JPS5825399A - Fishing net washing agent - Google Patents
Fishing net washing agentInfo
- Publication number
- JPS5825399A JPS5825399A JP56123050A JP12305081A JPS5825399A JP S5825399 A JPS5825399 A JP S5825399A JP 56123050 A JP56123050 A JP 56123050A JP 12305081 A JP12305081 A JP 12305081A JP S5825399 A JPS5825399 A JP S5825399A
- Authority
- JP
- Japan
- Prior art keywords
- sodium
- hypochlorite
- fishing net
- fishing nets
- composition example
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Farming Of Fish And Shellfish (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
この発明は、海藻類等の付着、繁殖して汚染された漁網
の洗滌剤に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a cleaning agent for fishing nets contaminated by adhesion and growth of seaweed.
漁網などには屡々水中に生息する海藻類が付着、繁殖し
て種々の障害を与えているが、これら障害の原因となる
汚染生物に対しては従来その繁殖を防ぐ薬剤、即ち防藻
剤として一般にトリブチル錫、トリフェニル錫等の錫化
合物を主成分とし、これに石油系樹脂、石油系溶剤を加
えたものが知られていた。Seaweed that lives in the water often attaches to fishing nets and grows, causing various problems. Conventionally, anti-algae agents have been used to prevent the growth of contaminant organisms that cause these problems. In general, it has been known that the main component is a tin compound such as tributyltin or triphenyltin, to which petroleum-based resin or petroleum-based solvent is added.
j −
しかしこの防藻剤は非常に高価で、し力1も防藻剤組成
液で漁網をデツピング処理して漁網の表面加工を行う際
に、含まれる溶剤は有害な有機物であるところから、作
業時マスク等の着用が必要であるとか、火気のないとこ
ろで行わなければならず、極めて長時間を要するという
難点がある。j - However, this algae-proofing agent is very expensive, and when the surface of the fishing net is treated by depping with the algae-proofing agent composition liquid, the solvent contained in it is a harmful organic substance. The disadvantages are that it is necessary to wear a mask while working, that the work must be done in a place without open flames, and that it takes an extremely long time.
また効果の面では上記防藻剤はアオノリ等に対して比較
的効果なく、シたがってアオノリ等の付着した漁網上げ
され、これが腐敗して悪臭、うじ等の発生など陸上での
公害源となるとともに漁網の損弱の原因となる等の欠点
がある。Furthermore, in terms of effectiveness, the above algaecides are relatively ineffective against blue laver, etc., and therefore fishing nets with green laver, etc. attached to them are washed up, which rots and becomes a source of pollution on land, such as the generation of foul odors and maggots. At the same time, it has disadvantages such as causing damage to fishing nets.
この発明はこれらの欠点を解決すぺ〈鋭意研究を重ねた
結果、次亜塩素塩が漁網に付着、繁殖するちらゆる汚染
生物に対して極めて優れた死滅、除去効果を有すること
を見出し、本願発明を完成したもので、本願の第1発明
は主成分として次亜塩素酸塩を溶解させた水溶液からな
る漁網の洗滌剤を提供するものである。This invention solves these drawbacks.As a result of intensive research, it was discovered that hypochlorite has an extremely excellent killing and removal effect on all kinds of contaminant organisms that adhere to fishing nets and breed. The invention has been completed, and the first invention of the present application provides a cleaning agent for fishing nets comprising an aqueous solution in which hypochlorite is dissolved as a main component.
ここで次亜塩素酸塩としてはナトリウム塩、カリウム塩
等の各種水溶性塩類を使用することができ、また次亜塩
素酸塩は真水又は海水いずれに溶解させて使用してもよ
い。Here, various water-soluble salts such as sodium salts and potassium salts can be used as the hypochlorite, and the hypochlorite may be used after being dissolved in either fresh water or seawater.
更に次亜塩素酸−塩の濃度は漁網の付着生物の種類、海
水より引色上けられた漁網に付着する海水量などにより
適宜選択するが、通常0.5〜20wt%程度の水溶液
として使用するのが好ましい。Furthermore, the concentration of hypochlorous acid-salt is selected depending on the type of organisms attached to the fishing net, the amount of seawater adhering to the fishing net, which has a lighter color than seawater, etc., but it is usually used as an aqueous solution of about 0.5 to 20 wt%. It is preferable to do so.
以上のように調整された次亜塩素酸塩水溶液又は海水溶
液を汚染生物の付着した漁網に散布し、或いは浸漬する
ことにより、漁網に付着する汚染生物を極めて短時間に
死滅、除去することができる。By spraying or immersing the hypochlorite aqueous solution or seawater solution prepared in the above manner onto fishing nets with contaminated organisms, the contaminated organisms attached to the fishing nets can be killed and removed in an extremely short period of time. can.
