JPS5838219B2 - Method for manufacturing cast steel parts with wear resistance on the surface layer - Google Patents
Method for manufacturing cast steel parts with wear resistance on the surface layerInfo
- Publication number
- JPS5838219B2 JPS5838219B2 JP4061877A JP4061877A JPS5838219B2 JP S5838219 B2 JPS5838219 B2 JP S5838219B2 JP 4061877 A JP4061877 A JP 4061877A JP 4061877 A JP4061877 A JP 4061877A JP S5838219 B2 JPS5838219 B2 JP S5838219B2
- Authority
- JP
- Japan
- Prior art keywords
- cast steel
- mold
- wear
- wear resistance
- surface layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
Description
【発明の詳細な説明】
本発明は内部に靭性を保有し、外表面層に耐摩耗性を具
備した鋳鋼部材の新しい製造方法の提供に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a new method for manufacturing a cast steel member having internal toughness and wear resistance on the outer surface layer.
従来における上述のような鋳鋼部材の製造には、炭化物
系のセラミックスたとえばWC , S i C ,
TiC等、あるいはNi,Cr ,Ni−Cr等の金属
粉末を何らかの粘結剤及び水またはアルコール等の溶媒
と共に混合し砂型の型表面に塗布して後、同鋳型へ鋳鋼
を鋳込み前記セラミックスあるいは金属粉末層を鋳物に
転与一体化させて耐摩耗層を形戒するか、あるいは鋳鋼
品にCrメツキ等のメッキや金属溶剤等による表面処理
を施して硬化層を形戒する方法が採られてきた。Conventionally, in the production of cast steel members as described above, carbide ceramics such as WC, SiC,
After mixing TiC, etc., or metal powder such as Ni, Cr, Ni-Cr, etc. with some kind of binder and a solvent such as water or alcohol and applying it to the surface of a sand mold, cast steel is poured into the same mold to form the ceramic or metal powder. Methods have been adopted to form a wear-resistant layer by transferring and integrating a powder layer to a casting, or to form a hardened layer by plating a cast steel product with Cr plating or surface treatment with a metal solvent, etc. Ta.
しかし前者は砂型に塗布されたコーテング層そのもの\
粒子間結合力並びに砂型への密着力が小さいため、かつ
コーテング層が粘結剤を含んでいるため、溶湯時の高熱
による粘結剤の分解と同分解に伴なうガス発生によって
コーテング層が崩壊し、更に溶湯による洗われを生じて
むらのない耐摩耗合金層を形成することが非常に困難で
あった。However, the former is the coating layer itself applied to the sand mold.
Because the bonding force between particles and the adhesion force to the sand mold are small, and because the coating layer contains a binder, the coating layer will deteriorate due to the decomposition of the binder due to the high heat during molten metal and the generation of gas that accompanies this decomposition. It was extremely difficult to form an even wear-resistant alloy layer because it collapsed and was further washed away by the molten metal.
また後者のメッキによる方法は硬化層が薄くかつ素材の
前処理工程が複雑でコスト高になるのであり、金属溶躬
の場合は適用できる部材の形状が限定されるという問題
点を有しているのである。In addition, the latter method using plating requires a thin hardened layer and a complicated pretreatment process for the material, resulting in high costs, and in the case of metal welding, there is a problem that the shapes of parts to which it can be applied are limited. It is.
本発明は上述のような従来方法の有する欠点問題点を解
決する目的を以ってなされたもので、従ってその特徴と
するところは、鋳型の型表面の所望箇所に自溶性合金等
の耐摩耗効果を有し溶剤可能な金属材料による溶躬被膜
を形成して後、同鋳型に鋳鋼を鋳込むことにより前記溶
躬被膜を鋳鋼品に転写し一体化するようにした点にある
。The present invention has been made with the aim of solving the drawbacks of the conventional methods as described above, and is therefore characterized by the use of a wear-resistant material such as a self-fusing alloy at desired locations on the mold surface of the mold. The present invention is characterized in that after forming a hot melt coating made of an effective and solvent-compatible metal material, cast steel is poured into the same mold, thereby transferring and integrating the hot melt coating onto the cast steel product.
以下本発明を詳述すると、第1図は本発明を説明するた
めの鋳型図であり、本発明では図示のように型表面の所
望箇所2,2.2に耐摩耗効果を有する溶躬可能材料に
よる溶躬被膜3,3,3を形戒した鋳型1に鋳鋼たとえ
ばSC37,SC47等を鋳込むのであり、上記溶剤被
膜3,3.3は鋳込まれた鋳鋼品に転写融着して耐摩耗
層を形成するのである。The present invention will be described in detail below. Fig. 1 is a mold diagram for explaining the present invention. In the present invention, as shown in the figure, it is possible to form a welding mold with a wear-resistant effect at desired locations 2, 2.2 on the mold surface. Cast steel, such as SC37, SC47, etc., is cast into a mold 1 in which a solvent coating 3, 3, 3 of the material is formed, and the solvent coating 3, 3.3 is transferred and fused to the cast steel product. This forms a wear-resistant layer.
