JPS58121225A - Bbc brown boveri & cie - Google Patents

Abstract

(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

DETAILED DESCRIPTION OF THE INVENTION As is well known, for twisted nematic cell type liquid crystal (PK) display devices (also referred to as TN displays), nematic liquid crystal materials (positive anisotropy of dielectric constant) are used. DK of
A) is required. In this case, DKA or ΔC is.

Δe=εI/-gI where b'g is the dielectric constant parallel to the longitudinal axis of the molecule and B4 is the dielectric constant perpendicular to the longitudinal axis of the molecule)
Defined by

For the multiplex operation of cells of this type, above all a contrast characteristic curve as steep as possible for the liquid-crystalline material is desired, i.e. as drastic a change as possible in the extinction properties when the applied field voltage changes. be done. This can also be improved by adapting the two selection criteria to the available anisotropic materials.

In other words, (1) the value of the ratio of the elastic modulus of the bending side and the spreading side (Ks
s/Ktt value) as small as possible.

(b) Optimization can be achieved by making the ratio of D K A (jg) to K (#) perpendicular to the nematic axis, that is, the value of Δ6/ε5, as small as possible. Detailed literature on these matters, such as F, G
haradjedagj i and others11IRev* Phy
s, °mupp1-' Volume 11, 1976, p. 467.

Written by A. R. Metz' 8ID Dlgest, T
echn, Papers' Volume ■, 1978% 7
Page 0 and P, M, Al by others.
Trams, B1. Dav, :Bd, '2nd
1, 1974, 146.

In order to select anisotropic compounds based on the above criteria, two types of anisotropic compounds are currently provided, each containing 2 or 3 rings and having the following structural formula: Type and Type II: and in the above formula, al, , 1 and - are carbon aromatic, heteroaromatic or alicyclic rings 5 such as benzene rings.

Pyrimidine ring and trans-cyclohexane ring
s x" and ya are so-called crosslinking groups, for example -00
0-, -0H=N-1-0HsO-1-N==N-, -
01(.

OH, - or a single bond and 1'L, R is a so-called side chain group, - for example an alkyl group in which the alkyl group generally contains from 1 to 12 carbon atoms in single-chain or branched steels. , an alkyloxy group, an alkanoyloxy group or an alkylamino group.

Type I materials have a high positive DKAfi and a correspondingly low threshold voltage due to the relatively strong polarization R''10N K in the direction of the long molecular axis (nematic axis or director), but with the exception of multiple They have a disadvantageously high ΔC/l value for plex driving and a relatively high *s/Ktt value which is likewise disadvantageous for the same purpose.The contrast characteristic curve of these materials is relatively flat.

Materials of type ■ are nonpolar or only slightly polar and have a small Δ required for a steep contrast characteristic curve.
#/IL value as well as a small Kss/Ku value compared to type I substances (at comparable chain lengths). Furthermore, the viscosity of type ■ substances is lower than that of type ■.

For all these reasons, the b-tropic material of type ■ is TN
! ! It is not acceptable as a component of the PK mixture for the multisolex drive shown.

A significant drawback of known anisotropic materials of type H is:

The tendency to form smectic phases is extreme, especially if the substances have relatively long chain groups, for example with some length of the alkyl group. There are several references on this subject, such as %Flυ-ss1gkrlstalle.
in Tabelleq', VER German Publishing House,
Known values are listed from E. Leibzig (1974).

The appearance of a smectic phase in a marketable compound narrows or eliminates the range of nematic phases that are the only ones suitable for rounding of the TN designation.

It is an object of the present invention to provide new anisotropic compounds of the type (1) in which the tendency to form smectic phases is suppressed or eliminated, and for this purpose it is essential that the compounds in question primarily Mention may be made of increasing the temperature of the nematic phase with a nematic phase or with a comparable structure.

Surprisingly, it has been found that said am can be especially achieved by introducing at least one so-called lateral substituent in a ring position into the basic structure in a precisely restricted nine group of compounds of type II.

The novel anisotropic compounds of the present invention of type (1) having a nematic phase are characterized by the formula (1):

In this case, A is the formula (to), (ti) or (12)
represents one cyclic group, in which case formula (11) can represent a 2°5-bonded pyrimidine ring as well as a 5,2-bonded pyrimidine ring.

The cyclic group of formula (12) is always present in the trans-configuration indicated by the dot, provided that Bl is not a hydrogen atom and thus does not form a cis/trans isomer.

The bridging member in formula (1) may be a single bond, an ethylene group (-OHmO-), a methyleneoxy group (-0H,0-) or a oxymethylene group (-008m), as long as it is not excluded below.
-).

The index represents the following = fi is 1 or 2°p is 0 or 1 or 2. r represents 0 or 1.

The substituent X on the side of at least iml, which is the gist of the present invention, is a halogen atom, that is, a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom, or a methyl group (-OHs) or a nitrile group (-ON). be.

If the molecule in formula (1) contains multiple lateral substituents X, these may be the same or different.

In this case, the following conditions exist for the compound of the invention of formula (1):
x).

