JPS58147493A

JPS58147493A - 熱分解法用の防汚剤

熱分解法用の防汚剤

Info

Publication number: JPS58147493A
Authority: JP; Japan
Prior art keywords: antifouling agent; tin; antimony; metal; bath
Prior art date: 1982-02-12
Legal status : Granted

Application number

JP1872883A

Other languages

English (en)

Japanese (ja)

Other versions

JPS6350399B2 (enrdf_load_stackoverflow

Inventor

ラリ−・エルバ−ト・リ−ド

ランド−ル・アラン・ポ−タ−

フロイド・イ−・フア−ハ・ジユニア

ジヤツク・ポ−ル・ギイロリイ

Current Assignee

Phillips Petroleum Co

Original Assignee

Phillips Petroleum Co

Priority date

1982-02-12

Filing date

1983-02-07

Publication date

1983-09-02

1983-02-07 Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co

1983-09-02 Publication of JPS58147493A publication Critical patent/JPS58147493A/ja

1988-10-07 Publication of JPS6350399B2 publication Critical patent/JPS6350399B2/ja

Status Granted legal-status Critical Current

Links

239000002519 antifouling agent Substances 0.000 title claims description 101
238000005979 thermal decomposition reaction Methods 0.000 title 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 83
229910052718 tin Inorganic materials 0.000 claims description 82
229910052787 antimony Inorganic materials 0.000 claims description 74
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 71
229910052751 metal Inorganic materials 0.000 claims description 40
239000002184 metal Substances 0.000 claims description 40
238000000034 method Methods 0.000 claims description 36
239000000571 coke Substances 0.000 claims description 27
229930195733 hydrocarbon Natural products 0.000 claims description 27
150000002430 hydrocarbons Chemical class 0.000 claims description 27
239000007789 gas Substances 0.000 claims description 22
239000007788 liquid Substances 0.000 claims description 20
239000004215 Carbon black (E152) Substances 0.000 claims description 18
239000000203 mixture Substances 0.000 claims description 18
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 15
230000015572 biosynthetic process Effects 0.000 claims description 9
229910052742 iron Inorganic materials 0.000 claims description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
230000003373 anti-fouling effect Effects 0.000 claims description 5
150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
239000013040 bath agent Substances 0.000 claims description 4
239000001301 oxygen Substances 0.000 claims description 4
229910052760 oxygen Inorganic materials 0.000 claims description 4
238000001816 cooling Methods 0.000 claims description 3
239000003350 kerosene Substances 0.000 claims description 3
238000000197 pyrolysis Methods 0.000 claims description 3
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 2
150000002894 organic compounds Chemical class 0.000 claims description 2
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 3
238000009833 condensation Methods 0.000 claims 1
230000005494 condensation Effects 0.000 claims 1
238000002360 preparation method Methods 0.000 claims 1
239000002689 soil Substances 0.000 claims 1
238000005336 cracking Methods 0.000 description 42
229910052732 germanium Inorganic materials 0.000 description 31
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 31
239000000243 solution Substances 0.000 description 28
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
238000002474 experimental method Methods 0.000 description 18
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 16
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 12
239000005977 Ethylene Substances 0.000 description 12
