JPS59120635A - Production of packaging film - Google Patents
Production of packaging filmInfo
- Publication number
- JPS59120635A JPS59120635A JP22654882A JP22654882A JPS59120635A JP S59120635 A JPS59120635 A JP S59120635A JP 22654882 A JP22654882 A JP 22654882A JP 22654882 A JP22654882 A JP 22654882A JP S59120635 A JPS59120635 A JP S59120635A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- film
- treatment
- heat
- packaging film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Wrappers (AREA)
Abstract
Description
【発明の詳細な説明】
」＼介、明は包装用ノイルノ・の製造方法に関し、訂ｊ
−２＜は自已粘措４１１（”）ツブ性）、耐熱性および
カット慴のいＪ−ｉｌにもすぐれた包装用フィルムの製
造方法に関−Ｊ＝る６、
従来、家庭＋＋＋ 、：５務川に用いらノＬる、いわゆ
る′ノン−１／イ・１ノ、どしては、ポリ塩化ビニリデ
ン樹脂−や高圧法低密度ボＩＪ 、ｒ −ｆ−Ｌ／ン樹
脂ｋｒ製膜し−こなるフイルノ、なとが実用化さＪＬで
いる６、とＩｒら′ン、ノブフィルムとしては、自己枯
甑１′１の他に使用１■ｂのカット性９強度、透明性、
面１熱４シ１など神々の１′口ｉ）゛。[Detailed Description of the Invention] ``Suke, Akira has revised the method for manufacturing Noirno® for packaging.
-2 < refers to a method for producing a packaging film that is excellent in self-adhesiveness (411 (") stickiness), heat resistance, and easy cutting. The so-called 'non-1/I-1' used in Mugawa is polyvinylidene chloride resin, high-pressure method low-density IJ, r-f-L/n resin KR film forming. - Konaru Furuno, Nato has been put into practical use in JL 6, and Irran, as a knob film, it is used in addition to self-destruction 1'1, cutability 9 strength, transparency,
Men 1 heat 4 shi 1 etc. 1'mouth i)゛ of the gods.
が要求されている。is required.
しかしながら、ポリ塩化ビこ＝リブノ樹脂やポリ塩化ビ
ーニール樹脂などは塩素を多駿に含んでいる／３−め、
焼却時に塩素ガスを発生したり、多１１１に３−まれる
＋ｉＪｉ！！１剤の不害性などが問題とな１）でいる９
、このだめ、このような問題点の少ない高Ｌ「法低密用
ポリエチレン樹脂も使用されているが、べれ自Ｊ、４自
己粘着性が非′帛に低く、種々の粘着伺り剤を添）ノ＋
］Ｌなけねばならないという欠点があるとともに、カッ
ト件に劣る欠点がある。However, polyvinyl chloride resin and polyvinyl chloride resin contain a large amount of chlorine.
It may generate chlorine gas during incineration or be exposed to 3-iJi! ! The problem is the non-toxicity of the drug 1)9
However, high-L low-density polyethylene resins with fewer such problems are also used, but their self-adhesiveness is extremely low, making it difficult to use various adhesive agents. attached)ノ+
]L, and it also has the disadvantage that it is inferior to the cut case.
１だ、ポリ塩化ヒニリブン樹脂製うノゾノイ／１ムは、
二軸延伸さノじＣいるだめカット時に斜めに裂けやすく
、１だ電子レンジで加熱し／べ場合なと著しく収縮する
。 −力、高圧法低密度ボＩＪ ：ｃ 、９−レン樹脂
製シソゾフイルノ、は耐熱性が十分−Ｃはなく、従って
近時めざ斗しく普及している電子レンジ−で−調■ψ、
ＪＩｌｌ熱−Ｊ−ｚ、場合に使用−４゛ると、ノーイ片
ノ・が溶１含：ｌ！ ｌ、、、、−（−破ｆｉｔ Ｌ
／：−リ、あるいに１フイルｌ、同１−が融４“′ｉし
−Ｃ糾れ／１−リ（？゛マ融−で容器、ケとに１７１拍
し−たりず２、欠点がＪ・るため、ぞの用途ｔ、１、大
幅に制限さね−Ｃい、く１５、
ｉ’ｒｊｌ［ｉ・の問題点を解消するものと１７で、ボ
リア１１ビＬ・７・糸樹脂を用いると−とも桿案さｔｌ
でいる。1. Unozonoi/1mu made of polychlorinated hinylive resin.
Biaxially stretched strips tend to tear diagonally when cut, and shrink significantly when heated in a microwave oven. - Power, high pressure method low density boiling IJ: c, 9-ren resin shisozophyrno has sufficient heat resistance -C.
JIll heat-J-z, use in case-4゛, Noi Katano-ga melts 1:l! l,,,,-(-break fit L
/:-li, or 1 file l, the same 1- is fused 4"'i-C 绿re / 1-li (?゛ma fused- in the container, 171 beats in the keto-dirizu 2, Due to the shortcomings of J, the use of t,1, is greatly limited. When using thread resin, it is possible to create a frame design.
I'm here.
し、か（ボ゛１ゾ１１−１ビしン系樹脂を用いた場合、
耐熱ｆ１といら点でｉｌ流１柚できるものであるが、自
已粘を’： （’−１’ ＜’ ｔｒツｌ−（−’ｌど
い゛）”・ツブフイノｔムの最も重要な！及・（ζｌ＜
ｌ、、 ｆ車を・満足゛することがてき７ない。However, (when using Vo1zo11-1 vinyl resin,
The heat resistance f1 is one of the most important points in terms of heat resistance, but its own viscosity is the most important!・(ζl<
I can't get enough of my car.
