JPS59157168A - Floor polish - Google Patents

Floor polish

Info

Publication number
JPS59157168A
JPS59157168A JP3316983A JP3316983A JPS59157168A JP S59157168 A JPS59157168 A JP S59157168A JP 3316983 A JP3316983 A JP 3316983A JP 3316983 A JP3316983 A JP 3316983A JP S59157168 A JPS59157168 A JP S59157168A
Authority
JP
Japan
Prior art keywords
floor
parts
weight
corundum
polishing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3316983A
Other languages
Japanese (ja)
Inventor
Takeo Sasaki
佐々木 丈夫
Kimio Yoshimi
吉見 仁男
Yasuo Fukatsu
深津 泰雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Mining and Cement Co Ltd
Mitsubishi Industries Cement Co Ltd
Original Assignee
Mitsubishi Mining and Cement Co Ltd
Mitsubishi Industries Cement Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Mining and Cement Co Ltd, Mitsubishi Industries Cement Co Ltd filed Critical Mitsubishi Mining and Cement Co Ltd
Priority to JP3316983A priority Critical patent/JPS59157168A/en
Publication of JPS59157168A publication Critical patent/JPS59157168A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To prepare a floor polishing agent for smoothing the surface of floor and removing stain therefrom, by adding a secondary agglomerate composed of tricalcium aluminate hexahydrate and corundum. together with a surface active agent and a suspending and thickening agent to water at specific ratios. CONSTITUTION:The objective floor polishing agent is prepared by adding (A) 5-40pts.wt. of a secondary agglomerate composed of tricalcium aluminate hydrate (3CaO.Al2O3.6H2O) and corundum, (B) 0.05-0.5pts.wt. of a surface active agent (e.g. polyoxyethylene nonylphenyl ether) and (C) 0.5-2pts.wt. of a suspending and thickening agent (e.g. methylellulose) to (D) 100pts.wt. of water. EFFECT:The floor is also imparted with luster.

Description

【発明の詳細な説明】 本発明は弾性化学床材、石質床材など床材の表面を平滑
にし汚れを除去し同時に適度の光沢を伺午する床磨き剤
に関す・る。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a floor polishing agent that smooths the surface of flooring materials such as elastic chemical flooring materials and stone flooring materials, removes dirt, and at the same time imparts a suitable gloss.

弾性化学床材、石質床材など床材の表面は5層程度のワ
ックスで被覆され゛ている。
The surface of flooring materials such as elastic chemical flooring materials and stone flooring materials is coated with about five layers of wax.

床磨き剤は、このような床材が使用中に表面が油状汚染
物や粘着、性汚物などにより汚染され床材表面の美観や
光沢を失った時に、汚染した床材表面の美観や光沢を再
現させるために用いられるも、のである。過去において
は種々の床磨き剤が使用されたが、現在は汚玲した表面
のワックス層を溶解させて清掃する各種溶剤が主として
用いられている。・ このような溶剤は散布の仕方や散布量の調整が難しく、
床磨き作業に際して専用の機材を必要とするほか清掃効
果が作業員の熟練度に著しく左右゛されるために、清掃
効果を常時一定に保つことがむつかしい。清掃効果を一
定に保つために床材表面の汚れを除去する目的で床材表
面を研磨または・琢磨するという考え方もあるが、現在
のところ、研磨材や琢磨材を利用した床磨き剤は知られ
ていない。
Floor polishing agents are used to restore the beauty and luster of the contaminated flooring surface when the surface of such flooring materials becomes contaminated with oily contaminants, adhesives, and sexual impurities during use and loses its beauty and luster. It is also used for reproducing. In the past, various floor polishes were used, but currently various solvents are mainly used to dissolve and clean the dirty wax layer on the surface. - It is difficult to adjust the method and amount of spraying for such solvents;
Floor polishing requires specialized equipment and the cleaning effectiveness is significantly dependent on the skill level of the worker, making it difficult to maintain a constant cleaning effectiveness at all times. There is a concept of polishing or polishing the surface of the flooring material in order to remove dirt from the surface of the flooring material in order to maintain a constant cleaning effect, but at present, there are no known floor polishing agents that use abrasives or polishing materials. It has not been done.

