JPS5887178A - Chemical crushing agent - Google Patents
Chemical crushing agentInfo
- Publication number
- JPS5887178A JPS5887178A JP18442781A JP18442781A JPS5887178A JP S5887178 A JPS5887178 A JP S5887178A JP 18442781 A JP18442781 A JP 18442781A JP 18442781 A JP18442781 A JP 18442781A JP S5887178 A JPS5887178 A JP S5887178A
- Authority
- JP
- Japan
- Prior art keywords
- cao
- agent
- crushing agent
- chemical crushing
- cacl2
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- Disintegrating Or Milling (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、コンクリート、岩石等を火薬類を使うことな
く安全に且つ、徐々に破壊する化学的破砕剤に関するも
のである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a chemical crushing agent that can safely and gradually destroy concrete, rocks, etc. without using explosives.
従来、土木工事等でコンクリート、岩石等を破壊する場
合には、火薬類による爆発解体又はブレーカ−などによ
る機械的解体が行なわれてきた。Conventionally, when destroying concrete, rocks, etc. during civil engineering work, explosive demolition using explosives or mechanical demolition using breakers or the like has been carried out.
しかしこれらは、騒音、振動、飛石、粉塵、ガス等を発
生し安全、公害面での対策が必要となり都市ビルの破壊
、住宅密集地での工事には不向きとされている。However, these systems generate noise, vibration, flying stones, dust, gas, etc., and require safety and pollution countermeasures, making them unsuitable for destroying urban buildings or for construction in densely populated residential areas.
一方生石灰を主成分として、これらの水和にＪ：る膨張
圧を利用して、コンクリ−１〜、ン′１石等を静的に破
壊しうることは以前より知Ｉうれていたが、生石灰の水
和速度は非常に速く１石灰のスラリーが膨圧する際、破
砕孔よりスラリーが流出１ノ膨張圧が逃げてしまうため
、破砕剤どしてはこのままでは使用できない。On the other hand, it has been known for some time that it is possible to statically destroy concrete stones, etc. by using quicklime as the main component and by utilizing the expansion pressure caused by hydration. The hydration rate of quicklime is very fast, and when the lime slurry expands, the slurry flows out of the crushing holes and the expansion pressure of quicklime escapes, so it cannot be used as a crushing agent as it is.
これを改善覆る方法どじで、破砕孔の間口部を急硬性セ
メン１〜又は器具により塞ぐ方法が提案さねでいるが、
操作がや・）かいで実用的Ｃはない。As a way to improve this problem, a method has been proposed in which the frontage of the fracture hole is closed with rapidly hardening cement or an instrument.
There is no practical C because the operation is difficult.
本発明は、こねらの欠点を改良すべく ？ｉｌｔ究した
結果なされたもので、焼成によって得た主成分組成とじ
Ｔ’ Ｃａ Ｏを３０〜８０ｗｔ％、ＣａＣｌ ２をＣ
ａ Ｏ／Ｃａ Ｃｌ ２の重！ Ｌｔが１−．８０と
なるＪ：うに含み、かつＣａＯがＣａ（’：：ｌ ２と
ＣａＯの複ノーで菫ねれていることを特徴とする化学的
破砕剤をぞの要旨どづるｂのである。Is the present invention intended to improve the drawbacks of konera? This was made as a result of research, and the main component composition obtained by firing is 30 to 80 wt% T'CaO, C
The weight of a O/Ca Cl 2! Lt is 1-. This is a chemical crushing agent characterized by containing 80 J: sea urchins and having Ca('::l2 and CaO mixed together).
すなわち本発明は焼成による主成分がＣａ０（゛、ぞの
ＣａＯがＣａ Ｃ１２−Ｃａ ０１ＣａＣｌ ２・３Ｃ
ａＯのような複塩あるいはこねらの水和物で覆わｔｌ、
ｉ、、−、ｔ）の１．１、ノド川）中１ｑが比較的）
Ｆｉいが膨圧率が人４することの知見に早づいて＜ｉさ
ねたしのである。That is, in the present invention, the main component by firing is Ca0 (゛, the CaO is Ca C12-Ca 01 CaCl 2.3C
tl covered with a double salt such as aO or a hydrate of knead,
1.1 of i,, -, t), 1q of Nodo River) is relatively)
I was quick to discover that the turgor rate was 4 times higher than that of humans.
