JPS59118043A - Powdered cream soluble in cold water - Google Patents

Powdered cream soluble in cold water

Info

Publication number
JPS59118043A
JPS59118043A JP57226681A JP22668182A JPS59118043A JP S59118043 A JPS59118043 A JP S59118043A JP 57226681 A JP57226681 A JP 57226681A JP 22668182 A JP22668182 A JP 22668182A JP S59118043 A JPS59118043 A JP S59118043A
Authority
JP
Japan
Prior art keywords
oil
cold water
powdered
cream
melting point
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP57226681A
Other languages
Japanese (ja)
Inventor
Shigeo Chiba
千葉 茂夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NOF Corp
Original Assignee
NOF Corp
Nippon Oil and Fats Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NOF Corp, Nippon Oil and Fats Co Ltd filed Critical NOF Corp
Priority to JP57226681A priority Critical patent/JPS59118043A/en
Publication of JPS59118043A publication Critical patent/JPS59118043A/en
Pending legal-status Critical Current

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  • Dairy Products (AREA)
  • Grain Derivatives (AREA)

Abstract

PURPOSE:A powdered cream having improved dispersibility and solubility even in ice water, and improved shelf stability, comprising a vegetable oil as a fat and oil component, containing a specific amount of powder having particle diameters >=a fixed size. CONSTITUTION:A powdered cream soluble in cold water comprising a vegetable oil(e.g., colza oil, etc.) having 86-95 iodine value and <=20 deg.C melting point as a fat and oil component, containing >=80wt% powder having >=150mu particle diameters.

Description

【発明の詳細な説明】 本発明は冷水に可溶な粉末クリームに関し、さらに詳し
くは、氷水中でも良好な分散溶解性を有し、保存安定性
の優れた粉末クリームに関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a powdered cream that is soluble in cold water, and more particularly to a powdered cream that has good dispersion and solubility even in ice water and has excellent storage stability.

最近、食生活の多様化により食品への簡便性の要求も高
まっているが、そのなかで洋風化に伴なって、粉末クリ
ームに対する冷水可溶性の要求が高まっている。特に自
動販売機においてアイスコーヒー用クリームとして大き
な需要がある。
Recently, with the diversification of dietary habits, there has been an increasing demand for convenience in food products, and in line with Westernization, there has been an increasing demand for powdered creams to be soluble in cold water. It is in great demand, especially as cream for iced coffee in vending machines.

ところが、従来の粉末クリームは温湯には分散溶解する
が、冷水には不溶性のものであった。従来の粉末クリー
ムを冷水に加えた場合、クリームは大部分冷水表面に浮
き、撹拌しても「ダマ」になるだけで分散溶解させるの
は困難であった。
However, conventional powdered creams can be dispersed and dissolved in hot water, but are insoluble in cold water. When conventional powdered cream is added to cold water, most of the cream floats on the surface of the cold water, and even when stirred, only "clumps" form, making it difficult to disperse and dissolve.

従来の粉末クリームの油脂は乳脂、ヤシ油またはパーム
カーネル油あるいはそれらの硬化油などであり、融点は
30℃を越えるものかはとんどであシ、冷水不溶の性質
は油脂の高融点に起因していた。
The fats and oils in conventional powdered creams are milk fat, coconut oil, palm kernel oil, or their hydrogenated oils, and most of them have melting points above 30°C, and their insolubility in cold water depends on the high melting point of the fats and oils. It was caused by

