JPS5831178A - Wall lining material or ceiling lining material - Google Patents

Wall lining material or ceiling lining material

Info

Publication number
JPS5831178A
JPS5831178A JP57124542A JP12454282A JPS5831178A JP S5831178 A JPS5831178 A JP S5831178A JP 57124542 A JP57124542 A JP 57124542A JP 12454282 A JP12454282 A JP 12454282A JP S5831178 A JPS5831178 A JP S5831178A
Authority
JP
Japan
Prior art keywords
film
covering material
ceiling
wall
perforations
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP57124542A
Other languages
Japanese (ja)
Inventor
ジヨン・ブライアン・ジヤツクソン
ピ−タ−・ケイス・タ−ナ−
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Publication of JPS5831178A publication Critical patent/JPS5831178A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B26HAND CUTTING TOOLS; CUTTING; SEVERING
    • B26FPERFORATING; PUNCHING; CUTTING-OUT; STAMPING-OUT; SEVERING BY MEANS OTHER THAN CUTTING
    • B26F1/00Perforating; Punching; Cutting-out; Stamping-out; Apparatus therefor
    • B26F1/24Perforating by needles or pins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/56After-treatment of articles, e.g. for altering the shape
    • B29C44/5627After-treatment of articles, e.g. for altering the shape by mechanical deformation, e.g. crushing, embossing, stretching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C7/00Paperhanging
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Forests & Forestry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Laminated Bodies (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
  • Registering Or Overturning Sheets (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 本発明F:Iポリオレフィンの発泡フィルムより本Tf
的になる型式のQ装利又は天井張り((に関する。
DETAILED DESCRIPTION OF THE INVENTION Invention F: I From a foamed film of polyolefin, this Tf
Q-type or ceiling covering ((related to).

壁装材又は天井張り材(以下ではJ1弓ζ「1(し装材
」と記載する)用の基材としてポリオレフィンノ14に
ポリエチレンの発泡フィルムを用いることは、例えば英
国特許第1 、220 i 053−号及び第1.30
6.573号明細JJ1:及び欧州特Wf公告第[1,
[1[]1,807月明細書に既に提案されている。更
にt二[、欧州特W1公告第0.001,807刊明細
引°は、棒性基含有エチレン共重合体を少)11′配合
した低密度1】?リエチレンの発泡フィルムから訪’z
51. l、たJli装材を記載しており、該フオーム
を構成する気泡杭J特徴として実質的に全て独立してい
る。か\る壁装材V1、とりわけ耐暦耗性及び印刷適性
に関して利点をイイすると述べられている。しかしなが
ら実際の経験が示す処によれば、独立気泡のポリエチレ
ンフオーム4q7装材け、これらを壁紙張り「1的に通
常用いる1111 !l’Aの水性接着剤で壁表面に塗
着させた直後にフクレを生じ易く、これは壁装材と壁表
面との間の接着力が吹抜に局部的に失われることによる
ものである。
The use of a polyethylene foam film as a polyolefin material 14 as a base material for wall covering material or ceiling covering material (hereinafter referred to as J1 bow ζ "1") is disclosed in, for example, British Patent No. 1, 220 i. No. 053- and No. 1.30
6.573 Specification JJ1: and European Special Wf Publication No. [1,
[1[] Already proposed in the July 1,800 specification. In addition, t2[, European Patent Publication No. 0.001,807 Specification is low density 1] which contains a small amount of rod group-containing ethylene copolymer) 11'? From polyethylene foam film
51. 1 and 2 are described, and the cellular piles forming the form are substantially all independent. The wall covering V1 is said to have advantages, inter alia with regard to its resistance to abrasion and its printability. However, practical experience has shown that closed-cell polyethylene foam 4Q7 coverings can be applied to wallpaper immediately after being applied to the wall surface with the commonly used 1111!l'A water-based adhesive. Blisters are likely to occur, and this is due to localized loss of adhesion between the wall covering material and the wall surface in the atrium.

坏’/+1.明者が今般見出した所によればこの欠点は
、発泡フィルムのDiさに亘って伸びしかも該フィルム
の全表面に分布した穿孔を設けることにより克服しII
る。
坏'/+1. The present inventors have now discovered that this drawback can be overcome by providing perforations that extend over the Di of the foamed film and are distributed over the entire surface of the film.
Ru.

