JPS5890503A - Herbicidal composition - Google Patents

Herbicidal composition

Info

Publication number
JPS5890503A
JPS5890503A JP18840081A JP18840081A JPS5890503A JP S5890503 A JPS5890503 A JP S5890503A JP 18840081 A JP18840081 A JP 18840081A JP 18840081 A JP18840081 A JP 18840081A JP S5890503 A JPS5890503 A JP S5890503A
Authority
JP
Japan
Prior art keywords
weeds
herbicide
isopropylamino
ethylamino
triazine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP18840081A
Other languages
Japanese (ja)
Inventor
Tetsuo Takematsu
竹松 哲夫
Hiromi Tomioka
富岡 博実
Sadaji Morinaka
森中 定治
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chugai Pharmaceutical Co Ltd
Original Assignee
Chugai Pharmaceutical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chugai Pharmaceutical Co Ltd filed Critical Chugai Pharmaceutical Co Ltd
Priority to JP18840081A priority Critical patent/JPS5890503A/en
Publication of JPS5890503A publication Critical patent/JPS5890503A/en
Pending legal-status Critical Current

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  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PURPOSE:To prepare the titled composition effective to gramineous weeds and broad-leaved weeds, by using a mixture of 2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine and methyl sulfanilylcarbamate as an active component. CONSTITUTION:The objective herbicide contains 2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine and methyl sulfanilylcarbamate as active components. The ratio of the active components is selected according to the time of application, place of application and the growth state of the plant. It is applied in the form of wettable powder, emulsifiable concentrate, etc. by mixing various carriers widely used in the preparation of agricultural chemicals, at a rate of usually 30-1,300g, preferably 60-500g per 10 ares. It can be used in combination with other herbicide, fungicide, etc.

Description

【発明の詳細な説明】 本発明は、雪−タロロ−4−エチルア々ノー6−イツプ
ービルア建ノーL%5− )リアジンC以下「アトラジ
ン」という)とスルファ二呼ルカルパ電ド酸メチル(以
下「アシ纂ラム」という)との温金物を有効成分として
含有する除草用組成物に関するもOで、各種雑草を発芽
前を九は発芽後KwI鎗することを目的としてお)、適
用範謹が広<、*用個値の高い除草剤を提供するもので
ある。
DETAILED DESCRIPTION OF THE INVENTION The present invention discloses the use of lyazine C (hereinafter referred to as "atrazine") and methyl sulfa dicarpate (hereinafter referred to as "atrazine"). Regarding herbicidal compositions containing hot metals as active ingredients, the scope of application is wide. <, *Provides a herbicide with high individual value.

アトツジyは非ホルモン型移行性の除草剤で、あらゆる
−年性雑草に高い殺草力を示す0作物選択性はトウ毫−
謬シは耐性を示す0本剤は同系のシマジンに比べ速効的
であるが、草種によって枯死するのに数週間もかかるこ
とがある。また、発芽前または発芽直後の幼植物に対し
ては非常に効果が高いが成育した雑草、多年生、SS性
の雑草には効果が劣る。
Atotsuji Y is a non-hormonal translocated herbicide that exhibits high herbicidal power against all annual weeds and has zero crop selectivity.
This drug is more quickly effective than the similar simazine, but depending on the grass species, it may take several weeks for the grass to die. In addition, it is very effective against seedlings before or just after germination, but less effective against grown weeds, perennials, and SS weeds.

まえ、一方のアシ轟ツムは酸アミド系化合物で非ホルモ
ン型の吸収移行性除草剤で、雑草の茎葉部から吸収され
て生長点に移行し、細胞分裂を阻害し枯死に至らせる。
On the other hand, Ashidorotsumu is an acid amide compound and non-hormonal translocating herbicide that is absorbed from the foliage of weeds and transferred to the growth points, inhibiting cell division and causing death.

雑草の発生前から生育期に、土壌感層iえは茎葉処理す
ることによりて、広い範囲の雑草に強い殺草力を持つ、
しかし、カヤツリグを科あるいはずクーノウ科の雑草に
は効果が劣る。
By treating the soil sensitive layer with foliage before weed emergence and during the growing season, it has strong herbicidal power against a wide range of weeds.
However, it is less effective against weeds that belong to the Cyperaceae family and not the Cyperaceae family.