しかも次亜塩素酸塩は安価に入手でき、また食品添加物
として認められるように毒性がなく、且つ分解も早いた
め、海洋汚染公害等の問題を生じない。Furthermore, hypochlorite is available at low cost, is non-toxic as recognized as a food additive, and decomposes quickly, so it does not cause problems such as marine pollution.
なおこの発明の水溶液の漁網に対する散布量は付着生物
の種類、漁網に付着する海水量などにより適宜に選択さ
れるが、本願の第2発明のように水中に次亜塩素酸塩の
外に凝集剤、好ましくは0.01〜3−Owt % を
加えるようにすれば、漁網に散布した場合網地の表面に
凝集体を形成するため、散布量を少くてすみ、延いては
次亜塩素酸塩の使用量が少くてすむ。The amount of the aqueous solution of this invention to be sprayed onto the fishing net is appropriately selected depending on the type of attached organisms, the amount of seawater adhering to the fishing net, etc. If an agent, preferably 0.01 to 3-Owt%, is added, when sprayed on fishing nets, aggregates will form on the surface of the nets, so the amount of spraying can be reduced, and as a result, hypochlorous acid Less salt is needed.
ここで凝集剤としては例えばマレイン酸ナトリウム等の
有機酸多価金属塩、ポリアクリル酸す) IJウム、O
Vaナトリウム塩等の高分子多価金属塩等を使用するこ
とができる。Here, the flocculants include, for example, organic acid polyvalent metal salts such as sodium maleate, polyacrylic acid, IJum, O
Polymeric polyvalent metal salts such as Va sodium salts can be used.
以下、この発明の実施例を示す。Examples of this invention will be shown below.
実施例1
俣)組成例1
海 水 95
wttチ亜塩素酸ナトリウム swt’16
Q)組成例2
真 水 90
tnt4次亜塩素酸ナトリウム to wt
’1r(3) 散布試験
試験場所 静岡県熱海市網代
試験期間 昭和55年8月〜昭和56年5月以上の組成
例(1) 、 (2)の除去剤を漁網に付着し S −
た生物の上から散布し、散布後1分間海中に漁網を入れ
て汚染生物の蘇生の状況を観察した。Example 1 Mata) Composition example 1 Seawater 95
wtt sodium chlorite swt'16
Q) Composition example 2 Fresh water 90
tnt4 sodium hypochlorite to wt
'1r (3) Spraying test Test location: Ajiro, Atami City, Shizuoka Prefecture Test period: August 1980 to May 1980 Removers of composition examples (1) and (2) were applied to fishing nets to remove S-organisms. The substance was sprayed from above, and a fishing net was placed in the sea for 1 minute after spraying to observe the resuscitation of contaminated organisms.
(4)試験結果 表中記号はm、+、+、−の順に蘇生程度を表す。(4) Test results The symbols in the table represent the degree of resuscitation in the order of m, +, +, -.
惜は全部生き返る。−は全部死滅を表す。All regrets will come back to life. - represents all dead.
上記表より明らかなように、この発明の洗滌剤を使用す
ることにより漁網に付着する汚染生物のほとんどが1分
以内で死滅して除去され1、漁網を海中に再び入れた時
には汚れがなく、きれいな状態であった。As is clear from the table above, by using the cleaning agent of this invention, most of the contaminant organisms that adhere to the fishing nets are killed and removed within one minute1, and when the fishing nets are put back into the sea, they are clean. It was in good condition.
実施例2
次に、次亜塩素酸す) IJウム水溶液にポリアクリル
酸ナトリウムを添加した下記の組成例について漁網への
付着量、散布量及び汚染生物の死滅、除去効果を試験し
た。Example 2 Next, the following composition example in which sodium polyacrylate was added to an aqueous solution of hypochlorous acid (IJ) was tested for the amount of adhesion to fishing nets, the amount of spraying, and the killing and removal effects of contaminant organisms.
a)組成例3
真 水 95 −次
亜塩素酸ナトリウム 5wt*+2) 組成
例4
真 水 94.7
wttチ亜塩素酸ナトリウム 5・Owi
*ポリアクリル酸ナトリウム o、a wt96
0)組成例5
真 水 96.7
wttチ亜塩素酸ナトリウム 3.0wt
T。a) Composition example 3 Fresh water 95 - Sodium hypochlorite 5wt*+2) Composition example 4 Fresh water 94.7
wtt Sodium Chlorite 5・Owi
*Sodium polyacrylate o, a wt96
0) Composition example 5 Fresh water 96.7
wtt Sodium chlorite 3.0wt
T.