−シＹ（゛、自已粘惰１〈１を（＝ＩＪｉ−１＃る、／
こめ桿、着イ」り削台配介−Ｊ′イ、と自己粘着＋１は
良く・５ろが、リット１′［が悪く使１１Ｋ ｉｒ＋ｒ
ｔぐ−５ない。ま／；−１１）２ノｌ＝ ４′、ｔの向
−１６ξ［１的に一１Ｚ１ルムを延伸すると粘着イ・Ｊ
’−！ｊ剤がフリー１・ｌ、なかったり、あるいはその
後配向を緩和させて）（！−１・さｄ−ｆ−も、ブリー
ドし／こ１１１１片１イー・１−リｉ’ｉｌ＋ンう・
７Ｗイ１；＋、 −ｃ ■、状となりフィルムの透明感
や光沢に−１＜”ｈた！イ２・【ｌ−をイ１＃る（−と
ができ４゛、しかも重ね含１−トた７−ｆ！レノ・を引
へはかし／ζζ場合皿面破壊牛１゛るなと／ｌ：）欠点
かあ、？１、。、１−２だが一：’−，）−（１、こ）
し１、でに自己枯椙＋！＋と１ノツトＨのいずｉ［Ｚａ
・も満Ｗ才るボリア１１ビしシ・糸１ｉｉ１脂からなる
ラソブノイノ１）、は得らノＬ −ｔ、 １７’Ｎ−６
＝い５、本発明はこれら」雪：［シの欠点台解消し、ラ
ツプブ・ｆルノ・占してな１滴な包装）ＩＩフイ？Ｌム
の製造Ｊ５法を擢供−Ｊ−ることを目的とするもの一〇
ある。-shiY(゛、self-reliance 1〈1(=IJi-1#ru,/
The rod is equipped with a grinding table - J'i, and self-adhesive +1 is good and 5 ro, but lit 1' [is bad and used 11K ir + r
There is no tgu-5. -11) 2 nol = 4', direction of t -16ξ
'-! If the j agent is free 1・l, or the orientation is relaxed afterwards) (!-1・sad−f− also bleeds/this 1111 piece 1e・1−li i'il+n・
7W I1; +, -c ■, and the transparency and gloss of the film are -1 Tota 7-f! If you pull Reno, you'll have a dishwasher destroyed by 1/l:) Is it a drawback? 1,., 1-2 but:'-,)- (1, this)
1. Self-destruction+! + and 1 note H I [Za
・Lasobunino 1) made of 11 parts of Boria 11 parts, 1), 17'N-6
=5, the present invention is these "Yuki: [Eliminates the disadvantages of shi, wraps, fruno, and fortune-telling one drop packaging) II Hui?" There are 10 products whose purpose is to provide the J5 method for manufacturing L.
寸なわ１：）本発明ＩＪ１ボリゾＩ−１ビし・ン糸樹脂
心・（二帖着（＝ｊ−り剤を配合しプこ樹脂組成物から
なり、か′う・Ｌ゛なくとも横方向に延伸された〕・１
ノ１ノ、を表面酸化処理４、・よび熱処理した後挨き取
り、次い−ｃ？ｔきＬｉｔ、４られだＳ′イルムを熟成
する（−とを！１！ｆ徴とする包装１月フィルｌ、の製
造方法を皆供−するも？７）］−ある３、本発明に丸・
いてＦＴｌいるボリゾ１コピ１〜ン〒” ｌ！’ｌ 脂
（１）種類０、ｌ↓＋ＴＫ １（ｉｌｌ限はなく、プロ
ピし、・ホモボＪ、ｉ −、−−−はも（−・ろ／、、
、、、、 ｘ ２丁−１−ン′等とブ１１ヒ【、２・の
コポリ−２′で才・′り千もＪ：い６、σら（′（−グ
「１ビ１２パ・と工′ｆ−Ｌ〕等他成分とのコｊ！リ−
＝−−−ｒｊう７．りノ、コポリ−イ・−、ブ［コック
＝１ポリマ・−のいずれであ−）でもよい１、なＪ、・
、このポリフロピトン糸樹脂の物４−′Ｉは各（Φ１１
１途、′４［イア１当に応１−で適′１゛口゛ぺ′Ａｔ
、−Ｊ’ねば、ｌ：いか１通常番Ｊ、メルト１．・−ｊ
ツクス（ＭＩ）６へ１１、密度０．９００−０．９１０
’ｉ／’Ｉ ０分のものがり了まし〜い。Dimensions 1:) The present invention IJ1 Borizo I-1 Bi-thread resin core (two-layered) (=J-2) consisting of a resin composition containing a resin composition, stretched in the direction]・1
After surface oxidation treatment 4 and heat treatment, dust is removed, and then -c? 3. The present invention provides a method for producing a packaged film with 1 and 1! f characteristics for aging the 4-layered S'ilm. Maru・
There is a FTl bolizo 1 copy 1~n 〒” l!'l fat (1) type 0, l↓ + TK 1 (ill limit, propi, ・ homobo J, i −, --- hamo (-・reactor/,,
,,,,・Collaboration with other components such as
=---rj7. Rino, copoly-i-, bu [cock = 1 polymer--] may be 1, na J, .
, this polyfuropitone thread resin thing 4-'I is each (Φ11
1 way, '4
, -J' Nene, l: squid 1 regular number J, melt 1.・−j
Tux (MI) 6 to 11, density 0.900-0.910
'i/'I The story of 0 minutes is over.
次に−［記ボリグロビＬ／ン系樹脂に配合される情片′
ｊ伺Ｊ、剤、１−Ｌ−７″に、非イオン仕官２面活性剤
あるいは分ｊ’ ｈｉ’、 ３０ （Ｉ Ｑ以下の比較
的低分子肚の樹脂が用いら〕１イ）。、
（−り二、で非イ］ン１イ）・界面活性剤とり、ではブ
ルー１−１１と脂肪酸、Ｌ−ｔ’／） Ｉス−ｉルおよ
びぞの誘導体を意味し、こ（−（−用いる一ｒルコール
の１列としてクリセリフ／ｌボリクｌ）士；；／、ノ！
レビタン、ソノＬ［−トール。Next,
Add a non-ionic surfactant or a relatively low molecular weight resin with an IQ or less to 1-L-7''. (-ri2, denon-i]n1i)・Surfactant, then Blue 1-11 and fatty acid, L-t'/) -Used as a column of 1 rrukoru kuri serif/l borik l) 士;;/、ノ!
