JPS5863732A - Corrosion-inhibiting foam - Google Patents

Corrosion-inhibiting foam

Info

Publication number
JPS5863732A
JPS5863732A JP56162558A JP16255881A JPS5863732A JP S5863732 A JPS5863732 A JP S5863732A JP 56162558 A JP56162558 A JP 56162558A JP 16255881 A JP16255881 A JP 16255881A JP S5863732 A JPS5863732 A JP S5863732A
Authority
JP
Japan
Prior art keywords
corrosion
foam
synthetic resin
vapor
resin foam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP56162558A
Other languages
Japanese (ja)
Inventor
Tatsuo Fukui
福井 龍雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TACHIBANA KOGYO KK
Original Assignee
TACHIBANA KOGYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TACHIBANA KOGYO KK filed Critical TACHIBANA KOGYO KK
Priority to JP56162558A priority Critical patent/JPS5863732A/en
Publication of JPS5863732A publication Critical patent/JPS5863732A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To provide a corrosion-inhibiting foam having light weight and high durability, formable freely to an arbitrary shape, and usable as various corrosionproof covers, by filling powder of a vapor-phase inhibitor in a synthetic resin foam. CONSTITUTION:The objective corrosion-inhibiting foam is prepared by filling powder of a vapor-phase inhibitor (e.g. ammonium nitrite) in a synthetic resin foam (e.g. styrene resin foam). The amount of the vapor-phase inhibitor is preferably 5-100wt% of the synthetic resin. EFFECT:Cushioning, corrosionproofing, and heat insulation of the packaged product.

Description

【発明の詳細な説明】 この発明は、カメラ等金属製品の梱包防食カバー、金属
等の断熱防食カバー等に利用することので自る気化性防
錆剤を含む防食性発泡体に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an anticorrosive foam containing a volatile rust preventive agent, which can be used as a packaging anticorrosion cover for metal products such as cameras, a heat insulating anticorrosion cover for metals, and the like.

従来、亜硝酸アンモニウム等・の気化性物質がガス化し
て金属表面Ew7に着して該金属表面を電気化学的作用
により防錆するという原理は一毅に知られており、この
ような気化性防錆剤の応用例として、亜硝酸アンモニウ
^の粉末を適宜の接着剤によ)紙に塗着した防食包装用
紙略が提案されて−る。
Conventionally, the principle that vaporizable substances such as ammonium nitrite gasify and adhere to the metal surface Ew7 and prevents the metal surface from rusting by electrochemical action is known to Ikki. As an example of the application of a rust agent, anti-corrosive packaging paper has been proposed in which ammonium nitrite powder is applied to paper using a suitable adhesive.

本発用は、軽量で十分な耐久性を有し、しかも梱包防食
カバー、断熱防食カバー等の任意の形状に自由に形成す
ることがで畠る防食性発泡体t−提供する屯ので、以下
図面を譲照して本発明の詳1mt−説明する。
The present invention provides an anti-corrosive foam that is lightweight, has sufficient durability, and can be freely formed into any shape such as a packing anti-corrosion cover, an insulating anti-corrosion cover, etc. The present invention will be explained in detail with reference to the drawings.

本発明における発泡体としては、ポリスチレンJ、&リ
ウレタン系、塩化ビニル系、ポリエチレン系、シリコン
系等の合成at脂の発泡体がある。
Foams used in the present invention include foams made of synthetic AT resins such as polystyrene J, urethane, vinyl chloride, polyethylene, silicone, and the like.

又、気化性防錆剤には、IMfa#アンモニウム、亜硝
酸ジシクνヘキシルアンモニウム、ji m@ it 
lロヘキシルアンモニウム、亜硝酸イソプ曹ビルアンモ
ニウ^、nii酸ジイソプロピルアンモニウム、亜硝酸
トリエチルアンモニウム等があシ、これら防錆剤のw4
形物が粉末、縫皺等の粉粒体として上記合成111iI
発泡体に包含されている。気化性防錆剤の添加量は用途
に応じ適宜選定されるが、好ましくは発泡すべき合成樹
脂に対し1−100%C重朧比)である。
In addition, volatile rust preventives include IMfa#ammonium, dicyclohexylammonium nitrite, and jim@it.
lhexyl ammonium, isopobyl ammonium nitrite, diisopropylammonium nitrite, triethylammonium nitrite, etc., and these rust preventives W4
The above synthetic 111iI as a powder or granular material with a shape such as a powder or wrinkled material.
Encased in foam. The amount of the volatile rust preventive agent to be added is appropriately selected depending on the application, but it is preferably 1-100% (C weight ratio) based on the synthetic resin to be foamed.

