JPS59123721A - Production of cold rolled steel sheet having excellent processability - Google Patents

Production of cold rolled steel sheet having excellent processability

Info

Publication number
JPS59123721A
JPS59123721A JP23397782A JP23397782A JPS59123721A JP S59123721 A JPS59123721 A JP S59123721A JP 23397782 A JP23397782 A JP 23397782A JP 23397782 A JP23397782 A JP 23397782A JP S59123721 A JPS59123721 A JP S59123721A
Authority
JP
Japan
Prior art keywords
rolling
cold
rolled steel
steel
hot
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP23397782A
Other languages
Japanese (ja)
Inventor
Junichi Mano
純一 間野
Osamu Hashimoto
修 橋本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP23397782A priority Critical patent/JPS59123721A/en
Publication of JPS59123721A publication Critical patent/JPS59123721A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Continuous Casting (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Sheet Steel (AREA)

Abstract

PURPOSE:To obtain a cold-rolled steel sheet having excellent processability by casting continuously a molten steel contg. limited amt. of C and Nb in the steel compsn. and subjecting the cast steel directly to hot rolling under a limited average cooling rate and hot rolling conditions. CONSTITUTION:A molten steel contg. <=0.0030wt% C, <=0.4% Mn, 0.01-0.08% Sol Al, and <=0.023% Nb with an atom ratio in a range of 0.2<=Nb/C<=1.0 and consisting of the balance Fe and unavoidable impurities is continuously cast. The cast steel is continuously cooled, after solidification, at <=35 deg.C/min average cooling rate from 1,400 deg.C to the Ar3 transformation point. The cooled steel is subjected to rough rolling at hot at >=60% draft and after the finish rolling is completed at >= (the Ar3 transformation point-100 deg.C), the rolled steel is coiled at >=550 deg.C. The coiled steel is cold rolled and is then continuously annealed. A cold-rolled steel sheet having excellent ductility and processability is obtd. by the above-mentioned method.

Description

【発明の詳細な説明】 本発明は加工性にすぐれた冷延鋼板の製造方法に係り、
特に極低炭素Nb鋼の連続鋳造、直送圧延による製造方
法に関する。
[Detailed description of the invention] The present invention relates to a method for manufacturing a cold rolled steel sheet with excellent workability,
In particular, it relates to a manufacturing method of ultra-low carbon Nb steel by continuous casting and direct rolling.

一般に加工性にすぐれた冷延鋼板は延性を確保するため
に通常Coo、02%以下の低C鋼としているのでAr
、変態点が高い。そのため鋳造後のスラブを再加熱処理
すること々く熱間圧延を終了させるいわゆる直送圧延を
行う場合には熱間圧延終了時にAr、変態点以下の2相
域圧延と々りやすい。
In general, cold-rolled steel sheets with excellent workability are usually made of low C steel of Coo, 02% or less to ensure ductility, so Ar
, the metamorphosis point is high. Therefore, when so-called direct rolling is performed in which hot rolling is repeatedly completed by reheating the slab after casting, Ar is likely to occur at the end of hot rolling, resulting in rolling in a two-phase region below the transformation point.

一般に2相域圧延を行うと(100)面集合組織か発達
し、冷延焼鈍後にも(1,OOJ面集合組織が強く残り
〒1直を低下はせ加工性が劣化する。このため加工性を
重視する低炭素冷延鋼板においてはスラブの再加熱処理
が必須であり直送圧延処理は採用しがたいと考えらね、
ていた。
Generally, when two-phase region rolling is performed, a (100) plane texture develops, and even after cold rolling annealing, a strong (1, OOJ plane texture remains), which lowers the 〒1 straightness and deteriorates the laminar workability. For low-carbon cold-rolled steel sheets, where importance is placed on low-carbon cold-rolled steel sheets, slab reheating treatment is essential, and direct rolling treatment is difficult to adopt.
was.