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
229910052799 carbon Inorganic materials 0.000 description 10
229910052757 nitrogen Inorganic materials 0.000 description 10
239000002253 acid Substances 0.000 description 9
-1 antimony trisulfate Chemical compound 0.000 description 9
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 8
239000007983 Tris buffer Substances 0.000 description 8
238000004519 manufacturing process Methods 0.000 description 8
229910000831 Steel Inorganic materials 0.000 description 7
229910001293 incoloy Inorganic materials 0.000 description 7
239000010959 steel Substances 0.000 description 7
KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 6
150000001875 compounds Chemical class 0.000 description 6
229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 5
150000001463 antimony compounds Chemical class 0.000 description 5
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
150000007513 acids Chemical class 0.000 description 4
229910002091 carbon monoxide Inorganic materials 0.000 description 4
238000004939 coking Methods 0.000 description 4
229910052736 halogen Inorganic materials 0.000 description 4
150000002367 halogens Chemical class 0.000 description 4
239000002904 solvent Substances 0.000 description 4
238000012360 testing method Methods 0.000 description 4
238000012546 transfer Methods 0.000 description 4
229910019142 PO4 Inorganic materials 0.000 description 3
229910045601 alloy Inorganic materials 0.000 description 3
239000000956 alloy Substances 0.000 description 3
238000000576 coating method Methods 0.000 description 3
238000000354 decomposition reaction Methods 0.000 description 3
230000008021 deposition Effects 0.000 description 3
239000003085 diluting agent Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000012530 fluid Substances 0.000 description 3
125000001183 hydrocarbyl group Chemical group 0.000 description 3
239000000463 material Substances 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
239000002245 particle Substances 0.000 description 3
235000021317 phosphate Nutrition 0.000 description 3
150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
239000010453 quartz Substances 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
150000003606 tin compounds Chemical class 0.000 description 3
QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical class [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 description 3
LBMNROZFDOBCLI-UHFFFAOYSA-N 2,4,5-trioxa-1-phospha-3-stibabicyclo[1.1.1]pentane Chemical class P([O-])([O-])[O-].[Sb+3] LBMNROZFDOBCLI-UHFFFAOYSA-N 0.000 description 2
229910000851 Alloy steel Inorganic materials 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
241000252067 Megalops atlanticus Species 0.000 description 2
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
LJCFOYOSGPHIOO-UHFFFAOYSA-N antimony pentoxide Chemical compound O=[Sb](=O)O[Sb](=O)=O LJCFOYOSGPHIOO-UHFFFAOYSA-N 0.000 description 2
ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
239000010953 base metal Substances 0.000 description 2
SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 2
229940077388 benzenesulfonate Drugs 0.000 description 2
DAMJCWMGELCIMI-UHFFFAOYSA-N benzyl n-(2-oxopyrrolidin-3-yl)carbamate Chemical compound C=1C=CC=CC=1COC(=O)NC1CCNC1=O DAMJCWMGELCIMI-UHFFFAOYSA-N 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000011651 chromium Substances 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
230000002301 combined effect Effects 0.000 description 2