本発明によると、熱可塑性ポリオレフィンから形成した
発泡フィルム、1:りなる壁装材又は天井張す旧であっ
て該フオームの気泡が実質的に全て独立気泡型でありそ
の密度が0.05〜0.5 V/πの範囲にある壁装材
又は天井張υ材において、前記フ・1ルノ、は多数の穿
孔を備えており該穿孔の各々はフィルムの全厚を通して
伸びており、しかもフィルJ、表面の1on’毎にか\
る穿孔を平均して1〜30個与えZ)ように該穿孔がフ
ィルムの表面上に分布していることを性徴とする壁装材
又は天井張り材が提供される。
According to the present invention, a foamed film formed from a thermoplastic polyolefin is used for wall covering or ceiling covering, wherein substantially all the cells in the foam are of the closed cell type and the density thereof is from 0.05 to 0.05. In wall coverings or ceiling coverings in the range of 0.5 V/π, the film is provided with a number of perforations, each of which extends through the entire thickness of the film, and which extends through the entire thickness of the film. J, every 1on' on the surface?
There is provided a wall or ceiling covering material whose characteristic is that the perforations are distributed on the surface of the film in such a manner that the film has an average of 1 to 30 perforations.

41′;泡フィルムは、エチレン(高密度又は低密1ω
、プロピレン、ブテン−1及び4−メチル−はンテシー
1の11(合体及び共重合体を含めて何れかの熱可塑性
ポリオレフィンから形成し得る。l[!1に適当す発泡
フイルノ・は、全体がエチレンホモ〕「合体力ら誘導さ
れたフィルムあるいは共重合体の全fiL141の一部
例え610〜70チで[)1f配した他のオレフィンの
1つ以上と混合してエチレンから誘導した共重合体から
11+られるフィルムである。エチレンのか\る重合体
又は共j(f合体と、発泡フィルムの全1(匍′のうち
の小計例えば4〜20チの異なる重合体又は共i1r合
体イタ11えばエナ1/ンと1v1酸ビニルとの共tl
r合体とのブレンドゞから形成した発泡フィルムもまた
適当なフィルムとして包槍される。
41'; Foam film is made of ethylene (high density or low density 1ω
, propylene, butene-1 and 4-methyl- may be formed from any thermoplastic polyolefin, including polymers and copolymers. Ethylene homo] "A copolymer derived from ethylene mixed with one or more other olefins with a part of the total fiL141 of the film or copolymer derived from the coalescence force, e.g. 610 to 70[)1f" It is a film consisting of 11+ of different polymers or co-j(f) of ethylene and a subtotal of the total 1(4') of the foamed film, e.g. Co-tl of 1/n and 1v1 vinyl acid
Foamed films formed from blends with r-coalesce may also be packaged as suitable films.