The methyleneoxy group or oxymethylene group is not directly bonded to any of the aromatic groups of (13), (14) or (15) at one carbon atom of said group, i.e. the molecule of formula (1) In other words, the formula:
, (14) or (15)), i.e. a benzyl ether having a group of formula 1: (in which Ar and Human are as defined above) and the corresponding compounds have been found to have a tendency to destabilize when used as or in liquid crystals.

(B) In addition, for the novel compounds of the invention of formula (1), the following conditions exist: only one of the groups R1, R'' represents a cyclic group of formula (13) or (16), or both If neither represents the cyclic group, and the person has formula (12), and the bridge member zl or z6 represents a single bond, then at least one of X in the molecule of formula (1) is a methyl group. be.

Furthermore, for many purposes, it is possible that the cyclic group of formula (12) and the cyclic group of formula (16) are not directly bonded to an oxygen atom on the one hand and an oxygen or nitrogen atom on the other hand, respectively. is advantageous.

Finally, for particularly stable compounds of formula (1), if the aromatic ring has a side substituent X=ON attached to the ring in 4G, then Advantageously, it is not present between atoms.

Bl and RM may be the same or different and each represents a hydrogen atom, an alkyl group having 1 to 12 carbon atoms in the alkyl group, an alkoxy group, an alkanoyl group [alkyl-0(0)-0- ) or an alkylamino group [represented by alkyl-N(I()-), in which case the alkyl group may be linear or branched and optionally chiral, furthermore Bl and/ Or 8 filth is formula (13)
% formula % of ~(16): In the above formulas (13) to (16), the @ groups Bl,..., B@ represent the enumerated circles with respect to the acyclic R1 and 83, and XbP and r are the above-mentioned Same as) and bridge base ZS
-Z. represents 9 things described with respect to 2, and in this case, 2 and z1 to 2- in the molecule of formula (1) may be the same or different.

The novel compounds of formula (1) of the present invention are generally dinuclear.

Advantageous new compounds of the invention, which may be trinuclear or tetranuclear, have the formulas (22) to (33) as described and defined in claims 2 to 13.

Furthermore, the present invention provides at least one compound of formula (1),
For example, it is a liquid crystal mixture containing one or more of the compounds of formulas (22) to (33). This will be explained further below.

In one group of preferred compounds of the invention, X represents a methyl group; in another group of preferred compounds of the invention, X represents a fluorine, chlorine, bromine or iodine atom, in which case fluorine Particular preference is given to single atoms and chlorine atoms.

In another group of compounds according to the invention, X represents a nitrile group.

If the compounds of formula (1) have strong lateral dipolar moments (which can occur, for example, as a result of two or more X being nitriles and/or halogens), they generally also have strong negative polar moments. For liquid crystal displays which must have a Δε and then be able to operate on the basis of the so-called inverse guest/host effect, for example, and also for certain types of diffusive scattering cells, DAP and HN displays. can be used for.

Compounds of the invention have at least 1 ff1oI! φ containing a substituent in the 1-position may, however, also have two or more substituents in the 1-position, in which case each molecule (1) may contain substituents X1 in the same or different lateral positions, e.g. It can have methyl+halogen, methyl-nitrile, halogen-nitrile or hamethyl+halogen+nitrile.

Regarding the novel compounds of the invention of formula (1).

It is based on the recognition that in order to prevent or suppress the tendency to form a smectic phase in compounds with properties of type II, the substituent at position 11 should have a constant but not too large volume. The lower limit of the volume of substituents at appropriate side positions in the present invention depends on the tendency of the basic structure B [i.e., how many positions of substituents X are present and formula (1)] to form a smectic phase. . Generally, the introduction of one or more substituents having a large volume compared to the corresponding basic structure without substituents at any position causes a decrease in the clearing point. Therefore, for the dinuclear compound of formula (1), the side substituents fluorine, chlorine and methyl, which have a small volume, are advantageous. The volume of substituent X is t! increasing in the following order: v<at<OHs #Br<J<ON Two synthetic methods are particularly suitable for preparing the compounds (1) according to the invention, ie on the one hand, e.g. or introducing one or more desired substituents X into the corresponding base compound by bromination, followed by optionally one substituent X1
For example, chlorine is replaced by another, such as fluorine, by halogen exchange, or, to introduce a nitrile group, K is replaced by reaction of the corresponding halogen compound with a metal cyanide. In a similar manner, a carzenyl group can be introduced into the corresponding base compound and then reduced to a methyl group, for example by catalytic reaction with a formylating agent such as oxalyl chloride.

Another synthetic method consists of using partial compounds already provided with the corresponding substituents X and combining them (for example by condensation) to form the compound (1).

In order to further transform one side group Bl, B@, the compound of the invention can be converted into another compound of the invention using methods known per se.

Suitable bases or starting compounds are known or can be obtained on the basis of methods analogous to known methods; suitable starting compounds with a pyrimidine nucleus are described, for example, in East German Pat. It is known from Japanese Patent Application Publication No. '2641724 FIiIJII.

A general example for producing a novel anisotropic compound is shown in the following reaction formula, where the symbols in the formula represent those described in formula (1).

