JPS5820145A - Method for keeping scarlet color of frozen meat - Google Patents

Method for keeping scarlet color of frozen meat

Info

Publication number
JPS5820145A
JPS5820145A JP11893181A JP11893181A JPS5820145A JP S5820145 A JPS5820145 A JP S5820145A JP 11893181 A JP11893181 A JP 11893181A JP 11893181 A JP11893181 A JP 11893181A JP S5820145 A JPS5820145 A JP S5820145A
Authority
JP
Japan
Prior art keywords
raw meat
meat
raw
frozen
freezing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11893181A
Other languages
Japanese (ja)
Inventor
Isao Uemura
功 植村
Akio Oide
大出 昭夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ajinomoto Co Inc
Original Assignee
Ajinomoto Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ajinomoto Co Inc filed Critical Ajinomoto Co Inc
Priority to JP11893181A priority Critical patent/JPS5820145A/en
Publication of JPS5820145A publication Critical patent/JPS5820145A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:The time while the surface layer of raw meat passes through the temperature range of maximum ice-crystal formation is controlled to prevent frozen meat, especially raw meat to be frozen from discoloration with time when frozen or stored, thus keeping its scarlet color. CONSTITUTION:Processed meat or raw meat products such as raw hamburger or meat ball is frozen wherein the time while the surface layer of the raw meat passes through the temperature range of the maximum ice-crystal formation is controlled to be 30min to 10hr to effect relatively gradual cooling, and preferably, the raw meat is kept tightly packed or kept from direct contact with the cooling air during the refrigeration.

Description

【発明の詳細な説明】 本発明は、冷凍肉類、特に生肉類の凍結時及び保存時に
おける経時的な褪色乃至は変色を防止し、鮮紅色を保持
する方法に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for preventing fading or discoloration of frozen meat, especially fresh meat, over time during freezing and storage, and maintaining a bright red color.

畜肉、鳥肉、魚肉、鮭肉等の赤身を有する生肉類は、肉
牛に含まれるミオグロビン(及びヘモグロビン)が酸素
と結合し、オキシミオグロビン(及びオキシヘモグロビ
ン)1こ変化することにより鮮紅色の肉色を呈するが、
その肉色の良否が、特Vこ鮮度との関連を大きく印象づ
けるためVこ、生肉類の商品価値を左右する大きな要因
となっている。一般に、冷蔵保存において、生肉類は、
好ましい肉色を呈するオキシミオグロビン(及びオキシ
ヘモグロビン)が酸化されてメトミオグロビン(及びメ
トヘモグービン)に変化し、褐色化する。或いは、肉牛
の酵素により酸素が消費されて還元することにより、ミ
オグロビン(及びヘモグービン)に戻るため、鮮紅色の
好ましい肉色の保持期間が短く、従って、商品価値を可
及的に維持するために、種々の改善が試みられている。
Raw red meat such as livestock meat, poultry, fish, and salmon has a bright red color due to the myoglobin (and hemoglobin) contained in beef cattle combining with oxygen and changing oxymyoglobin (and oxyhemoglobin) by 1. However,
The quality of the meat color is a major factor in determining the commercial value of raw meat, as it has a strong relationship with freshness. Generally, when storing raw meat under refrigeration,
Oxymyoglobin (and oxyhemoglobin), which exhibits a desirable flesh color, is oxidized and changes to metmyoglobin (and methemoglobin), resulting in browning. Alternatively, oxygen is consumed and reduced by the enzymes of beef cattle and returns to myoglobin (and hemoglobin), so the preferred bright red meat color is retained for a short period of time. Therefore, in order to maintain the commercial value as much as possible, Various improvements have been attempted.

即ち、食肉保存における問題として、鮮紅色を如何に発
現し、それを保持するかが、非常に重要な課題の一つと
なっている。
That is, one of the very important issues in meat preservation is how to develop and maintain the bright red color.

一方、生肉類を鮮度を保持したまま、より長期間保存す
るためには、生肉類を冷凍する方法が一般的であるが、
冷凍生肉類においては、上記冷蔵保存で生ずる肉色の退
色乃至は変色という問題とは別に、冷凍工程において、
肉色が白色化し、それがそのまま冷凍保存中にも維持さ
れるという問題点を有する。このため、そのまま小売用
にスライスされ、或いはブロックのままフィルム包装等
されて売られる冷凍生肉類においても、又は、冷凍生ハ
ンバーグその他に加工されて販売される場合においても
商品の外観として好ましくない。
On the other hand, in order to preserve raw meat for a longer period of time while maintaining its freshness, it is common to freeze raw meat.
In frozen raw meat, in addition to the problem of fading or discoloration of the meat color that occurs during refrigerated storage, in the freezing process,
The problem is that the meat color turns white and remains that way even during frozen storage. For this reason, the appearance of the product is unfavorable even when frozen raw meat is sold as is, sliced for retail sale, or as a block wrapped in film, etc., or when processed into frozen raw hamburger steaks or the like and sold.