本発明の目的は上記従来技術の問題点を解決し。The object of the present invention is to solve the above-mentioned problems of the prior art.

極低炭素Nb鋼の連続鋳造鋳片の直送圧延による加工性
のすぐれた冷延鋼板の製造方法を提供するにある。
It is an object of the present invention to provide a method for manufacturing a cold rolled steel plate with excellent workability by directly rolling a continuously cast slab of ultra-low carbon Nb steel.

本発明の要旨とするところは次のとおりである。The gist of the present invention is as follows.

すhわち5重量比にてC:0.0030%以下j’vi
n二04%以下、  5oiAt : 0.01〜0.
08%、  Nb:0.023%以下を含みかつ原子比
が0.2 < Nb/C<1.0の範囲内にあシ残部が
Feおよび不可避的不純物から成る溶鋼を連続鋳造する
工程と、前記連続鋳造鋳片を鋳片内溶鋼が完全凝固後連
続的に1400℃よすAr、変態点までの平均冷却速度
を35℃/min以下で冷却する工程と、前記冷却鋳片
を熱間のまま引続いて圧下率60%以上の粗圧延後(A
r3変態点−100℃)以上で仕上圧延を終了し550
℃以上で巻取る熱間圧延工程と、前記熱延鋼帯を冷間圧
延後焼鈍する工程と、ケ有(−で成ることを特徴とする
加工性にすぐれた冷延鋼板の製造方法である。
C: 0.0030% or less j'vi at a weight ratio of 5
n204% or less, 5oiAt: 0.01-0.
08%, Nb: 0.023% or less, and the atomic ratio is within the range of 0.2 < Nb/C < 1.0, and the remaining part consists of Fe and inevitable impurities; After the molten steel in the continuously cast slab is completely solidified, the continuously cast slab is continuously cooled to 1400°C in Ar at an average cooling rate of 35°C/min or less until the transformation point; After rough rolling with a reduction rate of 60% or more (A
Finish rolling is completed at the r3 transformation point -100°C) or higher, and the rolling is completed at 550
℃ or higher, a step of annealing the hot rolled steel strip after cold rolling, and a method for producing a cold rolled steel sheet with excellent workability, the method comprising: .

本発明における成分限定理由について説明する。The reason for limiting the components in the present invention will be explained.

C: C量の限定に本発明におけるもつとも重要な要件である
。従来からCの含有量が少ない程、鋼の伸び、rf[等
の加工性は向上することが知られている。しかし、C量
が0.0030%以下になるとAr、点以下の2相域圧
延となり(100)集合組織が発達して冷延焼鈍板の加
工性が劣化するので、通常はスラブの再加熱処理により
仕上圧延温度を確保して2相域圧延を避は加工性の劣化
7防いでいる。
C: Limiting the amount of C is the most important requirement in the present invention. It has been known that the lower the C content, the better the elongation and RF workability of steel. However, when the C content is less than 0.0030%, rolling occurs in the two-phase region below the Ar point and the (100) texture develops, deteriorating the workability of the cold-rolled annealed plate. Therefore, the slab is usually reheated. By ensuring the finish rolling temperature and avoiding rolling in the two-phase region, deterioration in workability7 is prevented.

本発明者らは次の基礎実験ケ行った。すなわち、Cの含
有量を変化させMn : 0.40%以下、  Si 
:02%以下、Nb/cの原子比が0.2 < Nb/
C< 1.0の連鋳製鋳片を鋳造後1400℃よりAr
、点までの平均冷却速度を35℃/min以下で冷却を
行い。
The present inventors conducted the following basic experiment. That is, by changing the C content, Mn: 0.40% or less, Si
:02% or less, Nb/c atomic ratio 0.2 < Nb/
After casting continuous cast slabs with C < 1.0, Ar
Cooling is performed at an average cooling rate of 35° C./min or less up to the point.