本発明の破ｆ１１．＋剤の成づ）範囲１１． Ｃａ Ｏ
３０−８５ｗｔ％りｆましくは４５へ・８０ｗ［％であ
るが、Ｃａ□の含イ４甲が３０ ｗ ｔ％禾渦の場合に
−１，１（’； ａ Ｏの６）＋ 甲が１−分に発揮さ
れず、破砕に必要な膨圧１１：が得られ、イ１い。さ’
７）Ｉ；、−８！＋ ｗ １％を越える場合には、１：
’ｉ １．′顕−１贅な膨圧圧増加は認められず、８５
ｗ １％ＪスＦ ’＜” −１分である。Destruction of the present invention f11. + Formation of agent) Range 11. Ca O
30-85wt% or preferably 45 to 80w[%, but if the content of Ca□4A is 30wt%, then -1,1('; 6 of a O) + A is not exerted within 1 minute, and the turgor pressure required for crushing is 11:, which is good. difference'
7) I;, -8! +w If it exceeds 1%, 1:
'i 1. 'No significant increase in turgor pressure was observed, 85
w 1%JsuF'<"-1 minute.
（：ａ （〕ｔｌ ２はＣａ Ｏ，、’Ｃａ Ｃｌ
２の甲吊比で・１、−．８０どなるように含むものであ
り、その比が１．１、り小さい場合には、他の成分との
亜合すあるが、比較的にＣａ○含早が少むくなるため１
分な膨張圧が１ｑられす、また、ＣａＣｌ７）活Ｐ１を
抑えでざる結果どなり、比較的短時間での破砕が行なえ
ず、効果的ではない。また、Ｃａ Ｑ、・ＣａＣ１２の
ｍｆＵ仕が８０を越える場合にＦｊｌ、１−分な水１１
遅延効宋が得られ＜’にい１、ＣａＳＯ４の存在は本川
抑制のイ１用を采し、ぞのｉｔ ｋｌ、’ ２０ｗｔ％
１ス下がなｒましい。(:a (]tl 2 is Ca O,,'Ca Cl
With a suspension ratio of 2, 1, -. 80, and if the ratio is smaller than 1.1, it may be sub-combined with other components, but the Ca○ content will be relatively low, so 1.
In addition, CaCl7) active P1 cannot be suppressed, resulting in a loud explosion, and crushing cannot be performed in a relatively short time, which is not effective. In addition, if the mfU specification of Ca Q, ・CaC12 exceeds 80, Fjl, 1-minute water 11
The delayed effect of Song was obtained and the presence of CaSO4 led to the suppression of the main effect, resulting in an increase of 20 wt%.
1st below is annoying.
化学的破砕剤は所定の組成となるように、生石灰または
炭酸力ルシウ１１を、またはさらに無水石こうを加えて
混合し、８００−．１０００℃にて焼成し、該焼成物を
粉砕りることにより１！７らねろものである。この焼成
濡ｍは８００℃未満では上のな水ｆ［１）イ延効宋が１
０られり“、１０００°Ｃを越えると、特に水和万延効
果が増大することもないため、１０００℃以）での焼成
で十分である。The chemical crushing agent is mixed with quicklime or carbonic acid 11, or anhydrous gypsum to give a predetermined composition. By firing at 1000°C and pulverizing the fired product, it is made into 1!7 grains. This firing temperature is lower than 800℃, and the water f[1] is 1.
If the temperature exceeds 1000°C, the hydration effect does not particularly increase, so firing at a temperature of 1000°C or higher is sufficient.
