JPS5913603A - Composition of chlorine and/or chlorine dioxide generating agent - Google Patents

Composition of chlorine and/or chlorine dioxide generating agent

Info

Publication number
JPS5913603A
JPS5913603A JP57120411A JP12041182A JPS5913603A JP S5913603 A JPS5913603 A JP S5913603A JP 57120411 A JP57120411 A JP 57120411A JP 12041182 A JP12041182 A JP 12041182A JP S5913603 A JPS5913603 A JP S5913603A
Authority
JP
Japan
Prior art keywords
composition
chlorine
polysaccharide
clo2
chlorine dioxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP57120411A
Other languages
Japanese (ja)
Other versions
JPS6121162B2 (en
Inventor
Hiroo Kumami
熊巳 博夫
Akita Okamoto
明大 岡本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nasa KK
Original Assignee
Nasa KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nasa KK filed Critical Nasa KK
Priority to JP57120411A priority Critical patent/JPS5913603A/en
Publication of JPS5913603A publication Critical patent/JPS5913603A/en
Publication of JPS6121162B2 publication Critical patent/JPS6121162B2/ja
Granted legal-status Critical Current

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  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PURPOSE:To obtain the titled composition having increased safety and sustaining the generation of Cl2 and/or ClO2 for a long term by mixing a thixotropic composition contg. polysaccharide with a Cl2 and/or ClO2 generating agent. CONSTITUTION:To a thixotropic composition contg. polysaccharide is added 0.05-0.5wt% amphoteric surfactant such as alkylbetaine, and a Cl2 and/or ClO2 generating agent is further added so that the concn. of available chlorine in the resulting composition becomes 0.5-10wt%, preferably about 1-7wt%. The resulting composition generates stably gaseous Cl2 and/or ClO2, it can generate a very small amount of gaseous Cl2 and/or ClO2 over a long term, and the superior stability is not affected by a sudden change in the temp. of the environment. The polysaccharide can be selected from various kinds of polysaccharides including homo- and heteropolysaccharides.

Description

【発明の詳細な説明】 本発明は、ポリサッカライドを含有するーチキントロピ
ック組成物中に、塩素及び/又は二酸化塩素発生剤を混
合させたことを特徴とする塩素及び/又は二酸化塩素発
生剤組成物に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention provides a chlorine and/or chlorine dioxide generating composition characterized in that a chlorine and/or chlorine dioxide generating agent is mixed into a chicken tropic composition containing a polysaccharide. It is about things.

塩素や二酸化塩素が強い酸化性を持つことは知られてお
り、消青剤、殺藻剤、殺菌剤、脱臭剤、漂白剤、防カビ
剤、防腐剤等として使用されている。しか(〜ながら、
このような塩素や二酸化塩素は不安定で取扱いにくいも
のであることから、それ単独で用いることは困ψ(fで
、安定性の高められた組成物の形にすることが行われて
いる。従来、このような安定性の高められた組成物とし
ては、例えば、炭酸ナトリウムの過酸化物で安定化され
た二酸化塩素水溶液(USP 3123521 )や、
安定化二酸化塩素水溶液又はアルカリ金属もしくはアル
カリ土類金属の亜塩素酸塩の水溶液を塩基性吸着剤に吸
着させたもの(特公昭48−32079号公報)、二酸
化塩素水溶液をゼラチンと共にゲル化させたも−の等が
知られている。しかしながら、従来の組成物はその安定
性においても未だ十分なものではなかった。
Chlorine and chlorine dioxide are known to have strong oxidizing properties, and are used as blue bleaching agents, algaecides, disinfectants, deodorizing agents, bleaching agents, antifungal agents, preservatives, etc. However,
Since such chlorine and chlorine dioxide are unstable and difficult to handle, it is difficult to use them alone, and efforts are being made to form compositions with increased stability. Conventionally, such compositions with increased stability include, for example, an aqueous solution of chlorine dioxide stabilized with peroxide of sodium carbonate (USP 3123521);
A stabilized chlorine dioxide aqueous solution or an aqueous solution of an alkali metal or alkaline earth metal chlorite adsorbed on a basic adsorbent (Japanese Patent Publication No. 1983-32079), a chlorine dioxide aqueous solution gelatinized with gelatin Mo-no et al. are known. However, the stability of conventional compositions has not yet been sufficient.

本発明は、従来の組成物とは異なり、安定性の高められ
かつ塩素及び二酸化塩素発生持続性のすぐれた組成物を
提供することを目的とする。
An object of the present invention is to provide a composition that has increased stability and excellent persistence in generating chlorine and chlorine dioxide, unlike conventional compositions.