230000000295 complement effect Effects 0.000 description 2
235000009508 confectionery Nutrition 0.000 description 2
RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 2
QVKQJEWZVQFGIY-UHFFFAOYSA-N dipropyl hydrogen phosphate Chemical compound CCCOP(O)(=O)OCCC QVKQJEWZVQFGIY-UHFFFAOYSA-N 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
229910052750 molybdenum Inorganic materials 0.000 description 2
239000011733 molybdenum Substances 0.000 description 2
APRJFNLVTJWEPP-UHFFFAOYSA-M n,n-diethylcarbamate Chemical compound CCN(CC)C([O-])=O APRJFNLVTJWEPP-UHFFFAOYSA-M 0.000 description 2
239000005871 repellent Substances 0.000 description 2
230000002940 repellent Effects 0.000 description 2
238000005507 spraying Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 2
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
FSBZGYYPMXSIEE-UHFFFAOYSA-H tin(2+);diphosphate Chemical compound [Sn+2].[Sn+2].[Sn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O FSBZGYYPMXSIEE-UHFFFAOYSA-H 0.000 description 2
FAKFSJNVVCGEEI-UHFFFAOYSA-J tin(4+);disulfate Chemical compound [Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FAKFSJNVVCGEEI-UHFFFAOYSA-J 0.000 description 2
ZSUXOVNWDZTCFN-UHFFFAOYSA-L tin(ii) bromide Chemical compound Br[Sn]Br ZSUXOVNWDZTCFN-UHFFFAOYSA-L 0.000 description 2
JTDNNCYXCFHBGG-UHFFFAOYSA-L tin(ii) iodide Chemical compound I[Sn]I JTDNNCYXCFHBGG-UHFFFAOYSA-L 0.000 description 2
QPBYLOWPSRZOFX-UHFFFAOYSA-J tin(iv) iodide Chemical compound I[Sn](I)(I)I QPBYLOWPSRZOFX-UHFFFAOYSA-J 0.000 description 2
TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
AHBGXHAWSHTPOM-UHFFFAOYSA-N 1,3,2$l^{4},4$l^{4}-dioxadistibetane 2,4-dioxide Chemical compound O=[Sb]O[Sb](=O)=O AHBGXHAWSHTPOM-UHFFFAOYSA-N 0.000 description 1
ODNBVEIAQAZNNM-UHFFFAOYSA-N 1-(6-chloroimidazo[1,2-b]pyridazin-3-yl)ethanone Chemical compound C1=CC(Cl)=NN2C(C(=O)C)=CN=C21 ODNBVEIAQAZNNM-UHFFFAOYSA-N 0.000 description 1
RDFRTKTYYPFBKS-UHFFFAOYSA-H 2-[(4-sulfanylidene-1,3,2-dioxastibetan-2-yl)oxycarbothioyloxy]-1,3,2-dioxastibetane-4-thione Chemical class C([O-])([O-])=S.[Sb+3].C([O-])([O-])=S.C([O-])([O-])=S.[Sb+3] RDFRTKTYYPFBKS-UHFFFAOYSA-H 0.000 description 1
239000010963 304 stainless steel Substances 0.000 description 1
235000001674 Agaricus brunnescens Nutrition 0.000 description 1
235000001270 Allium sibiricum Nutrition 0.000 description 1
229910021630 Antimony pentafluoride Inorganic materials 0.000 description 1
GUNJVIDCYZYFGV-UHFFFAOYSA-K Antimony trifluoride Inorganic materials F[Sb](F)F GUNJVIDCYZYFGV-UHFFFAOYSA-K 0.000 description 1
238000012935 Averaging Methods 0.000 description 1
RXWUWLVAEZLXCV-UHFFFAOYSA-N C(=S)O.[Sn] Chemical class C(=S)O.[Sn] RXWUWLVAEZLXCV-UHFFFAOYSA-N 0.000 description 1
TVPJHWWUFLJTEE-UHFFFAOYSA-K C(N)([O-])=O.[Sb+3].C(N)([O-])=O.C(N)([O-])=O Chemical class C(N)([O-])=O.[Sb+3].C(N)([O-])=O.C(N)([O-])=O TVPJHWWUFLJTEE-UHFFFAOYSA-K 0.000 description 1
KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
229910001182 Mo alloy Inorganic materials 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
229910000589 SAE 304 stainless steel Inorganic materials 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
229910021623 Tin(IV) bromide Inorganic materials 0.000 description 1
229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
FPNWMBLCHOUQEC-UHFFFAOYSA-N [Sb+3].[Sb+3].[Sb+3].C=1C=CC=CC=1P([O-])([O-])([O-])C1=CC=CC=C1.C=1C=CC=CC=1P([O-])([O-])([O-])C1=CC=CC=C1.C=1C=CC=CC=1P([O-])([O-])([O-])C1=CC=CC=C1 Chemical compound [Sb+3].[Sb+3].[Sb+3].C=1C=CC=CC=1P([O-])([O-])([O-])C1=CC=CC=C1.C=1C=CC=CC=1P([O-])([O-])([O-])C1=CC=CC=C1.C=1C=CC=CC=1P([O-])([O-])([O-])C1=CC=CC=C1 FPNWMBLCHOUQEC-UHFFFAOYSA-N 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