本発明においては、水和遅延効果及び作ｔｅ１等を考慮
して６秤助剤を添加づることで、４ｊ、り実用的な破砕
剤を盲るものである。具体的な助剤どし乙は、減水剤、
保持剤、硬化始発遅延剤等があり、減水剤を用いること
により操作性が向」−づるｂのであり、この減水剤とし
ては、リグニン系、高級多価アルコールのスルホンＩＩ
ＩＩ塩おＪ：びぞの高縮合化合物系、ポリオール複合体
系、水溶性メラミン樹脂系、β−ｊフタリンスルホン１
１５ ’Ｉ＼ルンリン縮合物系などの各種のしのを用い
ることがひき、添７ＪＩＩ ａとしては０．５〜２５−
ｗ １．”、（＋の範囲が好よ【、い、 ０．！ｉｌ
〜ｌ ｌ （ｉ６木偵Ａ （１ａ減７１＜作用が現われ
ず、２Ｖ１％を越える添加をしくｂ“（の効果は向１シ
ｌｒ ＆’ 、。In the present invention, by adding 6 weighing aids in consideration of the hydration retardation effect and the production te1, etc., 4j is a more practical crushing agent. Specific auxiliary agents include water reducing agents,
There are retaining agents, hardening start retardants, etc., and the use of water reducing agents improves operability.These water reducing agents include lignin-based and higher polyhydric alcohol sulfone II.
II Salt OJ: Bizo's high condensation compound system, polyol composite system, water-soluble melamine resin system, β-j phthaline sulfone 1
It is possible to use various compounds such as 15'I\Runlin condensate type, and the value of Attachment 7JIIa is 0.5 to 25-w1. ”, (+ range is preferable [,i, 0.!il
〜l l(i6木译A(1a 71<effect did not appear, so it is recommended not to add more than 2V1%).
ま１．Ｘ、保持剤どして水硬性ｔｉこう４添加りること
に、Ｊ、す、石こうが速やかに硬化し、破砕剤の！（ｌ
ｊの保１島及び況入水の保１が１に役ｖＩ′″）ｔ）の
である。水硬すノ［石こうの吊１．ｔ ３ｗ１％未満ζ
゛は硬化が不１分て型の保持がでさ４“、あ、［り多部
に４１−ると他成分との兼合もあるが、主成分の出が相
３＝１的（、−少イー−くなるＩＣめ、３０１Ｖ Ｉ％
ｊスＦ’ ４’ｉ！ ａがθｒまし。1. By adding hydraulic titanium as a retention agent, the gypsum hardens quickly and becomes a crushing agent! (l
J's 1st island and the 1st part of the water supply are 1).
゛The curing does not take 1 minute and the mold retention is difficult. 4", ah, [41- in many parts may be combined with other components, but the output of the main component is phase 3 = 1 (, - Low E- IC, 301V I%
jsuF'4'i! a is better than θr.
い。また、水１ｉ１Ｆ ｔ’Ｌｎこ）と］ノで（１、α
−゛１′水行こう、β−半水石こう、■Ｔ１１１無水？
ｉこ、）ｈｐを用いるＪとが出来るが、での水和速度か
らα、β゛１２水にうの使用が好Ｌ（）い、、 ′Ａ：
ＩＬ 、硬化始発’Ｉｔ延剤どしては、り■ン耐、］ハ
ク酎、リンゴ酸、マＩ−Ｉン酸ζりの右はノ１ルボン酸
、砂糖等の多糖類、トリポリリｌυ酸ソーダ、ピロりん
酸ソーダ、りん酸力ルシウｌＸ等のりん酸塩、小つ砂等
の小ウソ化合物、銅化合物、ケイフッ化物、Ｐミノ酸、
たんばく分解物の内にり選択１−、 ｌＪＩ ＴｉＦ
６−
類まＩＬ： １．１混合ｉｉ］能１．Ｔものイｊらば２
種類以」を使用することが出来、その添加早は杼湾竹、
実効を勘案した場合（１，０１・−・０．５Ｎｖ１％の
範囲が好ましい５、
本発明の破砕剤を実際に用いる場合には、破砕剤１００
市品部に水３０へ・４０重畠部を加えスラリー化し被破
砕物に穿孔［−、た孔中に１１人（１、＾′１１置づれ
ば、１、く、徐〕７にＣａＯの水和が進行１ノ硬化膨張
覆ることで被破砕物を無へイノ（態で破砕づる３、実施
例１〜６、比較例１−・２
６０・〜、１（）Ｏ′ｌ−７シーｌの！１石灰に１２１
１化力ルシウノ、〈純厖７：’Ｈ′＋；）及び無水石こ
うをよく混合し、電気炉に（約９００″（ロ、＝Ｃ焼成
し／；：、２時間焼成複電う炉から取り出し、デシリー
ターにて放冷後、粉ｆ、ｌ＋ ｌ、、４０メッシｌ以１