つまり本発明は従来の粉末混練物によるコーテング層の
転写に替えて溶剤膜を転写するようにしたのであり、従
って従来のように鋳造時コーテング層が崩壊したり溶湯
による洗われなども起こさないし、膜厚の調整も容易に
できることからメッキ法におけるような耐摩耗層が薄き
に過ぎることもなく、そして溶躬膜形戒が鋳物そのもの
へでなく鋳型へ形戒し転写するものであるから、たとえ
ば曲り穴のような場合でもその表面に耐摩耗層を形戒す
ることが可能であるなど適用形状の制限が殆んどない等
従来方法の欠点問題点を全て解決しているのである。In other words, in the present invention, a solvent film is transferred instead of the conventional transfer of a coating layer using a powder kneaded material, and therefore the coating layer does not collapse during casting or be washed away by molten metal as in the conventional method. Since the film thickness can be easily adjusted, the wear-resistant layer is not too thin as is the case with plating methods, and since the coating film shape is transferred to the mold rather than to the casting itself, for example, Even in the case of curved holes, it is possible to form a wear-resistant layer on the surface of the hole, and there are almost no restrictions on the shape of the hole.This method solves all of the disadvantages of conventional methods.
溶剤金属については溶剤が可能で耐摩耗効果のあるもの
は全て適用できるのであり、たとえば一般に耐摩耗用の
溶剤材料として市販されている自溶性合金を使用して優
れた耐摩耗層を有する製品が得られるのであって以下に
自溶性合金使用の場合をその実施例と共に説明する。As for solvent metals, any material that can be used as a solvent and has a wear-resistant effect can be applied.For example, products with excellent wear-resistant layers using self-fluxing alloys that are generally commercially available as solvent materials for wear resistance are applicable. The case of using a self-fluxing alloy will be explained below along with its examples.
第2図は鋳鋼用フラン砂型の型表面の一部に下表に示す
ような組成の自溶性合金を溶剤し厚さ約0,3rnmの
溶剖被膜を形成して後、同鋳型にSC37を1500℃
で鋳込んだ鋳物の断面の顕微鏡組織写真であり、同断面
において測定した硬さは、溶躬被膜の転写層のほゾ±深
さのところでHV447、2
更に下方でHV 5 3 0を示すところもあったのに
対して鋳鋼材部ではHV 1 2 0前後であった。Figure 2 shows a part of the surface of a flan sand mold for casting steel coated with a self-fusing alloy having the composition shown in the table below to form a dissolution film with a thickness of about 0.3 nm, and then SC37 applied to the same mold. 1500℃
This is a micrograph of a cross section of a casting cast in the same cross section, and the hardness measured on the same cross section is HV447.2 at the depth of the tenon of the transfer layer of the melt coating, and HV5.30 further below. However, in the cast steel part, the HV was around 120.
自溶性合金は上掲のようにNi,Crの他に相当量のB
を含んでおり、Ni,CrはFeとの合金及びCrは更
にCrカーバイドを形成して耐摩耗性を付与しているこ
とはいうまでもないが、前記Bが容躬被膜の転与に際し
て極めて有効に働くのである。As mentioned above, self-fusing alloys contain a considerable amount of B in addition to Ni and Cr.
It goes without saying that Ni and Cr are alloyed with Fe, and Cr further forms Cr carbide to provide wear resistance, but B is extremely important when transferring the surface coating. It works effectively.
すなわち鋳造時溶剤被膜と鋳造材との境界部に濃化され
る酸化物が鋳造材と溶剤被膜との密着を阻害するもので
あるが、前記Bはこれを防止する働きを有しているので
あり、更に生戒するボロン窒化物、ボロン炭化物が硬度
を高めて耐摩耗性付与にも寄与しているのである。In other words, the oxides that are concentrated at the boundary between the solvent coating and the cast material during casting inhibit the adhesion between the casting material and the solvent coating, but B has the function of preventing this. In addition, boron nitride and boron carbide, which are added to the diet, increase hardness and contribute to wear resistance.
溶剤被膜の厚さについては0.05〜1間が好マしい厚
さであり、0.05mm以下では薄きに過ぎて十分な耐
摩耗効果が得られず、1朋以上は実用上無駄でコスト高
を招来して好ましくない。The preferable thickness of the solvent coating is between 0.05 and 1 mm. If it is less than 0.05 mm, it is too thin and sufficient wear resistance effect cannot be obtained, and if it is more than 1 mm, it is practically useless and costly. I don't like it because it causes high temperatures.
鋳込温度は溶剤被膜転与に影響するところ大なる要素で
ある。The casting temperature is a major factor that affects the transfer of the solvent film.