本発明者らは、これらの欠点を補足する目的で種々研究
し九結果、アトラジンとアシ轟ツムの混合物を非農耕地
あるい轄畑地で雑草発芽前を友は発芽後生育期に処理す
るととKより、芝生あるいは作物に全く書を与えず優れ
た除草効果をあげることを見出し本発明を完成した。
The inventors of the present invention have carried out various studies aimed at supplementing these drawbacks, and as a result, we have determined that a mixture of atrazine and reeds can be applied to non-agricultural land or cultivated fields before weed germination and during the growing season after germination. K. completed the present invention by discovering that it has an excellent weeding effect without causing any damage to lawns or crops.

本発明の組成物は、相加的効果によ〕イネ科雑草および
広葉雑草いずれKも強い殺草作用を示し、除草する雑草
の種類が拡大したうえに、意外にも相乗的効果の発現が
認められえ、なお、他のトダアジン系薬剤についてもア
シ&う為との混合を検討し九が、効果、実用性の面では
アトラジンとの混合は4h−)とも有用であり九。
The composition of the present invention exhibits a strong herbicidal effect on both grassy weeds and broad-leaved weeds due to the additive effect, expanding the types of weeds that can be weeded, and surprisingly exhibiting a synergistic effect. However, in terms of efficacy and practicality, mixing with atrazine is also useful for other todazine drugs.

すなわち、本発明はアトラジンにアシ為ツムを配合して
なる除草用組成物に関するもので、有効成分の配合にも
とづく相乗的効果により、除草剤としての性能を著しく
改善したことを特徴とする%Oである。ま光、アトラジ
ンおよびアシ為ツムは除草剤としていずれも公知の物質
であるが、これらを配合しえ除草剤の相乗効果の発明は
いずれも新規である。
That is, the present invention relates to a herbicidal composition comprising atrazine and acidum, which is characterized by significantly improved performance as a herbicide due to the synergistic effect based on the combination of active ingredients. It is. Although mako, atrazine, and acitomum are all known substances as herbicides, the invention of the synergistic effect of herbicides when these are combined is new.

本発明の除草用組成物に含有せしめる有効成分の配合割
合は使用時期、使用場所あるいは植物の生育状況に応じ
て任意の割合に配合して使用することができる。
The active ingredients contained in the herbicidal composition of the present invention can be blended in any proportion depending on the time of use, place of use, or growth conditions of plants.

本発明の組成物は、通常10アール当り30〜13GO
f好ましくは60〜500Fの割合で使用するのが適当
であるが、植物の状況により適宜に薬量を調節し得るこ
とはいうまでもない。
The composition of the present invention usually contains 30 to 13 GO per 10 ares.
Although it is appropriate to use preferably at a ratio of 60 to 500 F, it goes without saying that the dosage can be adjusted as appropriate depending on the situation of the plant.

まえ、製剤化に当っては、一般の農薬の調剤に用いられ
る固体、液体の各種担体と混合して、水和剤、乳剤、粉
剤9粒剤等に製造することができる。さらに薬剤に分散
剤、希釈剤、乳化剤、浸透剤、粘結剤等の補助剤を添加
して4よい、tた、使用目的に応じて上記構成盛会を他
の殺草剤、殺−剤、殺曵剤、植物生長調節剤、肥料など
と併用することができる。
For formulation, it can be mixed with various solid and liquid carriers commonly used in the preparation of agricultural chemicals to produce wettable powders, emulsions, powders, etc. Furthermore, auxiliary agents such as dispersants, diluents, emulsifiers, penetrants, and binders may be added to the drug.Depending on the purpose of use, the above components may be combined with other herbicides, curing agents, etc. It can be used in combination with drainage agents, plant growth regulators, fertilizers, etc.

次に実験例を示し、本発明による効果を詳細に説明する
Next, an experimental example will be shown and the effects of the present invention will be explained in detail.