粗圧延圧下率78%、仕上圧延温度870℃、仕上厚2
.8 wn 、巻取温度660℃の条件で熱間圧延し、
次いで0.8 tanに冷間圧延した後780℃×40
 secの条件で連続焼鈍し08%の調質圧延を行い、
製造した冷延鋼板のr値を測定し、r値とC量の関係を
第1図に示した。第1図においてC量が0.0030%
以下においては7値は1.5を越えすぐれた加工性を示
しているのでC量の上限値0.0030%を本発明の必
要条件とした。
Rough rolling reduction rate 78%, finish rolling temperature 870°C, finish thickness 2
.. 8 wn, hot rolled at a coiling temperature of 660°C,
Then, after cold rolling to 0.8 tan, 780℃×40
Continuously annealed and temper rolled at 0.08% under conditions of sec,
The r value of the manufactured cold rolled steel sheet was measured, and the relationship between the r value and the amount of C is shown in FIG. In Figure 1, the amount of C is 0.0030%
In the following description, since the value 7 exceeds 1.5 and indicates excellent workability, the upper limit of the amount of C, 0.0030%, was set as a necessary condition for the present invention.

Mn: Mnは熱間圧延時における低融点のFeSの形成を防止
するために必要な元素であるが、0.4%を越える過剰
の添加の場合はr@が低下し加工用冷延鋼板として不適
となるので、 Mnの上限を04%に限定した。
Mn: Mn is an element necessary to prevent the formation of FeS with a low melting point during hot rolling, but if it is added in excess of 0.4%, r@ decreases and it cannot be used as a cold rolled steel sheet for processing. Since this would be inappropriate, the upper limit of Mn was limited to 0.4%.

5otAL : 5olAtは値中のNを固定する作用を有するが、0.
01%未満でlI′ltNの固定が困難となり、固溶N
の一部がNbにより消費され、 NbのC固着能力が低
下し基地中に固溶Cが残留する。この固溶Cの増加はr
@w低下芒せ加工性を著しく劣化プせるおそれがある。
5otAL: 5olAt has the effect of fixing N in the value, but 0.
If it is less than 0.01%, it becomes difficult to fix lI′ltN, and solid solution N
A part of the C is consumed by Nb, and the C fixation ability of Nb decreases, so that solid solution C remains in the base. This increase in solid solution C is r
@w Decrease There is a possibility that the machinability of awning may be significantly deteriorated.

−万、  5o7AtがO,OS%を越えると置換型固
溶原子となって基地の強度を高め延性を劣化はせる。こ
のため5otAtに0.01〜0.08%の範囲に限定
した。
-If 5o7At exceeds O,OS%, it becomes a substitutional solid solution atom, increasing the strength of the matrix and deteriorating its ductility. For this reason, the content was limited to 0.01% to 0.08% at 5otAt.

Nb : Nb1I−f本発明において、Cに次いで重要な化学成
分で、Nb(C,N)としてC量−を固着して加工性を
向上式せる働き7有するが、 Nbが0.023%を越
え ”b/C原子比が1.0%暑越えると基地の強度が
上がり延性が劣化する。一方Nb/c原子比が0.2未
満の時にはNb添加による加工性改善効果が見られなく
々る。これらの理由により、Nb量を0、023 %以
下、 カッ”b/C原子比’a: 0.2〜1.0の範
囲に限定した。
Nb: Nb1I-f In the present invention, it is the second most important chemical component after C, and has the function of fixing the amount of C as Nb(C,N) and improving workability7, but Nb accounts for 0.023%. ``When the b/C atomic ratio exceeds 1.0%, the strength of the base increases and the ductility deteriorates.On the other hand, when the Nb/C atomic ratio is less than 0.2, the workability improvement effect of Nb addition cannot be seen. For these reasons, the Nb content was limited to 0.023% or less, and the C/C atomic ratio was limited to a range of 0.2 to 1.0.

次に上記の限定成分を有する本発明鋼の製造条件につい
て説明する。
Next, the manufacturing conditions for the steel of the present invention having the above-mentioned limiting components will be explained.

