JPS59140038A - Formation of rim urethane molding - Google Patents

Formation of rim urethane molding

Info

Publication number
JPS59140038A
JPS59140038A JP58014041A JP1404183A JPS59140038A JP S59140038 A JPS59140038 A JP S59140038A JP 58014041 A JP58014041 A JP 58014041A JP 1404183 A JP1404183 A JP 1404183A JP S59140038 A JPS59140038 A JP S59140038A
Authority
JP
Japan
Prior art keywords
molding
urethane
mold
rim
expanded
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP58014041A
Other languages
Japanese (ja)
Other versions
JPH0410B2 (en
Inventor
Chihiro Suenaga
末永 千尋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mazda Motor Corp
Original Assignee
Mazda Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mazda Motor Corp filed Critical Mazda Motor Corp
Priority to JP58014041A priority Critical patent/JPS59140038A/en
Publication of JPS59140038A publication Critical patent/JPS59140038A/en
Publication of JPH0410B2 publication Critical patent/JPH0410B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/02Moulding by agglomerating
    • B29C67/04Sintering
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/02Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
    • B29C44/12Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
    • B29C44/1271Incorporating or moulding on preformed parts, e.g. inserts or reinforcements the preformed parts being partially covered
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2027/00Use of polyvinylhalogenides or derivatives thereof as moulding material
    • B29K2027/06PVC, i.e. polyvinylchloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2075/00Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/25Solid
    • B29K2105/251Particles, powder or granules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/30Vehicles, e.g. ships or aircraft, or body parts thereof
    • B29L2031/3044Bumpers

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

PURPOSE:To raise the adhesion in the interface of molding by a method in which the molding faces of upper and lower split type molding machine are heated, PVC powder is packed into the molding cavity, and while melting the PVC powder, urethane resin is injected and expanded to form urethane molding integrated with PVC molding. CONSTITUTION:The molding faces of an upper and lower split type molding device provided with an upper mold 14 and a lower mold 16 having a molding groove 20 in a part of its cavity 18 are heated to a temperature at which urethane resin is expanded. Polyvinyl chloride powder 26 is uniformly packed into the groove 20 of the molds. While softening and melting the vinyl chloride powder 26 at the temperature of the molds, RIM urethane monomer liquid is injected through a mixing head into the molds 10 and expanded in such a way as to integrally forming polyvinyl chloride molding layer 26 on the expanded RIM urethane molding 28. A RIM urethane bamper 30 having strongly joined connections can thus be obtained.

Description

【発明の詳細な説明】 本発明は、ウレタンの@泡成杉品の表面に塩化ビニール
製のモールを一体成形する方法に1ス1する・近年、ウ
レタン製のパンパ、7エイシヤ、7エンダ等が増えてい
るが、これらのウレタン製品の上にモール処、・里を行
なうに当って、従東、別:)1“1に成形したモール・
;オをファスナーあるいは接イえ剤で+41的に組付け
ることが知られている。しかし、この方法ではモールの
成形1.阻f」工程が必°〃となって工数が多くなると
いう間両とともに、モールとウレタン製品との間の接合
部が面突時にはかnやずいζtの問題もある。また、第
7段の成形後、要を少し開いて第Ω段の射出を行なうと
いう方法でインモールドでモール部分と本1本幌品部分
とを積層成形することが知られている。この方法は、成
形工程が榎:1であるとともに、接着力が弱いという問
題がある。さらに、モール部分と本体−品部分とを一体
で成形し、モール部分だけを植装しないで塗り残すとい
うモール処24方法か考えられるが、この方法ではモー
ル、16分′の耐朕1生が悪く、特に成形品がバンパー
である場合には問題がある。
Detailed Description of the Invention The present invention is an improvement on the method of integrally molding a molding made of vinyl chloride on the surface of a urethane foamed cedar product. However, when molding molds on top of these urethane products, it is important to
It is known to assemble the parts using a zipper or adhesive. However, in this method, molding 1. In addition to the fact that the "blocking process" becomes necessary and increases the number of man-hours, there is also the problem that when the joint between the molding and the urethane product collides with each other, it is difficult to make the joint between the molding and the urethane product. Furthermore, it is known that after the seventh stage molding, the molding part and the one-piece hood part are laminated and molded by in-mold, by opening the main part slightly and performing the Ωth stage injection. This method has problems in that the molding step is 1:1 and the adhesive strength is weak. Furthermore, it is conceivable that the molding part and the main part and the product part are integrally molded, and only the molding part is left unpainted, but in this method, the molding has a durability of 16 minutes. This is particularly problematic when the molded product is a bumper.