Reaction Warrior Chemie, Volume 93 (1981) 65 Sukai Yume Brittle Reaction Formula C Ll, L!=Leaving group 3) Reiche and other domains, -Ohem, Ha
r” @Volume 93 (1960) 88j [Reference reaction formula Reaction formula E The compound of the present invention of formula (1) is the known compound K of type ■
It can be used in a similar manner for PK mixtures in multiplex driven T-N displays and offers the advantage of eliminating or reducing smectic phase problems.

The PK mixtures of the present invention can contain one or more compounds of formula (X) in total to about 60 molar proportions. In this case the proportion of the individual compounds of formula (1) is approximately 30% of the mixture.
It becomes less than molti. As the remaining component, 1 P of the present invention
The K mixture usually contains one or preferably several compounds of type (I).The invention will now be explained in more detail in the Examples. The temperature properties of the mesophase are indicated by the corresponding temperature values between the signs X (crystalline), S (smectic), N (nematic) and IC anisotropy.

Example 1 4-Hydroxy-4'-hentyl-diphenyl is reacted with elemental chlorine to produce 3-4-4-hydroxy-4'-
pentyl diphenyl and condensed with n-hexyl iodide to form a compound of the invention of formula (1), i.e. formula (100)
2-3-chloro-4-hexyloxy-4'-hentyl-
Shimaru converted to biphenyl.

In a similar form, but without chlorination, formula (101): was manufactured. We will investigate this mesophase temperature.

K 1.7 N 11. The compound of the invention of formula (Zoo) with II exhibits a pure nematic phase, while 82
The surprising fact has been found that the comparative compound of formula (101) having 884& has no nematic phase and is smectic within the entire meso phase range.

Example 2 A compound of the invention of formula (200) was prepared and compared with a compound of formula (201) which is not covered by the invention, based on the method described in the example.

The compound (200) of the present invention is a monotropic nematic (K2S,IN(7,5)I), while the comparative compound (201) is a smectic mesophase (K37880.1).
1i188. It turns out that K with II) is not too much.

Example 3 Preparation method (300) by esterifying 3-chloro-4-hydroxy-4'-hentyldiphenyl
: The compound is monotropic nematic (K22.3N(
-5) I) "t" A), compounds of formula (301) which are not included in the present invention are smectic mesophase (K2S,
7887.4I).

Example 4 The novel anisotropic compound of the present invention of formula (400) does not exhibit a smectic phase, whereas the comparative compound of formula (401) exhibits a smectic phase (K2O,6847,
7I).

Example 5 Formula (500): % Formula % D The novel anisotropic compound of the present invention does not exhibit a smectic phase, but the comparative compound of formula (501): which is not included in the present invention exhibits a smectic mesophase (K39.58189. 2I) A circle with an o-shape.

Example 6 The novel anisotropic compound of the present invention of formula (600) has a trace 9 tick phase [K11
1.2N(103)I), and one formula (601):
Comparative compounds not included in the present invention have only a smectic mesophase (K106.451185,2 I ).

Example 7 A cold mixture of 16f of oxalyl chloride, 45f of 1,4-bis-(4-tonsupentylcyclohexyl)-4-benzene, and 16t of anhydrous aluminum chloride in 100% of @ym-tetrachloroethane (ca. The mixture was stirred in an autoclave until the temperature of the mixture was close to room temperature (10-20 minutes). Anhydrous sodium acetate 101 and Pd10 catalyst 11 were then added.

After purging with nitrogen, hydrogen was added to the reaction mixture under stirring for 30 minutes.
The mixture was introduced until an overpressure of 1.5 mm was reached. Approximately 120 at this pressure
After minutes, the autoclave contents were heated to 50°C. After 30 minutes at this temperature, the two reaction mixtures were cooled to room temperature and the hydrogen overpressure was then released, the autoclave was flushed with nitrogen and opened.

The reaction mixture was washed with water and separated, with cooling as necessary, to remove the solvent from the organic phase.

The residue was recrystallized.

The resulting product of formula (700) had a melting point of 55.5C and exhibited a nematic phase up to 8665C.

Example 8 Two compounds of the invention 2'-fluoro-4-butyloxy-4'-pentyl-
diphenyl and 3'-fluoro-4-butyloxy-4'-pentyl-
Diphenyl showed significant nematic phase, 2'- or 3'-
Corresponding compounds not included in the invention without fluorine in position did not have a significant nematic phase.

Compounds other than those mentioned above according to the present invention in (1) are as follows.

