JPS58168637A - Bromine-containing flame retarder - Google Patents
Bromine-containing flame retarderInfo
- Publication number
- JPS58168637A JPS58168637A JP5337982A JP5337982A JPS58168637A JP S58168637 A JPS58168637 A JP S58168637A JP 5337982 A JP5337982 A JP 5337982A JP 5337982 A JP5337982 A JP 5337982A JP S58168637 A JPS58168637 A JP S58168637A
- Authority
- JP
- Japan
- Prior art keywords
- tetrabromobisphenol
- flame retarder
- bromine
- diglycidyl ether
- containing flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【発明の詳細な説明】
本発ｌ３１１σ電気杷縁材料、ガχは成形品、積層板等
のせ成衝廁に添加して蒙用さｎる臭累を含有する麺燃剤
に圓する。DETAILED DESCRIPTION OF THE INVENTION The 1311σ electrolyte material of the present invention is added to a molded product, a laminate plate, etc., and then mixed into a noodle fire agent containing an odor.
鴫気絶鰍材料において、Ｊｌｌｌ燃規制に敵しく。In terms of raw material, Jllll flame regulation is not met.
臭素含にυ嶋い勉燃剤か資本さｎる禄になってきている
。It has become a very expensive study agent that contains bromine.
この代表例として、ナト２ブロモビス２エノールＡ１テ
ト２ブロモビスフエノールＡジグリシジルエーテル、ジ
ブロモクレジルモノグリシジルエーテル、ジブロモ２エ
ニルモノグリシジルエーテル、臭率化ビ２エニルエーテ
ル等カメる・
龜力ｌさｎるせ戚樹刀旨ＶＣ工９差共があるが、亀気絶
械材料（ｔＪ軸性を損なわない為には１反応性のめる碌
燃剤が良好でるる拳か知らｎている。Typical examples include nato2bromobis2enol A1te2bromobisphenol A diglycidyl ether, dibromocresyl monoglycidyl ether, dibromo2enyl monoglycidyl ether, brominated bi2enyl ether, etc. There are 9 different types of VC engineering, but I know that a refractory agent with 1 reactivity is good in order not to impair the tJ axis properties.
ｃｙｔら０離燃剤のうち、テトラブロモビスフェノール
Ａに、分牌鴎度か低く１九億性が強いため％＃終製品で
少ｌ″″ｃｔモノマーを残丁と。Among cyt et al. 0 flame retardants, tetrabromobisphenol A has a low oxidation rate and a strong 1.9 billion tonne, so a small amount of ct monomer remains in the final product.
観気狩性ｊ？工ひ耐熱性等のレベル低下を招く０”！
’ｆｃ ｓグリシジルエーテルｔもりた美系糸離燃剤に
、全てＩＩ！ｉｌＩ型智又に、結構１である為、側脂配
台時に２いて、作業性を着しく低下させるりみでなくＳ
ｆＪ≦刀ｌさｒ′Ｌ４）′ｔ！ｒ成粥脂にＬり差異かｚ
ｎｚｒｘ、ｃｒｔらの欠点ＶＣ＊みな式３７ｔ％のでめ
り、亀気杷縁材料の諸物性ｔ″損なわｒ、又。Sightseeing? 0" which causes a decrease in the level of heat resistance etc.
'fc s glycidyl ether t beautiful yarn flame retardant, all II! For the ilI type Tomomata, since it is quite 1, there are 2 when installing the side fat, and S is not a sludge that seriously reduces work efficiency.
fJ≦katana lsa r'L4)'t! Is there a difference between mature porridge and fat?
Disadvantages of nzrx, crt, etc. include 37t% loss of VC*, loss of physical properties t″ of the kameki loquat material, and.
提供するものでるる・
不発明にテトラブロモビスフェノールＡとテトラブロモ
ビスフェノールＡジグリシジルエーテルと倉外部町虜剤
の存在下で反応さゼ几美木１１ＭするＩＩｋ燃刑である
。What we provide is a reaction of Tetrabromobisphenol A and Tetrabromobisphenol A diglycidyl ether in the presence of Kuratomoto's 11M IIk.