Levitan, Sono L[-Toll.
＜−ｑｌ−リス１１） 〜 ルウポリ工すｌ、／′グリ
Ｚ１−ル。<-ql-Lis 11) ~ Ruupori Kosu l, /' Griz1-ru.
ボリブ［ｌビレ−グリコールなとかあり、脂肪酸の例と
し−（ア！ｌギＪＬ基の炭素数が５ ＝ １３個の直鎖
゛ＩＫ↑・胞和１１Ｙｊ肋酸、アルＮル基の炭素数が１
７〜２１個のｉ−ｉ’ｉ禎状不飽和脂肪酸なとがある。There is something like boli-glycol, and an example of a fatty acid is (a! lgi JL group has 5 carbon atoms = 13 straight chains ゛IK↑・Solation sum 11Yj costic acid, carbon number of AlN group is 1
There are 7 to 21 i-i'i sterile unsaturated fatty acids.
寸７’ｉｍ、１泣−■−人−７−ルの誘導体としではゴ
チし・・ンオギントイ・１加物し４−とが３；）る。こ
の、１１イオン性７Ｉｊ面活性剤を１１一体的に師承−
４−る。シ、ボリオギ〉′王手Ｌ・ン−ｊ−［キルニー
ｉ１ｔ 、 ホｌｌ ％ギつエチレン了）１キルフェニ
ルｆ−−、Ｔ、 、、＋ｔ、ボリーシキ、−１−ｆ−レ
ンア！に１り１−Ｉ−ベテ？Ｉ＋ポリ」ギン′工千しン
ソルビクン′−ｊ′ル４． 、ＪＬＪ：＜テノ（ｌボリ
オギ、王手シ、／アノ１ギル了ミ＞、／７り十りン脂肪
酸丁スデノＬ、ンルビタン脂ｔｌＪｉ酸−ｒ、スデ／Ｌ
、＝ ペン、々ユ、リスリ［・−）１脂肪酸ニス゛ｒ
゛ＩＩ、ゾＩ−１ビ１５・／グリコール脂肪酸丁スプル
、トリメ−ｆ−ｔ−＋・−ルゾＬ１・くン脂肪酸エステ
ル等が挙げられる３、この非・イオン性Ｗ面活性剤と１
記ポリブ１１ピＬ。As a derivative of 7'im, 1-■-person-7-ru, it is 3;). This 11-ionic 7Ij surfactant is integrated into 11-
4-ru. shi, boryogi〉'Ote L・n-j-[Kilney i1t, holl %gitsu ethylene completed) 1 kylphenyl f--, T, ,, +t, borishiki, -1-f-lena! ni1ri1-I-bete? I+poly'gin'techsensorubikun'-j'ru4. , JLJ: <Teno (l Boryogi, Oteshi, /Ano 1 Gil Ryomi>), /7 Rijurin fatty acid Ding Sudeno L, Nrubitan Fatty acid tlJi acid-r, Sude/L
, = pen, taiyu, risuri [・-) 1 fatty acid varnish ゛r
゛II, zoI-1bi15./glycol fatty acid ester, trime-f-t-+.-ruzoL1.kun fatty acid ester, etc.3, this non-ionic W surfactant and 1
Polyb 11 pyL.
／系樹脂との配合比は、ボリプｌ’ｊビレ／糸（４ｊ脂
１００重量部に対し７、非イＡンｒｔ胃−面活＋１剤１
−５重用゛部の範囲で用いるＣ−とがθイましい。、Ｉ
−イＪン件界１ｎ１話性剤の配合１１が１重Ｍ部未満で
ｋ）ると、十分な自己粘着性が得らＪｌす、−土１’ｒ
５重い部５−超える１ｊ二−ノイ、ルノ・表面にグリ
−トＬプこＪ１＋イー１．・１ノ１ゲ１１面活性剤か被
包装物面に移７」−するの−Ｃ／Ｉｆ −４Ｌ−、＜な
い。また、非−１−］ン性胃而面４／Ｉ剤とし２では常
温において液状のものが好斗シ、い１、
寸／３−１分子Ｔｉｉ、’ ３０００以−１の１し１１
交的低分子］ｊ：の＋ａｔ脂′とｌ、ては、例えばテル
ペン（１１１脂、クマ「１）樹脂、クツ１１ンーイ〕テ
ン樹脂、Ａ／ｌ／ン樹脂、シ・−１し ］・ＩＩｒ！Ｉ
ｉｉ’ 、１１泊（りｊｊ脂に−との１・１、か但小合
庶ポリ」ｔ７−７１ ／（ポリ２丁−ザし・ン、ボリゾ
デン、ボリイ／／゛１■：〕ｊ’ｒ 、に）を挙げる仁
、１ができる。パ−の；ｙ１’−、ｔｉｔ３（，１０ｔ
）以斗の田較的低分子昂の樹脂とト記ポリプロピＬ−・
ンｆＡ ＩＩＩ脂との配合１ヒは後者１００重１１１部
に月！１、＋ｉｉＪ 、！′￥１〜ｌＯ市１ｄ部の範囲
で用いるこコかＩＩｒまｌ−、ｌ、）。The blending ratio with / system resin is 7 parts per 100 parts by weight of volip l'j fillet/thread (4j fat, 1 part of non-inorganic Anrt stomach active + 1 agent)
- C- used in the range of 5-fold use is preferably θ. , I
- If the blending agent 11 is less than 1 part M, sufficient self-adhesiveness can be obtained.
5 heavy part 5-1j two-noy, Luno surface Greet L puko J1+E1.・1 No. 1 Ge 11 The surface active agent is transferred to the surface of the packaged object -C/If -4L-, <No. In addition, non-1-] gastrointestinal 4/I agent 2 has a liquid form at room temperature.
