JPS589963A - Production of steel plate applied with metallic plating on one side - Google Patents

Production of steel plate applied with metallic plating on one side

Info

Publication number
JPS589963A
JPS589963A JP10693781A JP10693781A JPS589963A JP S589963 A JPS589963 A JP S589963A JP 10693781 A JP10693781 A JP 10693781A JP 10693781 A JP10693781 A JP 10693781A JP S589963 A JPS589963 A JP S589963A
Authority
JP
Japan
Prior art keywords
steel plate
plate
furnace
plating metal
plating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10693781A
Other languages
Japanese (ja)
Inventor
Tatsuo Nakayama
中山 龍夫
Hidetaro Tanihara
谷原 秀太郎
Toru Akagawa
赤川 融
Satoru Suzuki
了 鈴木
Hiroshi Masuda
博 増田
Kazuo Tagusari
田鎖 和男
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kawatetsu Galvanizing Co Ltd
Original Assignee
Kawatetsu Galvanizing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawatetsu Galvanizing Co Ltd filed Critical Kawatetsu Galvanizing Co Ltd
Priority to JP10693781A priority Critical patent/JPS589963A/en
Publication of JPS589963A publication Critical patent/JPS589963A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C26/00Coating not provided for in groups C23C2/00 - C23C24/00
    • C23C26/02Coating not provided for in groups C23C2/00 - C23C24/00 applying molten material to the substrate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating With Molten Metal (AREA)

Abstract

PURPOSE:To obtain a one side plated steel plate of uniform quality at a low cost with a simple device by bringing plating metal into contact with the steel plate in a solid state, and melting the plating metal by the sensible heat of the steel plate preheated to temps. higher than the m.p. of the plating metal. CONSTITUTION:The atmosphere in a horizontal heating furnace 1 is maintained reducing or neutral by a gaseous mixture of H2 and N2, etc. and the temp. in the furnace 1 is maintained slightly higher than the prescribed preheating temp. of a steel plate (a) to be plated. Near the inlet 2 of the furnace 1, a solid plating metal 4 plate heated to near the melting temp. in a preheating furnace 5 is supplied onto the steel plate (a), and a roll 6 supports the plate (a) below the furnace 5. The plate (a) is fed through the inlet 2 into the furnace 1, and is heated to temps. higher than the m.p. of the plating metal 4 in the atmosphere in the furnace to melt the plate of the plating metal 4 with which it comes in contact on the roll 6, thereby forming the plated surface. The thickness (t) of the plating on the top surface of the plate (a) is controlled by changing the rate of supply of the plating metal 4.

Description

【発明の詳細な説明】 この発明は片面に金属めっきを施した鋼板の製造方法に
関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method of manufacturing a steel plate having one side metal plated.

従来、熔融めっき法、電気めっき法などによって亜鉛、
錫、アルミニウムなどの金属を鋼板に被覆し、耐食性を
向上させることは広く行われている。
Conventionally, zinc,
It is widely practiced to coat steel plates with metals such as tin and aluminum to improve their corrosion resistance.