テトラブロモビスフェノールＡとテトラブロモビスフェ
ノールＡジグリシジルエーテルの反応管に通常σ園調切
でるり１作頻性會良くする為にトルエンやメチルエテル
ケトン寺Ｌ）ｎ剤を用いてａＳする揚ｔｔあるが１時間
が鮭つと沈ＩＭ智を生ずる０
七Ｃ′ｔ″檎々慣討した結果、テトラブロモビスフェノ
ールＡとテトラブロモビスフェノールＡジグリシジルエ
ーテルを反応させるＫめ′ｆｃ９、外部町−剤を介在さ
せる事にＬり、前記欠点を飛−的に改良で＠るＪｌ夷を
見出さｎた０こυ反応Ｋｊ？いて、テトラブロモビスフ
ェノールＡの配付型か多いと電気特性ン１ぴ耐廃注に患
影＊を及ぼし、１次テトラプロモビスフェ匣性か悪くな
り、Ｃ（７Ｊ配甘電σ、ナト２ブロモビスフエノールＡ
：テトラプロモビスフエノールＡジグリシジルエーテル
＝１：１〜１：５（モル比）か好しく、Ｊｌ［好ましく
に１＝２〜１：４である。The reaction tube of tetrabromobisphenol A and tetrabromobisphenol A diglycidyl ether is usually treated with aS using toluene or methyl ether ketone to improve the crop frequency. However, as a result of extensive study, it was found that tetrabromobisphenol A and tetrabromobisphenol A diglycidyl ether were reacted using an external agent. In order to improve the above-mentioned drawbacks, I discovered that the above-mentioned drawbacks could be dramatically improved, and I discovered that the distribution type of tetrabromobisphenol A had a high resistance to waste injection due to its electrical properties. It causes a diseased shadow*, the primary tetrapromobisphenolity becomes worse, C (7J distribution sweetden σ, nato2bromobisphenol A
:Tetrapromobisphenol A diglycidyl ether=1:1 to 1:5 (molar ratio) is preferable, Jl [preferably 1=2 to 1:4.
外部句朦剛ａ１外部りり添刀口して物質のり塑性を付与
、同上させるちりであり、本発明でにクレジルジフェニ
ルホス７ｓ−）、）！７フエニルホス２エート、トリク
レジルホス７ ｇ −ト、トリキシレニルホスフェート
、オクチルジフェニルホス７ ｇ −） ｓキシレニル
ジフェニルホス２エート４Ｐりりン歌エステル、ジメチ
ル２タレート、ジエチルフタレート等υ２タル鍍エステ
ル、ポリグリコールエステル、オキシ鍍エステル尋が使
用さｊＬる・
ナト２プ１モに’Ｘ７−ノー″Ａとテトランｃｒ
。It is the dust that gives plasticity to the material by applying the external groove a1 to the outside, and it is the dust that makes the material plastic. 7 phenyl phos 2ate, tricresyl phos 7 g-to, tricylenyl phosphate, octyl diphenyl phos 7 g-) s xylenyl diphenyl phos 2 ate, 4P phosphorus ester, dimethyl 2 talate, diethyl phthalate, etc. υ2 tal ester, poly Glycol ester, oxy-ester ester is used, 'X7-No'A and Tetrane CR in Nato 2P1Mo
.
モビスフェノールＡジグリシジルエーテル９５〜６０嵐
＊ｍに対し、外＄ｃＩＪｍ刑Ｏ５〜４０ Ｊ［ｊ［ｓ使
用ざｆＬる０
テトラブロモビスフェノールＡとテトラブロモビス２エ
ノールＡジグリシジルエーテルとの反五６に８０〜１５
０℃、６０分〜５時閣の条件で？Ｔなわｎる・＆応触媒
として、第１．ｍ２゜ｍ５Ｍアミン、パラトルエンスル
ホン酸等の敵等が使用さｎる。Mobisphenol A diglycidyl ether 95-60 Arashi*m, external $cIJm punishment O5-40 80-15 on 6
Under the conditions of 0℃, 60 minutes to 5 o'clock? As a T rope & reaction catalyst, 1st. Enemies such as m2゜m5M amine and para-toluenesulfonic acid are used.
こｃｔＪ嫌にして侍らｆ′Ｌ丸臭系七言有富有離愁剤に
、一般式
％式％）
あり、電気絶縁材料用として迩する。There is a general formula (%) in the round-smelling acupuncture agent, and it is used as an electrical insulating material.