また、一体成形後、モール部分と本体製品部分とを塗装
色を変えて塗り分けるという方法も考えられる。しかし
、この方法では塗装工程が複雑になり塗装費用が高くな
るという問題がある。
Another possible method is to paint the molding part and the main product part in different colors after integral molding. However, this method has the problem of complicating the painting process and increasing the painting cost.

本発明の目的は、ウレタン製品にモール処理を行なうに
当って、本体製品部分とモール部分とを一体成形するこ
とにより工坂、加工費を低減できるとともに、出来た一
娼品のモール部分と本体製品部分との接合を強固にする
ことができるウレタン1度形品におけるモールの成形方
法を与えることでめる。
The purpose of the present invention is to reduce the processing cost by integrally molding the main product part and the molding part when molding a urethane product, and to It is possible to provide a method for molding a molding in a urethane one-time product that can strengthen the bond with the product part.

本発明の構成は、上型と下型とf:υiえ下型のキャビ
ティの一部にモール成形用の溝を有する上下習1]型成
形装置の成形面をウレタンの発泡成形温度まで加熱し、
前記モール成形用溝内に塩化ビニール粉末を装填し、前
記塩化ビニール粉末を型温で軟化溶・触させながらウレ
タンを前記成形装置内に5射出し前記ウレタンを発泡成
形してウレタンの発泡成形品の上に塩化ビニール製のモ
ールを一体成形することを特徴とするRIMウレタン成
形物におけるモール成形方法である。ここで、RIMは
反応射出成形を意味する。
The structure of the present invention consists of an upper mold, a lower mold, and a molding molding groove formed in a part of the cavity of the lower mold. ,
Load vinyl chloride powder into the groove for molding, and inject urethane into the molding device while softening and melting the vinyl chloride powder at the mold temperature, and foam molding the urethane to produce a urethane foam molded product. This is a molding method for a RIM urethane molded product, which is characterized by integrally molding a vinyl chloride molding on top of the RIM urethane molding. Here, RIM means reaction injection molding.

本発明によれば、先に型内に装填されたモール部材であ
るポリ塩化ビニールが軟化溶融して型+Miに粘溶着し
ており、この状態で適当に調合された本体製品となるR
IMウレタンモノマーがミキシングヘッドを通して型内
に注入される。このRIMウレダンモ/マーはポリ塩化
ビニールと上溶着しつつ発泡固化する。この際、ぼり塩
化ビニールと81Mウレタンは界面で互いに絡み合い強
固な接合状態を形成する。すなわち、本発明によれば異
種材料を使用するにも拘わらず、容易にモール部分と本
体・4品部分とを同時に一体成形することができ、しか
も両者の接合AS分が慶れた接着強度を有する製品を鴎
ることができる。
According to the present invention, polyvinyl chloride, which is the molding member loaded into the mold, is softened and melted and adhesively adhered to the mold + Mi, and in this state, R becomes the properly blended main product.
IM urethane monomer is injected into the mold through a mixing head. This RIM uredanmo/mer is foamed and solidified while being welded to the polyvinyl chloride. At this time, the vinyl chloride and 81M urethane are intertwined with each other at the interface to form a strong bond. In other words, according to the present invention, although different materials are used, the molding part and the main body/four-part part can be easily integrally molded at the same time, and the bonding AS between the two parts can have a good adhesive strength. You can make products with it.