また、融点の低い液状油としては、大豆油、コーン油な
どが一般的であるが、これらはリノール酸、リルン酸な
どの高度不飽和酸を多く含むものであり、安定性は非常
に悪い。これらの油脂をそのまま用いた粉末クリームは
、冷水に溶ける点では大変良好であるが、風味の劣化が
早く、長期間保存するととはできない。粉末クリームの
生命である風味安定性を高め、長期間保存を可能にする
ためには、安定性の高い油脂の使用が要求される。即ち
、融点が低く、かつ安定性の高い油脂を使用することが
、冷水可溶性粉末クリームの必須条件である。
In addition, soybean oil, corn oil, etc. are commonly used as liquid oils with low melting points, but these oils contain a large amount of highly unsaturated acids such as linoleic acid and lyric acid, and therefore have very poor stability. Powdered creams made using these oils and fats as they are have excellent solubility in cold water, but their flavor deteriorates quickly and cannot be stored for long periods of time. In order to enhance flavor stability, which is the lifeblood of powdered cream, and to enable long-term storage, it is necessary to use highly stable fats and oils. That is, it is essential for cold water-soluble powder creams to use oils and fats that have a low melting point and high stability.

冷水可溶性のある粉末クリームを製造する方法として、
適当な植物性油脂に中鎖トリグリセリドを混合したもの
を利用した特許出願(特開昭50−135254号)が
あるが、中鎖トリグリセリドは、炭素数8を主とした、
いわゆる中級脂肪酸から成る油脂であるため、加水分解
性が強く、また、M劣敗した場合の劣化臭は、高級脂肪
酸で構成される一般植物油に比較してはるかに強いこと
から、粉末クリームを長期間保存した場合の風味の点で
問題があり、また価格の点でも工業的に不利である。
As a method for producing cold water soluble powder cream,
There is a patent application (Japanese Unexamined Patent Publication No. 135254/1989) that utilizes a medium-chain triglyceride mixed with a suitable vegetable oil, but the medium-chain triglyceride mainly has 8 carbon atoms.
Because it is an oil composed of so-called intermediate fatty acids, it is highly hydrolyzable, and the odor of deterioration when M is degraded is much stronger than that of general vegetable oils composed of higher fatty acids, so it is difficult to keep powdered cream for a long time. There is a problem in terms of flavor when stored for a period of time, and it is also disadvantageous industrially in terms of price.

本発明者は、冷水に良好な分散溶解性を示し、長期間保
存しても風味劣化のない粉末クリームを得るために研究
開発を重ねた結果、油脂成分のヨウ素価と融点を特定し
、さらに粉末クリームの粒径を特定することにより、所
期の目的が満たされることを見出し、本発明を完成させ
た。
As a result of repeated research and development in order to obtain a powdered cream that exhibits good dispersion solubility in cold water and does not deteriorate in flavor even when stored for a long period of time, the inventor identified the iodine value and melting point of the oil and fat components, and further By specifying the particle size of the powdered cream, the inventors discovered that the intended purpose could be met and completed the present invention.

すなわち本発明は、粉末クリームにおいて、ヨウ素価8
6〜95、融点20℃以下の植物油を油脂成分とし、粉
末の粒径が150ミクロン以上のものを少くとも80重
41%含有することを特徴とする冷水可溶性粉末クリー
ムを提供するものである。
That is, the present invention provides powdered cream with an iodine value of 8.
To provide a cold water soluble powder cream, which contains vegetable oil having a melting point of 6 to 95°C and a melting point of 20°C or lower as an oil and fat component, and containing at least 80% by weight and 41% of powder having a particle size of 150 microns or more.

本発明に用いる油脂成分は、ヨウ素価および融点が上記
の範囲の植物油でなければならない。
The fat and oil component used in the present invention must be a vegetable oil with an iodine value and melting point within the above range.

植物油のヨウ素価が86未満のものは、安定性は向上し
風味的にも好ましいが、融点が高くなり冷水への分散溶
解性が悪くなり、一方、ヨウ素価が95を越えるものは
、融点が低下し冷水への分散溶解性は良くなるが、リノ
ール酸などの高度不飽和脂肪酸含量が多く安定性が悪く
なシ風味劣化の面で好捷しくない。
Vegetable oils with an iodine value of less than 86 have improved stability and are preferable in flavor, but have a high melting point and poor dispersibility in cold water.On the other hand, vegetable oils with an iodine value of more than 95 have a melting point. Although it improves dispersion solubility in cold water, it is unfavorable in terms of poor stability and deterioration of the flavor due to the high content of highly unsaturated fatty acids such as linoleic acid.