本発明は、塩素及び/又は二酸化塩素発生のために、二
酸化塩素それ自体を用いるものではなく、二酸化塩素や
塩素を徐々に発生し得る塩素及び/又は二酸化塩素発生
剤を用いると共に、このものをポリサッカライドを含む
チギノトロピノク組成物中に添加混合した組成物を提供
するもので4・ンる。
In order to generate chlorine and/or chlorine dioxide, the present invention does not use chlorine dioxide itself, but uses a chlorine and/or chlorine dioxide generating agent that can gradually generate chlorine dioxide and chlorine. The present invention provides a composition in which polysaccharide is added and mixed into a polysaccharide-containing composition.

塩素及び/又は二酸化塩素発生剤としては、次亜塩素酸
や亜塩素酸等の塩素含有酸の塩、例えばアルカリ金属塩
やアルカリ土類金属塩が適用される。他方、ポリサッカ
ライドを含むチキソトロピック組成物は、特願昭48−
63494〜63499号等として公知であり、ポリサ
ンカライドを適当な分散媒中に分散させたものである。
As the chlorine and/or chlorine dioxide generating agent, salts of chlorine-containing acids such as hypochlorous acid and chlorous acid, such as alkali metal salts and alkaline earth metal salts, are used. On the other hand, thixotropic compositions containing polysaccharides are disclosed in Japanese Patent Application No. 1973-
These are known as Nos. 63494 to 63499, and are obtained by dispersing polysancalide in a suitable dispersion medium.

この場合、ポリサッカライドゝとしては、ホモポリサッ
カライ]:″、ヘテロボリザノカライドを含めて広範囲
のものが使用可能であり、例えば、ガラクトマノナノ、
グルクロノグルコマンナンめような植物粘出物をはじめ
とする天然物から誘導されるポリサッカライFや、ロイ
コノストック細菌の生産物、ザントモナス族細菌の生産
物の如き微生物醗酵によって得られるポリサッカライド
等が挙げられる。これらのホモ又はへテロのポリサッカ
ライドは単独又は組合せて用いることができる。ポリサ
ッカライドの分散媒としては、各種のものがあるが、水
、糖アルコール及びHL 8価5以上で浸透力40秒以
内のアニオン又はノニオン基の界面活性剤からなる水溶
液が好ましく適用される。糖アルコールとしてハ、グリ
セリンの他、ソルビトール、マンニトール、クルコース
、フラクトース、ショ糖、ラヒノール等がある。
In this case, a wide range of polysaccharides can be used, including homopolysaccharides and heterobolyzanocalides, such as galactomanano,
Polysaccharide F derived from natural products such as plant exudates such as glucuronoglucomannan, polysaccharides obtained by microbial fermentation such as products of Leuconostoc bacteria, and products of Xanthomonas bacteria, etc. Can be mentioned. These homo or hetero polysaccharides can be used alone or in combination. There are various types of dispersion medium for polysaccharide, but an aqueous solution consisting of water, a sugar alcohol, and an anionic or nonionic surfactant with an HL 8 value of 5 or more and a penetrating power of within 40 seconds is preferably used. In addition to glycerin, sugar alcohols include sorbitol, mannitol, glucose, fructose, sucrose, and lahinol.

本発明の組成物は、ポリサッカライドを含むチキソトロ
ピック組成物に対し、塩素及び/又は二酸化塩素発生剤
を添加混合させたもので、この塩素及び/又は二酸化塩
素発生剤の添加量は特に制約されないが、一般的には、
全組成物中、有効塩素濃度として0.5〜lO重量係、
好ましくは1〜7重量係程度である。
The composition of the present invention is a thixotropic composition containing a polysaccharide mixed with chlorine and/or a chlorine dioxide generator, and the amount of the chlorine and/or chlorine dioxide generator added is not particularly limited. However, in general,
In the whole composition, the effective chlorine concentration is 0.5 to 1O by weight,
Preferably it is about 1 to 7 weight coefficients.