これらは、普通、鋼板全面を熔融金属浴あるいは電気め
っき浴に浸漬してめっきが行われるので、・鋼板の両面
が被覆される。しかし場合によっては製品の加工性や外
観、経済性などの観点から、必ずしも両面被覆を必費と
せず、むしろ片面のみ被覆するのが好ましいこともある
。特に近年自動車用や尤気器具用の防錆鋼板として、片
面のみに亜鉛などを核種した鋼板の需要が筒まりつつあ
シ、この要望にこたえるため、各種の片面めっき鋼板の
製造方法が提案されている。例えば、両面にめっきした
後片面のめつき層を機械的に除去する方法°があるが、
この方法は製品の品質や作業性に難がある。1だ片面に
めっき阻止剤を塗布してめっきを行った後阻止剤を除去
する方法があるが、この方法はめつき後の阻止剤の除去
が困難であったり、作業性、経陽性に問題があったりす
る。さらに、超音波、電磁力、表面張力効果などを用い
て熔融金属を鋼板の片面のみに接触させる工夫もなされ
ているが、浴表面が汚れたシ、熔融金属の反対面への浸
入を完全に阻止するのが困難であったりする点に問題が
残されており、未だ安定した被覆を得るまで°に至って
いない。
These are usually plated by immersing the entire surface of the steel plate in a molten metal bath or an electroplating bath, so that both sides of the steel plate are coated. However, in some cases, from the viewpoint of product processability, appearance, economic efficiency, etc., it may not be necessary to coat both sides, and it may be preferable to coat only one side. Particularly in recent years, the demand for steel plates containing zinc or other nuclides on only one side has been increasing as rust-proof steel plates for automobiles and appliances, and in order to meet this demand, various methods of manufacturing single-sided plated steel plates have been proposed. ing. For example, there is a method that involves plating both sides and then mechanically removing the plating layer on one side.
This method has problems with product quality and workability. 1. There is a method of applying a plating inhibitor to one side of the plate and removing the inhibitor after plating, but this method makes it difficult to remove the inhibitor after plating and has problems with workability and positive results. There are some. Furthermore, methods have been devised to bring the molten metal into contact with only one side of the steel plate using ultrasonic waves, electromagnetic force, surface tension effects, etc.; Problems remain in that it is sometimes difficult to prevent this, and it has not yet been possible to obtain a stable coating.

この発明はこれらの方法とは根本的に異なる新、 しい
片叫熔融めっき方法を提供するもので、込つき金属を固
体の状態で鋼板基材面に供給し、基材の有する顕熱によ
シ接触部でめっき金属を熔融させると同時にめっきを完
了させるものである。
This invention provides a new hot-dip plating method that is fundamentally different from these methods, in which the embedded metal is supplied in a solid state to the surface of the steel plate base material, and the plating method is applied using the sensible heat of the base material. The plating is completed at the same time as the plating metal is melted at the contact area.

次に、図示した、この発明を実施する一つの装置を説明
して、この発明に係る、片面に金属めっきを施した鋼板
の製造方法を説明すると、図面において1は水平加熱炉
であって、炉内雰囲気は水素、窒素の混合ガスなどで還
元性又は中性に保たれており、炉内温度は被めっき鋼板
aの所定予熱温度より幾分高く保持されており、加熱炉
1の一方に入口2、他方に出口3があり、加熱炉の入口
2近くには、縦に、固体状のめつき金属であるめっき金
属板4の予熱炉5が設けられ、該予熱炉5の下方には被
めっき鋼板aの支持ロール6が回転自在に設けられてい
るものである。
Next, the method for manufacturing a steel plate with metal plating on one side according to the present invention will be explained by explaining one of the illustrated apparatuses for carrying out the present invention. In the drawing, 1 is a horizontal heating furnace, The atmosphere inside the furnace is kept reducing or neutral with a mixed gas of hydrogen and nitrogen, and the temperature inside the furnace is maintained somewhat higher than the predetermined preheating temperature of the steel sheet to be plated. There is an inlet 2 and an outlet 3 on the other side. Near the inlet 2 of the heating furnace, a preheating furnace 5 for a plated metal plate 4, which is a solid plated metal, is installed vertically. Below the preheating furnace 5, a preheating furnace 5 is provided. A support roll 6 for the steel plate a to be plated is rotatably provided.

上記の装置によって実施されるこの発明にかがる方法は
、脱脂、酸洗によって表面を清浄にされた被めっき鋼板
aは、入口2より加熱炉1内に送り込まれ、支持ロール
6上を通って出口3に導かれるが、その間、入口2より
支持ロール6上に来るまでにめっき金属の融点より高い
所定予熱温度になるように加熱され、一方、めっき金属
板4は支持ロール6上の被めっき鋼板aに向って所定の
送シ速度で送られ、予熱炉4内では略、その金属の熔融
温度に近くまで加熱されているので、めっき金属板4と
、該被めっき鋼板aとの接触部は、該めっき金属板4の
融点より高く加熱されている被めっき鋼板aの有する顕
熱によシ熔かされ、直ちに被めっき鋼板aの表面に被覆
される。
In the method according to the present invention, which is carried out by the above-mentioned apparatus, a steel plate a to be plated whose surface has been cleaned by degreasing and pickling is fed into a heating furnace 1 through an inlet 2, and passed over a support roll 6. During this time, the plated metal plate 4 is heated to a predetermined preheating temperature higher than the melting point of the plated metal by the time it reaches the support roll 6 from the inlet 2; The plated steel plate a is fed at a predetermined feeding speed, and is heated in the preheating furnace 4 to approximately the melting temperature of the metal, so that contact between the plated metal plate 4 and the steel plate to be plated is reduced. The portion is melted by the sensible heat of the plated steel plate a, which is heated to a temperature higher than the melting point of the plated metal plate 4, and is immediately coated on the surface of the plated steel plate a.