また、融点が20℃を越えるものは冷水溶解性が悪くな
り、ヨウ素価が上記の範囲内のものでも使用できない。
Moreover, those having a melting point exceeding 20°C have poor solubility in cold water, and cannot be used even if their iodine value is within the above range.

本発明において、原料油脂として利用できる植物油は、
例えばナタネ油、大豆油、コーン油、米ヌカ油、ヒマワ
リ油、サフラワー油、ビーナツツ油、小麦胚芽油などの
半乾性植物油があシ、この他にオリーブ油や椿油も利用
できる。
In the present invention, vegetable oils that can be used as raw material fats and oils are:
For example, semi-drying vegetable oils such as rapeseed oil, soybean oil, corn oil, rice bran oil, sunflower oil, safflower oil, peanut oil, and wheat germ oil, as well as olive oil and camellia oil, can also be used.

ナタネ油、大豆油などの半乾性植物油を構成する脂肪酸
は、オレイン酸、リノール酸、リルン酸などの不飽和脂
肪酸が大部分であり、バルミチン酸、ステアリン酸など
の飽和脂肪酸はほぼ重量で15%以下となっている。半
乾性植物油中のリノール酸、リルン酸を選択的に水素添
加してオレイン酸に変換することにょシ、椿油やオリー
ブ油などに近い、低融点で安定性の高い油脂が得られる
。また、水素添加の処理により、飽和脂肪酸が多少生成
し、融点が上昇した場合は、その後、分別処理を行なう
ことにより、融点の高い三飽和酸トリグリセリド、二飽
和酸トリグリセリドを除去すれば、同様に低融点で安定
性の高い油脂が得られる。
The fatty acids that make up semi-drying vegetable oils such as rapeseed oil and soybean oil are mostly unsaturated fatty acids such as oleic acid, linoleic acid, and lylunic acid, and saturated fatty acids such as valmitic acid and stearic acid account for approximately 15% by weight. It is as follows. By selectively hydrogenating linoleic acid and linolenic acid in semi-drying vegetable oils and converting them to oleic acid, a low-melting point, highly stable oil and fat similar to camellia oil and olive oil can be obtained. In addition, if some saturated fatty acids are generated and the melting point increases due to the hydrogenation process, the same effect can be achieved by removing trisaturated acid triglycerides and disaturated acid triglycerides, which have high melting points, by performing a fractionation process afterwards. Obtains highly stable fats and oils with a low melting point.

ル交換反応を行なうことにより、融点が低下する現象が
見られるので、これらの油脂を使用する場合は、水素添
加後、エステル交換反応を行なうのが効果的である。
When these oils and fats are used, it is effective to carry out the transesterification reaction after hydrogenation, since the melting point is lowered by carrying out the transesterification reaction.

本発明においては、上記のような加工処理を施した半乾
性油が、原料入手の面で工業的に有利であるが、低融点
で安定性の高いオリーブ油や椿油をそのまま使用するこ
ともできる。
In the present invention, the semi-drying oil that has been processed as described above is industrially advantageous in terms of raw material availability, but it is also possible to use olive oil or camellia oil as they are, which have a low melting point and high stability.

本発明の粉末クリームは、粉末の粒径がis。The powder cream of the present invention has a powder particle size of IS.

ミクロン以上のものを少くとも80重量%含有するもの
でなければならない。
It must contain at least 80% by weight of microns or larger.

