2図および第3図に示すごとく支
持部7.7′によって支持されており、支持部7.7′
の一部が後部パネル8に固定されている。支持部7.7
′は回動する酸化チタンパー3の被支持部3′と接する
部分に金属からなるり/グ9を設けるの方がよい。これ
は酸化チタンパー3の回動によって支持部7.7′が摩
耗し、酸化チタンパー5を糸条Yとの接触長召が変動す
るのを阻止するためであり、接触長βは05乃至25期
の範囲がよい。酸化チタンパー5の被支持部3′の摩耗
をも減少させることができ、糸条Yと酸化チタンパー5
の糸条Yに接触部分の〃を粍によってのみ酸化チタンパ
ー6を交換すればよい。n&化チタンパー5は前記のよ
うに回動させることにより少なくとも3ケ月の使用に耐
えることができ、糸条Yの品種に、よっては8ケ月乃至
1年間使用に而jえうる。酸化チタンパー5と糸条Yと
の接触長lが05Mよりも小さい時糸条Yを形成する各
単糸の広がりが一定でなく、重なり合ったまま給油ロー
ラ4に到達し、それを通過するので均一な油剤のイ」与
がなされないことがあり好ましくない。また2、5闘を
こえた場合、各単糸の広がりが拡大しすぎろこと、給油
ローラ4の表面との接触が円滑に行かなく単糸の一部が
給油ロー24に接することなく通過してしますことがあ
る。したがって接触長4は05乃至2.5 wRの範囲
とするのが好ましい。
The titanium oxide bar 5 is supported by a support portion 7.7' as shown in FIGS. 2 and 3.
A part of is fixed to the rear panel 8. Support part 7.7
It is preferable to provide a metal plate 9 at a portion of the rotating titanium oxide pad 3 that contacts the supported portion 3'. This is to prevent the support portions 7 and 7' from being worn out due to the rotation of the titanium oxide spar 3 and the contact length between the titanium oxide spar 5 and the yarn Y changing. A range of is good. The wear of the supported portion 3' of the titanium oxide par 5 can also be reduced, and the thread Y and the titanium oxide par 5
It is only necessary to replace the titanium oxide par 6 by removing the part that is in contact with the yarn Y. By rotating the N& titanium par 5 as described above, it can be used for at least 3 months, and depending on the type of yarn Y, it can be used for 8 months to 1 year. When the contact length l between the titanium oxide par 5 and the yarn Y is smaller than 05M, the spread of each single yarn forming the yarn Y is not constant, and it reaches the oil supply roller 4 while overlapping and passes through it, so it is uniform. This is undesirable because the proper amount of oil may not be applied. Moreover, if it exceeds 2 to 5 strokes, the spread of each single yarn may expand too much, and the contact with the surface of the oil supply roller 4 may not be smooth, and some of the single yarns may pass through without contacting the oil supply roller 24. There are times when I do this. Therefore, the contact length 4 is preferably in the range of 0.5 to 2.5 wR.

糸条Yを冷却固化したのち油剤付与ローラに到達する直
前の250Mの範囲内で2X10−’乃至45XiO−
“倍の表面速度で回動させ前記糸条と直交して設けられ
た酸化チタンパー6に05乃ffi 2.5 m接触走
行させる0とによって、前記糸条Yを形成する各単糸の
重なりをなくし、給油ローラ4との接触と均一に行わせ
ることができることから得られる糸条Yの品質品位を著
しく向上させることができ、特に油剤付与斑によって生
じやすい糸条巻取ボビンのテーパ一部分。の横縞をなく
し品位を向上させるとともに糸条Yの物理特性すなわち
強伸度収縮特性などを均一とすることができる。
After the yarn Y is cooled and solidified, it is 2X10-' to 45XiO- within a range of 250M just before reaching the oil application roller.
The overlap of each single yarn forming the yarn Y is determined by rotating the yarn at twice the surface speed and running it in contact with a titanium oxide perforator 6 installed perpendicularly to the yarn for 05 to 2.5 m. The quality of the obtained yarn Y can be significantly improved because the contact with the oil supply roller 4 can be made uniform, and the tapered part of the yarn winding bobbin, which is particularly prone to be caused by uneven application of oil, can be improved. Horizontal stripes can be eliminated to improve the quality, and the physical properties of the yarn Y, such as strength, elongation, and shrinkage characteristics, can be made uniform.