実施例
テトラブロモビス２ＸノールＡとデト２７°ロモピスフ
ェノールＡジグリシジルエーテルｔモル比で１：２ｔ７
０貞Ｊｌｌ鄭お１ひクレジルジフェニルホス２ニー）３
０崖ＪＩＨｆｌ−配甘し、ついでベンジルジメチルアミ
ン０．２Ｊ［１１部に加え１１２０℃で２時間反応場せ
７ｊｏここで傅らｎ沈ＤＬ応切に、敵状でめり、２１℃
の１度で５ｏ日間株管しても、にこりおＬひ沈殿σなか
った。Example Tetrabromo bis 2
0 Chung Jll Chung Oh 1 Hi cresyl diphenylphos 2) 3
Add 0.2 J [11 parts of benzyldimethylamine] and place in a reaction chamber at 1120°C for 2 hours.
Even when the stock was kept in a tube for 50 days at 1 degree, there was no precipitation.
比ｌＩＲ例
テトラブロモビスフェノールＡとテトラブロモビス２エ
ノールＡジグリシジルエーテルｔ０皇駕ｓ配甘し、つい
で、ベンジルジメチルアミンｔ）、２ＭｊＩｋ部を刃口
え、１２０℃で２時間反応させたＯにで侍らｎ次反応物
ｒｒ敵坏でるるか、２１℃の１直で保官し丸ところ、２
日間で沈毅した・
以上．＊施ガ，比［？！Ｉからも明らかな樟に、テトラ
ブロモビスフェノールＡとテトラブロモビス２エノール
Ａジグリシジルエーテルとの反応ＶＣおいて，リン酸エ
ステル系化合智を介在させたことにエフ、電気絶縁材料
として鳩し次数状１ＩＩｉ燃剤を襄造する事が出米几。Comparison IR Example Tetrabromobisphenol A and tetrabromobis2enol A diglycidyl ether were mixed, then benzyldimethylamine (t) and 2MjIk were added to the knife and reacted at 120°C for 2 hours. So, the samurai and the n-th reactant rr are the enemies, and the officer is on the 1st shift at 21℃, and the 2
It all settled down in just a few days. *Sega, ratio [? ! In the reaction VC of tetrabromobisphenol A and tetrabromobis2enol A diglycidyl ether, it is clear from I that phosphoric acid ester-based compound technology is interposed in camphor, and F. is used as an electrical insulating material. It is now possible to produce Type 1IIIi fuel.
Claims (1)
スフェノールＡジグリシジルエーテルと全外部ＯＪｍ鏑
Ｏ存在下で反応させ九美累ｔｔ有する＃ｌ燃剤。 ２、テトラブロモビスフェノールＡとテトラブロモビス
２エノールＡグリシジルエーテルの反応モル比か１：１
〜１：５でめる臀ＦＦ縛求のｊｌ＠ｆｌｌＪＪＥ躯の臭
素を富有する娯燃剤。[Scope of Claims] 1. #1 refueling agent having a total of 90% by reacting tetrabromobisphenol A and tetrabromobisphenol A diglycidyl ether in the presence of OJmO. 2. The reaction molar ratio of tetrabromobisphenol A and tetrabromobis2enol A glycidyl ether is 1:1.
A bromine-rich recreational combustion agent with a 1:5 ratio.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5337982A JPS58168637A (en) | 1982-03-30 | 1982-03-30 | Bromine-containing flame retarder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5337982A JPS58168637A (en) | 1982-03-30 | 1982-03-30 | Bromine-containing flame retarder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58168637A true JPS58168637A (en) | 1983-10-05 |
| JPS6224014B2 JPS6224014B2 (en) | 1987-05-26 |
Family
ID=12941180
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5337982A Granted JPS58168637A (en) | 1982-03-30 | 1982-03-30 | Bromine-containing flame retarder |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58168637A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009537651A (en) * | 2006-05-15 | 2009-10-29 | ブロマイン コンパウンズ リミテッド | Flame retardant composition |
-
1982
- 1982-03-30 JP JP5337982A patent/JPS58168637A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009537651A (en) * | 2006-05-15 | 2009-10-29 | ブロマイン コンパウンズ リミテッド | Flame retardant composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6224014B2 (en) | 1987-05-26 |
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