111 resin, 11 resin, 11 resin, 1 resin, 1 resin, 1 resin, 1 resin, 1 resin, 1 resin, 1 resin, 1 resin, 1 resin, IIr!I
ii', 11 nights (1.1 with Rijj fat, katan small joint poly' t7-71 / (Poly 2-cho-za-shi-n, Bolizoden, Bolii//゛1■:〕j'y1'-, tit3(,10t
) Polypropylene resin and polypropylene resin
The combination with N fA III fat is 100 parts of the latter 111 parts! 1,+iiJ,! 'Koko II r ma l-, l,) used in the range of ¥1 to lO city 1d part.
＋、２明にあ′）ズ゛は、１ずポリゾロピレン糸樹脂に
、Ｊ１イー→・ｆ′Ｉν■′面活性剤あるいは分子１３
ｏｏ。+, 2) Z') is 1) added to the polyzolopyrene thread resin with J1E→・f'Iν■'surfactant or molecule 13
oo.
以上の比較的低４トｒ量の（引揃か１）〕々る粘憾イ・
ｊｈ剤を配合しブ（樹脂組成物を゛１゛−ダイ法、イン
フレ −’ｌ’ Ｆｌ ｙ法などの手段によ−）で溶融
押出製膜１−で原反す：１ｌｌ−ニア°を、 ｊｊ（す
ｉ；賢１゛る。１、左。The above relatively low 4-tor amount (all together or 1)] is sticky.
The resin composition is melt-extruded into a film by a method such as die method or inflation fly method. , jj (sui; wise 1゛ru. 1, left.
次いで７！Ｉら、ｆ＋ンケ原原反−ｆ−、：１．・−）
゛・法、う’７り一法などの王１グによって延伸ず−る
。、本発明においでｄ、原反−ｆ−・−−−ブイ−輔Ｉ
ＩＬ伸装置々とを用いて少なくとも横／ｊ白に々１１ｏ
伸し−（ｔ、・ぐことが心安で４（）す、延伸倍率は＃
１ｉｙｉ力向しτ２１ン１以−１−１／！ｆましくは３
−６倍−Ｃあメ：１１、（二、のように１９反−ｆ二１
、−ブを１〉７なくＬｌ−も横ツノ向に※ｉＬ （ｔｉ
ｔ −ｆ Ｚ）と、シ（・ｊより、）ｌットイく１−や
強度が向ｌし［かも表ｒ「１１状態の良Ｑｆな一ノイ１
１ 、、／、ヲｆ！）る２二、１が１へる５、
ここで゛フイノ１ノ、の厚みは通常（ｉ・・〜（ｉ（）
μ、４１′まし ぐ シ１−８ へ−１５／ｌ −こ
゛ ｌ上） る 。Next is 7! I et al., f+Nke original fabric-f-,: 1.・−)
゛・Law, U'7 ri 1 law etc. are extended by the king 1g. , in the present invention, d, original fabric-f----bui-suke I
At least horizontal/j white 11o using IL expansion equipment
Stretching - (t, ・You can rest assured that it is 4 (), the stretching ratio is #
1iyi force facing τ21 n1 -1-1/! Preferably 3
-6 times -C candy: 11, (2, like 19 anti-f21
, -B is not 1>7, Ll- is also towards the horizontal horn *iL (ti
t −f Z), s (from ・j), the 1- and the intensity are in the opposite direction.
1,,/, wof! ) 22, 1 becomes 1 5, where the thickness of ``Fino 1 no'' is usually (i... ~ (i()
μ, 41' increase 1-8 to 15/l - 15/l - 1).
このようにして得らノＬ／こノイルｌ−ζ」カット性か
向−［−し７たと幻、言うものの自已桿仁着（イ１をイ
１せず必ずしもう、／゛ブノイ！【ｌ・とＩ、 −Ｃ−
ｉ分にＡ星ｊ・）・；）ものであるとは［ｉえない。In this way, you can obtain ノL/Konoiru l-ζ' Cut property or direction - [- and 7 and illusion, but it is said that it is self-contained (I do not necessarily have to do it without I1, /゛Bnoi! [l・and I, -C-
It is impossible to say that it is an A star j・)・;) in i minutes.
ぞ（−で本発明においては、このよｉ）にＬ −ＣＩ’
） ｃｌ）れたフイノＩムをスリッター等で切り開き表
面酸化処理および熱処理し／こ後巻き取り、次いで巻き
取らＪＩだフイルノ・を熟成して包装用フィノ１ノ・と
−するものである１、
本発明によ、・いては表面酸化処理と熱処理な↓いずれ
を先に行なってもよいが、画処理とも巻き取り前の通常
緊張−１−の状態において行なわＩする、。(-) In the present invention, L -CI'
cl) The obtained fins are cut open with a slitter or the like, subjected to surface oxidation treatment and heat treatment, and then rolled up. According to the present invention, either the surface oxidation treatment or the heat treatment may be performed first, but both the image treatment and the image treatment are performed in a normal tension state of -1- before winding.
ここで表面酸化処理の方法は特（ｌζ制限はなり、−ｊ
［１ヲ放電処即、火焔処理、］シー処理、紫外線処ｒ’
ｌ’ ｌ酸化性薬液処理等を適用することができ、Ｊ・
りわε・Ｊ−＝１０ノ放電処理か＆−１’寸し７い。表
面の酸化枚用ｔｅｌ、表面酸化処耶イ′ノ、などＦＣよ
−）″（異なり−・義的に決定−することは困φＩＣｆ
ｉ５イ、３、−ｙ「１す放電処理のψ、含、表面張１
１が３５ ｄ ｙ ｎ 、／”ｃｍ ｌ−なるように行
なうことか１）了ｔ １．。Here, the method of surface oxidation treatment is particularly (lζ limit becomes, -j
[1] Discharge treatment, flame treatment, sea treatment, ultraviolet treatment r'
l'l Oxidizing chemical treatment etc. can be applied, and J.