なお酸化チタンパー3は第1図に示すように走行する糸
条Yに対して給油ローラ4と同じ方向に設(jるのが望
ましい。これiよ糸かけ作業の時に狭いところに糸を通
すことな〈従来と同様の作業をすればよく、また糸条Y
との接触長lが変動しないよう両端部に支持部−7,7
′を設けることができるようにするためである。
As shown in Fig. 1, the titanium oxide parser 3 is preferably installed in the same direction as the oil supply roller 4 with respect to the running yarn Y. 〈You just have to do the same work as before, and also
Support parts -7, 7 are provided at both ends so that the contact length l does not change.
This is to make it possible to provide .

酸化チタンパー6は好ましくはまず酸化チタンtごけの
バーを成形し、次いでその酸化チタンだけのバーの外周
から炭素を浸透させ、次いで表面を滑らかに研削、研磨
することによって得ることができる。炭素の含有量は酸
化チタンパーの静止時あるいは回転時の静°醒気帯電瀘
が02乃至0.5KVの範囲となるようにすることによ
って本発明法に使用される酸化チタンパーとすることが
できる。
The titanium oxide par 6 can preferably be obtained by first molding a titanium oxide bar, then impregnating carbon from the outer periphery of the titanium oxide bar, and then grinding and polishing the surface to make it smooth. The carbon content of the titanium oxide par used in the method of the present invention can be adjusted so that the static air charge filter when the titanium oxide par is stationary or rotating is in the range of 02 to 0.5 KV.

実施例、比較例 比較例として、油剤ロールの下流側に糸条走行方向に直
交する方向に伸びた銅からなる電極に3KVの電圧を印
加し、該電極に走行糸条(ナイロン6繊維)を接触させ
て開繊させた。
Examples and Comparative Examples As a comparative example, a voltage of 3 KV was applied to an electrode made of copper extending in a direction perpendicular to the thread running direction on the downstream side of the oil agent roll, and a running thread (nylon 6 fiber) was applied to the electrode. The fibers were brought into contact and opened.

本発明に係るものとして紡糸糸条(ナイロン6繊維)を
冷却固化したのち、該糸条に油剤を付与する位置よりも
10〜前で糸条速度に対して+ox+o’の表面速度で
回動させiU記糸条に対して略直角の方向に設けtコ酸
化チタンバーに接触走行させ開繊させた。
According to the present invention, after the spun yarn (nylon 6 fiber) is cooled and solidified, the yarn is rotated at a surface speed of +ox+o' relative to the yarn speed at a point 10 to before the position where the oil is applied. The fibers were spread by running in contact with a titanium oxide bar provided in a direction substantially perpendicular to the iU yarn.

すなわち、糸条の開繊方法以外については同じ条件であ
り、これらの操業結果を表に示す。
That is, the conditions were the same except for the yarn opening method, and the results of these operations are shown in the table.

表における横縞とは糸条をボビンに巻いた時に生しるね
ずみ色の縞であり、糸条の長さ方向における不均一性を
示すものである。
The horizontal stripes in the table are gray-colored stripes that appear when the thread is wound around a bobbin, and indicate non-uniformity in the length direction of the thread.

N=+00 米 品質 品位が悪く製品とならない。N=+00 Rice quality is poor and cannot be used as a product.

未来 品位が愚く等級外品となる。In the future, the quality will be foolish and the product will be out of grade.