実験例L スズメツヒエがきわめて大型化1株化している宇都宮カ
ントリークラブのコウライシパ地(ラフ)K1区がlm
X1mの試験区を設は友、薬剤は下記実施例1と同様に
して所定の有効成分薬量の水利剤を調整し、(アトラジ
ンおよびアシエラム単用の場合本同様にして製剤化し、
クレーを増減して有効成分濃度を一定にし九、)所定の
薬量となるように水で希釈し200羞/ 10 mの割
合で手動式の噴霧器により散布し九、効果の調査は薬剤
処理後26日目にスズメツヒエの残存生体重量を測定し
対照区と比較した。更にコウライシノ(の薬害について
も観察した。その結果は第3表に示すとお塾である。
Experimental example L The rough K1 section of Utsunomiya Country Club, where the Sparrowfish have grown extremely large and become one stock, is lm.
A test plot of x1m was set up, and the drug was prepared in the same manner as in Example 1 below, with a predetermined amount of active ingredient.
The concentration of the active ingredient was kept constant by increasing or decreasing the amount of clay (9)) It was diluted with water to a predetermined dose and sprayed with a manual sprayer at a rate of 200 μm/10 m (9) The effectiveness was investigated after treatment with the chemical. On the 26th day, the remaining live weight of the Sparrowfly was measured and compared with the control plot. Furthermore, we also observed the chemical damage caused by Kouraishino. The results are shown in Table 3.

なお、得られた結果は下記第1表の数値會使って示し九
ものである。
The results obtained are shown using the numerical values in Table 1 below.

第1表 ま九、薬害について得られた結果は下紀第2表の数値を
使って示し友ものである。
The results obtained for drug damage in Table 1 are shown using the values in Table 2 below.

第2表 第3表 実験例2 幼植物検定器において土耕により食用ビニとメヒシバを
育て、これらが253の草丈のとき、実施例1と同様に
して所定の有効成分薬量の水利剤を調整し、(アトラジ
ンおよびアシ為ラム単用の場合も同様にして製剤化し、
クレーを増減して有効成分濃度を一定にした。)所定の
薬量となるように水で希釈し150 j / 10 m
の割合で噴霧処理した。効果の調査は薬剤処理後12日
目に観察した。その結果は第4表に示すとお参である。
Table 2 Table 3 Experimental Example 2 Grown edible chinensis and crabgrass by soil cultivation in a seedling plant tester, and when these had a plant height of 253 cm, an irrigation agent with a predetermined amount of active ingredient was adjusted in the same manner as in Example 1. (Atrazine and acitameram alone are formulated in the same manner,
The active ingredient concentration was kept constant by increasing or decreasing clay. ) Dilute with water to the specified dose and add 150 j / 10 m
It was sprayed at a ratio of The effectiveness was observed on the 12th day after drug treatment. The results are shown in Table 4.

なお、表中の数値は第1表にしたがう。Note that the numerical values in the table are in accordance with Table 1.

第4表 実験例1 幼植物検定器において土耕によ一シダイプンを育て、草
丈30C1lで6葉期になったとき、実施例1とFjJ
様にして所定の有効成分薬量の水利剤を調整し、(アト
ラジンとアシ為ラム単用の場合も同様にして製剤化し、
クレーを増減して有効成分IIIwILを一定にした。
Table 4 Experimental Example 1 Ichishidaipun was grown by soil cultivation in a seedling plant tester, and when it reached the 6-leaf stage with a plant height of 30C1l, Example 1 and FjJ
Prepare an aquarium with a predetermined amount of active ingredients in the same way (atrazine and acitamerum alone are also formulated in the same way,
The active ingredient IIIwIL was kept constant by increasing or decreasing clay.

vP)所定の薬量となるように水で希釈し150 A 
/ 1 G mの割合で噴霧した。効果の調査は薬剤処
理後20日目に観察し友、その結果は第5表に示すとお
)である、なお、表中の数値は第1表にし九がう。
vP) Dilute with water to the specified dose and use 150 A
/ 1 G m. The effects were investigated on the 20th day after treatment with the drug, and the results are shown in Table 5.The numerical values in the table are the same as those in Table 1.