239000003905 agrochemical Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
229910000410 antimony oxide Inorganic materials 0.000 description 1
VBVBHWZYQGJZLR-UHFFFAOYSA-I antimony pentafluoride Chemical compound F[Sb](F)(F)(F)F VBVBHWZYQGJZLR-UHFFFAOYSA-I 0.000 description 1
229910000379 antimony sulfate Inorganic materials 0.000 description 1
229910000411 antimony tetroxide Inorganic materials 0.000 description 1
FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 description 1
229940007424 antimony trisulfide Drugs 0.000 description 1
WAFWAXOYAJEMTA-UHFFFAOYSA-K antimony(3+) N-phenylcarbamodithioate Chemical compound [Sb+3].[S-]C(=S)Nc1ccccc1.[S-]C(=S)Nc1ccccc1.[S-]C(=S)Nc1ccccc1 WAFWAXOYAJEMTA-UHFFFAOYSA-K 0.000 description 1
AUPGZUAMQOQBJL-UHFFFAOYSA-K antimony(3+) cyclohexene-1-carboxylate Chemical compound [Sb+3].[O-]C(=O)C1=CCCCC1.[O-]C(=O)C1=CCCCC1.[O-]C(=O)C1=CCCCC1 AUPGZUAMQOQBJL-UHFFFAOYSA-K 0.000 description 1
PTKKMZFSLBMRNL-UHFFFAOYSA-K antimony(3+);ethanethioate Chemical compound [Sb+3].CC([O-])=S.CC([O-])=S.CC([O-])=S PTKKMZFSLBMRNL-UHFFFAOYSA-K 0.000 description 1
XDEOZZDFNYGLHY-UHFFFAOYSA-K antimony(3+);octadecanoate Chemical compound [Sb+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XDEOZZDFNYGLHY-UHFFFAOYSA-K 0.000 description 1
KIQKNTIOWITBBA-UHFFFAOYSA-K antimony(3+);phosphate Chemical class [Sb+3].[O-]P([O-])([O-])=O KIQKNTIOWITBBA-UHFFFAOYSA-K 0.000 description 1
SICICTORIQWAKP-UHFFFAOYSA-K antimony(3+);thiophosphate Chemical class [Sb+3].[O-]P([O-])([O-])=S SICICTORIQWAKP-UHFFFAOYSA-K 0.000 description 1
PALVEAZBDSAOLL-UHFFFAOYSA-K antimony(3+);tribenzoate Chemical compound [Sb+3].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 PALVEAZBDSAOLL-UHFFFAOYSA-K 0.000 description 1
RPJGYLSSECYURW-UHFFFAOYSA-K antimony(3+);tribromide Chemical compound Br[Sb](Br)Br RPJGYLSSECYURW-UHFFFAOYSA-K 0.000 description 1
SEKOGOCBEZIJIW-UHFFFAOYSA-H antimony(3+);tricarbonate Chemical class [Sb+3].[Sb+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O SEKOGOCBEZIJIW-UHFFFAOYSA-H 0.000 description 1
NJGBSFDVMQSDTF-UHFFFAOYSA-K antimony(3+);triformate Chemical compound [Sb+3].[O-]C=O.[O-]C=O.[O-]C=O NJGBSFDVMQSDTF-UHFFFAOYSA-K 0.000 description 1
MVMLTMBYNXHXFI-UHFFFAOYSA-H antimony(3+);trisulfate Chemical compound [Sb+3].[Sb+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O MVMLTMBYNXHXFI-UHFFFAOYSA-H 0.000 description 1
NVWBARWTDVQPJD-UHFFFAOYSA-N antimony(3+);trisulfide Chemical compound [S-2].[S-2].[S-2].[Sb+3].[Sb+3] NVWBARWTDVQPJD-UHFFFAOYSA-N 0.000 description 1
VMPVEPPRYRXYNP-UHFFFAOYSA-I antimony(5+);pentachloride Chemical compound Cl[Sb](Cl)(Cl)(Cl)Cl VMPVEPPRYRXYNP-UHFFFAOYSA-I 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
MCHIUNWYDRZDHI-UHFFFAOYSA-K bis(2-ethylhexanoyloxy)stibanyl 2-ethylhexanoate Chemical compound [Sb+3].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O MCHIUNWYDRZDHI-UHFFFAOYSA-K 0.000 description 1
VLPHFAGGIRDLBN-UHFFFAOYSA-K bis(ethanethioylsulfanyl)stibanyl ethanedithioate Chemical compound [Sb+3].CC([S-])=S.CC([S-])=S.CC([S-])=S VLPHFAGGIRDLBN-UHFFFAOYSA-K 0.000 description 1
SKGVGRLWZVRZDC-UHFFFAOYSA-N butyl 2-sulfanylacetate Chemical compound CCCCOC(=O)CS SKGVGRLWZVRZDC-UHFFFAOYSA-N 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
150000001721 carbon Chemical class 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