上記生肉の鮮紅色がメトミオグロビン(及びメトヘモグ
ロビン)の生成により褐色化するのを防止する方法とし
ては、アスコルビン酸等の還元剤の使用、酸化防止剤の
使用、或いは密封包装等による酸素の遮断等が挙げられ
る。また、ミオグロビン(及びヘモグロビン)に還元す
るのを防止するものとしては、内申の酵素に対する阻害
剤の使用や、凍結等1こより酵素活性を抑制する等の方
法が挙げられるが、これらはいずれも上記冷凍工程にお
ける生肉類の白色化現象を妨げるものではない。従って
、冷凍生肉類について、鮮紅色の外観を保持するための
ものとして、十分満足できる手段は未だ見出されていな
い状況にある。
Methods to prevent the bright red color of the raw meat from turning brown due to the production of metmyoglobin (and methemoglobin) include the use of reducing agents such as ascorbic acid, the use of antioxidants, or the blocking of oxygen through sealed packaging, etc. etc. In addition, methods to prevent the reduction to myoglobin (and hemoglobin) include the use of inhibitors against the internal enzyme and methods such as freezing and suppressing the enzyme activity, but none of these methods are mentioned above. It does not prevent the whitening phenomenon of raw meat during the freezing process. Therefore, a fully satisfactory means for maintaining the bright red appearance of frozen raw meat has not yet been found.

本発明者は、上記現状に鑑み、化学物質等の添加に頼ら
ず、また肉の品質を維持して、冷凍生肉類の肉色を鮮紅
色に保つ方法につき鋭意研究を重ね、生肉類の表層部が
、最大氷結晶生成温度領域を通過するまでの所要時間を
30分〜10時間とすることtこより、上記目的が達成
できるとの知見に至り、本発明を完成したものである。
In view of the above-mentioned current situation, the present inventor has conducted extensive research on a method to maintain the bright red color of frozen raw meat without relying on the addition of chemical substances, etc., and to maintain the quality of the meat. However, the present invention has been completed based on the finding that the above object can be achieved by setting the time required to pass through the maximum ice crystal formation temperature region to 30 minutes to 10 hours.

従来行われている生肉類の冷凍は、一般に生肉類が最大
氷結晶生成温度領域を通過するまでの所要時間が30分
以下程度で急速に凍結する方法が行われている。これは
、例えば豚や牛等の枝肉や、ハンバーグ類その他の加工
肉類な冷凍処理する場合でも同等に好ましい方法として
採用されており、最大氷結晶生成温度領域をできるだけ
短時間で通過させて凍結処理することtこ関心が払われ
ていた。
Conventional methods of freezing raw meat are generally performed by rapidly freezing the raw meat in a period of about 30 minutes or less until the raw meat passes through the maximum ice crystal formation temperature range. This method is equally preferred when freezing carcasses of pigs, cows, etc., hamburgers, and other processed meats, and the freezing process is performed by passing through the maximum ice crystal formation temperature range in as short a time as possible. There was a lot of attention paid to what they were doing.

従来法の具体例としては、マグロの場合で、一般1こ肉
色を良くするためtこは、冷媒温度は2段圧縮機により
一50C1空気温度−40〜−45c下チェアブロスト
凍結を行う。また、ブロイラーの場合でも、−30〜−
40cでエアブロスト凍結するのが一般である。
As a specific example of the conventional method, in the case of tuna, in order to improve the color of the tuna, the refrigerant temperature is 150 C and the air temperature is -40 to -45 C, and chair-brown freezing is performed using a two-stage compressor. In addition, even in the case of broilers, -30 to -
Air blast freezing at 40c is common.

一方、本発明においては、上記従来法とは異なり、生肉
類の表層部が最大氷結晶生成温度領域を通過するまでの
時間が30分〜10時間という、比較的緩やかな温度低
下勾配条件下で冷凍処理を行う。
On the other hand, in the present invention, unlike the above-mentioned conventional method, the time required for the surface layer of raw meat to pass through the maximum ice crystal formation temperature range is 30 minutes to 10 hours, under relatively gentle temperature decreasing gradient conditions. Perform freezing treatment.

最大氷結晶生成温度領域は、通常−1c〜−5C程度で
あるが、例えば加工生肉類等で、氷点降下物質が添加さ
れている場合その他により、この温度領域はずれる。
The maximum ice crystal formation temperature range is usually about -1C to -5C, but this temperature range may vary depending on, for example, processed raw meats in which a substance that lowers the freezing point is added.