Riwa ε・J-=10 discharge treatment or &-1' dimension 7. FC for surface oxidation treatment, surface oxidation treatment, etc.
i5 i, 3, -y "1" ψ of discharge treatment, including surface tension 1
Do it so that 1 is 35 dyn, /"cm l-1) Completed 1..
い７、ξ”の。１．・）、を表面酸化処理により粘着ｆ
（Ｉ与剤をツーｆ！１）、、、ｔ＜而に均−Ｕ（′シリ
ー１・させることができる、っ
−また、熱処理の−）７法も特に制限ｉｔなく、加熱Ｖ
］−！１法、 ７−、、、 ’ｊ）’ン法等により行な
うことができる。、熱処理￥＝１ｆ１と１−τ＆ｊ、結
晶融点以下でありで５０’Ｃ以１の１１１１冒（リ−（
〕−■カー〇ことが好１ｌｌ）、、 ま／こ、熱処理
の時間は熱如、 Ｉｉｆ！のｉＡ、１１ｊｌやノイルト
のＪ望み等によ壬）−７’−穴なり一義的い賜卜めるこ
占は困菓１（で、ぢるが、通常２＝２ｆｌ砂−τ、７・
）る１、な１、・、熱処理後し１、冷却口・−ル舌を二
用い−Ｃ冷却１．． Ｅｌ ：ｌ；・くζどが好ｔ Ｌ
、い。7,
(I give the agent to f! 1),,,t
]-! This can be carried out by the 1 method, 7-, , 'j)' method, etc. , heat treatment ￥=1f1 and 1-τ&j, below the crystal melting point and below 50'C 1111
〕-■Car〇 is good 1ll),, Ma/ko, heat treatment time is like heat, Iif! According to iA, 11jl and Noirt's J wish, etc.) -7' - Hole is a unique gift, Merko's fortune telling is difficult 1 (but usually 2 = 2fl sand - τ, 7.
) After heat treatment 1. After heat treatment 1. Using two cooling ports and tongues - C cooling 1. ．． El :l;・I like ζdo L
,stomach.
この３Ｌうに表面酸化処１１Ｈおよび熱処理したブイ７
４ノ・を紙管等に巻きＩＩｒす、次いで巻き取らｔｒ／
ζソイノ１ノ、を熟成させる６、熟成はフィルム台高温
下に短時間？−酉ζ−７）−”（もよぐ、あるいは低温
−卜に長時間放置する（−と６′（−上り？−Ｊなりで
もよく、温度や時間６、・ 省的に決定［イ、こ、し
は困難で、ちる１、フィルノ、の′−１産４１Ｆ等答−
考慮すると６０ ＝ Ｉ ２ ｏ’Ｑ（７′）温庶−Ｃ
゛３０分１、え＋、々」−！ Ｌ ＜は９０〜１１０°
ｃ−Ｃ＋・〜５時間熟成さしとる。１
、′！ｆお、本発明（５二ありでは前記樹脂組成物中に
、必要により適宜各種の添加剤を加えることもｒＪきる
。添加剤としでは滑剤やアシー丁ブロソギング剤等が挙
げらｉｔ、、 、３体的し′こはステアリン酸カフ（１
、′１′・〕・、−ステアリン酸バリウムなどの金属石
けＡ１、ステアリン酸アミド、バルミヂン酸アミドなと
の脂肪酸了ミド゛、スーファリン酸モノグリ十う・ｆｌ
・や粉末２ノリカ、ケイ藻上、カオリン、クルジ４・ど
を例示−ンる（−とができる。This 3L sea urchin surface oxidized 11H and heat treated buoy 7
4. Wrap it around a paper tube etc. IIr, then roll it up tr/
Aging ζ Soino 1 6. Aging for a short time under high temperature on a film stand? -Rooster ζ-7)-"(Moving or leaving it in a low temperature for a long time (- and 6'(-up?-J may be fine, the temperature and time 6) - Determine it conveniently [I, This is difficult, Chiru 1, Firno,'-1 production 41F etc. answer-
Taking into account, 60 = I 2 o'Q(7') Onsho-C
゛30 minutes 1, e+, t' -! L< is 90~110°
c-C+・Age for ~5 hours. 1,'! In the present invention (52), it is also possible to add various additives to the resin composition as necessary. Examples of additives include lubricants and acetic blotting agents. Physically, stearic acid cuff (1
,'1'・]・,-Metallic soap A1 such as barium stearate, fatty acid amide with stearic acid amide, valmidic acid amide, suphalic acid monoglyceride, fl
・Powder 2 Norica, diatom, kaolin, Kurji 4 ・ etc. are examples.
こ６−）ような構成からなる本発明の））法によれば、
自己粘着性、耐熱性およびカット性の内債４り１を満Ｊ
ｊ二するソイルノ・をｒ坪ることが″（“きる。According to the method)) of the present invention having the configuration as shown in 6-),
Self-adhesive, heat resistant and cuttable with 4-1 rating.
It is possible to make two soils by r tsubo.
しかも、本発明の方法によりイＵられ；”ｔ’ｌ−７−
１・ト）、は延伸配向さノ１でいるので強度が高く、さ
らにカット性にもすぐｆ＋でおり、カット］［、−に斜
めに製膜ることもないっまた、延伸配向（こより：１イ
・１〕・の厚みを薄肉化でき省ｆｔ源きもなる１、ン＼
［・（・（１＼゛、′に、 ｊｌｌ、ｌ （、’Ｄ
ツノを去＋／７７ よ リ 得らｊ１／ｊ ’、７
イ ７１ ノ、は；、％ ｔｌｌ １′Ｈに−ｆ＜’
！＋るとともにダト観か■′ｊりｌ′である。Ｉ−７か
も４熱１′１にもすぐ１１．−Ｃオリ、？Ｅ ｆ ｌｚ
’ ７ ’； −Ｃ調ＪＪ！、 ＋力１１熱−Ｊ−る。Moreover, the method of the present invention allows
1.G), has high strength because it has a stretch orientation of 1, and also has excellent cuttability, and does not form a film diagonally to the cut] [, -. The thickness of the 1.1] can be made thinner, resulting in ft savings.