粉末の粒径が150ミクロン未満の微粉末は冷水に加え
ただけでは沈降性が悪く表面に浮いておシ、撹拌すると
ある程度は分散溶解するが「ダマ」ができやすい。これ
は微粉末の場合、粉末クリームが塊になりやすく、内部
に空気を抱き込んでしまうためであシ、充分な分散溶解
性を持たせるためには、沈降性があり塊になりにくいあ
る一定以上の粒径が望ましく、150ミクロン以上の粒
径が必要である。
If a fine powder with a particle size of less than 150 microns is simply added to cold water, it will not settle well and will float on the surface, and when stirred, it will be dispersed and dissolved to some extent, but "clumps" will easily form. This is because powdered cream tends to clump when it is a fine powder and traps air inside.In order to have sufficient dispersion and solubility, it is necessary to have a certain level of sedimentation that prevents clumps from forming. A particle size of 150 microns or more is desirable.

しかしながら、一般に粉末製品の粒径はある分布を持っ
ているので、100ミクロン以上のものが少くとも80
重量%含まれるような粉末クリームは、所望の冷水溶解
性を満足させることができる。
However, the particle size of powdered products generally has a certain distribution, so that those over 100 microns are at least 80 microns in size.
Powder creams such as % by weight can satisfy the desired cold water solubility.

本発明の冷水可溶性粉末クリームは、前記のように特定
した油脂成分と、これに粉末クリームに通常用いる原料
、例えば脱脂粉乳、カゼイン、カゼインナトリウム、乳
糖、砂糖、デキストリン、乳化剤などを適宜配合し、混
合物を乳化、均質化、殺菌後、噴霧乾燥して製造したも
のである。粉末でも1〜3℃の氷水中で速やかに沈降し
て良好な分散溶解性を示し、また長期間保存しても風味
の劣化はなく安定性が優れている。
The cold water-soluble powdered cream of the present invention is prepared by appropriately blending the oil and fat components specified above with raw materials normally used for powdered creams, such as skim milk powder, casein, sodium caseinate, lactose, sugar, dextrin, and emulsifiers. It is produced by emulsifying, homogenizing, and sterilizing a mixture, followed by spray drying. Even as a powder, it quickly settles in ice water at 1 to 3°C, exhibiting good dispersion and solubility, and exhibits excellent stability without deterioration of flavor even after long-term storage.

次に実施例によって本発明を説明する。以下部は重量係
を示す。
Next, the present invention will be explained by examples. The following section shows the weight section.

実施例1 ナタネ油をニッケル触媒を用いてヨウ素価9゜まで選択
的に水素添加した後、ナトリウムメチラートを触媒とし
て、エステル交換反応を行ない、その後、常法によシ精
製、脱臭して融点14℃の油脂ち得た0この油脂4,8
00fにモノグリセリド160?を添加し、乳糖350
0t、粉末コーンシロップ5600f、カゼインナトリ
ウム1300f1蔗糖脂肪酸エステル160tを水29
kI7に溶解したところに混合し、60℃で30分間攪
拌乳化し、150kg/−の圧力で均質化したものを加
熱殺菌してクリーム組成物を得た。
Example 1 After selectively hydrogenating rapeseed oil to an iodine value of 9° using a nickel catalyst, a transesterification reaction was performed using sodium methylate as a catalyst, and the melting point was then purified and deodorized by conventional methods. This oil and fat obtained at 14℃ 4,8
Monoglyceride 160 in 00f? and lactose 350
0t, powdered corn syrup 5600f, sodium caseinate 1300f1 sucrose fatty acid ester 160t water 29
The mixture was mixed with kI7, stirred and emulsified at 60° C. for 30 minutes, homogenized under a pressure of 150 kg/−, and then heat sterilized to obtain a cream composition.

このクリーム組成物を、アトマイザ一式スプレードライ
ヤーを用い熱風温度170℃、排風温度105℃、アト
マイザ−回転数400 Orpmの条件で粉末化し、粒
径150ミクロン以上のもの84チの粉末クリームを得
た。
This cream composition was powdered using an atomizer-equipped spray dryer under the conditions of hot air temperature of 170°C, exhaust air temperature of 105°C, and atomizer rotation speed of 400 rpm to obtain 84 pieces of powdered cream with a particle size of 150 microns or more. .

