JPS58134738A - Manufacture of flame-retarded laminated board - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for constructing flammable paper-2 enol horizontal layer plates (7) into frame steel (9 horizontal layers, 1 m).Recently, insulating materials have become increasingly popular. The laminate plate 17t used for L and Denshi Shinyagi was made by training in the steel industry. I don't like Demei C, so I use it in conjunction with 0qr Dan's full-kil 2 enol T-7S Norm and denature it with drying oil etc. as a 7t7 for use in punching boards.
Snoichiru I/M Maro is contributing◎ 4゛.

However, absolutely 11$l+Kll! Cooled laminate/
, □.

It is cheaper than steel 91 and laminate. ) Chemical qJ Hosui is becoming stronger, and from another point of view, I-type agents such as drying oil, which are conveniently used to improve punching workability, are becoming more and more popular. JII combustion of laminates is becoming more complicated, and phosphorization is difficult.
Is there a method that uses a reaction maximum refueling agent that is chemically bonded to the rX additive type refueling agent and the refueling agent that is added in the middle of the process? Kame4oM@rXJk
Life agent remains on surface item A due to water reaction'fcK)Il
Is it preferable to react with 14C to a conventional sidyl ether-type oxidation-type oxidation agent with a noeboxy island? If the varnish is used or σga is used, it will react in the clay paper and if it remains, the varnish will be applied to the base of the reaction and the varnish. There was a problem with Nisokochoto & J Kozosaku Tosei.

The purpose of the present invention is to cut out the above-mentioned interstitial points, and to improve the punching processability at 9%♀, and to reduce the threat of the layer by causing a reaction. '(Production and production of laminates with halogenated snouts for use as mold release copper, (lJ't
``Meru 0, 2 Enol embroidery, Phosphorus unconverted, Chi 1, Halogen unconverted, 1! twta brittle varnish, τ Choku, friends, this nt play base material, t agitation, prepreg. [Create a JII flammable copper layer by heating and press-forming it on prepreg with a steel foil or without bending to produce a JII flammable copper layer. As threading 8 cuts a) Epoxidized culture oil (1) and Cm +) 11 + a + n halogenated bisphenol ([1m (01L)
X10Br1ft, tDC6'tyy, j=1~4
m, n=0 to 3, jj? ! Even if they are the same, they are different and have a different percentage) and phenolic steel (where X means Br housing or C1 means Lm).
= 1 to 5 CRU hydroxide (1tH alkyl group) is subjected to a heating reaction under the presence of a salt catalyst and the resulting reaction product is used as a tq# image. The present invention is unique in that it provides a combustible oJki that can achieve low knitting punching properties and kCsC. Seed wJ strawberry and halogenated bisphenol compound 7z/-klil (il)
l) k411ti-5+42 2nd stage 6th soft amine, 4th stage ammonium salt, alkoxide alkaline lid 14-
A water reaction (/J) 10 in which the reaction catalyst between the epoxidized product and the 7-enol water tank was added, the reaction bath was added, and the reaction was carried out again with a 0* bath agent (/J) 10 Gunn bisphenol f'tl? ! 1, which almost eliminates halogenated phenols, can be used for medical treatment; As a bath additive used in combination with a net
tolueno, benzene, xylene, methyl ether ketone,
Ketone thread bath media such as methyl imbutyl ketone and hydrocarbon water turbines are preferably used. When applied to a chemical, it may cause a decrease in fermentation and electrical properties, so it is best to use a VC to leave almost no unreacted halogenated material. Bisphenolated ft1
The ratio of Il11 and halogenated phenol [10 to 4
0 mol % = 90-60 mol % - AsM”tt, <s 1:! as halogenated bisphenolization ft111 increases.
〇Epoxidation according to the present invention 4*--Oxidize and epoxidize 2J [# 曾] of the oil in the oil, which does not bind with oil, and epoxidize with the following. 7 Seed oil, epoxidized soybean straw, epoxidized castor oil, epoxidized [contains water castor oil, etc.] The halogenated bisphenol compound represented by general formula (1) contains tetrapro-bisphenol-□ A (TBA). Teijinka l1tIIiJ #1 name 'Raiya Guard 20'.