The following compounds may be mentioned: 2-Fluor-4,4'-dipropyl-7-er 2-fluor-4,4/-dipropyl-7-er 3-fluor-4,4'-dipropyl-7-er 3- Fluor-4,4'-dipentyl-diphere 2-fluor-4-f Robi-4'-"e-Enthyl-diphenyl 2/-Fluor-4-propyl-47-pentyl-diphenyl 3-fluor-4-2' Robi- 4'-pentyl-diphenyl 3'-fluoro-4-fC'biru-4'-pentyl-diphenyl 2-fluor-4-pentyl-4/-jfk-diphenyl 2'-fluoro-4-pentyl-4'- heptyl-diphenyl 3-fluoro-4-pentyl-4'-heptyl-diphenyl 3'-fluoro-4-pentyl-4'-hestyldiphenyl 2-chloro-4-pentyl-4'-hestyl-diphenyl 2'- 10-4-pentyl-4/-hephthyldiphenyl 3-chloro-4-pentyl-4'-hephthyldiphenyl 3'-chloro-4-pentyl-4'-hestyldiphenyl 3-fluoro-4-butyloxy- 4'-pentyl-diphenyl 3-fluoro-4-hexyloxy-4'-pentyl-
Diphenyl 3-fluoro-4-butyloxy-4'-hephthyldiphenyl 3-fluoro-4-hexyloxy-4'-heptyldiphenyl, 3-chloro-4-propanoyloxy-4'-hezotyldiphenyl 3-10ru4-7'lonoξnoyloxy-4'-pentyl-diphenyl3-chloro-4-zoronozonoyloxy-4'-nonyl-diphenyl3-chloro-4-pentanoyloxy-4'-hestyloodiphenyl 3-fluoro-4-butylamino-4'-pentyl-diphenyl 3-fluoro-4-hexylamino-4'-pentyl-
Diphenyl 3-fluoro-4-butylamino-4'-hebutyl-diphenyl 2.5-difluoro-4.47-dipentyl-diphenyl 2.5-difluoro-4.4'-diheptyl-diphenyl 2.5-difluoro- 4.47-Ditunyldiphenyl 2.5-dichloro-4,41-dinonyl-diphenyl 2゜5-dinolol-4-pentyl-4'-hebutyl-
Diphenyl 2.5-difluoro-4-hedityl-4'-pentyl-diphenyl 3.5-difluoro-4-zotyloxy-41-pentyl-diphenyl 3.5-difluoro-4-hexyloxy-4'-pentyl-diphenyl 3 .5-difluoro-4-hexoxy-4'-heptyl-diphenyl 3.3'-dinol-4,4'-digtyloxy-diphenyl 3.3'-difluoro-4-butyloxy-4/-hexyloxy-diphenyl3. 3'-Dichloro-4,4'-dihexyloxy-diphenyl 3.3'-dichloro-4-hexyloxy-41-octyloxy-diphenyl 3.3'-dinolol-4#4'-di(butylamino)
-diphenyl3.3/-dichloro-4,47-di(hexylamino)
~diphenyl 1-(2-fluoro-4-pentylphenyl)-2-(
4-pentylphenyl)-ethane 1-(3-fluoro-
4-pentylphenyl)-2-(4-pentylphenyl) - ethane 1-(2-ri*-4-hebutylphenyl)
-2-(4-hebutylphenyl)-ethane 1-(3-/
Crew 4-hebutylphenyl)-2-(4-hebutylphenyl)-ethane 1-(3-fluoro-4-'thyloxyphenyl)-2-(4-hebutylphenyl)-ethane 1-(3- / crew 4-hexyloxyphenyl)-2
-(4-hebutylphenyl)-ethane 1,2-bis-(
2-Fluoro-4-pentylphenyl)-ethane 1.2-bis-(3-fluoro-4-bentylphenyl)-ethane 1.2-bis-(3-fluoro-4-butyloxyphenyl9-ethane 1) .2-bis=(3-fluoro-4-hexyloxyphenyl)-nitane 1.2-bis-(3-chloro-4-hexyloxyphenyl)-ethane 1-(3,5-dinol-4 -butyloxyphenyl)-2-(4-pentylphenyl)-ethane 1-(3-fluoro-4-pentanoyloxyphenyl)-2-(4-pentylphenyl)-ethane 1-(3,5-dichloro- 4-pe/tileoxyphenyl)-2-(4-pentylphenyl)-ethano2-fluoro-4-globyl-4'-(4-pentylphenyl>-diphenyl2-fluoro-4-pentyl-4'-( 4-Pentylphenyl)-diphenyl3-fluoro-4-pentyl-4'-(4-pentylphenyl)-diphenyl2-chloro-4-pentyl-4'-(4-pentylphenyl)-diphenyl3-chloro-4 -Pentyl-4'-(4-pentylphenyl)-diphenyl2-bromo-4-pentyl-4'-(,4-pentylphenyl)-diphenyl3-bromo-4-pentyl-4'-(4-pentylphenyl )-diphenyl2-iodo-4-pentyl-4'-(4-pentylphenyl)-diphenyl3-iodo-4-pentyl-4'-(4-pentylphenyl)-diphenyl2-cyan-4-pentyl-4 '-(4-pentylphenyl)-diphenyl3-cyan-4-pentyl-4'-(4-pentylphenyl)-diphenyl2-methyl-4-pentyl-4'-(4-pentylphenyl)-diphenyl3- Methyl-4-pentyl-4'-(4-pentylphenyl)-diphenyl 3-fluoro-4-butyloxy-4'-(4-pentylphenyl)-diphenyl 3-chloro-4-butyloxy-4'-(4- pentylphenyl)-diphenyl 3-butyl-4-butyloxy-4'-(4-pentylphenyl)-diphenyl 3-iodo-4-butyloxy-4'-(4-pentylphenyl)-diphenyl 3-cyan-4-butyloxy -4'-(4-pentylphenyl)-diphenyl3-methyl-4-butyloxy-4'-(4-pentylphenyl)-diphenyl3-fluoro-4-butyloxy-4'-(3-fluoro-4-butyl oxyphenyl)-diphenyl 3-chloro-4-butyloxy-4'-(3-chloro-
4-Butyloxyphenyl)-diphenyl 3-bromo-4-butyloxy-4'-(3-bromo-
butyloxyphenyl)-cyphenyl 3-iodo 4
-Butyloxy-4'-(3-yoF'-4-butyloxyphenyl)-diphenyl3-methyl-4-butyloxy-4'-(3-methyl-
4-Butyloxyphenyl)-diphenyl 2-fluoro-1,4-bis-(4'4'-dipentylphenyl-benzene 2-chloro-1,4-bis-(4',4'-dibentylphenyl) -benzene2-bromo-1,4-bis-(4',4'-dipentylphenyl)-benzene2-iodo-1,4-bis-(4',4'-dipe7tylphenyl)-benzene 2-cyan-1,4-bis-(4',4'-dipentylphenyl)-benzene2-methyl-1,4-bis-(4',4'-dipentylphenyl)-benzene2,5-chlorool-1 .4-bis-(4'.