この粉末クリームは2℃の氷水に良く分散溶解した。ま
た、この粉末クリームを40℃で10チ月間保管しても
風味は良好であった。
This powdered cream was well dispersed and dissolved in ice water at 2°C. Further, even when this powdered cream was stored at 40° C. for 10 months, the flavor remained good.

実施例2 大豆油をヨウ素価86まで水素添加した後、分別を行な
い、ヨウ素価94、融点13℃の油脂を得た。この水素
添加分別大豆油を使用して、実施でいた。
Example 2 After hydrogenating soybean oil to an iodine value of 86, it was fractionated to obtain an oil with an iodine value of 94 and a melting point of 13°C. The experiment was carried out using this hydrogenated fractionated soybean oil.

この粉末クリームは、3℃のアイスコーヒーに良く分散
溶解した。この粉末クリームを40℃で10チ月間保管
しても風味は良好であった。
This powdered cream was well dispersed and dissolved in iced coffee at 3°C. Even when this powdered cream was stored at 40° C. for 10 months, the flavor remained good.

実施例3 コーン油を水素添加して得られたヨウ素価88、融点1
8℃の油脂5ゆに、モノグリセリド2002を添加し、
粉末コーンシロップ8ゆ、乳糖4.4kg、カゼインナ
トリウム1.6kg、蔗糖脂肪酸エステル400?を水
30kl?に溶解したところに混合−ドライヤーを・用
いて、熱風温度160℃、排風温度100℃、アトマイ
ザ−回転数4 s o o rpmの条件で粉末化し、
粒径150ミクロン以上のもの82%の粉末クリームを
得た。
Example 3 Iodine value 88, melting point 1 obtained by hydrogenating corn oil
Monoglyceride 2002 was added to 5 ounces of oil and fat at 8°C,
Powdered corn syrup 8 yu, lactose 4.4 kg, sodium caseinate 1.6 kg, sucrose fatty acid ester 400? 30kl of water? The mixture was pulverized using a mixing dryer under the conditions of a hot air temperature of 160°C, an exhaust air temperature of 100°C, and an atomizer rotation speed of 4 soo rpm.
A powdered cream was obtained in which 82% had a particle size of 150 microns or more.

この粉末クリームは2℃の氷水およびアイスコーヒーの
いずれにも良く分散溶解し、また40℃で10チ月間保
管しても風味は良好であった。
This powdered cream was well dispersed and dissolved in both iced water and iced coffee at 2°C, and had a good flavor even when stored at 40°C for 10 months.

比較例1 コーン油を水素添加した後、分別を行ない、ヨウ素価9
8、融点11℃の油脂を得、これを使用して実施例1と
同様にして粒径150ミクロン以上のもの85チの粉末
クリームを製造した。
Comparative Example 1 After hydrogenating corn oil, it was fractionated and the iodine value was 9.
8. An oil and fat having a melting point of 11° C. was obtained, and using this oil, 85 pieces of powdered cream having a particle size of 150 μm or more were produced in the same manner as in Example 1.

この粉末クリームは2℃の氷水に良く分赦したが、ヨウ
素価が高いので、40℃で保・Rしたところ、5ケ月で
風味が劣化してしまった。
This powdered cream was well soaked in ice water at 2°C, but since it had a high iodine value, the flavor deteriorated after 5 months when it was kept at 40°C.

比較例2 ナタネ油を水素添加して得られたヨウ素価84、融点2
3.5℃の油脂を使用して実施例1と同様にして粒径1
50ミクロン以上のもの86係の粉末クリームを製造し
た。
Comparative Example 2 Iodine value 84, melting point 2 obtained by hydrogenating rapeseed oil
Particle size 1 was obtained in the same manner as in Example 1 using oil at 3.5°C.
86 powdered creams with a diameter of 50 microns or more were manufactured.