研磨材や琢磨材が床磨き剤として使用されない理由は次
の・ように考えられる。
The reasons why abrasives and polishing materials are not used as floor polishing agents are thought to be as follows.

すなわ゛ち、従来研磨材としそ使用されているセリウム
、アルミナ、ジルコニア、粘土鉱物などは磨砕・粉砕な
どにより製造されるために数gmからloOgmにおよ
ぶ広範囲の粒度分布を持ち、なかには鋭角の鋭い角度を
有する粒子も含まれているので、このような研磨材を主
成分とした床磨き剤を使用すると清掃後の床表面に多数
のえぐられたような傷跡が残り、著しく美観を損ねるか
らである。またこのような欠点を除くために、h記の研
磨材を数ルm以下まで微粒化するすることは極めてft
11コストとなり実用的でない。
In other words, cerium, alumina, zirconia, clay minerals, etc., which are conventionally used as abrasives, have a wide range of particle size distribution ranging from several gm to 100 gm because they are manufactured by grinding and crushing, and some have sharp angles. Since floor polishers containing particles with sharp angles are used as a main ingredient, the use of floor polishers based on such abrasives will leave many gouged-like scars on the floor surface after cleaning, significantly impairing its aesthetic appearance. It is from. In addition, in order to eliminate such drawbacks, it is extremely difficult to atomize the abrasive material described in h to a particle size of several micrometers or less.
11 and is not practical.

木発明名らは、ヒ述′のようなワックスを積層した床材
の表面を傷つけないように琢磨し、容易に汚れを除去す
るとともに美麗な表面や光沢を回復させる清掃効果のす
ぐれた床磨き剤を開発すべく研究を重ね、トライ力ルシ
ウムアルミネートヘキサハむトレード(3Ca O・A
ε203  ’6H2o)(以下C3A、 Hs ト略
記する)とコーyンダ□ムとからなる二次凝1体を用い
ることにより、床表面に傷をつけることなく表面ワ・ン
クス層の表面の極めて漬い層を琢磨することができ、安
価に、熟練を要せずに従来の欠点を克服することができ
ることを確かめ、本発明を完成する番こ至った。
The inventor of the invention is a floor polisher with an excellent cleaning effect that polishes the surface of flooring materials laminated with wax as described above without damaging them, easily removes dirt, and restores the beautiful surface and gloss. After conducting repeated research to develop a new lucium aluminate hexahamtrade (3Ca O・A
By using a secondary aggregate consisting of ε203 '6H2o) (hereinafter abbreviated as C3A, Hs) and coyundum, the surface of the surface wax layer can be completely soaked without damaging the floor surface. After confirming that it is possible to polish a thick layer and overcome the drawbacks of the conventional method at a low cost and without requiring skill, the time has come to complete the present invention.

本発明の目的とするところは、C3AHeとコランダム
とから成る二次凝集体を用いることにより従来技術の欠
点を改良し、汚染された床表面を琢磨することにより適
度な光沢を有する清浄なjPバ′1面にすることの出来
る床磨き剤を提供することである。
It is an object of the present invention to improve the drawbacks of the prior art by using a secondary aggregate consisting of C3AHe and corundum, and to polish a contaminated floor surface to produce a clean jP floor surface with a moderate gloss. To provide a floor polishing agent that can be applied to one surface.

すなわち本発明は、水100重量部に対してC□AH6
とコランタムとから成る10#Lm以ドの一二次凝集体
5乃至40重礒部、界面活性剤0.05乃至0.5重嫉
部、および懸濁増粘剤0.5.乃至2.0重重部を添加
して構成したことを特徴とする床磨き剤である。
That is, in the present invention, C□AH6 is added to 100 parts by weight of water.
5 to 40 parts of a primary secondary aggregate of 10 #Lm or more consisting of collant and corantum, 0.05 to 0.5 parts of a surfactant, and 0.5 parts of a suspension thickener. This is a floor polishing agent characterized by adding 2.0 parts to 2.0 parts by weight.