4'-Dipentylphenyl)-benzene 2,5-tuclo
mu-1,4-bis-(4',4'-cypentylphenyl
)-benzene2,5-trichrome-1,4-bis-(4',4'-cype
tylphenyl)-benzene2,5-short-1,4-bis-(4',4'-cybe
tylphenyl)-benzene 2,5-dimethyl-1,4-bis-(4',4'-cipe
pentylphenyl)-benzene 1-(2-fluoro-4-pentylphenyl)-2-(
4'-pentyldiphenyl)-ethane 1-(3-fluoro
-4-pentylphenyl)-z-<4'-pentylphenyl
phenyl)-ethane]-(2-chloro-4-pentylph
(pentyldiphenyl)-2-(4'-pentyldiphenyl)-ethane
1-(3-chloro-4-pentylphenyl)-2-(4
'-pentyldiphenyl)-ethane 1-(3-'Romu
4-pentylphenyl)-2-(4'-pentyldife
1-(3-cyano-4-pentylphenyl)-ethane
)-2-(4'-pentyldiphenylene-ethane 1)
-(2-fluoro-4-pentylphenyl)-2-(3
-Fluoro-4'-pentyldiphenyl)-ethane 1-(2-fluoro-4-pentylphenyl)-2-(
3'-Fluoro-4'-pentyldiphenyl)-ethane 1,4-bis-[β-(4-pentyl-2-fluorophenyl)-ethane
phenyl)-ethyltwobenzene 1,4-bis-[β-(
4-pentyl-3-fluorophenyl)-ethyl]-h
1,4-bis-[β-(4-pentyl-2-chloro
ruphenyl)-ethyl]-Hensen1,4-bis-[β-(4-pentyl-3-chlorophene)
nyl)-ethyl-benzene 1,4-bis-[β-(4-pentyl-2-bromphene)
1,4-bis-[β-(4-pentyl-3-bromphene)
Nyl)-ethyl-2-benzene 1,4-bis-[β-(4-butyloxy-2-fluoro
ruphenyl)-ethyl]-Hensen1,4-bis-[β
-(4-butyloxy-3-fluorophenyl)-ethyl
Ruthubenzene 1,4-bis-[β-(4-butyloxy)
cy-3-chlorophenyl)-ethyltwobenzene 1-(
4'-pentylphenyl)-2-(2-fluoro-4-
(4'-)Lance-pentylcyclohexyl)-phenylene
]-ethane 1-(4'-pentylphenyl)-2-(2-chloro-
4-(4'-1 lanceupentylcyclohexylnof
enyl]-ethane 1-(4'-pentylphenyl)-2-(2-bromo-
4-(4'-trans-pentylcyclohexyl)-ph
phenyl]-ethane 1-(4'-bentelphenyl)-2-(3-fluor
-4-(4'-) lance-pentylcyclohexyl)-
phenyl]-ethane 1-(4'-pentylphenyl)-2-(3-chloro-
4-(4'-)U/supentylcyclohexyl)-F
1-(4'-pentylphenyl)-2-[3-bromo-
4-(4'-trans-pentylcyclohexyl)-ph
phenyl]-ditane 1-(4'-pentylphenyl)-2-(3-cyan-
4-(4'-trans-pentylcyclohexyl)-ph
phenyl]-ethane1-(4'-pentylphenyl)-2-(3-methfk-
4-(4'-pentylcyclohexyl)-
phenyl]-ethane 1-(4-butyloxyphenyl)-2-(2-cyan
-4-(4'-) lance-pentylcyclohexyl)-
phenyl]-nitane 1-(4-butyloxyphenyl)-2-(3-cyan
-4-(4'-trans-pentylcyclohexyl)-
Phenyltoethane 1-(4-butyloxy-3-fluoro-7enyl)-2
-(2□-fluoro-4-(4'-) lance-pentyl
cyclohexyl)-phenyltoethane 1-(4-butyloxy-3-chlorophenyl)-2-
(2-chloro-4-(4'-1 lance-pentylcyclo
hexyl)-phenyltoethane 1-(4-butyloxy-3-fluorophenyl)-2
-(3-fluoro-4-(4'-)lansupenochyl
chlorohexyl)-phenyltoethane 1-(4-butyloxy-3-/lorphenyl)-2-
(3-chloro-4-(4'-) lance-pentylcyclo
hexyl)-phenyltoethane 1-(4-butyloxy-3-bromphenyl)-2-
(3-bromo-4-(4'-)u/supentylcyclo
hexyl)-phenyltoethane 1-(4-butyloxy-3-methylphenyl)-2-
(3-methyl-4-(4'-) lance-pentylcyclo
hexyl)-phenyltoethane5-(4-pentylphenyl)-2-C2-fluoro-
4-(4'-):EF-pentylcyclohexylme