前記の発泡フィルムは技術的に既知の方法の何れかによ
って製造畜れる0これらの方法は一般に高圧帯域かC〕
低王帯域に浴11連J); 7.ilの111合体又打
l −1ff合体ブレンドを押出すことを伴ない、適当
ケ発泡剤を押出成形前の111[合体月11に均一に入
り人するものである。前u14の発泡剤は、押出の渦1
([で生起する化学分解の結果としてガスを411生ず
るI4IIJ質例えはアゾジカルボンアミド又はクエン
酸と1」」炭酸すトリウムとの混合物であることができ
、あるいは押出条件下で重合体と混オ゛[1件の化学的
に不活性な液体であって前記の低圧下で押出温度よシも
少くとも1(1’c低い温度で沸1ffPする化学的に
不活性な液(Cであることができ;か\る適当な液体に
ははンタン、ヘギザン及び仙の石油留分、二塩化メチ1
/ン及び1.1.2− トリクロロ−1,2,2−)リ
フルオロエクンがある。発泡剤の割合は通常重合体又k
l: il(合体ブレンドの7II:計の5〜15チの
範囲に在り、用いる特定の割合はフオームが有するのが
望ましい密度に応じて決せる。不活性液体の発泡剤’5
7 Jllいる場合には、押出成形すべき材料中に少量
の成核i’+lIを有利に導入することができ、これに
よって(44られるフオームの気泡構造の均一性を促進
式ぜl!% 2b ;か\る成核剤は既述した種類の熱
分解性物質であり1!〕るか又は押出温間よりも低い限
界温)Wを有する化学的に不活性な化合物、例えば窒1
ガスであり得る。押出は管状押出し物を製造するために
]ζI状ダイを通して行いIGるのが有利であり、次い
で押出し物を膨張さぜ、扁平にし且つ切開して平411
なフィルムを形成すZ+ 6押出し成形される重合体旧
料口七の重セ1の5〜20係の不透明剤、す↓に詳しく
貫え&f二酸化チクン2炭酩カルシウム又は硫酸Izリ
ウムの如き高ンノリ1ゑ力の顔料を配合しているのが好
オしい。
The above-described foamed films may be manufactured by any of the methods known in the art; these methods are generally high pressure zone.
11 consecutive baths in the low band J); 7. The 111 coalescence of the il is accompanied by extrusion of the 1-1ff coalescence blend, in which a suitable blowing agent is uniformly introduced into the 111 [coalescence month 11] before extrusion. The foaming agent in front u14 is extrusion vortex 1
(I4IIJ examples that produce gases as a result of the chemical decomposition that occurs at゛[a chemically inert liquid (C) which has a boiling point of 1 ffP at extrusion temperature at least 1 (1'C) under the above-mentioned low pressure; Suitable liquids include Hantan, Hegizan and Xian petroleum distillates, Methyl dichloride 1
/n and 1.1.2-trichloro-1,2,2-)lifluoroecne. The proportion of blowing agent is usually polymer or
l: il (7II of the combined blend: ranges from 5 to 15 total; the specific proportions used will depend on the desired density of the foam; inert liquid blowing agent '5)
7 Jll, it is possible to advantageously introduce a small amount of nucleating i'+lI into the material to be extruded, thereby promoting the homogeneity of the cell structure of the foam (44)% 2b The nucleating agent is a thermally decomposable substance of the kind already mentioned;
It can be gas. Extrusion is advantageously carried out through a ζI-shaped die to produce tubular extrudates, and the extrudate is then expanded, flattened and cut into flat 411
Z+ 6 extruded polymers 1. 5 to 20 opacifying agents, ↓ detail &f. It is preferable that it contains pigments with a strength of 1.

発泡フィルムの独立気泡は(1,r)1〜1鶴の範囲の
平均直径をイーするのがAIましい。
It is preferable that the closed cells of the foamed film have an average diameter in the range of (1,r)1 to 1.

押出成形後の発Qjlンイルノ、Ll所(イアならば既
知の表面処理をMnすことができ; ltj、にコrJ
す放電処理を施すことができ、これに、しってフィルム
の印刷適(テ1”を向上さぜ1qる0か\Z)槽重db
・−共相の夕1表rTh即ち装飾面を形成しようとする
フ・fルムの表面に限定しく支)るが、別法として壁面
に結合でれる別の表1a1をも包含してその接着4)性
を向上さぜiける。
After extrusion, known surface treatments can be applied;
It can be subjected to electrical discharge treatment, which improves the printing suitability of the film.
・-Limited support to the surface of the film on which a decorative surface is to be formed, but also covers and adheres to another surface, which can alternatively be joined to a wall surface. 4) Improve your sexuality.

壁装材の装ずイ1百f++けフレキソ印刷、クラビア印
刷。
Wall covering materials include 100F++ flexo printing and Clavia printing.