以下本発明の実施例につき、図面を参照しつつ説明する
Embodiments of the present invention will be described below with reference to the drawings.

請/図を参照すれば、モール付ウレタン・贋・マンパを
成形する上下割型成形型1′0の横断面が示されている
。fkJ形型10け中央部に下方向に突出するコア12
を有しコア型を構成する上型14と、キャビティ型を4
成する下型16とをす1dえている。
Referring to the figure, a cross section of a molding die 1'0 with upper and lower parts for molding urethane with molding, counterfeiting, and manpa is shown. Core 12 protruding downward from the center of 10 fkJ type molds
an upper mold 14 constituting a core mold, and a cavity mold 4
A lower mold 16 and a lower mold 16 are provided.

下型16は中央部に凹み、すなわちキャビティ18を有
し、さらにキャピテイ18の中央部にモール部分を形成
するための溝20を備えてイル。
The lower mold 16 has a recess or cavity 18 in the center thereof, and is further provided with a groove 20 for forming a molding portion in the center of the cavity 18.

また、−上型16の一方の上端部にはRIMウレタンモ
ノマーを注入するための注入ダート21か設けられてお
り、キャビティ18を挾んで反対側の上端部にはエア抜
き22が設けられている。また、+420の下方には型
を部分的に加熱する補助ヒータ24が設けられている。
- An injection dart 21 for injecting the RIM urethane monomer is provided at one upper end of the upper mold 16, and an air vent 22 is provided at the upper end on the opposite side with the cavity 18 in between. . Further, an auxiliary heater 24 is provided below +420 to partially heat the mold.

製品は上型と下型とが閉じ合わされたときコア12とキ
ャビティ18の1田に形成される空間の形状に成形され
る。
The product is molded into the shape of the space formed between the core 12 and the cavity 18 when the upper and lower molds are closed together.

製品を成形するに当たり成形型10を所定の型温まで加
熱し、その温度に保持する。本例の81Mウレタンを使
用する場合には70〜gOCが適当である。この所定温
度に保持した下型16の溝20にポリ塩化ビニール/母
つダー26を、第2図に示すように高さが2〜3困程度
になるように均一に散布する。この/4’クダーは粒陛
がa/〜5μ程度で、JISKA7.2.7による加熱
針入度が73〜gOC禰度が好ましい、散布されたポリ
塩化ビニール・母ウダー26は約60秒経過すると軟化
して該パウダー26の層は第3図に示されるように山盛
り状態から約200〜300μ厚さの平坦層状になる。
When molding a product, the mold 10 is heated to a predetermined mold temperature and maintained at that temperature. When using the 81M urethane of this example, 70 to gOC is appropriate. The polyvinyl chloride/mother 26 is uniformly sprinkled onto the groove 20 of the lower mold 16 maintained at a predetermined temperature so that the height is about 2 to 3 mm, as shown in FIG. This /4' kudder has a grain size of about a/~5μ, and the heating penetration according to JISKA7.2.7 is preferably 73 to gOC fineness.The sprayed polyvinyl chloride mother powder 26 has elapsed for about 60 seconds. Then, the layer of powder 26 is softened and becomes a flat layer with a thickness of about 200 to 300 μm from a heaped-up state as shown in FIG.