本発明の冷凍処理は、具体的には、生ハンバーグの場合
で、−18tl’で除々に凍結すればよいが、冷凍方法
は冷気が生肉表面Vこ直接吹きつけられるような方法、
例えばエアプラスト凍結などは避けるほうが好ましく、
また、生肉類を密封状態で冷凍処理することが好ましい
。すなわち、生肉類の表層は、冷凍室の雰囲気温度に敏
感であり、冷気をその表層に直接吹きつけるよりは、密
封状態で表層の急速な温度低下を防止するような条件下
で冷凍することが、より望ましい。尚、生肉類の表面が
冷凍処理により白色化する原因は必ずしも明らかでない
が、生肉類の表面が、急速に凍結し、最大氷結晶生成温
度領域を可及的速かに通過することtこより、表面部に
、微細な氷結晶が生成し、これが光の乱反射をもたらす
ことが主たる原因であると考えられる。一方、本発明の
方法1こよれば、生肉類の表面1こおける急速な温度低
下は、生肉類の品質そのものに悪影響をもたらさない範
囲で、可及的に緩やかに進行するため、光の乱反射の原
因となる微細な氷結晶の生成も少なくなり、本来の生肉
類の鮮紅色がそのまま保持されるものと思惟される。
Specifically, the freezing treatment of the present invention is performed in the case of raw hamburger steak by gradually freezing it at -18 tl';
For example, it is better to avoid airplast freezing.
Further, it is preferable to freeze the raw meat in a sealed state. In other words, the surface layer of raw meat is sensitive to the ambient temperature in the freezer, and rather than blowing cold air directly onto the surface layer, it is better to freeze the surface layer under conditions that prevent the surface layer from rapidly decreasing in temperature. , more desirable. Although the reason why the surface of raw meat turns white due to freezing treatment is not necessarily clear, the surface of raw meat freezes rapidly and passes through the maximum ice crystal formation temperature range as quickly as possible. The main cause is thought to be the formation of fine ice crystals on the surface, which causes diffuse reflection of light. On the other hand, according to method 1 of the present invention, the rapid temperature drop on the surface of raw meat proceeds as slowly as possible within a range that does not adversely affect the quality of the raw meat itself, so that the diffused reflection of light It is thought that the formation of fine ice crystals, which can cause browning, is also reduced, and the original bright red color of raw meat is maintained.

本発明における生肉類は、牛肉、豚肉、羊肉等の畜肉、
鶏肉、■聰鮭肉、鮪、鰹等の魚肉その例えば、内部を急
速1こ凍結し、表面は緩やかに凍結するという特別の手
段を講する場合は別として、一般的には、肉組織をその
まま維持するような、厚みのあるブロック状の生肉類の
凍結よりも、肉組織を切断した生肉類又は加工生肉類、
例えば、生ハンバーグ、生ミートボール類等への適用が
望ましい。すなわち、これらの生肉類にあっては、仮り
に、比較的大きな氷結晶が内部に生成した場合であって
も、それ1こよる品質への影響はほとんど感ぜられない
し、冷凍保存温度を一18C以下1こ維持する限り、従
来法1こ比べての品質上のデメリットはまず生じないか
らである。
Raw meat in the present invention includes livestock meat such as beef, pork, and mutton;
Fish meat such as chicken, salmon, tuna, bonito, etc.In general, the meat tissue is Rather than freezing thick block-shaped raw meat that is kept as is, raw meat or processed raw meat with cut meat tissue,
For example, it is desirable to apply it to raw hamburgers, raw meatballs, etc. In other words, even if relatively large ice crystals were to form inside these raw meats, this would have almost no effect on the quality, and the frozen storage temperature should be kept constant. This is because as long as the temperature is maintained below 18C, there will be no disadvantage in terms of quality compared to the conventional method.

尚、本発明の目的を損わない限り、他の品質改良剤や肉
色保持剤の加配や、予備凍結その他の適当な冷凍方法を
組合わせることを妨げるものでないことはいうまでもな
い。
It goes without saying that this does not preclude the addition of other quality improving agents or flesh color preserving agents, or the combination of pre-freezing or other suitable freezing methods, as long as the purpose of the present invention is not impaired.

次に、実施例により、本発明を更tこ説明する。Next, the present invention will be further explained with reference to Examples.