[・(・(１\゛、′、jll、l （、'D
Leave the horn +/77 yo ri get j1/j ', 7
I 71 ノ、は；、%tll 1′Hに−f<'
! Along with +ru, there is a view of Dato or ■'jril'. I-7 or 4 fever 1'1 or 11. -C Ori? E f lz
'7'; -C key JJ! , +force 11 heat -J-ru.
用台に幻適に使Ｊ「−４ることかでき、寸／こ＋１ａ１
１却１介棄１１．’ｉにポリ塩化ビニｌデン悼１脂やボ
１１ ｔ’Ａｉ化し＝ ／ｌ−（ＷＪ脂なとのように塩
素カスを発什づることがツク・ぐ、〃′全十′１がｊ９
迅）ものである。、したが〜νζ４、本光明は家庭用う
５ソブフイ！１ノ、。It is possible to use J "-4" in the table, and it is +1a1.
1 rejection 1 intervention 11. 'i is polyvinyl chloride 1 fat and 11 t'Ai = /l- (It is difficult to emit chlorine scum like WJ fat, 〃'all 10'1 is j9
It is a thing. However, ~νζ4, this light is for home use! 1 no.
業務用′ノノブフィルノ・などの包装用−、フイＪＬノ
・の製造方法としでイ１用である０、
次に、イ＼発明を実施例により説明する５、実施例１−
４
第１図に７トー４″装、置を用い−Ｃフ・（、，１＋１
、を製造しだ６、−１−ｒ、ホ’Ｉ ）ｔ＋ビシン樹脂
（密度０ 、９１ ！ｉ’ ／’ｃｎｌ 。For the packaging of commercial products such as ``Nonobufilno'', the manufacturing method for ``FiJL'' is used.Next, the invention will be explained with examples.
4 Using the 7 toe 4'' device in Figure 1, -Cfu (,,1+1
, 6, -1-r, H'I) t+bicine resin (density 0, 91!i'/'cnl).
Ｍｌ ７ Ｆ、／”１０分）に第１表に示寸粘着（”
Ｉ’ 、ｆｉ剤を所定Ｆｉｔ配合（マスターパップ−使
用）した樹脂組成物を′１−１−−−−フ製造押出機１
を用いて樹脂温度２００°Ｃで水冷「吹きノ５法で押出
し、径ｉ ｏ ｏ ｍｍ 、 ｓみ１００ ｔｒの原反
チューブ２を得た。イ４ｔらノ１だ原反壬：１．−フを
引き続き−ｆ−ユーブラ法法用側１延伸装買３Ｃ導入し
、延伸（没入１−Ｊｉ中１！３２．２ ｊｌｌ、４ト、
々１「伸＋痕（ｔ、ｌｔ １．１速Ｉ！Ｊ−８、０”ｙ
分の延伸条件に、１、す１１６（、購−そ−７＋ −ｒ
ｆｉの延伸倍率が約４倍の一ノ・ｆハノ・（１°ｌみ
７ ／ｉ ） ％、ｔｌすｆ（、、次いで１１々 ）
・ｆ ！Ｌ ノ、を ス リ ソ 々 ・−４て （刃
ｊ） 開 き 、１３０℃のｊＪＩＩ熱ロ ル５を
・用い−Ｃ接触ＩＬ’ｉ ｌｉｌ ４ ｆ／ｐ （７）
熱処理を行ない４却ローＡ−（’冷却後、表向張Ｊ１が
３８ ｄｙｎ／ｃｍ、Ｌ：）、ｌ−となるように：１０
ナ放電謁ＩＡ６を用い１表面酸化処伸を行なっ／、−１
、次い−７−１１，ＩＣ・（／１）、を巻取装置７を用
いて紙管に巻き取り、杏、き取らノ１だフイ・Ｌノ、を
熟成装置７（加熱炉）４・用いて＋ ００００−（５１
１６間熟成し７て包装用フィＩｔ）、づｉｉ！Ｊだ。、
得られだ７４７１人の物性、ラノゾフィルｌ、１ｌ−ｊ
−この評価語Ｉ■を第１表に示才９．
１１−較例１
ポリプロピレン樹脂（実施例］、−４で用いたと同じも
の）に第１表に示−ノー粘γｉｌ・ＩＩＪ剤を・所定）
ｊ１配合し、た樹脂組成物を５ｏｍｍｃｚしイ（リソゾ
開１１１０．５ ｍｍ ） ４・用いて樹脂温度２００
”Ｃで水冷１・吹き方法で押出し、径１００ ＋ＩＩｍ
、 Ｎみ１０ Ｉｔの７２イノ１ノ・をイ５ｇ （、。Ml 7F, /"10 minutes) with the adhesive size shown in Table 1 ("
I', a resin composition containing a fi agent in a predetermined fit (using a master pap) was put into an extruder 1 for producing fi
Using a resin temperature of 200°C, water cooling was extruded by the blowing method to obtain a raw fabric tube 2 with a diameter of 100 mm and a depth of 100 tr. Continuing to -f- Eubra method use side 1 stretching equipment 3C was introduced, stretching (immersion 1-Ji middle 1!32.2 jll, 4t,
1 "Extension + trace (t, lt 1.1 speed I! J-8, 0"y
Under the stretching conditions of 1, 116 (, 7 + -r
The stretching magnification of fi is about 4 times (1°l7/i)%, tlsf(..., then 11)
・f! Slice the L-4 (blade j) open and use JJII heat roll 5 at 130°C to make -C contact IL'i lil 4 f/p (7)
Heat treatment was performed so that the surface tension J1 was 38 dyn/cm, L: 10 after cooling.
