JPS58171811A - Method of producing solid electrolytic condenser - Google Patents

Method of producing solid electrolytic condenser

Info

Publication number
JPS58171811A
JPS58171811A JP5390282A JP5390282A JPS58171811A JP S58171811 A JPS58171811 A JP S58171811A JP 5390282 A JP5390282 A JP 5390282A JP 5390282 A JP5390282 A JP 5390282A JP S58171811 A JPS58171811 A JP S58171811A
Authority
JP
Japan
Prior art keywords
solid electrolytic
carbon
layer
electrolytic capacitor
manufacturing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP5390282A
Other languages
Japanese (ja)
Other versions
JPS6321335B2 (en
Inventor
良平 柴田
堀 直之
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lincstech Circuit Co Ltd
Original Assignee
Hitachi Condenser Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Condenser Co Ltd filed Critical Hitachi Condenser Co Ltd
Priority to JP5390282A priority Critical patent/JPS58171811A/en
Publication of JPS58171811A publication Critical patent/JPS58171811A/en
Publication of JPS6321335B2 publication Critical patent/JPS6321335B2/ja
Granted legal-status Critical Current

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  • Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
  • Measuring Oxygen Concentration In Cells (AREA)
  • Conductive Materials (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 本考案は、固体電解コンデンサの製造方法に関し、特に
、焼結体に設ける陰極層を改良した固体電解コンデンサ
に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for manufacturing a solid electrolytic capacitor, and particularly to a solid electrolytic capacitor in which a cathode layer provided on a sintered body is improved.

タンタル等の弁作用金属の粉末からなる焼結体に陽極酸
化等の処理を施して製造した固体電解コンデンサは最高
でも19v程度の耐圧が低い欠点があり、耐圧不良が多
く、その対策が望まれている。
Solid electrolytic capacitors manufactured by applying anodic oxidation to a sintered body made of powder of valve metal such as tantalum have the disadvantage of a low withstand voltage of around 19V at most, and there are many breakdown voltage failures, so countermeasures are desired. ing.

本考案は1以上の点に鑑み、耐圧を向上しうる固体電解
コンデンサの製造方法の提供を目的とするものである。
In view of one or more points, the present invention aims to provide a method for manufacturing a solid electrolytic capacitor that can improve the withstand voltage.

本考案は、上記の目的を達成するために、半導体層を設
けた後に1粒径の大きい第1のカーボンを塗布し1次い
で粒径のより小さい第2のカーポ/を塗布することを特
徴とする固体電解コンデンサの製造方法を提供するもの
である。
In order to achieve the above object, the present invention is characterized in that after providing a semiconductor layer, a first carbon having a large particle size is applied, and then a second carbon having a smaller particle size is applied. The present invention provides a method for manufacturing a solid electrolytic capacitor.

以下1本発明の実施例を図面に基づいて説明する。An embodiment of the present invention will be described below based on the drawings.

先ず、タンタル線1の先端を引き出すようにしてタンタ
ルの粉末の焼結体2を形成する。このり/タルの焼結体
2をリン酸により化成して1表面に陽極酸化皮膜5を形
成する。次に、硝酸マンカ゛ン溶液中に浸漬して二酸化
マンガン層4を設ける。
First, the tip of the tantalum wire 1 is pulled out to form a sintered body 2 of tantalum powder. The sintered body 2 of this resin/tal is chemically treated with phosphoric acid to form an anodic oxide film 5 on one surface. Next, a manganese dioxide layer 4 is provided by immersing it in a manganese nitrate solution.

二酸化マンガンからなる半導体層を設けた後、先づ粒径
が3μ以上の第1のカーボンを二酸化マンガン層4上に
塗布して#11のカーボン層5を設ける。次いで1粒径
が5μ未満の第2のカーボンを塗布して第2のカーボン
層6を設ける。これ等の9を接続し、タンタル線1には
陽極リード線10を接続して、樹脂外装置1を施す。
After forming a semiconductor layer made of manganese dioxide, first carbon having a particle size of 3 μm or more is coated on the manganese dioxide layer 4 to form a #11 carbon layer 5. Next, a second carbon layer 6 is provided by applying a second carbon having a grain size of less than 5 μm. These 9 are connected, the anode lead wire 10 is connected to the tantalum wire 1, and the resin outer device 1 is applied.