Toxy)-phenyltwoethane 1-(4-pentylphenyl)
nyl)-2-(3-fluoro-4-(4'-)lance-
(pentylcyclohexylmethoxy)-phenyltwoeta
1-(4-pentylphenyl)-2-(2-chloro-
4-(4'-) lance-pentylcyclohexylmethoxy
c)-Pheny]-ethane 1-(4-pentylphenyl
)-2-(3-chloro-4-(4'-) lance-pliers
(cyclohexylmethoxy)-phenyltwoethane J-
(4-) lance-pentylcyclohexyl)-2-(2
-Fluoro-4'-pentyldiphenyl)-nitane 1-(4-)lanse-pentylcyclohexyl)-2-
(2-chloro-4'-pentyldiphenyl)-ethane 1-(4-trans-pentylcyclohexyl)-2-
(2-Bromo-4'-bentyldiphenylphethane]-(4-) lance-pentylcyclohexyl)-2-
(2-Iodo-4'-pentyldiphenyl)-ethane 1-(4-) lance-pentylcyclohexyl)-2-
(2-methyl-4'-hentyldiphenyl-ethane-1-(4-) lance-pentylcyclohexyl)-2-
(2-cyan-4'-pentyldiphenyl)-etha/1-(4-) lance-pentylcyclohexyl)-2-
(2,2'-chlorool-4'-pentyldiphenylon)
-ethane]-(4-) lance-pe/tylcyclohexyl)-2-
(2,2'-dichloro-47-pentyldiphenyl)-
Ethane 1-(4-, trans-pentylcyclohexyl)-2
-(3,3'-chlorool-4'-pentyldiphenyl
)-ethane 1-(4-) lance-pe/tylcyclohexyl)-2-
(3,3'-dichloro-4'pentyldiphenyl)-eth
[tan]-(4-) lance-pentylcyclohexyl)-2-
(3-Fluoro-4'-pe7tyldi7enyl)-ethane 1-(4-) lance-pentylcyclohexyl)-2-
(3-chloro-4'=pentyldiphenyl)-ethane 1-(4-.trans-pentylcyclohexyl)-2
-(3-methyl-4'-pentyldi7-di-1-(4-)
lance-pentylcyclohexyl)-2-(3-cyan)
-4'-Hentyldiphenyl)-ethane 1-(4-trans-pentylcyclohexyl)-2-
(3,3'-dinolol-4'-pentyldiphenyl)
-ethane]-(4-1 lance-pentylcyclohexyl)-2-
(3,3'-dichloro-4'-pentyldiphenyl)-
Ethane 1-(4-trans-pentylcyclohexyl)-2-
(2'-fluoro-4'-pentyldiphenyl)-etha
1-(4-)7ysubet/tylcyclohexyl)-2-
(2'-chloro-4'-pen-tyldiphenyl)-etha
1-(4-) lance-pentylcyclohexyl)-2-
(3'-chloro-4'-pentyldiphenyl)-etha
1-(4-) lance-pentylcyclohexyl)-2-
(3'-chloro-4'-pentyldiphenyl)-nitane]-(4-trans-pentylcyclohexyl)-2-
, (3'-methyl-4'-pe/tyldiphenyl)-etha
3-(4-trans dipentylcyclohexyl)-2-
(3°'-cyan-4'-pentyldiphenyl)-etha
1-(4-h lansupe/tylcyclohexyl)-2-
(3'-fluoro-41-butyloxydiphenyl)-
Ethane 1-(4-trans-pentylcyclohexyl)-2-
(3'-chloro-4'-butyloxydiphenyl)-eth
Tan 1-(4-trans-pentylcyclohexyl)-2-
(3'-bromo-4'-butyloxydiphenyl)-eth
Tan 1-(4-trans-pentylcyclohexyl)-2-
(3'-iodo-4'-butyloxydiphenyl)
Tan 1-(4-trans-pentylcyclohexyl)-2-
(3'-cyan-4'-butyloxydiphenyl)-eth
[tan]-(4-tonsupentylcyclohexyl)-2-
(3'-methyl-4'-butyloxydiphenyl)-ethyl
Tan1- (4-) Lance-pentylcyclohexylethyl
)-2-(3'-fluoro-47-butyloxydif)
phenyl) -x pyl-(4-) lance-pentyl
cyclohexylethyl)-2-(3'-chloro-4'-
butyloxydiphenyl)-ethane (1-(4-) lance-pentylcyclohexylethyl)
-2-(3'-fluoro-4'-propanoyloxydi
phenyl)-ethane 5-globyl-2-(2-fluoro-4-globyl fluoride)
phenyl)-pyrimidine 5-heptyl-2-(2-fluoro-4-globilfe)