この粉末クリームは油脂のヨウ素価が低く融点が高いの
で3℃の氷水に分赦しに<<、(ν拌しても1部表面に
浮いたま\であった。
Since the iodine value of this powdered cream is low and the melting point of the fat is high, it was soaked in ice water at 3°C for some time (ν) Even when it was stirred, a portion remained floating on the surface.

比較例3 実施例1と同様にして得たクリーム組成物を、熱風温度
160℃、排風温度1oo℃、アトマイこの粉末クリー
ムは温水には分散溶解したが、3℃の冷水では微細粒子
が表面に浮いておシ、かなり攪拌しても「ダマ」ができ
完全には分散溶解しなかった。
Comparative Example 3 A cream composition obtained in the same manner as in Example 1 was heated at a hot air temperature of 160°C, an exhaust air temperature of 100°C, and the powdered cream was dispersed and dissolved in hot water, but in cold water of 3°C, the fine particles appeared on the surface. It floated on the surface, and even though I stirred it quite a bit, ``clumps'' formed and it was not completely dispersed and dissolved.

Claims (1)

【特許請求の範囲】[Claims] 粉末クリームにおいて、ヨウ素価86〜95、融点20
℃以下の植物油を油脂成分とし、粉末の粒径が150ミ
クロン以上のものを少くとも80重量饅含有することを
特徴とする冷水可溶性粉末クリーム。
In powder cream, iodine value 86-95, melting point 20
A cold water soluble powder cream, characterized in that it contains at least 80 parts by weight of vegetable oil having a temperature of 150 microns or more and a vegetable oil having a temperature of 150 microns or more.
JP57226681A 1982-12-27 1982-12-27 Powdered cream soluble in cold water Pending JPS59118043A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57226681A JPS59118043A (en) 1982-12-27 1982-12-27 Powdered cream soluble in cold water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57226681A JPS59118043A (en) 1982-12-27 1982-12-27 Powdered cream soluble in cold water

Publications (1)

Publication Number Publication Date
JPS59118043A true JPS59118043A (en) 1984-07-07

Family

ID=16848982

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57226681A Pending JPS59118043A (en) 1982-12-27 1982-12-27 Powdered cream soluble in cold water

Country Status (1)

Country Link
JP (1) JPS59118043A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62239949A (en) * 1986-04-11 1987-10-20 Snow Brand Milk Prod Co Ltd Fat-containing milk powder easily dispersible in cold water
AU650983B2 (en) * 1991-06-14 1994-07-07 Montec International Limited Monounsaturated dairy products
US5580600A (en) * 1991-06-14 1996-12-03 Associated Food Technology Pty, Ltd. Monounsaturated dairy products
WO1998007329A1 (en) * 1996-08-21 1998-02-26 Societe Des Produits Nestle S.A. Cold water soluble creamer
US6589586B2 (en) 1996-08-21 2003-07-08 Nestec S.A. Cold beverage creamer
JP2020018172A (en) * 2018-07-30 2020-02-06 アサヒグループ食品株式会社 Powder creamer and producing method of the same

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62239949A (en) * 1986-04-11 1987-10-20 Snow Brand Milk Prod Co Ltd Fat-containing milk powder easily dispersible in cold water
AU650983B2 (en) * 1991-06-14 1994-07-07 Montec International Limited Monounsaturated dairy products
US5580600A (en) * 1991-06-14 1996-12-03 Associated Food Technology Pty, Ltd. Monounsaturated dairy products
WO1998007329A1 (en) * 1996-08-21 1998-02-26 Societe Des Produits Nestle S.A. Cold water soluble creamer
US6287616B1 (en) 1996-08-21 2001-09-11 Nestec S.A. Cold water soluble creamer
US6589586B2 (en) 1996-08-21 2003-07-08 Nestec S.A. Cold beverage creamer
JP2020018172A (en) * 2018-07-30 2020-02-06 アサヒグループ食品株式会社 Powder creamer and producing method of the same

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