239000012159 carrier gas Substances 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
239000003610 charcoal Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
GVEHJMMRQRRJPM-UHFFFAOYSA-N chromium(2+);methanidylidynechromium Chemical compound [Cr+2].[Cr]#[C-].[Cr]#[C-] GVEHJMMRQRRJPM-UHFFFAOYSA-N 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
238000004891 communication Methods 0.000 description 1
230000001351 cycling effect Effects 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
NZNMSOFKMUBTKW-UHFFFAOYSA-N cyclohexanecarboxylic acid Chemical compound OC(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-N 0.000 description 1
GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 1
238000005235 decoking Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
JVLRYPRBKSMEBF-UHFFFAOYSA-K diacetyloxystibanyl acetate Chemical compound [Sb+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JVLRYPRBKSMEBF-UHFFFAOYSA-K 0.000 description 1
238000010586 diagram Methods 0.000 description 1
JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
FFGHLLOLFQHABK-UHFFFAOYSA-L dibutyltin(2+);dodecane-1-thiolate Chemical compound CCCCCCCCCCCCS[Sn](CCCC)(CCCC)SCCCCCCCCCCCC FFGHLLOLFQHABK-UHFFFAOYSA-L 0.000 description 1
229940116901 diethyldithiocarbamate Drugs 0.000 description 1
LMBWSYZSUOEYSN-UHFFFAOYSA-N diethyldithiocarbamic acid Chemical compound CCN(CC)C(S)=S LMBWSYZSUOEYSN-UHFFFAOYSA-N 0.000 description 1
NKCWZXPMTVCPSF-UHFFFAOYSA-L difluorostannane Chemical compound F[SnH2]F NKCWZXPMTVCPSF-UHFFFAOYSA-L 0.000 description 1
AUYOHNUMSAGWQZ-UHFFFAOYSA-L dihydroxy(oxo)tin Chemical compound O[Sn](O)=O AUYOHNUMSAGWQZ-UHFFFAOYSA-L 0.000 description 1
238000007865 diluting Methods 0.000 description 1
LQRUPWUPINJLMU-UHFFFAOYSA-N dioctyl(oxo)tin Chemical compound CCCCCCCC[Sn](=O)CCCCCCCC LQRUPWUPINJLMU-UHFFFAOYSA-N 0.000 description 1
KUMNEOGIHFCNQW-UHFFFAOYSA-N diphenyl phosphite Chemical compound C=1C=CC=CC=1OP([O-])OC1=CC=CC=C1 KUMNEOGIHFCNQW-UHFFFAOYSA-N 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000000428 dust Substances 0.000 description 1
230000003628 erosive effect Effects 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
CTCOPPBXAFHGRB-UHFFFAOYSA-N ethanolate;germanium(4+) Chemical compound [Ge+4].CC[O-].CC[O-].CC[O-].CC[O-] CTCOPPBXAFHGRB-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000000446 fuel Substances 0.000 description 1
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YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 1
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150000004820 halides Chemical class 0.000 description 1
150000004678 hydrides Chemical class 0.000 description 1
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150000002431 hydrogen Chemical class 0.000 description 1
150000003949 imides Chemical class 0.000 description 1
229910001055 inconels 600 Inorganic materials 0.000 description 1
238000001764 infiltration Methods 0.000 description 1
230000008595 infiltration Effects 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
150000002484 inorganic compounds Chemical class 0.000 description 1
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150000002576 ketones Chemical class 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
150000004767 nitrides Chemical class 0.000 description 1
125000000082 organogermanium group Chemical group 0.000 description 1
VPPWQRIBARKZNY-UHFFFAOYSA-N oxo(diphenyl)tin Chemical compound C=1C=CC=CC=1[Sn](=O)C1=CC=CC=C1 VPPWQRIBARKZNY-UHFFFAOYSA-N 0.000 description 1
VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 1
238000012856 packing Methods 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Chemical group 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000002203 pretreatment Methods 0.000 description 1
239000001294 propane Substances 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
FUQQDLUELDZSJX-UHFFFAOYSA-N propylcarbamothioic s-acid Chemical compound CCCNC(S)=O FUQQDLUELDZSJX-UHFFFAOYSA-N 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000010926 purge Methods 0.000 description 1
239000013557 residual solvent Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000009738 saturating Methods 0.000 description 1
238000002791 soaking Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
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239000001119 stannous chloride Substances 0.000 description 1
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238000004230 steam cracking Methods 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
239000012085 test solution Substances 0.000 description 1
HDVLQIDIYKIVRE-UHFFFAOYSA-N tetrabutylgermane Chemical compound CCCC[Ge](CCCC)(CCCC)CCCC HDVLQIDIYKIVRE-UHFFFAOYSA-N 0.000 description 1
AFCAKJKUYFLYFK-UHFFFAOYSA-N tetrabutyltin Chemical compound CCCC[Sn](CCCC)(CCCC)CCCC AFCAKJKUYFLYFK-UHFFFAOYSA-N 0.000 description 1
FDNSKZMGQQDYQB-UHFFFAOYSA-N tetradodecylstannane Chemical compound CCCCCCCCCCCC[Sn](CCCCCCCCCCCC)(CCCCCCCCCCCC)CCCCCCCCCCCC FDNSKZMGQQDYQB-UHFFFAOYSA-N 0.000 description 1
JTGNPNLBCGBCMP-UHFFFAOYSA-N tetraoctylstannane Chemical compound CCCCCCCC[Sn](CCCCCCCC)(CCCCCCCC)CCCCCCCC JTGNPNLBCGBCMP-UHFFFAOYSA-N 0.000 description 1
ILEXMONMGUVLRM-UHFFFAOYSA-N tetraphenylgermane Chemical compound C1=CC=CC=C1[Ge](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 ILEXMONMGUVLRM-UHFFFAOYSA-N 0.000 description 1
CRHIAMBJMSSNNM-UHFFFAOYSA-N tetraphenylstannane Chemical compound C1=CC=CC=C1[Sn](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 CRHIAMBJMSSNNM-UHFFFAOYSA-N 0.000 description 1
DUYAAUVXQSMXQP-UHFFFAOYSA-M thioacetate Chemical compound CC([S-])=O DUYAAUVXQSMXQP-UHFFFAOYSA-M 0.000 description 1
ALRFTTOJSPMYSY-UHFFFAOYSA-N tin disulfide Chemical compound S=[Sn]=S ALRFTTOJSPMYSY-UHFFFAOYSA-N 0.000 description 1
229910001887 tin oxide Inorganic materials 0.000 description 1
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UVZCKHGWDSETCE-UHFFFAOYSA-B tin(4+) tetrathiophosphate Chemical class P(=S)([O-])([O-])[O-].[Sn+4].P(=S)([O-])([O-])[O-].P(=S)([O-])([O-])[O-].P(=S)([O-])([O-])[O-].[Sn+4].[Sn+4] UVZCKHGWDSETCE-UHFFFAOYSA-B 0.000 description 1
229910000375 tin(II) sulfate Inorganic materials 0.000 description 1
AFNRRBXCCXDRPS-UHFFFAOYSA-N tin(ii) sulfide Chemical class [Sn]=S AFNRRBXCCXDRPS-UHFFFAOYSA-N 0.000 description 1
LTSUHJWLSNQKIP-UHFFFAOYSA-J tin(iv) bromide Chemical compound Br[Sn](Br)(Br)Br LTSUHJWLSNQKIP-UHFFFAOYSA-J 0.000 description 1
HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
YUOWTJMRMWQJDA-UHFFFAOYSA-J tin(iv) fluoride Chemical compound [F-].[F-].[F-].[F-].[Sn+4] YUOWTJMRMWQJDA-UHFFFAOYSA-J 0.000 description 1
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
229910003470 tongbaite Inorganic materials 0.000 description 1
HVYVMSPIJIWUNA-UHFFFAOYSA-N triphenylstibine Chemical compound C1=CC=CC=C1[Sb](C=1C=CC=CC=1)C1=CC=CC=C1 HVYVMSPIJIWUNA-UHFFFAOYSA-N 0.000 description 1
239000000052 vinegar Substances 0.000 description 1
235000021419 vinegar Nutrition 0.000 description 1
238000005406 washing Methods 0.000 description 1