スクリーン印刷又は平版、印刷法の如き悄111技術の
何れかによって適当な模様に印刷し?与る。
Print the appropriate pattern by any of the 111 techniques such as screen printing or lithographic printing method? give

発泡フィルムを印刷しようとする代りに又1すの印刷に
加えて、発泡フィルムは適当な1年起模様fc Kf 
する硬υ1エンボスロールとバックアップロールとの間
のニップに既知の要領で通送させることにJ:リエンボ
ス加工でき、前記の72ツクアツプロールは、弾性を有
しておシしかもエンボスロールと接触回転することによ
シ対応のくほんだエンボス模様を押印するバックアップ
ロールであるか又は硬質であって対応のくぼんだ模様を
彫刻するバックアップロールである0 発泡フィルムは押出直後に0.2〜1・mrxよυ好ま
l〜くけ0.3〜r3.6tnmの範囲の厚さを有する
のが好ましい。フィルムを続いてエンボス加工する場合
にVl、エンボス加工法によって圧縮される領域でvj
その厚さを元のエンボス加工されなかった厚さの50チ
〜75チの値にまで減少させ得る。
Instead of trying to print the foam film, in addition to printing one square, the foam film can also be printed with any suitable annual pattern fc Kf
The re-emboss process can be carried out by passing it through the nip between the hard υ1 embossing roll and the backup roll in a known manner. It is a backup roll that stamps a corresponding concave embossed pattern, or a hard backup roll that engraves a corresponding concave pattern. It is preferable to have a thickness in the range of 0.3 to 3.6 tnm. Vl when the film is subsequently embossed, vj in the area compressed by the embossing method.
The thickness may be reduced to a value between 50 and 75 inches of the original unembossed thickness.

発泡フィルムが備えている穿孔は好ましくは!1.05
龍〜[]、5mm範囲の直径を有する。所望ならtj穿
孔dフィルλの表面に関l−で規則正しい幾何学的配列
で例えば四角の格子模様で設けられるが、壁装材の最終
的な見ばえを落さないためには穿孔は表面上に不均一に
分布しであるのが好ましい。
Preferably the foam film has perforations! 1.05
Dragon to [ ], with a diameter in the 5 mm range. If desired, the perforations can be provided in a regular geometrical arrangement with respect to the surface of the fill λ, e.g. Preferably, it is distributed non-uniformly on the top.

フィルム表面の1 cm2毎に平均して1〜25個の穿
孔があるのが好ましい。
Preferably, there is an average of 1 to 25 perforations per cm2 of the film surface.

前記の穿孔は、適当な直径と間隔どをイJすZ+ :r
v岐の突起個所又d針状部に一ドル)を表面に担持する
硬γFロールと、弾性のあるバックアップロール例えば
フェルトから作られるロール又はフェルトで波切したロ
ール(こ)1によってニードル4一完全にフィルムに通
送させる)との間のニップに発泡フィルムを>III 
;ii4させることに。しり発泡フィルムに容易に形成
し1;する。均せいのとれた穿孔よりもむしろフィルム
の引裂き傾向を最低とするようにニードルはロール表面
について放射状に配置庁し′〔あるのが好ましい。穿孔
操作&lk都合によって、発泡フィルムの印frill
前に、印刷と′−p ′hq的に同時K、又は印刷後に
行い得る。しかしy(がら、〕・fルムをエンボス加工
しようとする場合にを」、このエンボス加工操作は穿孔
後に行うのが好捷しい。何故ならばエンボス加工によっ
て生起されるフィルムの変形は穿孔模様の見かけの規則
性を有用に隠し得るからである。穿孔は、壁装材の印刷
及びエンボス加工で慣用である速度で即ち20〜2QQ
y+a/分の範囲の速度で連続的に移動するフィルム上
で通常満足に行い得るので、全てのこれらの操作はフィ
ルム材料を1回進行させるだけで都合良く行い得る。
The above-mentioned perforations should be made with appropriate diameter and spacing.
The needle 4 is completely rolled by a hard γF roll that supports the protruding portion of the V-branch or the needle-like portion d on its surface, and an elastic backup roll such as a roll made of felt or a roll cut with corrugated felt. Place the foam film in the nip between the
;ii I decided to make it 4. Easily formed into a foamed film. Rather than uniform perforations, the needles are preferably arranged radially about the roll surface to minimize the tendency to tear the film. Perforation operation & stamping of foam film according to convenience
It can be done before, simultaneously K with printing, or after printing. However, when attempting to emboss a film, it is preferable to carry out this embossing operation after perforation, since the deformation of the film caused by embossing will result in a change in the perforation pattern. The perforations are carried out at a speed customary for printing and embossing wall coverings, i.e. from 20 to 2 QQ.
All these operations can be carried out conveniently with only one advance of the film material, since they can usually be carried out satisfactorily on a continuously moving film at a speed in the range of y+a/min.