本発明の組成物に対しては、両性界面活性剤の添加が好
ましく、このようなものとしては、例えば、アルキルベ
タイノ類、アルキルノエチレ/トリアミノ酢酸類等が挙
げられ、その使用量は、通常、0.05〜0.5重量係
の範囲である。この両性界面活性剤は、塩素及び/又は
二酸化塩素発生剤を組成物中に均一に分散させる他、防
カビ、消毒、殺菌効果を高める効果を有し、さらに組成
物からの塩素ガス、又は二酸化塩素ガスの発生量をコン
スタントに発生させるという作用効果を示す。
It is preferable to add an amphoteric surfactant to the composition of the present invention, examples of which include alkyl betainos, alkylnoethylene/triaminoacetic acids, etc., and the amount used is as follows: Usually, it is in the range of 0.05 to 0.5 weight factor. This amphoteric surfactant not only uniformly disperses chlorine and/or chlorine dioxide generating agent in the composition, but also has the effect of enhancing anti-fungal, disinfecting, and sterilizing effects, and also has the effect of increasing chlorine gas or chlorine dioxide generating agent from the composition. It has the effect of constantly generating chlorine gas.

本発明の組成物は、塩素及び/又は二酸化塩素発生剤を
ポリサッカライドを含むチキントロピック組成物に混合
させたものであることから、従来の塩素及び/又は二酸
化塩素発生組成物では見られなかった種々の利点を有す
る。即ち、本発明の組成物の場合、塩素及び/又は二酸
化塩素ガスを安定(コンスタント)に発生させると共に
、微量ガス量を長期間にわたり発生可能にし、さらに、
急激な環境温度や湿度変化が生じても、本発明組成物は
安定性にすぐれている。また、その物性は格別変化しな
い。さらに、本発明の組成物は、寒天やゼラチンでゲル
化したものに比較すると、次のような利点がある。即ち
、寒天やゼラチンでゲル化したものは塩素及び/二酸化
塩素発生組成物により、長期保存中に組成が劣下しやす
いがこの組成物の場合には劣下しにくく、ガスの発生量
は非常にコンスタントになる。
Since the composition of the present invention is a mixture of a chlorine and/or chlorine dioxide generating agent with a chicken tropic composition containing polysaccharide, the composition of the present invention is not found in conventional chlorine and/or chlorine dioxide generating compositions. It has various advantages. That is, in the case of the composition of the present invention, chlorine and/or chlorine dioxide gas can be generated stably (constantly), and a trace amount of gas can be generated over a long period of time, and further,
The composition of the present invention has excellent stability even when sudden changes in environmental temperature and humidity occur. Moreover, its physical properties do not change significantly. Furthermore, the composition of the present invention has the following advantages compared to those gelled with agar or gelatin. In other words, products gelled with agar or gelatin tend to deteriorate in composition during long-term storage due to the composition that generates chlorine and/or chlorine dioxide, but this composition does not deteriorate easily and the amount of gas generated is extremely low. become constant.

本発明の組成物は、その発生する塩素及び/又は二酸化
塩素の作用を利用し、消臭、殺菌、防カビ、殺藻などの
目的の他、生鮮食品などに対する鮮度保存の目的等に対
して応用され、一般的には環境浄化剤として利用される
。また本発明の組成物自体はチキントロピーを有するも
のであることから、その取扱いは容易であり、流動化さ
せることにより、容器や袋に対し容易に充填することが
できる。さらに、本発明の組成物は、含有する多糖類又
は親水コロイISの種類や量の選定により、ゲル化又は
固体化させることもできるし、脱水することにより粉末
化することもできるので、所望する形状で任意に適用す
ることができる。
The composition of the present invention utilizes the action of chlorine and/or chlorine dioxide generated, and can be used for purposes such as deodorization, sterilization, anti-mold, algaecide, etc., as well as for preserving the freshness of fresh foods. It is commonly used as an environmental purification agent. Furthermore, since the composition of the present invention itself has chicken tropism, it is easy to handle, and by fluidizing it, it can be easily filled into containers and bags. Furthermore, the composition of the present invention can be made into a gel or solid by selecting the type and amount of the polysaccharide or hydrophilic colloid IS contained, or can be made into a powder by dehydration. Can be applied in any shape.

次に本発明の組成物の実施例を示す。Next, examples of compositions of the present invention will be shown.

実施例1 下記組成物Aとして示すポリサンカライド含有チキソト
ロピック組成物90重量部に対し、亜塩素酸ソーダ6重
量部及びアルキルベタイア 0.09重量部を添加混合
した。なお、亜塩素酸ソーダは、25%の水溶液として
添加した。
Example 1 6 parts by weight of sodium chlorite and 0.09 parts by weight of alkyl betaia were added and mixed to 90 parts by weight of a polysancalide-containing thixotropic composition shown as Composition A below. Note that sodium chlorite was added as a 25% aqueous solution.