本発明になる床磨き剤の構成成分であるC3AH6とコ
ランダムとから成る10gm以ドの一゛1次凝集体はO
,1〜1″O用mのれ度分布を有し、C3AH6やコラ
ンダムの一次粒子直径は0.1〜0、5 h m程度で
それぞれの一次粒子が顆粒状に集塊となって凝集し形状
は鋭角の角度を持たない粒子である。さらに詳しくは、
これらの物質が単純に配合されているのではなくC3A
HeがコランダL・を包むような形状で個々の一次粒子
が結合しLO,gm以下の二次粒子を形成している。こ
のような−次凝東体は床磨きの際、床表面に傷を付ける
ことなく床表面を極めで薄く琢磨して汚れを除去し、平
滑化させ、かつ適度な光沢を付与するのに効果的である
。この琢磨作用は2次凝集体から僅かに突出しているフ
ランダムとこれを包むC3AHeとの作用によるもの、
と考えられる。
The primary aggregate of 10 gm or more consisting of C3AH6 and corundum, which are the constituent components of the floor polishing agent of the present invention, is O
The primary particles of C3AH6 and corundum have a diameter of about 0.1 to 0.5 h, and each primary particle aggregates into granules. The shape is a particle with no acute angles.More details:
These substances are not simply combined, but C3A
The individual primary particles are combined in such a shape that He wraps around the colander L to form secondary particles of less than LO, gm. When polishing a floor, this type of sub-condensation body is effective in polishing the floor surface extremely thinly, removing dirt, smoothing it, and giving it an appropriate gloss without damaging the floor surface. It is true. This polishing effect is due to the action of the flundum slightly protruding from the secondary aggregate and the C3AHe surrounding it.
it is conceivable that.

この二次凝集体の奏する優れた効果は、C3AH6が二
ランダムを包んだ□状態になっており、転動する二次凝
集体から僅かに突出しているコラ・ンダムの琢磨作用に
よるものと考えられる。二次凝集体からイφかに突出し
ているコランダムが度耗し琢磨力が低下する頃にはこの
二次凝集体が表面から崩れ新しいフランダム′が露出し
、二次凝集体が完全に崩れ、去るまで琢磨作用を継続す
る。
The excellent effect produced by this secondary aggregate is thought to be due to the polishing action of the C3AH6, which is in a □ state in which C3AH6 is wrapped around two random particles, and which slightly protrudes from the rolling secondary aggregate. . When the corundum protruding from the secondary aggregate wears out and the polishing force decreases, the secondary aggregate collapses from the surface, exposing new corundum, and the secondary aggregate collapses completely. , will continue to work hard until you leave.

しかしこのような粒子であっても、C,A、H6とコラ
ンダムとから成る二組l¥体の粒子の大きさが10jL
m以上であれば床表面を琢磨する際に仕ヒげ表面にえぐ
り取られたような傷が付きモ滑面とならないので10ト
m以下のものを用いる8星がある。。
However, even with such particles, the particle size of the two pairs of l\ bodies consisting of C, A, H6 and corundum is 10jL.
If the thickness is more than 10 tm, there are 8 stars that use 10 tm or less because when polishing the floor surface, there will be scratches like gouges on the surface of the floor and the surface will not be smooth. .

C3AH6とコランダムとから成る一次凝集体は水10
0屯量部に対して5〜40屯¥部′を配合する。
The primary aggregate consisting of C3AH6 and corundum is water 10
Add 5 to 40 parts by weight per 0 parts by weight.

この□配合量が5爪州部未満でも床表面の汚れの除去は
回部ではあるが琢磨効果が充分あられれない。一方40
重量部を越えて配合しても琢磨性能向J二の効果がなく
、また、ポリラシャ−によって拭い去られずに作業後の
床表面に残存することがあるため好ましくない、 界面活性剤はC3AH6とコランダムとから成る二次凝
集体を水に分散させるために8黄なものであっで、例え
ばノニルフェニル系化合物が好適である。
If this amount is less than 5 nails, the polishing effect will not be sufficient even though it will remove stains from the floor surface. On the other hand, 40
If more than 1 part by weight is added, it will not have the effect of improving polishing performance and may remain on the floor surface after work without being wiped off by the polyurethane, so it is not preferable. In order to disperse secondary aggregates consisting of corundum in water, it is preferable to use a nonylphenyl compound, for example, a nonylphenyl compound.