ポリアクリル酸ナトリウム 02utt%(4)組
成例6
海 水 9G
、tチ次亜塩素酸ナトリウム 10 wt*
(5) 組成例7
海 水 94.8
wtチ次次亜塩素酸ナトタウム 5.Owt
%マレイ/酸ナトリウム 0−2wt*(6)
組成例8
X 水94.6 wt%
散布試験については実施例1と同様に行った。Sodium polyacrylate 02utt% (4) Composition example 6 Seawater 9G
, t Sodium hypochlorite 10 wt*
(5) Composition example 7 Sea water 94.8
wt sodium hypochlorite 5. Owt
% Malay/Sodium Acid 0-2wt*(6)
Composition Example 8 X Water 94.6 wt% The spraying test was conducted in the same manner as in Example 1.
その結果を下記に示す。The results are shown below.
ヴ) 試験結果 9− 表中記号は実施例1と同時に、骨、賛。V) Test results 9- The symbols in the table are the same as in Example 1, ``bone'' and ``hyeon''.
+、−の順に蘇生程度を表わす。The degree of resuscitation is expressed in the order of + and -.
以上の結果より明らかなように、次亜塩素酸ナトリウム
水溶液にポリアクリル酸ナトリウムを加えた組成例Gt
) # (5)、マレイン酸ナトリウムを加えた組成例
σ)、OMOナトリウムを加えた組成例斡)はこれらを
放光なφ組成例(3) 、 (6)に比べて漁網への付
着率が良く、また汚染生物の死滅、除去効果について見
れば、次亜塩素酸ナトリウム5 wt ’J加えた組成
例(4) 、 (7) 、φ)、次亜塩素酸ナトリウム
3 wt 9に加えた組成例優)は次亜塩素酸ナトリウ
ム5 wt %加えた組成例0)に比べて格段に優れて
おり、更に次亜塩素酸ナトリウム10 wt %加えた
組成例(6)に比べて遜色ないものであった。As is clear from the above results, composition example Gt in which sodium polyacrylate was added to sodium hypochlorite aqueous solution
) # (5), composition example σ) with sodium maleate added, and composition example d) with OMO sodium added have a higher adhesion rate to fishing nets than the luminescent φ composition examples (3) and (6). In addition, when looking at the killing and removal effects of contaminant organisms, composition examples (4), (7), φ) in which 5 wt 'J of sodium hypochlorite was added, and 3 wt 'J added to sodium hypochlorite 9. Composition Example (Excellent) is much better than Composition Example 0), which added 5 wt% of sodium hypochlorite, and is comparable to Composition Example (6), which added 10 wt% of sodium hypochlorite. Met.
これよりポリアクリル酸ナトリウム、マレイン酸ナトリ
ウム、OMOナトリウムの如趣凝集剤を加えることによ
って次亜塩素酸ナトリウムの使用量を半減することがで
きる。By adding a flocculant such as sodium polyacrylate, sodium maleate, or sodium OMO, the amount of sodium hypochlorite used can be halved.
Claims (1)
なることを特徴とする漁網の洗滌剤。 @) 主成分として次亜塩素酸塩と凝集剤を加えた水溶
液からなることを特徴とする漁網の洗滌剤。[Claims] ←) A cleaning agent for fishing nets, comprising an aqueous solution in which hypochlorite is dissolved as a main component. @) A cleaning agent for fishing nets that is characterized by consisting of an aqueous solution containing hypochlorite and a flocculant as the main ingredients.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56123050A JPS5932518B2 (en) | 1981-08-07 | 1981-08-07 | fishing net cleaning agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56123050A JPS5932518B2 (en) | 1981-08-07 | 1981-08-07 | fishing net cleaning agent |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5825399A true JPS5825399A (en) | 1983-02-15 |
JPS5932518B2 JPS5932518B2 (en) | 1984-08-09 |
Family
ID=14850957
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56123050A Expired JPS5932518B2 (en) | 1981-08-07 | 1981-08-07 | fishing net cleaning agent |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5932518B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60184002A (en) * | 1984-03-01 | 1985-09-19 | Daiichi Seimo Kk | Agent for controlling fungus of red rot disease or green laver |
-
1981
- 1981-08-07 JP JP56123050A patent/JPS5932518B2/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60184002A (en) * | 1984-03-01 | 1985-09-19 | Daiichi Seimo Kk | Agent for controlling fungus of red rot disease or green laver |
JPH0122242B2 (en) * | 1984-03-01 | 1989-04-25 | Daiichi Seimo Kk |
Also Published As
Publication number | Publication date |
---|---|
JPS5932518B2 (en) | 1984-08-09 |
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