本発明の穿孔した独立気泡壁装材は、水性接着剤を用い
て壁面に塗着した直後にフクレを形成するという未変性
独立気泡壁装材の前記欠点を克服するか又は最小にする
。本発明の壁装材はまた、湿気が壁面中でその進路を見
出して壁装材を通って大気に湿気を逃出させ得る点で未
変性の壁装材と比較するとより長期の利点を有する。
The perforated closed cell wall coverings of the present invention overcome or minimize the aforementioned drawbacks of unmodified closed cell wall coverings of forming blisters immediately after being applied to a wall using a water-based adhesive. The wall coverings of the present invention also have longer term advantages compared to unmodified wall coverings in that moisture can find its way within the wall surface and allow moisture to escape through the wall covering to the atmosphere. .

本発明の壁装材は、穿孔前の同じ材料について15〜2
1 S’ / m2/24時間の水蒸気透過度と比較す
る々、1050〜1890 f/m2/24時間の範囲
の水蒸気透過度を一般に示す。穿孔材料の気孔率は通常
0.3〜3.5 ノ/分/ 100 tyn2/水頭備
の範囲である。
The wall covering of the present invention has a 15 to 2
They generally exhibit water vapor permeability in the range of 1050-1890 f/m2/24 hours, compared to a water vapor permeability of 1 S'/m2/24 hours. The porosity of the perforated material is usually in the range of 0.3 to 3.5 mm/min/100 tyn2/head.

本発明を次の実施例によシ説明するが、これに限定され
るものではない0 実施例 添附図面を参照しながら説明するに、96〜97%ポリ
エチレンと4〜6チのエチレン/酢酸ビニル共重合体と
のブレンドがらなり0.38+uの厚さと0.261f
/lr:tD密度と0.03〜0.3 tnm (D範
囲の気泡寸法とを有する独立気泡グー、泡フィルム1を
、フェルトで抜枠した鋼製バックアップロール2と表面
に放射状に配置したニードル4を多数有する硬質ロール
3との間のニップに通送する。ニードルの各々は長さ6
寵であり、ニードルI/:X 1 cln’  肖り2
5個の密度でロール表面の周囲に旧っ表面沿いに対称的
に配Vrされている。フィルムにt 20 m7分)速
度でニップに通送する。かくしてフィルムに生成された
穿孔は肉眼で明瞭に見られ;それらの寸法を測定すると
、フィルムの表面近くで最大幅の個所で0.3〜0.4
+nmの範II!Jiにありフィルムの!【ゾみの中心
に向かって最小幅の個所でo、16〜o、19市の範囲
にあることが見出された。
The present invention will now be illustrated by the following examples, but not limited thereto. Blend with copolymer has a thickness of 0.38+u and 0.261f
/lr: tD density and 0.03 to 0.3 tnm (closed cell goo having a cell size in the D range, a foam film 1, a steel back-up roll 2 made of felt and needles arranged radially on the surface) 4. Each of the needles has a length of 6.
Grace, Needle I/:X 1 cln' Portrait 2
They are distributed around the roll surface at a density of 5 symmetrically along the surface. The film is passed through the nip at a speed of t 20 m (7 min). The perforations thus created in the film are clearly visible to the naked eye; their dimensions, when measured, range from 0.3 to 0.4 at their widest point near the surface of the film.
+nm range II! There is a film in Ji! [It was found that the minimum width toward the center of the zomi was in the range of 16 to 19 cities.