1 surface oxidation treatment was carried out using Na discharge audience IA6 /, -1
, then -7-11, IC.・Use + 0000-(51
Aged for 16 hours and then packed for packaging). It's J. ,
Physical properties of 7471 people, lanozophile l, 1l-j
-This evaluation term I■ is shown in Table 1.9. 11-Comparative Example 1 Polypropylene resin (Example, same as used in -4) was treated with non-viscous γil IIJ agent shown in Table 1 (prescribed)
The resin composition was blended with J1 to 5 ommcz (lisozo opening 1110.5 mm) 4. Using resin temperature 200
Extruded with water cooling 1 and blowing method at ``C, diameter 100 +IIm
, Nmi 10 It's 72 Ino 1 No. 5g (,.
（！’） ”、Ｉ）だ−フイノＩノ・の物性、−ンノブ
ーノイノｔノ、としての評価語１１ｂを第１表に示す。Table 1 shows the evaluation words 11b as ``(!')'', I) DA-FinoI-no-physical properties, -Nnobu-no-inotno.
比１ト例２−＝ ６
りＪ、施ｊ２ｊｌ ：（ｐ（＝、１．・いて、第１表に
示す処理土層０〕ｔ、盲ろ・つたこと以外は実施例３に
準じて行なし）−ノイ１１ ノ、 Ｓ」！ｊ ノ
へ、
イ１↑１′−司また一フ・ｆ７１ノ、の物性、ラップノ
イノｔノ、トシ−この；；・１゛価結果を第１表に示す
。Ratio 1 t Example 2 - = 6 ri J, application j 2 jl: (p (=, 1., treated soil layer 0 shown in Table 1) t, carried out according to Example 3 except for blind filtering and pouring. None) - Neu11 ノ, S''!j ノ, I1↑1'-Tsukasa Mataichi F・f71ノ, physical properties of Lapnoinotノ, Toshi-this;;・1゛ value results are shown in Table 1 show.
比’ｒ＜ ｆ列 ７
高１１ρ、ボ１１エチし１．樹脂（密度０．９２２ ！
ｉｌ／ｃｎｉ。Ratio'r<f row 7 High 11ρ, Bo 11Echi 1. Resin (density 0.922!
il/cni.
Ｍ１５？／’１０テ１）にツノｌヒ゛タンモノオし・−
１〜を１ｉｔ；ｈｉ係配合しん樹脂組成物を１゛−ダイ
押出機をｔｒｉ ｔｚ）−（￥１．１髪１Ｏ−２６００
Ｃで成形し、ｊ♀み］、 ０ ／ｌσ）フイ！１ノ、を
イ’＋’ ｋ−ａ
（（ｊ ｐ＞ ｆ’ｌプどノイ＋１〕、の物性、ラノゾ
フイノｌ−１、とし−（の評価結１社台−第１表に示す
。M15? /'10 te 1) I played a horned fire.-
1 to 1 it; Hi-compound resin composition 1゛-die extruder tritz)-(￥1.1 hair 1O-2600
Shape with C, j♀mi], 0 /lσ) phi! The physical properties of 1 no, i'+' k-a ((j p>f'l +1), and the evaluation results of Ranozofino l-1 and (1 company) are shown in Table 1.
第 １
＋１．１ｌＳｌ＼６７１４１Ａ二＄ｐ
（、７Ｔ／ 、（、、ｌＬム（Ｑｌ ：；４．Ｉ Ｌ、
、、 Ｙ ９０１ｉ □１ＹＪＩ向、１、す、ｌｒＩ〆
請（’Ｉｋ 、’ｉ ’ ”−Ｉ ａｎ ｌＬ、’；＜
（−ｖ）ｎ、’、内１（す） １丁）曲線、ｌ； ｌ）
ｔ−ネ？Ｉキ ４（量定し４−１．１３１ｉ主Ａ投肉
ｊ′−イ・ｉ、７、（包ノドＩＩＬ子Ｉ、・′ジＣ３分
間処理しい−その［祭い−）１１ ホ１；ノリ” ”−
１１ｔｊ’１ｌＪ−ｉ酸−１４−１：ｌＩＡ ｉ Ｈｌ
−Ｂ ３．３ＢＩＨ１，１号（））
（（５） ０１８： ｌｌ １ − １ − １
− １４＋＋ム・ｌ）度付を１．（、”Ｊく％二、７Ｓ
： 、１１、−１１、己比重’：４ｆ牛１１６にｔ・い
でＣ１１、７゛す〜 トシ、だ粘看１・ｌｔｉ剤力曽１
）１−隼し−Ｃ−ノイルノ、表面によだら模様がＪｆｉ
・、牛Ｌ／ｌ−，，。1st +1.1lSl\67141A2$p (,7T/ ,(,,lLm(Ql:;4.IL,
,, Y 901i □1YJI ward, 1, s, lrI〆request ('Ik,'i'''-IanLL,';<
(-v)n,', 1 (su) 1) curve, l; l)
T-ne? I Ki 4 (Measurement 4-1.131i Main A Throw j'-i・i, 7, (Wrap throat IIL child I,・'DiC 3 minutes processing-that [festival-)] 11 Ho 1; Nori” ”−
11tj'1lJ-i acid-14-1:lIA i Hl
-B 3.3 BIH1, 1 ()) ((5) 018: ll 1 - 1 - 1
-14++mu・l) The degree is 1. (,”J%2,7S
: , 11, -11, self-specific gravity': 4f cow 116 t.
) 1-Hayabushi-C-Noirno, the surface has a Jfi pattern
・, Cow L/l-,,.