実施例 生ハンバーグの配合 牛     肉         7     kf豚
     肉         3 玉ねぎ  2 〃 全    卵        1.5  〃パ  ン 
 粉         1.5   〃調味料  0.
2〃 香辛料  0.04 // 上記配合に従い、チョッパー処理した挽肉、ミジン切り
後炒め処理をした玉ねぎ、その他の原料をミキサーでよ
く混練した後、成型して生ハンバでおおったラック1こ
成型したI・ンバーグを入れ、−20C冷凍庫で凍結を
行った。このときの凍結温度の経時変化は最大氷晶生成
温度迄45分間要し、最大氷晶帯通過時間は2時間であ
った(試料A)。
Example raw hamburger combination Beef meat 7 kf pork 3 Onions 2 Whole eggs 1.5 Bread
Powder 1.5 Seasoning 0.
2. Spices 0.04 // According to the above formula, chopper-processed ground meat, minced and fried onions, and other ingredients were thoroughly kneaded with a mixer, then molded into one rack covered with fresh hamba. I. Nberg was added and frozen in a -20C freezer. At this time, the freezing temperature changed over time until it reached the maximum ice crystal formation temperature for 45 minutes, and the maximum ice crystal zone passage time was 2 hours (Sample A).

対照として、上記生ハンバーグを一35cのエアプラス
ト(風速2〜4 m / sec )中で30分間凍結
させた。この時の凍結温度の経時変化は最大氷晶生成温
度迄lO分最大氷晶生成帯通過時間は10分であった(
試料B)。
As a control, the above-mentioned raw hamburger steak was frozen for 30 minutes in an airplast (wind speed 2-4 m/sec) at 135 cm. At this time, the freezing temperature changed over time until the maximum ice crystal formation temperature was reached in 10 minutes, and the time required to pass through the maximum ice crystal formation zone was 10 minutes (
Sample B).

上記2種類の冷凍生ハンバーグ1こっき、冷凍前、冷凍
直後及び冷凍保存中tこおける色調変化を測定した結果
を第1表に示す。
Table 1 shows the results of measuring the color tone changes of the above two types of frozen raw hamburger steaks before freezing, immediately after freezing, and during frozen storage.

第  1  表 測定値は4ケの平均 第1表から明らかなように試料Aの方が表面の白化が少
なく赤味が強く感じられ、外観上良好な色調を呈してい
た。
As is clear from the average of the four measured values in Table 1, Sample A had less whitening on the surface and a stronger reddish feel, and had a better color tone in terms of appearance.

特許出願人 味の素株式会社Patent applicant: Ajinomoto Co., Inc.

Claims (1)

【特許請求の範囲】 1 冷凍生肉類を製造するtこ際し、生肉類の表層部が
最大氷結晶生成温度領域を通過するまでの所要時間が3
0分〜lO時間となるように生肉類を冷凍することを特
徴とする冷凍生肉類の鮮紅色保持方法。 2 上記冷凍を行うに際し、生肉類を密封状態にするか
及び/又は生肉類表面に直接冷風があたらない冷凍方法
によることを特徴とする特許請求の範囲第1項記載の冷
凍生肉類の鮮紅色保持方法。 3 生肉類が、肉組織を切断した生肉類又は加工生肉類
であることを特徴とする特許請求の範囲第1項又は第2
項記載の冷凍生肉類の鮮紅色保持方法。 4 上記加工生肉類が生ノ・ンバーク若しくは生ミート
ボール類であることを特徴とする特許請求の範囲第3項
記載の冷凍生肉類の鮮紅色保持方法。
[Claims] 1. When producing frozen raw meat, the time required for the surface layer of the raw meat to pass through the maximum ice crystal formation temperature range is 3.
A method for maintaining the bright red color of frozen raw meat, which comprises freezing the raw meat for a time of 0 minutes to 10 hours. 2. The bright red color of the frozen raw meat as set forth in claim 1, wherein the freezing is carried out by sealing the raw meat and/or by a freezing method that does not expose the surface of the raw meat to cold air directly. How to hold it. 3. Claims 1 or 2, characterized in that the raw meat is raw meat obtained by cutting meat tissue or processed raw meat.
Method for preserving the bright red color of frozen raw meat as described in Section 1. 4. The method for preserving the bright red color of frozen raw meat according to claim 3, wherein the processed raw meat is raw pork or raw meatballs.
JP11893181A 1981-07-29 1981-07-29 Method for keeping scarlet color of frozen meat Pending JPS5820145A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11893181A JPS5820145A (en) 1981-07-29 1981-07-29 Method for keeping scarlet color of frozen meat

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11893181A JPS5820145A (en) 1981-07-29 1981-07-29 Method for keeping scarlet color of frozen meat

Publications (1)

Publication Number Publication Date
JPS5820145A true JPS5820145A (en) 1983-02-05

Family

ID=14748749

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11893181A Pending JPS5820145A (en) 1981-07-29 1981-07-29 Method for keeping scarlet color of frozen meat

Country Status (1)

Country Link
JP (1) JPS5820145A (en)

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