pyrimidi7 5-pentyl-2-(2-fluoro-4-pentylphenyl)
5-hebutyl-2-(2-fluoro-4-pentylphenyl)-pyrimidine
5-pentyl-2-(3-fluoro-4-pentylphenylene)-pyrimidine
5-hebutyl-2-(-3-fluoro-4-hebutyl)-pyrimidine
-H17 5-pentyl-2-(2-chloro-4゛-butylphenylene)
pyrimidi1 5-hebutyl-2-(3-chloro-4-heptylphenylene)
)-pyrimidine 5-pentyl-2-(3-fluoro-4-butyloxy
phenyl)-pyrimidine 5-hebutyl-2-(3-fluoro-4-butyloxy
phenyl)-pyrimidine 5-hexyl-2-(3-fluoro-4-hexyloxy)
Cyphenyl)-pyrimidine 5-pentyl-2-(3-chloro-4-butyloxyphenyl)-pyrimidine
phenyl)-pyrimidi1 5-heztyru-2-(3-chloro-4-butyloxyph)
phenyl)-pyrimidine 5-hebutyl-2-(3-chloro-4-hexyloxy
phenyl)-pyrimidine 5-pentyl-2-(3-fluoro-4-1 mouth, (+no)
yloxyphenyl)-biI):15-pentyl
-2-(3-fluoro-4-pentanoyloxyphenylene)
)-pyrimidine 5-hebutyl-(3-fluoro-
4-pentanoyloxyphenyl)-pyrimidine 5-pe
2-(3-chloro-4-pentanoyloxif)
phenyl)-pyrimidine 5-hetyl-2-(3-chloro-4-pentanoyl)
xyphenyl)-pyrimidine 2-propyl-5-(2-fluoro-4-f lobilfe
(2-fluoro-4-prohilf)-pyrimidine2-pentyl-5-(2-fluoro-4-prohilf)
phenyl)-pyrimidine 2-pentyl-5-(2-fluoro-4-pentylphenylene)
2-hebutyl-5-(2-fluoro-4-pentylphenyl)-pyrimidine
2-pentyl-5-(3-fluoro-4-pentylphenylene)-pyrimidine
2-hebutyl-5-(3-fluoro-4-hegetylphenyl)-pyrimidine
2-pentyl-5-(2-chloro-4-hebutylphenyl)-pyrimidine
2-hebutyl-5-(3-chloro-4-hebutylphenyl)-pyrimidine
)-pyrimidine 2-pentyl-5-(3-fluoro-4-butyloxy
phenyl)-pyrimidine 2-hebutyl-5-(3-fluoro-4-butyloxy
phenyl)-beerimidine 2-hebutyl-5-(3-fluoro-4-hexyloxy)
Cyphenyl)-pyrimidine 2-pentyl-5-(3-chloro-4-butyloxyphenyl)
phenyl)-pyrimidine 2-hetyl-5-(3-chloro-4-butyloxyph)
phenyl)-pyrimidine 2-hebutyl-5-(3-chloro-4-hexyloxy
phenyl)-pyrimidine 2-pentyl-5-(3-fluoro-4-pronocenoy)
oxyphenyl)-pyrimidine 2-pentyl-5-(
3-Fluoro-4-pentanoyloxyphenyl)-pi
Limidine 2-hebutyl-5-(3-fluoro-4-pene)
(tanoyloxyphenyl)-pyrimidine 2-pentyl
5-(3-chloro-4-pentanoyl manxyphenyl)
-Birimidine 2-hebutyl-5-(3-chloro-4-pentanoyl)
xyphenyl)-pyrimidine 1-(5-pentyl-2-pyrimidinyl)-2-(2-
Fluoro-4-pentylphenyl)-nitane 1-(5-pentyl-2-pyrimidinyl)-2-(3-
Fluoro-4-pentylphenyl)-ethane 1-(5-pentyl-2-pyrimidinyl)-2-(2-
Chlor-4-pentylphenyl)-ethane 1-(5-pentyl-2-pyrimidinyl)-2-(3-
Chlor-4-pentylphenyl)-ethane 1-(5-pentyl-2-pyrimidinyl)-2-(3-
Fluoro-4-P-thyloxyphenyl)-nitane 1-(5-pentyl-2-pyrimidinyl)-2-(3-
/l:l-4-butyloxyphenyl)-etha/1-(5-pentyl-2-pyrimidinyl)-2-(3-
Fluoro-4-pronoyloxyphenyl)-etha
1-(5-pentyl-2-pyrimidinyl)-2-(3-
10 ru 4-2'ronoyloxyphenyl)-nita
5-(4-pentylphenyl)-2-(2-)A/ #
A/-4-pentylphenyl)-bi IJ sewing machine 5
-(4~pentylphenyl)-2-(3-fluoro-4
-pentylphenyl)-pyrimidine 5-(4-pentyl