穿孔材料5を続いてエンボス加工し、エンボス加工した
領域で約20%だけフィルムの厚さが圧縮される。穿孔
の寸法を再び測定すると今回は最小幅の個所で0.05
〜0.1鰭の範囲にあることが見出された。
The perforated material 5 is subsequently embossed, compressing the film thickness by about 20% in the embossed areas. I measured the dimensions of the hole again and this time it was 0.05 at the smallest width.
It was found to be in the range of ~0.1 fin.

g:′I!孔前及び発孔後にフィルムについて実施した
水蒸気透過度の測定では次の結果を与えた;未穿孔のフ
ィルム 7   18f/ツu2724時間穿孔フィル
ム: 147097m2/ 24時間。
g:'I! Water vapor permeability measurements carried out on the film before and after perforation gave the following results: unperforated film 7 18f/2724 hours perforated film: 147097 m2/24 hours.

【図面の簡単な説明】[Brief explanation of the drawing]

図■lIは本発明の壁装材を製造するのに適焔な装置の
図解図であり、図中1はフィルム、 2はバックアップ
ロール、 3は硬質ロール、 4はニードル、 5は穿
孔材料をそれぞれ表わす。
Figure 1I is an illustrative diagram of an apparatus suitable for manufacturing the wall covering material of the present invention, in which 1 is a film, 2 is a backup roll, 3 is a hard roll, 4 is a needle, and 5 is a perforated material. Represent each.

Claims (1)

【特許請求の範囲】 1、 熱可塑性ポリオレフイ/から形成した発泡フィル
ムよυなる壁装材又は天井張り月であって該フオームの
気泡が実質的に全て独立気泡型でありその密度が0.0
5〜0.5 ?/πの範囲にある壁装材又は天井張シ材
において、前Niνフイルムは多数の穿孔を備えており
該穿孔の各々はフ・rルムの全厚を通して伸びており、
しかもフィルム表面の1ノ毎にか\る穿孔を平均して1
〜50frfA与えるように該穿孔がフィルムの表面上
に分布していることを特徴とする壁装材又は天井張り利
。 2、発泡フィルムをエチレンホモ重合体から形成する特
許請求の範囲第1項記載の壁装材又は天井張υ材。 3、 発泡フィルムは、プロピレン、ブテン−1及び4
−メチルはンテシー1から:、′DIんだ1つ以」1の
共単量体を共Mτ合体の全重量の10〜70チで混合し
たエチレンの共重合体から形成される特許請求の範囲笹
1項記載の壁装材又は天井張力材04、 発泡フィルム
は、該フィルムの全重量の4〜20チの量でのエチレン
と酢酸ビニルとの共重合体と、エチレンのホモ重合体又
は共重合体とのブレンドから形成される特許請求の範囲
第2項又tf第3項に記載の壁装材又は天井張シ材。 5、 フィルム材料の重量の5〜20係の不透明剤を配
合する特許請求の範囲第1項〜第4項の何れかに記載の
壁装材又は天井張シ材。 べ 独立気泡は0.01〜1.0mmの範囲の平均直径
を有する特許請求の範囲第1項〜第5項の何れかに記載
の壁装材又は天井張シ材。 2 穿孔け0.05〜Q、5amの範囲の直径を有する
特許請求の範囲第1項〜第6項の何れかに記載の壁装材
又は天井張り材。 8、 穿孔はフィルムの表面上に不均一に分布している
特許ii+’4求の範囲第1項〜第7項の何れかに記載
の壁装材又は天井張シ材。 9 フィルム表面の1σ2毎に平均して1〜25個の穿
孔が存在する特許1111求の範囲第1項〜Pl′18
項の何れかに記載の壁装材又は天井張りJ7L。
[Scope of Claims] 1. A wall covering or ceiling covering made of a foamed film formed from thermoplastic polyolefin, wherein substantially all of the cells in the foam are of the closed cell type and the density thereof is 0.0.
5~0.5? In wall coverings or ceiling coverings in the range /π, the front Niν film is provided with a number of perforations, each of the perforations extending through the entire thickness of the film;
Moreover, the number of perforations per hole on the film surface is 1 on average.
Wall covering or ceiling covering characterized in that the perforations are distributed on the surface of the film so as to provide ~50 frfA. 2. The wall covering material or ceiling covering material according to claim 1, wherein the foamed film is formed from an ethylene homopolymer. 3. The foam film is made of propylene, butene-1 and 4-
Claims are formed from a copolymer of ethylene mixed with one or more comonomers from 1 to 1:, DI, 1 to 70% of the total weight of the coMτ combination. Wall covering material or ceiling tension material 04 described in Sasa Item 1, the foamed film contains a copolymer of ethylene and vinyl acetate in an amount of 4 to 20 g of the total weight of the film, and a homopolymer or copolymer of ethylene. The wall covering material or ceiling covering material according to claim 2 or tf claim 3, which is formed from a blend with a polymer. 5. The wall covering material or ceiling covering material according to any one of claims 1 to 4, which contains an opacifier in an amount of 5 to 20 times the weight of the film material. The wall covering material or ceiling covering material according to any one of claims 1 to 5, wherein the closed cells have an average diameter in the range of 0.01 to 1.0 mm. 2. The wall covering material or ceiling covering material according to any one of claims 1 to 6, wherein the perforation has a diameter in the range of 0.05 to Q.5 am. 8. The wall covering material or ceiling covering material according to any one of Items 1 to 7 of the scope of Patent II+'4, wherein the perforations are distributed non-uniformly on the surface of the film. 9 Range 1 to Pl'18 of Patent No. 1111, in which there are 1 to 25 perforations on average for every 1σ2 of the film surface
Wall covering material or ceiling covering J7L described in any of the paragraphs.
JP57124542A 1981-07-21 1982-07-19 Wall lining material or ceiling lining material Pending JPS5831178A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8122397 1981-07-21
GB8122397 1981-07-21