00),) Ripromobis2-Mono-A1 Dibromo-bisphenol-A Monobrof Nigesphenol-A, 43
/5'-tetrabromo-4,4'-dihydroxydiphenylmethane, hlas/-tetrachloro-4,4'
-cyhydroxydi2enylgloban-2.2. s: to'
he5'-nato2chloro4.4'-dihydroxydi2enylmethane, s:s:b,b'-nato2promo4.4
'-dihydroxydiphenylbutane 2.2%s:5:s
, DATETO2CHLORO4.4'-DIHY SYNTHESIS (III)
Hexalogonated phenol @KU, monobromophenol, dibromophenol, tribromophenol, tetrabromo2enol, pentabromophenol,
Monochlorophenol, dichloro-2-enol, trichlorophenol, di-110-phenol, pentachlorophenol, monobromocresol, l□ dibromocresol゛ = tribromocresol□.

But-2-promocylene'-ol, monochlorocresol, di-cresol, tric-cresol, natoc-chlorocresol, monoglomoxylenol, dibromoxylenol, tribromoxylenol, mono-tetraoxylenol, dichloroxylenol, trichloro If xylenol etc. react with (1) and (11), a small amount of the epoxy group of the star will ultimately remain, and it will be difficult to form the laminated material. It is preferable to react with the 2 enol group H.The reason is that the epoxy 1 of (1)
Child q1 distribution Q, (it) hydroxyl μ.

It is preferable to make it so that Q/q>R/T+T/l, when the distribution turtle is T, it is preferable to set it so that Q/q>R/T+T/l. [Use (
ill) = 1/9 to 4/6 (mole ratio and cho Cbarl!1
A flame retardant with a large number of molecules and a large number of halogens is added to a single-layer laminated board.Next, this flame retardant base varnish contains resol type phenol 11ms and dry wood. Oil-modified phenol III fats, liquid polyptadiene/wrinkle-type phenol, xylene-based phenol fats, etc., which are usually used as enol additives for laminated layers, are used. Phosphorous chemical compounds include triphenylphos 2ate, talesyl diphenyl phosphate, xylyl diphenyl phos 7ate, and #1.

Below is an O1 with a beautiful body and a TMC salary of 1! r-defeating FFI case, cold 4I meeting, with tachometer (/J 4th eye lasco, epoxidized soybean 7481000g (7 Dekasizer U-130PA, Adele Argus oxirane Oxygen Hiro & 99, Evo Senshi Tooth MiFJ250, Q /q=4.5)
Mackerel≠〒Cutluene 46g, Tet 97'O% Bisphenol-A 272g (N1 ear card 2000 Maenin Kasei Ai product name water ginseng white 272, kt/γ = 1.0)? Rib p mophenol 827.5g (water tIk base pulse 331T/1=
2b) Heat to 100℃ with τ, scale in a bath, add 31.5g of diethylamine to 50℃, and heat to 115℃.
I went to a reaction school. At 8 o'clock, Yami Shun's reaction area was collected and collected, and the unreacted q>-r trabromobisphenol A & engineered human-libromonenophenol was obtained by sampling the molecular type distribution (HLC Toyo Toyo Soyu-801゛ type)-〇 molecular type distribution. -Rukaina Jin and tillMI
The weight was 40X neck%''titsu.