ζ稈度のものをｌｒ／ ｉこ。このＹ）末の大部分は陵
詑、１’ｌに乏しい生石灰とイイっ（（１５つ、表面か
１＝どして□ｉｔ Ｃｌ ２ ・Ｃａ （’）、ＣａＣ
１ｚ ・３（、：；ａＱの複塩で覆われているこ一′さ
Ｔ１１１認１）、、：、、このもの（Ｊ所定の助ハリを
添ＩＪｒ＋ シて、所定量の水に゛Ｃスラリー化し７０
ｘ ７０Ｘ ７（ｔｅｎ：の−１ンイＩリ−１−＋５１
！にあ【Ｊた３０ｃｍφＸ３（ｌｃｎｌ、＋穴（Ｊ充填
し、この結甲を観察した。各々の組成、及び結甲を人に
示η。stomach. In addition, water 1i1F t'Ln) and] no (1, α
-゛1'Let's go to water, β-hemihydrate gypsum, ■T111 anhydrous?
Although it is possible to use J using HP, it is preferable to use α, β゛12 water due to the hydration rate in L(), 'A:
IL, hardening starting agent, rinsing resistance, malic acid, malic acid, and the right side of the hardening agent are norubonic acid, polysaccharides such as sugar, and tripolylylic acid. Soda, sodium pyrophosphate, phosphates such as phosphoric acid lucium
Inner selection of protein decomposition products 1-, lJI TiF
6- Similar IL: 1.1 Mixture ii] Function 1. T-mono Ij Love 2
It is possible to use different types of bamboo, including Shuwan bamboo,
When considering the effectiveness (preferably in the range of 1,01...0.5Nv1%5), when the crushing agent of the present invention is actually used, the crushing agent 100
Add 30 and 40 layers of water to the market part to make a slurry, and drill into the material to be crushed. 3, Examples 1 to 6, Comparative Examples 1--2 60-, 1()O'l-7 Seal of! 121 to 1 lime
Thoroughly mix the 1-chemical power luciuno, 〈Pure 7:'H'+;) and anhydrous gypsum, and fire it in an electric furnace (approximately 900'' (Ro, =C)/;:, for 2 hours from a double electric furnace. Take out and leave to cool in a desiccator, then add powder f, l + l, 40 mesh l or more 1
The one with ζ culm degree is lr/i. Most of this Y
1z ・3 (,:; T111 recognized as being covered with double salt of aQ)... Slurry 70
x 70X 7 (ten: -1 -1 - +51
! The hole was filled with a diameter of 30cmφX3 (lcnl), and the cartilage was observed.The composition of each and the carp were shown to people.
実施例７
実施例４．５および比較例１．２の組成の破砕剤５０ｇ
をそれぞれ水２０（＋にてスラリー化し、内径３ａｍｍ
、深さ７０ｍｍの一シリンダに注入し７．１ｋｇの１
吊をかけ、スラリ一層の上端の目盛よりその体膨張率を
測定した。その結果を図に示す。Example 7 50 g of crushing agent with the composition of Example 4.5 and Comparative Example 1.2
Each was made into a slurry with 20% water (+), and the inner diameter was 3 mm.
, injected into one cylinder with a depth of 70 mm, and 7.1 kg of 1
The slurry was hung, and the coefficient of body expansion was measured from the scale at the top of one layer of slurry. The results are shown in the figure.