界面活性剤は本発明の床磨き剤の木100重l五部に対
して0.05〜0.5重量部を配合する。 −0,05
重量部未満ではC3AHe とコランダムとから成る二
次凝集録を分散させる効果が小さく、0.5重寸部を越
えて添加しても分散性は向ヒしない。
The surfactant is blended in an amount of 0.05 to 0.5 parts by weight per 100 parts by weight and 5 parts by l of the floor polishing agent of the present invention. -0,05
If it is less than 0.5 parts by weight, the effect of dispersing the secondary agglomerates composed of C3AHe and corundum will be small, and if it is added in excess of 0.5 parts by weight, the dispersibility will not be improved.

さらに本発明ではC,AHeと二ランダムとから成る二
次凝集体を完全に懸濁させるため、および清掃作業に際
し床磨き剤に適度な粘性を付与するために、懸濁増粘剤
を使用する。この懸濁増粘剤としてはコロイダル9.シ
リカ、コロイダルクレー、メチルセルロース、セルロー
ス重合体などを用いる。その配合量1走水100重量部
に対して0.5重量部未満では懸濁増粘効果が得られず
、2.0重量部を越えて配合すると床磨き剤の粘度が高
くなり過ぎ使用に際して流動性が悪いので0.5乃至2
.0重量部とする。
Furthermore, in the present invention, a suspension thickener is used in order to completely suspend the secondary aggregates consisting of C, AHe and dirandom, and to impart appropriate viscosity to the floor polish during cleaning work. . Colloidal 9. Silica, colloidal clay, methylcellulose, cellulose polymer, etc. are used. If the blending amount is less than 0.5 parts by weight per 100 parts by weight of running water, no suspension thickening effect will be obtained, and if it is blended in excess of 2.0 parts by weight, the viscosity of the floor polishing agent will become too high, making it difficult to use. 0.5 to 2 due to poor liquidity
.. 0 parts by weight.

次に本発明になる床磨き剤について実施例を挙げて本発
明の効果を具体的に詳述するが、この実施例は本発明を
何ら限定するものではない。
Next, the effects of the present invention will be specifically explained in detail with reference to examples of the floor polishing agent of the present invention, but these examples are not intended to limit the present invention in any way.

実施例 次に示す配合により床磨き剤を調製した。各配合物はケ
ミスターラを用い1000r、p、m。
Example A floor polishing agent was prepared according to the following formulation. Each formulation was prepared using Chemistra at 1000 r, p, m.

で30分間攪拌し、た。Stir for 30 minutes.

水                 ・・・・・・1
00重量部c、AHe とコランダムから成る1107
z以下の二次凝集体   ・・・・・・・・・10重量
部ポリオキシエチレンノニルフェニルエーテル・・・・
・・・・・0.2電融部 メチルセルロース   ・・・・旧・; 1. o 重
量s上記実施例の床磨き剤を床材表面に散布し、従来か
ら使用しているポリラシャ−で清掃作業を行い使用効果
を光沢性試験および平滑性試験により判定した。
Water ・・・・・・1
00 parts by weight c, 1107 consisting of AHe and corundum
Secondary aggregates of z or less: 10 parts by weight Polyoxyethylene nonylphenyl ether...
...0.2 Electric melting part methyl cellulose ... Old...; 1. o Weight s The floor polishing agent of the above example was sprinkled on the surface of the flooring material, and the cleaning work was performed with a conventionally used Polylasha, and the effect of use was determined by a gloss test and a smoothness test.