表に示すとねり本発明に係る糸条は品質・品位ともに良
好であり、糸巻ボビンの横縞は全く見られなく得られた
糸巻ボビンすべてが製品となるものであった。また、糸
切れについては本発明の方法に係るものは比較例のもの
に比して65乃至78%減少することができた。
As shown in the table, the yarn according to the present invention had good quality and quality, and no horizontal stripes were observed on the bobbins, and all the bobbins obtained could be used as products. Furthermore, yarn breakage was reduced by 65 to 78% in the method of the present invention compared to the comparative example.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明に係る合成繊維紡糸装置の概略正面図で
あり、第2図は第1図のI′部分の拡大正面図であり、
そして第5図は第2図の■−■′矢視図である。 1・・・・・紡糸部 6・・・・・炭素含有酸化チタン製パー4・・・・・給
油ローラ 5・・・・・軸 6・・・・ベルト 7・・・・・ホルダー 80・・ パネル Y・・・・・糸条 特許出願人   東  し  株  式  会  社第
1図 第2図 第3図
FIG. 1 is a schematic front view of a synthetic fiber spinning apparatus according to the present invention, and FIG. 2 is an enlarged front view of the I' portion in FIG.
FIG. 5 is a view taken along arrows ``--'' in FIG. 2. 1... Spinning section 6... Carbon-containing titanium oxide par 4... Oil supply roller 5... Shaft 6... Belt 7... Holder 80.・Panel Y... Yarn patent applicant Toshi Co., Ltd. Figure 1 Figure 2 Figure 3

Claims (1)

【特許請求の範囲】[Claims] 紡糸口金から紡出された糸条を冷却固化したのち該糸条
に油剤を付与するに際し、前記糸条の冷却固化域と油剤
付与域との間であって、前記油剤付与域から250mの
範囲内で、走行する糸条速度に対して2X10’乃至4
5x10’倍の表面速度で回動し、前記糸条の走行方向
と直交して設けられた炭素含有酸化チタンバーに、05
乃至2.5m、の糸条1]で接触走行させることを特徴
とする合成繊維の溶融紡糸方法。
When applying an oil to the yarn after cooling and solidifying the yarn spun from a spinneret, a range of 250 m from the oil applying area between the cooling and solidifying area of the yarn and the oil applying area. 2X10' to 4 for the running yarn speed
The carbon-containing titanium oxide bar rotates at a surface speed of 5x10' times and is installed perpendicular to the running direction of the yarn.
A method for melt-spinning synthetic fibers, characterized by carrying out contact running with a thread 1 of 2.5 m to 2.5 m.
JP2777083A 1983-02-23 1983-02-23 Melt spinning of synthetic yarn Pending JPS59157311A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2777083A JPS59157311A (en) 1983-02-23 1983-02-23 Melt spinning of synthetic yarn

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2777083A JPS59157311A (en) 1983-02-23 1983-02-23 Melt spinning of synthetic yarn

Publications (1)

Publication Number Publication Date
JPS59157311A true JPS59157311A (en) 1984-09-06

Family

ID=12230210

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2777083A Pending JPS59157311A (en) 1983-02-23 1983-02-23 Melt spinning of synthetic yarn

Country Status (1)

Country Link
JP (1) JPS59157311A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116043344A (en) * 2023-02-16 2023-05-02 宁波三邦超细纤维有限公司 Preparation process of nano zinc oxide heat-resistant composite superfine fiber

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4734262U (en) * 1971-05-10 1972-12-16
JPS5113530U (en) * 1974-07-19 1976-01-31
JPS5244648U (en) * 1975-09-25 1977-03-30

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4734262U (en) * 1971-05-10 1972-12-16
JPS5113530U (en) * 1974-07-19 1976-01-31
JPS5244648U (en) * 1975-09-25 1977-03-30

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116043344A (en) * 2023-02-16 2023-05-02 宁波三邦超细纤维有限公司 Preparation process of nano zinc oxide heat-resistant composite superfine fiber
CN116043344B (en) * 2023-02-16 2024-05-14 宁波三邦超细纤维有限公司 Preparation process of nano zinc oxide heat-resistant composite superfine fiber

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