４１ツｌ［川の伍１中を説明
２１１１図（・］［４＼発明の方法に用いる装僅の概略
図でイＸ、る１、
１ ・ −１−１−−−−７製造押出機、２・ 原反ザ
ユ−ブ、３ 輔延沖装置、４・・・・・ スリッ
ター、５ カＩｌ熱「１−りし、６ ・−・・コｒ
１す放電装装置、γ ｑ、 、１ｌｊ７装置、８
・・熟成装尚。41 [Figure 2111 explaining the inside of Kawa no Go 1 (・] [4\ Schematic diagram of the packaging used in the method of the invention. , 2. Original fabric, 3. Sukenobu equipment, 4.. Slitter, 5. Heat treatment, 6..
1 discharge equipment, γ q, , 1lj7 equipment, 8
・Aging style.
＝２９Ｅ
手続補正前（自発）
昭和５８年２月４ 日
！１１１’ ｉｉ′を片長′［・１ 若杉和夫 殿１
）１１イ′１の表示
Ｉ持）７ｆｉ昭 ５７−２２６５４８
２、 発明の名称
包装用フィルムの製造方法
５ｉｔｉ正をする者
事件との関係 特許用Ｎ１１人
出ゲ（１石油化学林式会社
４、 代 理 人
〒１０４
東京都中央区京橋１丁目１番１０号
５ 抽圧の対象
＋！ＩＪ ＃Ｉ占の発明の詳細な説明の（閑に訂正する
。=29E Before procedural amendment (voluntary) February 4, 1982! 111'ii' to Katanaga' [・1 Kazuo Wakasugi Tono 1
) 11 A'1 Indication I Hold) 7fi Showa 57-226548 2. Name of the Invention Method for Manufacturing Packaging Film 5 Relationship with the Case of Person Who Corrects Patent N11 Person Dege (1 Petrochemical Forest Company 4, Agent Address: 1-1-10-5 Kyobashi, Chuo-ku, Tokyo 104 Object of Lottery +!IJ #I Detailed explanation of the invention of divination (slightly corrected).
（２） 同第７頁１５行目の「チューブ」を「フィル
ム」に訂正する。(2) On page 7, line 15, "tube" is corrected to "film."
（３） 同第７頁１６行目の１−チューブ」を［−フ
ィルＡ Ｊに訂正する。(3) "1-Tube" on page 7, line 16 is corrected to [-Phil AJ.
（４） 同第８頁１５行目の「画処理とも」を「−表
面酸化処理は」に訂正する。(4) On page 8, line 15, "also known as image processing" is corrected to "-surface oxidation treatment".
（５） 同第８頁１６行目の１行なオー〕れる。・」
の後に１また熱処理は通常弛緩下の状態で行なわｊする
。−１を加入する。(5) Page 8, line 16, line 1.・”
After that, heat treatment is usually carried out in a relaxed state. Add -1.
（６） 同第９頁５行目の［５５ｔ３ｙｎ／ｃｍ Ｊ
を１−通常５５ ｄｙｎ／−以上」に訂正する。(6) Page 9, line 5 [55t3yn/cm J
is corrected to 1 - usually 55 dyn/- or more.
（以上）(that's all)
Claims (1)
た樹脂組成物からなり、かつ少なくとも横方向にり１」
−沖さ〕１／こソイ１１ノ、を表面酸化処理および熱処
理しまた後へき取り、次いで巻き取られたノイルノ、を
熟成する（−とを特徴とする包装用フィル・）、の製造
Ｊｊ法１． ２ ノく面酸化処理がコロナ放電処理である％π１請求
の範囲第１項記・１・（の方法。[Claims] l Voliv "composed of a resin composition containing an adhesive (4'j agent) in a 7-vinyl resin, and at least 1 in the lateral direction"
- Jj method for producing a packaging film characterized by surface oxidation and heat treatment of Okisa] 1/Kosoi 11, followed by peeling off, and then aging of the rolled up Noirno (a packaging film characterized by -) 1. 2. The method of claim 1.1.(), wherein the cross-sectional oxidation treatment is a corona discharge treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22654882A JPS59120635A (en) | 1982-12-27 | 1982-12-27 | Production of packaging film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22654882A JPS59120635A (en) | 1982-12-27 | 1982-12-27 | Production of packaging film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59120635A true JPS59120635A (en) | 1984-07-12 |
| JPH0214935B2 JPH0214935B2 (en) | 1990-04-10 |
Family
ID=16846874
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22654882A Granted JPS59120635A (en) | 1982-12-27 | 1982-12-27 | Production of packaging film |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59120635A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6858288B2 (en) | 2000-05-23 | 2005-02-22 | Oji Paper Co., Ltd. | Wrap film |
| WO2006019544A1 (en) * | 2004-07-13 | 2006-02-23 | Exxonmobil Chemical Patents Inc. | Improved surface treatment of polymeric articles |
| JP2009096499A (en) * | 2007-10-16 | 2009-05-07 | Okamoto Ind Inc | Household wrapping film |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0825593A (en) | 1994-07-13 | 1996-01-30 | Sumitomo Chem Co Ltd | Self-adhesive wrapping film |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5125547A (en) * | 1974-08-28 | 1976-03-02 | Mitsubishi Chem Ind | |
| JPS52152468A (en) * | 1976-06-15 | 1977-12-17 | Mitsubishi Chem Ind | Method of manufacture of polyolefine film |
-
1982
- 1982-12-27 JP JP22654882A patent/JPS59120635A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5125547A (en) * | 1974-08-28 | 1976-03-02 | Mitsubishi Chem Ind | |
| JPS52152468A (en) * | 1976-06-15 | 1977-12-17 | Mitsubishi Chem Ind | Method of manufacture of polyolefine film |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6858288B2 (en) | 2000-05-23 | 2005-02-22 | Oji Paper Co., Ltd. | Wrap film |
| WO2006019544A1 (en) * | 2004-07-13 | 2006-02-23 | Exxonmobil Chemical Patents Inc. | Improved surface treatment of polymeric articles |
| JP2009096499A (en) * | 2007-10-16 | 2009-05-07 | Okamoto Ind Inc | Household wrapping film |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0214935B2 (en) | 1990-04-10 |
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