第1図は、ポリスチレン樹脂のビーズにM!IIIIl
lジシク關ヘキシルアンモニウムの粉末jo修(重量比
)を添加混合し、この混合組成物をもって成形INKよ
シ発泡成形してなる梱包防食カバーの身+17と蓋(8
)である。
Figure 1 shows M! on polystyrene resin beads. IIIl
Add and mix hexyl ammonium powder (weight ratio), and use this mixed composition to foam-mold the body + 17 and lid (8
).

上記身il+及びIi (21からなる梱包防食カバー
内に例えばカメラ(G) を収納すると、411脂発泡
体内に包含されて−る気化性防錆剤粉末の気化ガスが梱
包カバー内のカメラの金属表面に吸着して電気化学的に
不動態化した皮膜を形成し、それにより金属表面の腐食
を抑制する。
When a camera (G), for example, is stored in the anti-corrosion packaging cover made of the 411 resin foam, the vaporized gas from the volatile rust preventive powder contained in the 411 resin foam will leak into the metal of the camera inside the packaging cover. It adsorbs to the surface and forms an electrochemically passivated film, thereby inhibiting corrosion of metal surfaces.

第2図は、ポリスチレン樹脂のビーズに亜硝酸シクロヘ
キシルアンモニウムの1粒SOS<重量比)を添加混合
した組成物tもって成形型により発泡成形してなるλつ
割りの半円筒状断熱防食カバー(1a)、(1a)を金
属管ケ)の表iiK被装して互KI!合した例である。
Figure 2 shows a semi-cylindrical heat-insulating and anti-corrosive cover (1a ), (1a) is coated with metal tube (iiK) and mutually KI! This is an example of a combination of

第3(2)は、嬉1図と同様の身(1b)及び蓋(2b
)の表面にアルミ箔、合成樹脂フィル五等の非通気性皮
膜(3b)を設けて、気孔性防錆剤が外部へ散逸するの
t防止するようにしたものである。
The third (2) is the same body (1b) and lid (2b) as in Figure 1.
) is provided with an impermeable film (3b) such as aluminum foil or synthetic resin film (3b) to prevent the porous rust preventive agent from escaping to the outside.

第!I−は、第2図と同様の断熱防食カバー(シ)、(
1G)を金属管に)の表面に被装した後、両力バー(l
a)、(le)の表面に、合成樹脂等非通気性材料から
なる接層テープ(40) を巻きつけて気化性防錆剤が
外部へ散逸するのを防止するようにした例である。
No.! I- is a heat-insulating and anti-corrosion cover (shi) similar to that shown in Fig. 2;
1G) on the surface of the metal tube), then the double force bar (L
This is an example in which a bonding tape (40) made of a non-breathable material such as synthetic resin is wrapped around the surfaces of a) and (le) to prevent the volatile rust preventive agent from escaping to the outside.

この発明の防食性発泡体によれば、これを金属製品の梱
包防食カバー、金属管等の断熱防食カバー等に利用する
と、その合成樹脂発泡体によって金属製品の緩衝保鏝、
金属管等の断熱を行うと共に、合成樹脂発泡体内部に含
まれる気化性防錆剤の粉粒体が徐々に気化してその気化
ガスにより上記金属製品や金属管の腐食を長期間にわた
って防止することができ、しかも本発明発泡体は軽重で
十分な耐久性を有すると共に任意の形状に自由に形成す
ることができるから、各種の防食カバーに利゛用するこ
とがで自る利点を有するのである。
According to the anti-corrosion foam of the present invention, when it is used as a packaging anti-corrosion cover for metal products, a heat-insulating anti-corrosion cover for metal pipes, etc., the synthetic resin foam can provide cushioning protection for metal products,
In addition to insulating metal pipes, etc., the volatile rust preventive powder contained inside the synthetic resin foam gradually vaporizes, and the vaporized gas prevents corrosion of the metal products and metal pipes for a long period of time. In addition, the foam of the present invention is light and heavy, has sufficient durability, and can be freely formed into any shape, so it has its own advantages when used in various anti-corrosion covers. be.