まず、連続鋳造鋳片の冷却に関する実験について述べる
。C:0.0025%、  Si :tr、Mn :0
.2%、 5otAt: 0.025%、Nb/c原子
比:052の連続鋳造鋳片の完全凝固後の1400℃か
らAr、点までの平均冷却速度を種々変えて冷却し、粗
圧延圧下率60%以上および60%未満。
First, an experiment regarding cooling of continuously cast slabs will be described. C: 0.0025%, Si: tr, Mn: 0
.. Continuously cast slabs of 2%, 5otAt: 0.025%, Nb/c atomic ratio: 052 were cooled at various average cooling rates from 1400°C after complete solidification to Ar, and the rough rolling reduction rate was 60. % or more and less than 60%.

仕上1ni880 t:、仕上厚3. Otm、巻取m
K65゜℃で熱間圧延し、次いで0.8m厚に冷間圧延
した後、800℃×40秒の条件で連続焼鈍を行った。
Finishing 1ni880t:, Finishing thickness 3. Otm, winding m
After hot rolling at K65°C and then cold rolling to a thickness of 0.8 m, continuous annealing was performed at 800°C for 40 seconds.

また、参考のため、鋳造後一旦Ar、点以下に冷却後再
度Ac、点以上の温度の炉中で2時間以上加熱したいわ
ゆる再加熱材についても、冷却、加熱以外の成分、圧延
条件等は同一として冷延鋼板な製造した。これらの冷延
鋼板のr値を測定し、 1400   −℃〜Ar、点
間の平均冷却速度とr値との関係を第2図に示した。第
2図における冷却、粗圧延条件の表示I″i第1表に示
すとおりである。
For reference, we have also included the so-called reheated material, which is heated in a furnace for 2 hours or more at a temperature of Ar, then cooled to below the Ar temperature point, then reheated to the Ac temperature for more than 2 hours after casting, and the components other than cooling and heating, rolling conditions, etc. The same cold-rolled steel sheet was manufactured. The r value of these cold rolled steel sheets was measured, and the relationship between the average cooling rate between points and the r value from 1400 -°C to Ar is shown in Figure 2. The cooling and rough rolling conditions in FIG. 2 are as shown in Table I''i.

第  1  表 第2図から1400℃〜Ar、点間の平均冷却速度35
℃/min以下で粗圧延圧下率が60%以上の時はT値
が1,5を越え加工性のすぐれていることがわかる。冷
却速度が遅くても粗圧延圧下率が60%未満では所期の
加工性が得られ力い。この結果から、加工性の良好な鋼
を得ろため、1400℃からAr、点までの平均冷却速
度ン35℃/min以下とし、粗圧延圧下率を60%以
上に限定した。
From Table 1 and Figure 2, 1400℃~Ar, average cooling rate between points 35
℃/min or less and the rough rolling reduction is 60% or more, the T value exceeds 1.5, indicating that the workability is excellent. Even if the cooling rate is slow, it is difficult to obtain the desired workability when the rough rolling reduction is less than 60%. From this result, in order to obtain a steel with good workability, the average cooling rate from 1400° C. to the Ar point was set to 35° C./min or less, and the rough rolling reduction was limited to 60% or more.

次に仕上圧延の仕上温度を(Ar、変態点−100℃)
以上に限定したのは、この温度未満で仕上げると冷延鋼
板の延性と7値が著しく低下し加工性が劣化するので(
Ar、変態点−100℃)以上で仕上圧延を終了する如
く限定した。また熱延の巻取温度乞550℃以上にした
のは、550℃未満で巻取ると冷延後の連続焼鈍によっ
ても十分に軟化せず冷延鋼板の延性が著しく劣化して加
工に適さないので熱延の巻取温度を550℃以上に限定
した。
Next, the finishing temperature of finishing rolling (Ar, transformation point -100℃)
The reason for this limitation is that finishing below this temperature will significantly reduce the ductility and 7-value of the cold-rolled steel sheet, resulting in poor workability (
Finish rolling was limited to finish at temperatures higher than Ar (transformation point -100°C). In addition, the coiling temperature of the hot rolled steel sheet is set at 550℃ or higher.If the coiling temperature is lower than 550℃, the ductility of the cold rolled steel sheet will deteriorate significantly as it will not be sufficiently softened even by continuous annealing after cold rolling, making it unsuitable for processing. Therefore, the winding temperature of hot rolling was limited to 550°C or higher.