第5表 実−倒毛 畑地に自然発生したギシギシ、アオビ工、オヒシバ、メ
ヒシバ、ノビエ、オナモミ、ムラサキカタバニに対し、
実施例1と同様にして所定の有効成分薬量の水和剤を調
整し、(アトラジンとアシ為ラム単用の場合も同様にし
て製剤化し、クレーを増減して有効成分濃1ft一定K
l、7’t、)  所定の薬量となるように水で希釈し
1001/10mの割合で茎菜処理を行り九、効果の調
査は薬剤処理後45日目に観察t、友、その結果−は第
6表に示すとお夛である。なお、表中の数値は第1表に
した次に実施例をあげて本発明t−m明する。
Table 5 Fruits - Against the naturally occurring grasshoppers, blueberry grass, blackberry grass, blackberry grass, wild grass, onion fir, and purple oak grass that naturally occur in fallen fields.
A hydrating agent with a predetermined amount of active ingredient was prepared in the same manner as in Example 1 (a formulation using only atrazine and acytameram was prepared in the same manner, and the amount of clay was increased or decreased to maintain a constant concentration of active ingredient of 1 ft.
1, 7't,) Diluted with water to the prescribed dose and treated with stem vegetables at a ratio of 1001/10m9.The effect was investigated by observing on the 45th day after treatment with the drug. The results are shown in Table 6. The numerical values in the table are shown in Table 1, and the present invention will be explained with reference to Examples.

実施例L アトラジン25重量部、アシ為ラム15重量部。Example L 25 parts by weight of atrazine, 15 parts by weight of Ashitaram.

アルキル硫酸エステル塩3重量部、ポリオ中ジエチレン
アルキルアリルエーテル2重量部およびタレ−55重量
部をよく粉砕混合して水和剤を得え。
A wettable powder was obtained by thoroughly grinding and mixing 3 parts by weight of alkyl sulfate, 2 parts by weight of diethylene alkyl allyl ether in polio, and 55 parts by weight of tare.

実施例2 アトラジン125重量部、アシうラムα75重量部、リ
グニンスルホン酸塩2重量部、ベントナイト30重量部
およびタルク66重量部をよく渦合し、水25重量部を
加えて練合し、押出し式造粒機により*膣し粒剤を得え
Example 2 125 parts by weight of atrazine, 75 parts by weight of Acilum α, 2 parts by weight of lignin sulfonate, 30 parts by weight of bentonite and 66 parts by weight of talc were thoroughly mixed, 25 parts by weight of water was added, kneaded, and extruded. Obtain granules by using a type granulator.

出願人  中外製薬株式会社Applicant: Chugai Pharmaceutical Co., Ltd.

Claims (1)

【特許請求の範囲】[Claims] カルバ々ド酸メチルとの混合物を有効成分として含有す
る除草用組成物。
A herbicidal composition containing a mixture with methyl carbamate as an active ingredient.
JP18840081A 1981-11-26 1981-11-26 Herbicidal composition Pending JPS5890503A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP18840081A JPS5890503A (en) 1981-11-26 1981-11-26 Herbicidal composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP18840081A JPS5890503A (en) 1981-11-26 1981-11-26 Herbicidal composition

Publications (1)

Publication Number Publication Date
JPS5890503A true JPS5890503A (en) 1983-05-30

Family

ID=16222973

Family Applications (1)

Application Number Title Priority Date Filing Date
JP18840081A Pending JPS5890503A (en) 1981-11-26 1981-11-26 Herbicidal composition

Country Status (1)

Country Link
JP (1) JPS5890503A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5320423A (en) * 1976-08-05 1978-02-24 May & Baker Ltd Weed killing composition
JPS5598104A (en) * 1979-01-13 1980-07-25 Nissan Chem Ind Ltd Herbicidal composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5320423A (en) * 1976-08-05 1978-02-24 May & Baker Ltd Weed killing composition
JPS5598104A (en) * 1979-01-13 1980-07-25 Nissan Chem Ind Ltd Herbicidal composition

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