なお上記のようにめっき金属板4を、予、熱炉5により
該めっき金属の融点近くまで加熱するようにすると、被
めっき鋼板aの予熱温度を幾分低く設定することができ
る。
Note that if the plated metal plate 4 is preheated in the heating furnace 5 to near the melting point of the plated metal as described above, the preheating temperature of the plated steel plate a can be set somewhat lower.

この発明方法において、使用されるめっき金属としては
、亜鉛、錫、アルミニウム、鉛−錫合金、亜鉛−アルミ
合金など、普通熔融めっきが行われている金属ならいず
れでも使用することができる。
In the method of this invention, any metal that is commonly subjected to melt plating, such as zinc, tin, aluminum, lead-tin alloy, zinc-aluminum alloy, etc., can be used as the plating metal.

又上述の実施例ではめっき金属として金属板を用いたが
その形状は、粉末状、箔状、板状などいずれであっても
よいが、特殊な場合を除き、鋼板と同幅の板状で用いる
のが最も好都合である。
In addition, in the above embodiments, a metal plate was used as the plating metal, but the shape may be powder, foil, plate, etc., but except in special cases, it may be in the form of a plate with the same width as the steel plate. It is most convenient to use

又、その際めっきの厚さtは、めっき金属の供給速度、
すなわち鋼板の単位表面積当りのめっき金属の供給量を
変えることにより制御される。
In addition, the thickness t of the plating is determined by the supply rate of the plating metal,
That is, it is controlled by changing the amount of plating metal supplied per unit surface area of the steel plate.

更に又、鋼板の予熱温度は、供給される゛めつき金属に
、それが熔融するのに必要な熱量を与えるのに十分なも
のでなければならないし、この温度はめつき金属の供給
速度(すなわちめっきの厚さ)、めっき金属の比熱、融
解熱、めっき金属の予熱温度、雰囲気温度などによって
決められるが、めっき金属の融点より10’〜100℃
高い温度が選ばれる。
Furthermore, the preheating temperature of the steel sheet must be sufficient to give the supplied plated metal the amount of heat necessary to melt it, and this temperature is dependent on the plated metal feed rate (i.e. It is determined by the plating thickness), the specific heat of the plating metal, the heat of fusion, the preheating temperature of the plating metal, the ambient temperature, etc., but it is 10' to 100°C below the melting point of the plating metal.
A high temperature is chosen.

なお、上述の実施例は被めっき鋼板aが水平に供給され
、めっき金属はめつき金属板4として被めっき鋼板aの
表面に供給されるものを示したが、めっき金属板4は被
めっき鋼板aの下面に供給するようにしてもよく、被め
っき鋼板は縦方向に下方から上方へ、或は上方より下方
に移動させ、その間、めっき金属板を被めっき鋼板aの
側方より供給するようにしてもよい。
In the above embodiment, the steel plate a to be plated is supplied horizontally, and the plating metal is supplied to the surface of the steel plate a to be plated as the plated metal plate 4. Alternatively, the steel plate to be plated may be moved vertically from the bottom to the top, or from the top to the bottom, while the plated metal plate is fed from the side of the plated steel plate a. It's okay.

こめ発明によると品質が一様の片面めっき鋼板を、簡潔
な装置により作業性もよく製造できるので、片面めっき
鋼板を低廉に供給できる。
According to the Kome invention, single-sided plated steel plates of uniform quality can be manufactured with good workability using simple equipment, so single-sided plated steel plates can be supplied at low cost.

次に一実施例を挙げる。Next, an example will be given.