組成物A イナゴマメゴム質       16重址部グルクロノ
ゲルコマ/ナノ     16重量部ソルビト−ル(7
0%水溶*)       62   n戸デシルベ/
ゼノスルホン酸の アンモニウム塩             5  〃ポ
リオキ/エチレンオレイルエーテル     2  〃
ンB 糖脂肪酸モノココニー1.          
l   〃水                   
  120  〃実施例2 下記組成物Bとして示す、1? 1.1ザノ力ライド含
有チキソトロピツク組成物885重量部に対し、次亜塩
素酸カルシウム4重量部及びアルキルジエチレノトリア
ミノ酢酸0.1重量部を添加し、混合した。
Composition A Locust bean gum substance 16 parts glucuronogel coma/nano 16 parts by weight Sorbitol (7 parts by weight)
0% water soluble *) 62 ndo decylbe/
Ammonium salt of xenosulfonic acid 5 Polyoxygen/ethylene oleyl ether 2
B Sugar fatty acid monococony 1.
l〃Water
120 Example 2 1?, shown as composition B below. 1.1 To 885 parts by weight of the thixotropic composition containing zanohydride, 4 parts by weight of calcium hypochlorite and 0.1 part by weight of alkyldiethylenotriaminoacetic acid were added and mixed.

組成物B ザノトモナス系多糖類     16重量部ガラクトマ
ンナン       16 〃グリセリン      
   62 〃ノニルフェノール        5 
 nアルギルラウリル系アミン       111ト
リエタノールアミン中和アルキル      2 Mt
 部ベンゼンスルホン酸 水                     130
   Il実施例3 下記組成物Cとして示すポリサッカライド含有チキソト
ロピック組成物80重量部に対し、次亜塩素酸ソーダ7
重量部及びアルキルジエチルトリアミノ酢酸0.15重
量部を添加混合した。
Composition B Zanotomonas polysaccharide 16 parts by weight Galactomannan 16 Glycerin
62 〃Nonylphenol 5
n Argyl lauryl amine 111 Triethanolamine neutralized alkyl 2 Mt
Part benzenesulfonic acid water 130
Il Example 3 To 80 parts by weight of a polysaccharide-containing thixotropic composition shown as Composition C below, 7 parts by weight of sodium hypochlorite was added.
parts by weight and 0.15 parts by weight of alkyldiethyltriaminoacetic acid were added and mixed.

組成物C 多糖類(ローカストビーンガムと     I O重量
部ザントモナス系多糖類の1=1の混合体)親水性コロ
イビ         2 〃(物質各アルギン酸ソー
ダ) グリセリン         70 “ドデ/ルベノゼ
/スルホネート        1  〃水     
                200  〃実施例
4 実施例1で示した組成物A80重量部に対し、次亜塩素
酸ソーダ4重量部を添加混合した。
Composition C Polysaccharide (1=1 mixture of locust bean gum and xanthomonas polysaccharide in parts by weight of IO) Hydrophilic Coroibi 2 (Substances Sodium Alginate) Glycerin 70 Dode/Rubenose/Sulfonate 1 Water
200 Example 4 To 80 parts by weight of the composition A shown in Example 1, 4 parts by weight of sodium hypochlorite were added and mixed.

比較例1 実施例1で示した組成物A70重量部に対し、二酸化塩
素の25%水溶液10重量部を添加混合した。この場合
には、組成物Aがあきらかに二酸化塩素により酸化分解
され、組成的に劣化した。
Comparative Example 1 To 70 parts by weight of the composition A shown in Example 1, 10 parts by weight of a 25% aqueous solution of chlorine dioxide was added and mixed. In this case, Composition A was clearly oxidized and decomposed by chlorine dioxide, resulting in compositional deterioration.

実施例5 実施例3で示した本発明組成物を原液として用い、これ
を希釈し、45℃に加温したPOTATO(]LIJO
O8EAGA11.培地に加えてよく混和した後、平板
とした。この寒天平板上に各試験菌の接種菌液を白金耳
で2crn程度の画線塗床し、25°Cで培養を行った
。培養5週間後に生ずる菌集落の有無により、殺菌効果
を判定した。次表に菌集落の発生を阻市し得る亜塩素酸
ソーダの最小濃度を前記原液の希釈倍数により示す。
Example 5 Using the composition of the present invention shown in Example 3 as a stock solution, this was diluted and heated to 45°C to make POTATO(]LIJO.
O8EAGA11. After adding it to the culture medium and mixing well, it was plated. On this agar plate, the inoculum solution of each test bacterium was streaked with a platinum loop to a thickness of about 2 crn, and cultured at 25°C. The bactericidal effect was determined based on the presence or absence of bacterial colonies after 5 weeks of culture. The following table shows the minimum concentration of sodium chlorite that can inhibit the development of bacterial colonies, based on the dilution ratio of the above-mentioned stock solution.