(1)光沢性試験 50cm角のワックスを塗布した黒色塩化ビニル製床材
の表面に油性マジックインキで○印を付け、その」二か
ら本発明の床磨き剤を適量滴下しポリッシτ−で2分間
清掃し、清掃後の黒色塩化ビニル製床材を20°C1相
対湿度60%の恒温恒湿室中に24時間放置し、反射率
計(安田精機製作所製ModelYFT)を用いJIS
Z8741 r光沢度測定方法」に準拠し60度鏡面反
射の測定により評価した。
(1) Glossiness test Mark the surface of a 50 cm square piece of wax-coated black vinyl chloride flooring material with oil-based marker ink, then drop an appropriate amount of the floor polishing agent of the present invention on the surface and apply polish τ-2. After cleaning, the cleaned black vinyl chloride flooring was left in a constant temperature and humidity room at 20°C and 60% relative humidity for 24 hours.
Evaluation was made by measuring 60 degree specular reflection in accordance with Z8741 r Glossiness Measuring Method.

光沢性試験の結果、新規床材をワックス処理した場合と
同様な65〜80%程度の値を示し琢磨により得られる
床材表面の光沢は丸打であることがわかった。
As a result of the gloss test, it was found that the gloss of the surface of the flooring material obtained by polishing was about 65 to 80%, which is the same as when the new flooring material was wax-treated.

(2)平滑性試験 り記(1)の試験を終えたサンプル表面に種々の角度で
光線を当て目視により傷の有無、凹凸の有無および上記
゛(1)の試験で付けた○印の油性マジックインキが消
えているか否か等を総合的に評価し、平滑性を判定した
(2) Smoothness test record After the test in (1) has been completed, the surface of the sample is irradiated with light at various angles to visually check the presence or absence of scratches, unevenness, and the oiliness of the circles marked in the test in (1) above. Smoothness was determined by comprehensively evaluating whether the marker ink had disappeared or not.

平滑性試験の結果では、琢磨により得られた床材表面は
、種々の角度で光線を当てても油性マジックインキは完
全に消えており、線条とか「きらさずJのようなものは
何ひとつなく、凹凸も無いので完全に平滑であると判定
された。
The results of the smoothness test showed that the oil-based marker ink on the surface of the polished flooring material completely disappeared even when exposed to light from various angles, and there were no streaks or anything like that. It was determined that the surface was completely smooth because there were no irregularities.

以上のように本発明の床磨き剤は床材表面の汚れや老化
したワックスの一部を平滑に除去し、床材表面、にほど
良い光沢を付与するため極めて有意義なものである。
As described above, the floor polishing agent of the present invention is extremely useful because it smoothly removes dirt and a portion of aged wax on the surface of the flooring material and imparts a moderate gloss to the surface of the flooring material.

出願人  玉菱鉱業セメント株式会社Applicant Tamabishi Mining Cement Co., Ltd.

Claims (1)

【特許請求の範囲】[Claims] 1  水100重量部に2、トライ力ルシウムアルミネ
ートヘキ、サバイドレートと二ランダム、とから成る1
0p’m以下の二次凝集体5乃至40重量部、界面活性
剤0.05乃至0.5重量部、および懸濁増粘剤0.5
乃至2.0重量部を加えてなる床磨き剤。
1 Consisting of 100 parts by weight of water, 2, lucium aluminate hexane, surfiderate and 2 random.
5 to 40 parts by weight of secondary aggregates of 0 p'm or less, 0.05 to 0.5 parts by weight of surfactant, and 0.5 parts by weight of suspension thickener.
2.0 parts by weight of a floor polishing agent.
JP3316983A 1983-02-28 1983-02-28 Floor polish Pending JPS59157168A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3316983A JPS59157168A (en) 1983-02-28 1983-02-28 Floor polish

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3316983A JPS59157168A (en) 1983-02-28 1983-02-28 Floor polish

Publications (1)

Publication Number Publication Date
JPS59157168A true JPS59157168A (en) 1984-09-06

Family

ID=12379029

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3316983A Pending JPS59157168A (en) 1983-02-28 1983-02-28 Floor polish

Country Status (1)

Country Link
JP (1) JPS59157168A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5312859A (en) * 1992-02-19 1994-05-17 J. M. Huber Corporation Acid acceptor for polymers containing acid moieties

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5312859A (en) * 1992-02-19 1994-05-17 J. M. Huber Corporation Acid acceptor for polymers containing acid moieties

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