【図面の簡単な説明】[Brief explanation of the drawing]

図面はこの発明の実施例を示し、第1図は梱包防食カバ
ーの断FjiJ図、第2図は管の断熱防食カバーの斜面
図、第3図は梱包防食カバーの他の例の断面図、第4c
図は管の断熱防食カバーの他の例の拡大機Wk向図であ
る。 呂+i:+、’q
The drawings show an embodiment of the present invention, and FIG. 1 is a cross-sectional view of a packing anti-corrosion cover, FIG. 2 is a slope view of a heat-insulating anti-corrosion cover for a pipe, and FIG. 3 is a cross-sectional view of another example of a packing anti-corrosion cover. 4th c
The figure is a view of another example of the heat insulating and anti-corrosion cover for the pipe, facing toward the enlarging machine Wk. Lu+i:+,'q

Claims (1)

【特許請求の範囲】[Claims] 合成樹脂発泡体の内部に気化性防錆剤の粉粒体が包含さ
れた、防食性発泡体。
An anti-corrosion foam that contains powder and granules of a volatile rust preventive agent inside a synthetic resin foam.
JP56162558A 1981-10-12 1981-10-12 Corrosion-inhibiting foam Pending JPS5863732A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56162558A JPS5863732A (en) 1981-10-12 1981-10-12 Corrosion-inhibiting foam

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56162558A JPS5863732A (en) 1981-10-12 1981-10-12 Corrosion-inhibiting foam

Publications (1)

Publication Number Publication Date
JPS5863732A true JPS5863732A (en) 1983-04-15

Family

ID=15756864

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56162558A Pending JPS5863732A (en) 1981-10-12 1981-10-12 Corrosion-inhibiting foam

Country Status (1)

Country Link
JP (1) JPS5863732A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04124971U (en) * 1991-02-28 1992-11-13 島畑三商株式会社 Cushioning material for packaging
EP0842031A1 (en) * 1995-05-24 1998-05-20 Eugene R. Lewis Method of making corrosion-inhibitor-containing foam
US6540959B1 (en) 1998-07-29 2003-04-01 Excor Korrosionsforschung Gmbh Vapor-phase corrosion inhibitors and methods for their production
US6752934B2 (en) 2001-07-30 2004-06-22 Excor Korrosionsforschung Gmbh Vapor-phase corrosion inhibitors and method of preparing same
JP2011246775A (en) * 2010-05-28 2011-12-08 Inoac Tokuzai Kk Rust prevention method for hollow steel material
EP3677706A1 (en) 2019-01-04 2020-07-08 EXCOR Korrosionsforschung GmbH Compositions and method for pre-treating substrates for subsequent fixation of vapor phase corrosion inhibitors

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04124971U (en) * 1991-02-28 1992-11-13 島畑三商株式会社 Cushioning material for packaging
EP0842031A1 (en) * 1995-05-24 1998-05-20 Eugene R. Lewis Method of making corrosion-inhibitor-containing foam
EP0842031A4 (en) * 1995-05-24 1999-11-24 Eugene R Lewis Method of making corrosion-inhibitor-containing foam
US6540959B1 (en) 1998-07-29 2003-04-01 Excor Korrosionsforschung Gmbh Vapor-phase corrosion inhibitors and methods for their production
US6752934B2 (en) 2001-07-30 2004-06-22 Excor Korrosionsforschung Gmbh Vapor-phase corrosion inhibitors and method of preparing same
JP2011246775A (en) * 2010-05-28 2011-12-08 Inoac Tokuzai Kk Rust prevention method for hollow steel material
EP3677706A1 (en) 2019-01-04 2020-07-08 EXCOR Korrosionsforschung GmbH Compositions and method for pre-treating substrates for subsequent fixation of vapor phase corrosion inhibitors
DE102019100123A1 (en) 2019-01-04 2020-07-09 Excor Korrosionsforschung Gmbh Compositions and methods for pretreating substrates for the subsequent fixation of vapor phase corrosion inhibitors
US11827806B2 (en) 2019-01-04 2023-11-28 Excor Korrosionsforschung Gmbh Compositions and methods for pretreating substrates for the subsequent fixing of vapor phase corrosion inhibitors

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