すなわち高過ぎると溶躬被膜が被転与材中へ拡散し、低
過ぎると溶湯の流動性の低下及び凝固速度の増大によっ
て十分な転写が行えないのであって、1500〜16
2 0 ’Cで好結果ヲ得てお代この範囲の鋳込みでは
前記溶剤被膜を3闘厚以上の鋳物へ良好な状態で転与す
ることが可能であり、被転与部材の厚さとしては3〜5
0間が好ましい範囲である。In other words, if it is too high, the molten film will diffuse into the material to be transferred, and if it is too low, sufficient transfer will not be possible due to a decrease in the fluidity of the molten metal and an increase in the solidification rate.
Good results were obtained at 20'C, and in casting within this range, it is possible to transfer the solvent coating in good condition to castings with a thickness of 3 or more, and the thickness of the member to be transferred is 3-5
The preferred range is between 0 and 0.
以上自溶性合金の場合について述べたが、本発明は上記
合金に限られるべきでなく耐摩耗効果のある溶躬可能金
属材料であれば適用できることはいうまでもない。Although the case of self-fusing alloys has been described above, it goes without saying that the present invention is not limited to the above-mentioned alloys, and can be applied to any metal material that has a wear-resistant effect and can be melted.
また鋳型も上例のフラン砂型の他にCO2型、自硬性砂
型等の砂型は勿論、金型、ダライ粉型等鋳鋼用として使
用できる鋳型は当然本発明においても適用できる。In addition to the above-mentioned furan sand mold, any mold that can be used for casting steel, such as a CO2 mold or a self-hardening sand mold, as well as a metal mold or a dry powder mold, can of course be used in the present invention.
本発明は以上の通りであって、既に述べたように耐摩耗
効果のある金属材料を鋳型へ溶躬しそれを鋳物へ転与し
耐摩耗層を形成するようにしたことによって、従来方法
の有する欠点、問題点を解消しており、表面に耐摩耗性
を具備した鋳鋼部材の製造方法としては極めて優れた方
法であって、スラリーポンプのケーシング等鋳放しのま
\で使用でき、かつ耐摩耗性及び低コストを要求される
ような部材の製造には極めて好適であり本発明の工業的
価値は著犬である。The present invention is as described above, and by melting a metal material with a wear-resistant effect into a mold and transferring it to a casting to form a wear-resistant layer, it is possible to eliminate the conventional method. It is an extremely excellent method for manufacturing cast steel parts with wear-resistant surfaces, and can be used as-cast, such as in slurry pump casings, and has high durability. The present invention is extremely suitable for manufacturing parts that require wear resistance and low cost, and the industrial value of the present invention is significant.
第1図は本発明するための鋳型図であり、第2図は本発
明1実施例鋳物の断面の顕微鏡組織写真である。
1・・・・・・鋳型、2・・・・・・型表面における所
望箇所、3・・・・・・溶躬被膜。FIG. 1 is a diagram of a mold for the present invention, and FIG. 2 is a micrograph of a cross-sectional microstructure of a casting according to a first embodiment of the present invention. 1...mold, 2... desired location on the mold surface, 3... melt coating.
Claims (1)
果を有し溶剤可能な金属材料による溶剤被膜を形威して
後、同鋳型に鋳鋼を鋳込むことにより前記溶剤被膜を鋳
鋼品に転写し一体化することを特徴とする表面層に耐摩
耗性を具備した鋳鋼部材の製造方法。1. After applying a solvent coating made of a wear-resistant and solvent-resistant metal material such as a self-fusing alloy to a desired location on the mold surface of a mold, cast steel is poured into the same mold to apply the solvent coating to a cast steel product. A method for manufacturing a cast steel member having a wear-resistant surface layer, the method comprising: transferring and integrating a cast steel member with a surface layer having wear resistance.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4061877A JPS5838219B2 (en) | 1977-04-07 | 1977-04-07 | Method for manufacturing cast steel parts with wear resistance on the surface layer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4061877A JPS5838219B2 (en) | 1977-04-07 | 1977-04-07 | Method for manufacturing cast steel parts with wear resistance on the surface layer |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS53125236A JPS53125236A (en) | 1978-11-01 |
JPS5838219B2 true JPS5838219B2 (en) | 1983-08-22 |
Family
ID=12585507
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP4061877A Expired JPS5838219B2 (en) | 1977-04-07 | 1977-04-07 | Method for manufacturing cast steel parts with wear resistance on the surface layer |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5838219B2 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6017397B2 (en) * | 1979-12-05 | 1985-05-02 | ソニー株式会社 | Flame retardant adhesive composition |
JPS61165263A (en) * | 1986-01-14 | 1986-07-25 | Sakae Kitsuta | Production of mechanical parts provided with wear resistant sliding surface |
JPH01180771A (en) * | 1987-12-28 | 1989-07-18 | Masuzo Hamamura | Iron casting formed different kind of metal film and production thereof |
US7028744B2 (en) * | 2004-03-17 | 2006-04-18 | National Research Council Of Canada | Surface modification of castings |
JP2009174014A (en) * | 2008-01-25 | 2009-08-06 | Tzu-Wen Sung | Method of forming surface layer on substrate |
-
1977
- 1977-04-07 JP JP4061877A patent/JPS5838219B2/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
JPS53125236A (en) | 1978-11-01 |
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