Publications (1)

Publication Number Publication Date
JPS5831178A true JPS5831178A (en) 1983-02-23

Family

ID=10523379

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57124542A Pending JPS5831178A (en) 1981-07-21 1982-07-19 Wall lining material or ceiling lining material

Country Status (4)

Country Link
JP (1) JPS5831178A (en)
AU (1) AU553602B2 (en)
NL (1) NL8202829A (en)
NZ (1) NZ201163A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002265661A (en) * 2001-03-08 2002-09-18 Sekisui Chem Co Ltd Method for producing open-cell foam

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002265661A (en) * 2001-03-08 2002-09-18 Sekisui Chem Co Ltd Method for producing open-cell foam

Also Published As

Publication number Publication date
AU8566182A (en) 1983-01-27
NZ201163A (en) 1984-11-09
NL8202829A (en) 1983-02-16
AU553602B2 (en) 1986-07-24

Similar Documents

Publication Publication Date Title
US5286428A (en) Polypropylene resin foamed sheet for thermoforming and process for producing the same
JPH0798349B2 (en) Method for producing thermoplastic resin foam
HU217800B (en) Process for increasing ellimination of foaming material from polyethylene foam
EP2135732A1 (en) Laminated film or sheet having foamed resin layer and process for producing the same
JP2001310429A (en) Polypropylene resin foamed sheet laminate
CA2060851A1 (en) Method of providing a dimensionally-stable, closed-cell polyolefin foam having reduced blowing agent content to the end user
KR970002312B1 (en) Polypropylene resin foamed sheet for thermoforming and process for producing the same
JPS5831178A (en) Wall lining material or ceiling lining material
JP3864604B2 (en) Method for producing foamed decorative material
GB2102808A (en) Perforated, foamed olefine polymer films
JPH04221636A (en) Decorative sheet
JP3976574B2 (en) Polyolefin resin laminated foam sheet and method for producing the same
JP2009214315A (en) Foamed decorative material
JP3764869B2 (en) Polystyrene resin foam and production method thereof
JP2018058266A (en) Transfer paper and method of fabricating decorative material
JPH07148878A (en) Decorative sheet
JP5481303B2 (en) Method for producing water-absorbing foam molded article
JP4122249B2 (en) Polystyrene resin foam sheet manufacturing method
JP3432139B2 (en) Laminated foam and foam molded article using the same
JP4545860B2 (en) Multilayer foam sheet and container
JP3077247B2 (en) Foam decorative material and method for producing the same
JP4737730B2 (en) Polypropylene resin extruded foam
KR102333019B1 (en) An wall paper and method for preparing the same
JPS62191127A (en) Manufacture of foamed decorative sheet
JP2820611B2 (en) Multilayer polyolefin sheet and method for producing the same