すなわち、陰極層としてカーボン層を塗布しないと、耐
圧不良が大幅に減少するが、これはカーボン粒子が半導
体層に入りこみ、半導体層の抵抗を降下させ耐圧が低下
する原因となっていることを示している。本発明によれ
ば、二酸化マンガン層4に直接接触する方に粒径の大き
い第1のカーボンを塗布しており、そのために、カーボ
ン粒子が二酸化マンガン層4に侵入し難く、二酸化マン
ガン層4の抵抗が降下するのが防止される。そして第1
のカーボン層5の上にさらに粒径のより小さい第2のカ
ーボン層6を設けて、カーボン層5及び6全体の厚さを
、はぼ従来通りとしている。
In other words, if a carbon layer is not applied as a cathode layer, breakdown voltage defects are significantly reduced, but this indicates that carbon particles enter the semiconductor layer, lowering the resistance of the semiconductor layer and causing a decrease in breakdown voltage. ing. According to the present invention, the first carbon having a larger particle size is coated on the side that is in direct contact with the manganese dioxide layer 4, so that carbon particles are difficult to penetrate into the manganese dioxide layer 4, and the carbon particles are less likely to enter the manganese dioxide layer 4. The resistance is prevented from dropping. and the first
A second carbon layer 6 having a smaller particle size is further provided on the carbon layer 5, and the overall thickness of the carbon layers 5 and 6 is kept almost the same as before.

それ故、 tanδの増加を防止できる。Therefore, an increase in tan δ can be prevented.

以上の通り1本発明によれば、半導体層の抵抗降下を防
止してコンデンサの耐圧不良を低減し5る固体電解コン
デンサの製造方法が得られる。
As described above, according to the present invention, there is provided a method for manufacturing a solid electrolytic capacitor that prevents a drop in resistance of a semiconductor layer and reduces breakdown voltage defects of the capacitor.

【図面の簡単な説明】[Brief explanation of drawings]

図は本考案の実施例により製造した固体電解コンデンサ
の正面断面図を示す。 2・・・・・・焼結体、3・・・・・・陽極酸化皮嘆。 4・・・・・・二酸化マンガン層。 5・・・・・・第1のカーボン層。 6・・・・・・第2のカーボン層、7・・・・・・銀ペ
ースト層。 8・・・・・・半田層、11・・・・・・樹脂外M。 特許出願人 日立コンデンサ株式会社
The figure shows a front sectional view of a solid electrolytic capacitor manufactured according to an embodiment of the present invention. 2...Sintered body, 3...Anodized skin. 4...Manganese dioxide layer. 5...First carbon layer. 6... Second carbon layer, 7... Silver paste layer. 8... Solder layer, 11... Outer resin M. Patent applicant Hitachi Capacitor Co., Ltd.

Claims (3)

【特許請求の範囲】[Claims] (1)  弁作用金属の粉末からなる焼結体に陽極酸化
皮膜を形成し、半導体層及び陰極層を順次設けた固体電
解コンデンサの製造方法において、半導体層を設けた後
に1粒径の大きい第1のカーボンを塗布し1次いで粒径
のより小さい第2のカーボンを塗布することを特徴とす
る固体電解コンデンサの製造方法。
(1) In a method for manufacturing a solid electrolytic capacitor in which an anodized film is formed on a sintered body made of valve metal powder, and a semiconductor layer and a cathode layer are sequentially provided, after the semiconductor layer is provided, 1. A method for manufacturing a solid electrolytic capacitor, which comprises applying first carbon, and then applying second carbon having a smaller particle size.
(2)第1のカーボンの粒径が3μ以上である特許請求
の範囲第1項記載の固体電解コンデンサの製造方法。
(2) The method for manufacturing a solid electrolytic capacitor according to claim 1, wherein the first carbon has a particle size of 3 μ or more.
(3)  第2のカーボンの粒径が5μ未満である。 特許請求の範囲第1項及び第2項記載の固体電解コンデ
ンサの製造方法。
(3) The particle size of the second carbon is less than 5μ. A method for manufacturing a solid electrolytic capacitor according to claims 1 and 2.
JP5390282A 1982-04-02 1982-04-02 Method of producing solid electrolytic condenser Granted JPS58171811A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5390282A JPS58171811A (en) 1982-04-02 1982-04-02 Method of producing solid electrolytic condenser

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5390282A JPS58171811A (en) 1982-04-02 1982-04-02 Method of producing solid electrolytic condenser

Publications (2)

Publication Number Publication Date
JPS58171811A true JPS58171811A (en) 1983-10-08
JPS6321335B2 JPS6321335B2 (en) 1988-05-06

Family

ID=12955644

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5390282A Granted JPS58171811A (en) 1982-04-02 1982-04-02 Method of producing solid electrolytic condenser

Country Status (1)

Country Link
JP (1) JPS58171811A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02265234A (en) * 1989-04-05 1990-10-30 Matsushita Electric Ind Co Ltd Solid-state electrolytic capacitor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02265234A (en) * 1989-04-05 1990-10-30 Matsushita Electric Ind Co Ltd Solid-state electrolytic capacitor

Also Published As

Publication number Publication date
JPS6321335B2 (en) 1988-05-06

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