図は実施例４．５、比較例１．２の破砕剤を用いた場合
の試験結果を示すグラフである。
特許出願人 セントラル硝子株式会社
代理人 弁理士 小松 秀岳
１０−
０ ４ ８ ＋２ ）６ ２０
２４ ２Ｂ先蟻後、時間 （ｈ【）
手続補正書
昭和５６年１２月１４日
特許庁長官 島田春樹 殿
１、事件の表示
昭和５６年特許願第１８４４２７号
２、発明の名称 化学的破砕剤
３、補正をする者
事件との関係 特許出願人
名称（２２０） ｔントラル硝子株式会社４、代理人
〒１０７（電話５８６−８８５４ ）住所 東京都港区
赤坂４丁目１３番５号赤坂オフィスハイツ
氏名 ＜７８９９）弁理士 小松秀岳
５、補正命令の日付 （自発）
６、補正により増加する発明の数 ０
７、補正の対象
明細書中、特許請求の範囲並びに発明の詳細な説明の欄
８、補正の内容 別紙のとおり
（別紙）
（１）明細書中筒１頁第４行以下の特許請求の範囲の記
載を下記のとおり訂正する。
「２、特許請求の範囲
１、焼成によって得た主成分組成として、ＣａＯを３０
〜８５ｗｔ％、ＣａＣｌ、をＣａ Ｏ／Ｃａ Ｃｌ ２
の手量比が１へ・８０となるように含み、かつ、ＣａＯ
がＣａＣｌ ２とＣａＯの複塩で覆われていることを特
徴とする化学的破砕剤。
２、焼成によって得た主成分にＣａＳＯ４を２０Ｗ［％
以下含む特許請求の範囲第１項記載の化学的破砕剤。
３、助剤としてレメント減水剤が０．５〜２ｗｔ％とな
るように添加されてなる特許請求の範囲第１項又は第２
項記載の化学的破砕剤。
４、助剤である保持剤として、水硬性石膏が３〜３０
Ｗ ｔ％となるように添加されてなる特許請求の範囲第
１項ないし第３項のいずれかに記載の化学的破砕剤。
１−
５、助剤である始発遅延剤として有機カルボン酸、多糖
類、りん酸塩、ホウ素化合物、銅化合物、ケイフッ化物
、アミノ酸、たｌυばく分解物のうちより選択１ノた少
なくとも１種以上が０ 、 （１１〜５ｗｔ％となるよ
うに添加されてなる特許請求の範囲第１項ないし第４項
のいずれかに記載の化学的破砕剤。］
（２）第７頁第３行の（’ ０．５ｗｔ％１を「５Ｗ（
％」とりる。
２−The figure is a graph showing the test results when the crushing agents of Example 4.5 and Comparative Example 1.2 were used. Patent applicant Central Glass Co., Ltd. Agent Patent attorney Hidetake Komatsu 10-0 4 8 +2 ) 6 20
24 2B After the first ant, time (h [) Procedural amendment December 14, 1980 Director General of the Patent Office Haruki Shimada 1, Indication of the case 1984 Patent Application No. 184427 2, Title of the invention Chemical crushing agent 3 , Relationship with the person making the amendment Patent applicant name (220) Ttoral Glass Co., Ltd. 4, Agent
107 (Phone: 586-8854) Address: Akasaka Office Heights, 4-13-5 Akasaka, Minato-ku, Tokyo Name <7899) Patent attorney Hidetake Komatsu 5 Date of amendment order (voluntary) 6. Number of inventions increased by amendment 0 7. In the specification to be amended, scope of claims and detailed description of the invention column 8, contents of the amendment as shown in the attached sheet (Attachment) (1) The patent claims on page 1 of the specification, line 4 and below. The description of the scope will be corrected as follows. "2. Claim 1. The main component composition obtained by firing is 30% CaO.
~85wt%, CaCl, CaO/CaCl2
CaO
is covered with a double salt of CaCl2 and CaO. 2. Add 20W [%] of CaSO4 to the main component obtained by firing.
A chemical crushing agent according to claim 1, which includes: 3. Claim 1 or 2, in which a Lement water reducing agent is added as an auxiliary agent in an amount of 0.5 to 2 wt%.