表−1 ALI3TOANS            1024
0PENIO[、LUM OHI’LYSOGENUM ALTBRMAR,TA TENLIIS Asl)El(、GLLUS NIGER2560 C1,、AI”)0811O比TUM (’jA)L)LJONIIS          5
120FASARJUM 0LANI 実施例6 実施例1の組成物において、ポリサッカライドの含有量
を約10倍に増量することによりゲル化された組成物を
得た。また、とのゲル化物は、こまか<(0,5cm角
)切り、急速冷凍乾燥することにより粉末化した。
Table-1 ALI3TOANS 1024
0PENIO[,LUM OHI'LYSOGENUM ALTBRMAR,TA TENLIIS Asl)El(,GLLUS NIGER2560 C1,,AI")0811O ratio TUM ('jA)L)LJONIIS 5
120FASARJUM 0LANI Example 6 A gelled composition was obtained by increasing the polysaccharide content by about 10 times in the composition of Example 1. In addition, the gelled product was cut into small pieces (0.5 cm square) and powdered by rapid freeze-drying.

次に、前記ゲル化物120cc又は粉末501を、内容
積200を家庭内の冷蔵庫の脱臭に適用したところ、い
ずれも、脱臭開始30分後には悪臭は完全に消え、平均
3〜4力月間その効果は持続した。
Next, when 120 cc of the gel or powder 501 was applied to deodorize a domestic refrigerator with an internal volume of 200, the bad odor completely disappeared 30 minutes after the start of deodorization, and the effects lasted for an average of 3 to 4 months. persisted.

特許出願人  株式会社 ナサ 代理人 弁理士  池 浦 敏 明Patent applicant: Nasa Co., Ltd. Agent Patent Attorney Toshiaki Ikeura

Claims (1)

【特許請求の範囲】[Claims] (+)  、i?ポリサッカライド含有するチキントロ
ピック組成物中に、塩素及び/又は二酸化塩素発生剤を
混合させたことを特徴とする塩素及び!又は二酸化塩素
発生剤。
(+), i? Chlorine and! characterized by mixing chlorine and/or a chlorine dioxide generator into a chicken tropic composition containing polysaccharide! Or chlorine dioxide generator.
JP57120411A 1982-07-10 1982-07-10 Composition of chlorine and/or chlorine dioxide generating agent Granted JPS5913603A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57120411A JPS5913603A (en) 1982-07-10 1982-07-10 Composition of chlorine and/or chlorine dioxide generating agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57120411A JPS5913603A (en) 1982-07-10 1982-07-10 Composition of chlorine and/or chlorine dioxide generating agent

Publications (2)

Publication Number Publication Date
JPS5913603A true JPS5913603A (en) 1984-01-24
JPS6121162B2 JPS6121162B2 (en) 1986-05-26

Family

ID=14785552

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57120411A Granted JPS5913603A (en) 1982-07-10 1982-07-10 Composition of chlorine and/or chlorine dioxide generating agent

Country Status (1)

Country Link
JP (1) JPS5913603A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59223201A (en) * 1983-06-02 1984-12-15 Hakugen:Kk Gelled product of chlorine dioxide and its manufacture
JPS62405A (en) * 1985-06-25 1987-01-06 Fujio Yoshida Method for cleaning environment of horticultural greenhouse

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6411046U (en) * 1987-07-09 1989-01-20
JPH0714087Y2 (en) * 1987-07-09 1995-04-05 トヨタ自動車株式会社 Adjustable Position Weber Webbing Anchor Device
JPS6415450U (en) * 1987-07-16 1989-01-26

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59223201A (en) * 1983-06-02 1984-12-15 Hakugen:Kk Gelled product of chlorine dioxide and its manufacture
JPH0121806B2 (en) * 1983-06-02 1989-04-24 Hakugen Co Ltd
JPS62405A (en) * 1985-06-25 1987-01-06 Fujio Yoshida Method for cleaning environment of horticultural greenhouse

Also Published As

Publication number Publication date
JPS6121162B2 (en) 1986-05-26

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