上記の如き条件で製造さねた本発明の熱延鋼帯の冷間圧
延および焼鈍は特に限定することなく通常の方法による
が、加工性のすぐれた冷延鋼板を得ることができる。
Cold rolling and annealing of the hot-rolled steel strip of the present invention produced under the above conditions are not particularly limited and may be carried out by conventional methods, but a cold-rolled steel sheet with excellent workability can be obtained.

実施例 第2表に化学成分を示した鋼ケ転炉で溶製し連続鋳造し
た鋳片を同じく第2表に記載の条件でそれぞれ冷却およ
び熱間圧延を行い板厚30簡の熱延鋼帯とし、更に酸洗
後0.8 mmまで冷間圧延し800℃×40SeCの
条件で連続焼鈍を行い、次第  3  表 いで圧下率08%の調質圧延を行った。なお、比較例の
第2表に示す化学成分および熱延条件において本発明の
限定条件を満足していない欄には○印を付けた。
Example: Steel slabs whose chemical compositions are shown in Table 2 are continuously cast in a converter and cooled and hot-rolled under the conditions listed in Table 2 to produce hot-rolled steel with a plate thickness of 30 sheets. After pickling, the strip was cold-rolled to a thickness of 0.8 mm, continuously annealed at 800° C. and 40 SeC, and then temper-rolled at a rolling reduction of 08%. Note that the columns in which the chemical components and hot rolling conditions shown in Table 2 of Comparative Examples do not satisfy the limiting conditions of the present invention are marked with a circle.

これらの冷延鋼板の機械的性質乞調査し、その結果を第
3表に示した。第3表において本発明の成分および製造
条件を満足する本発明例である供試鋼A−Fは伸び、7
値が高く加工性にすぐれるが、本発明の限定条件を満足
しない比較例である供試鋼G〜0は強度が高くV値は1
.5未満であって加工に適さないことがわかる。
The mechanical properties of these cold rolled steel sheets were investigated and the results are shown in Table 3. In Table 3, test steels A-F, which are examples of the present invention that satisfy the composition and manufacturing conditions of the present invention, have an elongation of 7.
Sample steel G~0, which is a comparative example that does not satisfy the limiting conditions of the present invention, has a high strength and a V value of 1, although it has a high value and excellent workability.
.. It can be seen that it is less than 5 and is not suitable for processing.

本発明は上記実施例からも明らかな如く、成分特にC1
へb量を限定し連続鋳造鋳片の平均冷却速度を35℃/
min以下に限定し、熱間圧延条件を限定する熱間直送
圧延により1加工性の良好な冷延鋼板を低コストで製造
することができる。
As is clear from the above examples, the present invention is applicable to components, particularly C1.
By limiting the amount of B, the average cooling rate of continuously cast slabs was reduced to 35℃/
Cold rolled steel sheets with good workability can be produced at low cost by hot direct rolling in which the hot rolling conditions are limited to less than 1 min.

【図面の簡単な説明】[Brief explanation of drawings]

第1図はC含有量と7値との関係を示す相関図、第2図
は鋳片の1400℃〜Ar3点間の平均冷却速度と7値
との関係を示す相関図である。
FIG. 1 is a correlation diagram showing the relationship between the C content and the 7-value, and FIG. 2 is a correlation diagram showing the relationship between the average cooling rate of the slab between 1400° C. and three Ar points and the 7-value.