Chemical disruption agents as described in Section. 4. Hydraulic gypsum is used as an auxiliary retention agent of 3 to 30%
The chemical crushing agent according to any one of claims 1 to 3, wherein the chemical crushing agent is added in an amount of Wt%. 1-5. At least one selected from the group consisting of organic carboxylic acids, polysaccharides, phosphates, boron compounds, copper compounds, silicofluorides, amino acids, and catalytic decomposition products as an auxiliary initial retardant. (Chemical crushing agent according to any one of claims 1 to 4, which is added in an amount of 11 to 5 wt%.) (2) Page 7, line 3 ( '0.5wt%1 to '5W(
%”. 2-
Claims (1)
を３０−８５ｗｔ％、Ｃａ Ｃ＋ ２をＣａｂ、／Ｃ
ａ ＣＩ □の重量比が１〜８ｏどなるように含み、か
つ、ＣａＯがＣａ Ｃｌ ２ど（Ｅ Ｏａ’＞複塩で沼
わ杓Ｃいることを特徴どりる化学的破砕剤。 ２、焼成によ−）て１ｑた主成分にＣａ ３０４を２０
Ｗ１％以下含む特許請求の範囲第１項記載の化学的破砕
剤。 ３、助剤として【？メント減水剤が０．５・−２Ｗ ｔ
％となるＪ：うに添加されてなる特許請求の範囲第１項
又は第２項記載の化学的破砕剤。 ４、助剤である保持剤として、水硬性石膏が３−３−３
ｑ％と４Ｔるように添加されてなる特許請求の範囲第１
項ないし第３慎のいずれかに記載の化学的破砕剤。 ５、助剤である始発遅延剤として有機カルボン酸、多糖
類、りん酸塩、ホウ素化合物、銅化合物、ケイフッ化物
、アミノ酸、たんばく分解物のうちより選択した少なく
とも１種以上が０．０１〜０．５ｗｔ％となるように添
加されてなる特許請求の範囲第１項ないし第４項のいず
れかに記載の化学的破砕剤。[Claims] 1. For firing J:・) (q ↑ component composition C1Ca○
30-85wt%, Ca C+ 2, Cab, /C
A chemical crushing agent characterized by containing a weight ratio of CI □ in the range of 1 to 8 degrees, and containing CaO as Ca Cl 2 (E Oa'> double salt). 2. For calcination. 20% of Ca 304 is added to the main component of 1q
The chemical crushing agent according to claim 1, which contains W1% or less. 3. As an auxiliary agent [? Mento water reducing agent is 0.5・-2Wt
% J: The chemical crushing agent according to claim 1 or 2, which is added to sea urchin. 4. Hydraulic gypsum is used as an auxiliary retention agent in 3-3-3
q% and 4T.
The chemical crushing agent according to any one of Items 1 to 3. 5. At least one selected from organic carboxylic acids, polysaccharides, phosphates, boron compounds, copper compounds, silicofluorides, amino acids, and protein decomposition products as an auxiliary initial retardant with a content of 0.01 to The chemical crushing agent according to any one of claims 1 to 4, which is added in an amount of 0.5 wt%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18442781A JPS5887178A (en) | 1981-11-19 | 1981-11-19 | Chemical crushing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18442781A JPS5887178A (en) | 1981-11-19 | 1981-11-19 | Chemical crushing agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5887178A true JPS5887178A (en) | 1983-05-24 |
Family
ID=16152959
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18442781A Pending JPS5887178A (en) | 1981-11-19 | 1981-11-19 | Chemical crushing agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5887178A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6080663A (en) * | 1983-10-12 | 1985-05-08 | 旭化成株式会社 | Static crushing method and expansible tablet therefor |
-
1981
- 1981-11-19 JP JP18442781A patent/JPS5887178A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6080663A (en) * | 1983-10-12 | 1985-05-08 | 旭化成株式会社 | Static crushing method and expansible tablet therefor |
| JPH0424505B2 (en) * | 1983-10-12 | 1992-04-27 | Asahi Chemical Ind |
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