Sweet and sour? ! 12 Amazur IFII and the same 11EJ7j Scooter Ebo Naka Shikasu plate?
*(Adekanizer 0-130PA provided by Adeka Argus, 2 in 1 lIl! Raw - Straight melon 9 u) 1000g (Q
/Q"4 island, toluene 142g, tetrabromobisphenol-^ (21 ear guard 2000f humanization @Mushinamen 136g (R/r-u5), jib-more mno #50
Add 4g (T/ to 2), heat to 100°C to dissolve, cool to 050°C, and then add 246gt of benzyldimethylamine.
mL, asst,, SO5℃'tabg, collected the 9th and 6th time, Pavilion IX, Yinglichi, ^Diankuro (HLC Quanyo 14 axis 80111m)'', 10-fold distribution in the field, bL corresponding Tetokupro peak Bisphenol A L Hijibromo 2 Eno k Kana - Koto tm Song 9・BTt Negative α2441 Dosi deme 9ta・ 曾*?H 曾IC111tFIIitJy9x:xtC1xg中V
4t, 7 mani oil 100100O Decacizer U-180
゜oxilanic acid accumulation degree 92% epoxy equivalent i゛approximately 167Q
/q=6.0) Toluene 46g1 Tetrabisphenol A (Fire Guard 2000 Teijin Kasei product name) 544g
(R/γ=2), Bentab O%7$nor 978g (T
/1=2) was added and the temperature was 100°C. After cooling to 50°C, tetramethylammonium chloride 37.8
gk was added and reacted at 150°C. At 10:00 RSJ wave, the reactant was collected and the molecular weight distribution was established using Tsutsuya So chromatography, and it was confirmed that there was no unreacted tetrabromobisphenol A or tribromophenol.
The weight content tr was 144.4% by weight.

Base resin 8bX example Synthesized amount of 206 and 3000g of tung oil Metafre:'.

Sol 4350g%'1': Halatoluenesulfone branch 1
0g was mixed and reacted at 110°C for 1 hour. Then 7650g of phenol, 50L of paraform, 102125%
480g of ammonia water for 5 hours at 80℃ - jJX ratio,
I let it happen. Then, it was concentrated under reduced pressure, and when the liquid temperature reached 85°C, the concentration was completely stopped, and the pressure was returned to normal pressure, and 2400 g of toluene was added.
, methanol 6800g':! The gelation time on a hot plate at 160°C was 216 seconds with 1% o resin and 65 varnishes.

This base varnish was impregnated with a non-flammable agent according to the composition shown in Table 1 on cotton linter paper pre-treated with a cooled zero-water bath phenol side fat. It was impregnated with varnish containing all non-combustible agents and dried to create Gregreg. A few pieces of Leslipreg were laid together, one side was coated with a shoulder adhesive, and a layer of fC copper foil was laid down and thermoformed for 60 minutes at 150°C under a pressure of 100 kg/- to create a copper layer board. The characteristics of the laminate are shown in its glazed coating 1, which was constructed in accordance with JISC-6481.

Table 1 Characteristics of copper hydrangea plate () Sosa 1. f++ssl

Claims (1)

[Scope of Claims] 1. Add phosphorus and phosphorus to phenol am, leave a face line, and then yoke it to paper material to create a grid. , to the GriGreg @
Do not heat and pressure mold the vessel until 1 hour.
1ll! 1 steel company 9 laminated 4& or when making a metal wire, halogenated bisphenolized e-chi (however, X
tffBr17ttffCj', 4=1~4s
Men = 0 to 5, k, 1, m, nrz are the same as each other, %JI and tL) and n halogenated enol (XrlBr1
fcrlCI': 21 g of μ water at t7r=p=1 to 5
1fcrI alkyl chicken) is heated to a clay & sex catalyst for a heating reaction. 4wILgJ oil fJ-T-boxy"kk'l"Q%") halogenated bisphenol with cut q-hydrogen 1kkr% Norihalogenated phenol 1i
As IJQJ Suijo Toyu Mkt, I) (/J Haikan Iris 9. Rofq) When I make distribution 1IIT of distribution ffkR1/9, Q/q>R/r+T/l″t'@aL ui'cIeit
The yoke of IFl-claims, etc., is that the reaction product sweetened by t is conveniently used as a halogen thread. U No. IJ
How to make the JWa board of JL Kiyoshi's Ginjitsujuku Hatoei. The halogen content of old halogenated Zengji is 20~