Claims (1)

【特許請求の範囲】[Claims] (1)重量比にてC:0.(3030%以下、Mn:0
4%以下、 5oLAt: 0.01〜0.08%、N
b二0.023%以下を含みかつ原子比が0.2 < 
Nb/Cり1.0の範囲内にあり残部がFeおよび不可
避的不純物から成る溶鋼を連続鋳造する工程と、前記連
続鋳造鋳片を鋳片固溶鋼が完全凝固後連続的に1400
℃よV、r Ar3変態点までの平均冷却速lff35
℃/min以下で冷却する工程と、前記冷却鋳片を熱間
のまま引続いて圧下率60%以上の粗圧延後(Ar、変
態点−100℃)以上で仕上圧延を終了し550℃以上
で巻取る熱間圧延工程と、前記熱延鋼帯火冷間圧延後焼
鈍する工程と、を有して成ることを特徴とする加工性に
すぐれた冷延鋼板のM遣方法。
(1) C:0 in weight ratio. (3030% or less, Mn: 0
4% or less, 5oLAt: 0.01-0.08%, N
Contains 0.023% or less of b2 and has an atomic ratio of 0.2 <
Continuously casting molten steel with a Nb/C ratio of 1.0 and the remainder consisting of Fe and unavoidable impurities;
°C to V, r Average cooling rate to Ar3 transformation point lff35
℃/min or less, and the cooled slab is subsequently rough rolled at a reduction rate of 60% or more (Ar, transformation point -100℃) or higher, and finish rolling is completed at 550℃ or higher. 1. A method for rolling a cold-rolled steel sheet with excellent workability, the method comprising the steps of: hot-rolling the hot-rolled steel strip; and annealing the hot-rolled steel strip after cold-rolling.
JP23397782A 1982-12-29 1982-12-29 Production of cold rolled steel sheet having excellent processability Pending JPS59123721A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP23397782A JPS59123721A (en) 1982-12-29 1982-12-29 Production of cold rolled steel sheet having excellent processability

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23397782A JPS59123721A (en) 1982-12-29 1982-12-29 Production of cold rolled steel sheet having excellent processability

Publications (1)

Publication Number Publication Date
JPS59123721A true JPS59123721A (en) 1984-07-17

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP23397782A Pending JPS59123721A (en) 1982-12-29 1982-12-29 Production of cold rolled steel sheet having excellent processability

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Country Link
JP (1) JPS59123721A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6141722A (en) * 1984-08-06 1986-02-28 Kawasaki Steel Corp Manufacture of ultralow carbon cold rolled steel sheet favorable to phosphate treatment
JPS61110749A (en) * 1984-11-05 1986-05-29 Nippon Kokan Kk <Nkk> Soft hot rolled steel plate having superior workability
EP0870848A1 (en) * 1997-03-27 1998-10-14 RECHERCHE ET DEVELOPPEMENT DU GROUPE COCKERILL SAMBRE, en abrégé: RD-CS Niobium containing steel and process for making flat products from this steel

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6141722A (en) * 1984-08-06 1986-02-28 Kawasaki Steel Corp Manufacture of ultralow carbon cold rolled steel sheet favorable to phosphate treatment
JPH0210853B2 (en) * 1984-08-06 1990-03-09 Kawasaki Steel Co
JPS61110749A (en) * 1984-11-05 1986-05-29 Nippon Kokan Kk <Nkk> Soft hot rolled steel plate having superior workability
JPH0517285B2 (en) * 1984-11-05 1993-03-08 Nippon Kokan Kk
EP0870848A1 (en) * 1997-03-27 1998-10-14 RECHERCHE ET DEVELOPPEMENT DU GROUPE COCKERILL SAMBRE, en abrégé: RD-CS Niobium containing steel and process for making flat products from this steel
BE1011066A3 (en) * 1997-03-27 1999-04-06 Cockerill Rech & Dev Niobium steel and method for manufacturing flat products from it.

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