次いで、i+図に示すように上下型を閉じ合わせ所定の
条件に調合したRIMウレタンモレマー液を所定の成形
条件でミキシングヘッドを通して成形型10内に注入す
る。RI Mウレタンモノマーは約7〜2秒で型内に完
全に注入され、3〜lf秒後には反応して発泡し固化が
始まる。RIMウレタン28の固化はライジングからク
リーム化を1廷で起展し、約30・沙談には脱型可能の
状態となる。RIMウレタン28は上記の反応過程にお
いて、特に発fd時において元熱し約720〜/りOC
程度になりポリ塩化ビニル26は半融化して均一なシー
ト状となる。RIMウレタン28及びポリ塩化ビニール
26は調度が70〜gOC程度に下った時点で型′から
取出される。
Next, as shown in Figure i+, the upper and lower molds are closed and the RIM urethane molemer liquid prepared under predetermined conditions is injected into the mold 10 through the mixing head under predetermined molding conditions. The RIM urethane monomer is fully injected into the mold in about 7-2 seconds and begins to react, foam and solidify after 3-1f seconds. RIM urethane 28 solidifies from rising to creaming in one step, and becomes ready for demolding in about 30 minutes. RIM urethane 28 is originally heated during the above reaction process, especially at the time of fd, and has an OC of about 720~/l
At a certain point, the polyvinyl chloride 26 becomes half-melted and becomes a uniform sheet. The RIM urethane 28 and polyvinyl chloride 26 are removed from the mold' when the consistency is down to about 70-gOC.

取出しiRIMウレタン及び塩化ビニールは完全に固化
し、第S図に示すようなポリ塩化ビニールの%−/1.
層25を有するRIMウレタン製パンパ30が漫らnる
The removed iRIM urethane and vinyl chloride are completely solidified and the percentage of polyvinyl chloride as shown in FIG.
A RIM urethane pump 30 having a layer 25 is provided.

このようにして瘤られたRIMウレタン製バンパのモー
ル部分と本体製品、゛ホ分の接合部分の状j、裏を従来
のコノ・ル成杉のものと比絞すれば、−第6図に示され
るように本例の場合にはモール部分26(、+9り塩化
ビニール)と本体製品28(RIMウレタン〕の界面で
は両者のノ師が互いに絡み合って1ヌイ雀な1イq寺に
なっている。これは、約3〜s秒間のウレタンの発温時
に約3〜り■ψ/dの発7W IEと灼/20C〜/3
θCの発泡熱が発生するので両省が互いに浸透し易くな
るためである。一方、従来の2・・せ成形品の場合には
、第7図に示されるようにモール:’+r<分26/と
本体製品部分28′との界面は上述のような互いの層の
絡み合いの現象1dみられない、従って、従来では通常
界面の接着力を得るために、異、浦材料で2層成形を行
う場合には接着剤が用いらn、同梱材料の場合には界面
を融着させて接着力を得るようにしているがこれらの接
す力はいずれも十分ではない。
If we compare the shape of the joint between the molding part of the RIM urethane bumper and the main part of the RIM urethane bumper that has been lumped in this way, and the back of the joint part of ゛, we can see - Figure 6. As shown, in this example, at the interface between the molding part 26 (+9% polyvinyl chloride) and the main product 28 (RIM urethane), the two pieces intertwine with each other and become one piece. This means that when the urethane heats up for about 3 to s seconds, approximately 3 to ψ/d is generated.
This is because foaming heat of θC is generated, making it easier for both components to penetrate each other. On the other hand, in the case of the conventional 2-thread molded product, as shown in FIG. Therefore, in the past, in order to obtain adhesive strength at the interface, adhesives were usually used when performing two-layer molding with different materials, and when using bundled materials, the interface was Although attempts are made to obtain adhesive strength by fusing them, the contact strength is not sufficient.

ポリ塩化ビニールとヂリウレタンの2層成形品の従来の
成形方法によるもの及び本発明に従うものについてAS
TMDgヲ’7−4’ g試1・−法に従い界面の接着
強さの実工5Il+を行う罠。結果を下表に示す。
AS for two-layer molded products of polyvinyl chloride and diurethane made by conventional molding methods and those according to the present invention
TMDgwo'7-4' gTest 1 - A trap to perform practical work 5Il+ of the adhesive strength of the interface according to the method. The results are shown in the table below.