厚さ0.25 龍、@280’mmのコイル状鋼板を脱
脂、酸洗して表面を清浄にし、加熱炉1内は水素30%
、窒素70%の混合ガスで還元性とし、温度Fi、64
0″CK保持し、鋼板aは5 m/min O:)速度
で加熱炉1に通し、亜鉛板と鋼板との接触面で460℃
になるように加熱し、又、亜鉛板3は、厚さ101II
+1幅280uの板状のものを用い、482B/min
の速度で下方に移動させて鋼板表面に供給し、めっき金
属板子熱炉5内は、温度を400℃とし、また雰囲気は
加熱炉1と同じく、水素3゜チ、望素70%の混合ガス
とした所、このようにして製造した片面亜鉛めっき鋼板
は目付量6011/rr?で均一であり裏面への亜鉛の
付着は全くみられなかった≦
A coiled steel plate with a thickness of 0.25 mm and 280 mm is degreased and pickled to clean the surface, and the inside of the heating furnace 1 is heated with 30% hydrogen.
, reduced with a 70% nitrogen gas mixture, temperature Fi, 64
Holding 0''CK, the steel plate a is passed through the heating furnace 1 at a speed of 5 m/min O:), and the contact surface between the zinc plate and the steel plate is heated to 460°C.
Also, the zinc plate 3 has a thickness of 101II
+1 Using a plate shape with a width of 280u, 482B/min
The temperature in the plating metal plate heating furnace 5 was set at 400°C, and the atmosphere was the same as that in the heating furnace 1, with a mixed gas of 3° hydrogen and 70% hydrogen. Therefore, the single-sided galvanized steel sheet manufactured in this way has a basis weight of 6011/rr? It was uniform and no zinc adhesion was observed on the back side.≦

【図面の簡単な説明】[Brief explanation of the drawing]

図面はこの発明にかかる片面に全域めっきを施した鋼板
の製造方法を実施する装置の一例の縦断正面図を示す。 特許出願人 川鉄鋼板株式会社
The drawing shows a longitudinal sectional front view of an example of an apparatus for carrying out the method of manufacturing a steel plate plated on one side over the entire area according to the present invention. Patent applicant Kawatetsu Steel Sheet Co., Ltd.

Claims (1)

【特許請求の範囲】[Claims] めっき金属の融点より高い温度に予め加熱した鋼板の片
面に固体状のめつき金属を供給し、鋼板と、めっき金属
との接触面に於て鋼板から与えられる熱によりめっき金
属を熔融させ、同時に被覆を完了させることを特徴とす
る片面に金属めっきを施しだ鋼板の製造方法。
A solid plating metal is supplied to one side of a steel plate that has been preheated to a temperature higher than the melting point of the plating metal, and the plating metal is melted by the heat given by the steel plate at the contact surface between the steel plate and the plating metal, and at the same time A method for manufacturing a steel plate with metal plating on one side, characterized by completing the coating.
JP10693781A 1981-07-10 1981-07-10 Production of steel plate applied with metallic plating on one side Pending JPS589963A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10693781A JPS589963A (en) 1981-07-10 1981-07-10 Production of steel plate applied with metallic plating on one side

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10693781A JPS589963A (en) 1981-07-10 1981-07-10 Production of steel plate applied with metallic plating on one side

Publications (1)

Publication Number Publication Date
JPS589963A true JPS589963A (en) 1983-01-20

Family

ID=14446297

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10693781A Pending JPS589963A (en) 1981-07-10 1981-07-10 Production of steel plate applied with metallic plating on one side

Country Status (1)

Country Link
JP (1) JPS589963A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0387985A2 (en) * 1989-03-14 1990-09-19 ROLLS-ROYCE plc Improvements in or relating to filament coating
US5020471A (en) * 1988-07-06 1991-06-04 Sharp Kabushiki Kaisha Developing unit

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS453448Y1 (en) * 1966-09-24 1970-02-17

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS453448Y1 (en) * 1966-09-24 1970-02-17

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5020471A (en) * 1988-07-06 1991-06-04 Sharp Kabushiki Kaisha Developing unit
EP0387985A2 (en) * 1989-03-14 1990-09-19 ROLLS-ROYCE plc Improvements in or relating to filament coating

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