この結果からも本発明に従う、2層成形品の界面の接着
強さは従来のものに比し:ごれていることがわかるl
This result also shows that the adhesive strength at the interface of the two-layer molded product according to the present invention is dirty compared to the conventional one.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明の方法を実地するのに使用される成ノ
ど型の断面図、第一図は゛ポリ塩化ビニールの赦711
テ状悪を示すIII明図、第、? 1fflは、IP 
+7塩化ビニールの溶着状想を示す説明図、第ダIAは
RIMポリウレタン注入後の状態を示す説明間、’m 
j図は本発明に従うモール1−J゛ウレタン1煤バンパ
の斜iid ’IJ、第6図は本発明に従う成形品の断
面の拡大図、第7図は従来の2層成形品の断面の拡大図
である。 符号の説明 10・・・I丸形型112・・・・コアー、14・・・
・上型・16 、、、下型、18.、、キャビティ、2
0.、、、溝、26 、、、、モール部分、28.、、
、本体製品部分。 ・侍許出願人 東洋工業株式会社 第4図 14
FIG. 1 is a cross-sectional view of a finished mold used to practice the method of the present invention;
III Ming diagram showing the state of evil, No.? 1ffl is IP
+7 An explanatory diagram showing the welding state of vinyl chloride, Part IA is an explanatory diagram showing the state after RIM polyurethane injection, 'm
Figure j is a diagonal iid 'IJ of a molding 1-J urethane 1 soot bumper according to the present invention, Figure 6 is an enlarged cross-sectional view of a molded product according to the present invention, and Figure 7 is an enlarged cross-sectional view of a conventional two-layer molded product. It is a diagram. Explanation of symbols 10...I round shape 112...core, 14...
・Upper mold 16 , , Lower mold 18. ,,cavity,2
0. , , groove , 26 , , molding part , 28 . ,,
, the main product part.・Samurai license applicant Toyo Kogyo Co., Ltd. Figure 4 14

Claims (1)

【特許請求の範囲】[Claims] 上型と下型とを備え下型のキャビティの一部にモール成
形用の溝を有する上下副型成形装置の成形面をウレタン
の発温成形温度まで加熱、し、前記モール1戊形用面内
に塩化ビニール粉末を装填し、(ifJ記塩化ビニール
粉末を型ン′IIAで軟化溶i独させながらウレタンを
前記成形装置内に射出し前記ウレタンを発γd成形して
ウレタンの発泡成形品の上に塩化ビニール劇のモールを
一体成形することを特徴とするRIMウレタン成形物に
おけるモール成彩方法。
The molding surface of the upper and lower sub-mold molding device comprising an upper mold and a lower mold and having a molding molding groove in a part of the lower mold cavity is heated to the thermoforming temperature of urethane, and the molding surface of the molding 1 is Load vinyl chloride powder into the mold, inject urethane into the molding device while softening and dissolving the vinyl chloride powder in a mold IIA, and perform γd molding of the urethane to form a urethane foam molded product. A molding method for a RIM urethane molded product, which is characterized by integrally molding a vinyl chloride molding on top.
JP58014041A 1983-01-31 1983-01-31 Formation of rim urethane molding Granted JPS59140038A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58014041A JPS59140038A (en) 1983-01-31 1983-01-31 Formation of rim urethane molding

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58014041A JPS59140038A (en) 1983-01-31 1983-01-31 Formation of rim urethane molding

Publications (2)

Publication Number Publication Date
JPS59140038A true JPS59140038A (en) 1984-08-11
JPH0410B2 JPH0410B2 (en) 1992-01-06

Family

ID=11850024

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58014041A Granted JPS59140038A (en) 1983-01-31 1983-01-31 Formation of rim urethane molding

Country Status (1)

Country Link
JP (1) JPS59140038A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013531116A (en) * 2010-07-13 2013-08-01 ディアブ インターナショナル アクチボラゲット Process for the production of foamed plastic materials, in particular polymer foams based on PVC, and blends of polymer blends for achieving the process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013531116A (en) * 2010-07-13 2013-08-01 ディアブ インターナショナル アクチボラゲット Process for the production of foamed plastic materials, in particular polymer foams based on PVC, and blends of polymer blends for achieving the process

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