phenyl)-2-(3-chloro-4-pentylphenyl
)-pyrimidine 5-(4-pentylphenyl)-2-(
3-Fluoro-4-butyloxyphenyl)-pyriζdi
5-(4-pentylphenyl)-2-(3-chloro-4
-butyloxyphenyl)-pyrimidine 5-(4-pentylphenyl)-2-(3-fluoro-
4-f lovanoyloxyphenyl)-pyrimidine 2,5-bis-(2-fluoro-4-pentylphenyl
-pyrimidine 2,5-bis-(3-fluoro-4-pentylphenyl
)-pyrimidine 2,5-bis-(3-chloro-4-pentylphenyl)
~pyrimidine 2,5-bis-(3-fluoro-4-butyloxyphene)
2,5-bis-(3-chloro-4-butyloxyfny)-pyrimidine
2,5-bis-(3-fluoro-4-propanoyl)-pyrimidine
Cyphenyl)・-pyrimidine2,5-bis-(3-riq-4-pronoyloyl-pyrimidine
Cyphenyl)-pyrimidine 1-(2-pentyl-5-pyrimidinyl)-2-(2-
Fluoro-4-pentylphenyl)-ethane 1-(2-pentyl-5-pyrimidinyl)-2-(3-
Fluoro-4-pentylphenyl)-ethane 1-(2-pentyl-5-pyrimidinyl)-2-(2-
/Roru-4-pentylphenyl)-ethane 1-(2-pentyl-5-pyrimidinyl°)-2-(3
-/lolu4-pentylphenyl)-nitane1-(2-pentyl-5-pyrimidinyl)-2-(3-
Fluoro-4-butyloxyphenyl)-ethane 1-(2-pentyl-5-pyridinyl)-2-(3-
Chlor-4-f-thyloxyphenyl)-ethane 1-(2-pentyl-5-pyrimidinyl)-2-(3-
Fluoro-4-10vanoyloxyphenyl)-nitane 1-(2-pentyl-5-pyrimidinyl)-2-(3-
a-4-fronoyloxy7enyl)-ethane2-(4-pentylphenyl)-5-(2-fluoro-
4-bentylphenyl-pyrimicin 2-(4-pentylphenyl)
(ruphenyl)-5-(3-fluoro-4-pentylphenyl)
Nil)-'! J Midine 2-(4-pentylphenyl)-
5-(3-chloro-4-pentylphenyl)-pyrimidine
2-(4-pentylphenyl)-5-(3-fluoro
-4-butyloxyphenyl)-pyrimidine 2-(4-pentylphenyl)-5-(3-chloro-4
-butyloxyphenyl-pyrimidine 2-(4-pentylphenyl)-5-(3-fluoro-
4-propanoyloxyphenyl)-pyrimidine 2-pentyl-5-(2-,yl-4'-pentyl
diphenyl)-pyrimidine 2-pentyl-5-(2-chloro-4'-pentyl diphenyl)
phenyl)-pyrimidine 2-pentyl-5-(2-from-4'-pentyl diph
enyl)-pyrimidine2-pentyl-5-(3-fluoro-41-pentyldi
phenyl)-pyrimidine 2-pentyl-5-(3-chloro-4'-pentyldif)
phenylph-pyrimidi/2-pentyl-5-(3-bromo-4'-pentyldiph)
phenyl)-pyrimidine 2-pentyl-5-(3-cyan-4'-pentyldif
phenyl)-pyrimidine2-pairyl-5-(3'-fluoro-4'-butyl-pyrimidine)
xydiphenyl)-pi') mi') y2-pe/chiru
5-(3'-chloro-4'-butyloxydiphenyl)
-pyrimidine 2-pentyl-5-(3'-pro5-4'-butyloxy
cydiphenyl)-pyrimidine 2-pentyl-5-(3'-cyan-4'-butyloxy
2-pentyl-5-(3'-methyl-4'-butyloxy)-pyridine
sidiphenylin-virimigene 2-pentyl-5-(3
'-chloro-4'-gropanoyloxydiphenyl)-
Pyrimidine 5-pentyl-2-(2-fluoro-4-(
4-pentylphenylethyl)-phenyl]-hili
Midine 5-pentyl-2-[2-chloro-4-(4-pentyl
phenylethyl)-phenyltwopyrimidine 5-pentyl-2-[2-bromo-4-(4-pentyl
phenylethyl)-phenyl2-pyrimidine 5-pentyl-2-[2-cyan-4-(4”-pentyl
ruphenylethyl)-phenyl]-hyrimidine 5-pentyl-2-(2-fluoro-4'-pentyl di
phenyl) -hiIJ me/n 5-pentyl-2-(
2-chloro-4'-be/tyldiphenyl)-pyrimidine 5-pentyl-2-(2-bromo-4'-pentyldiphenyl)-pyrimidine
1 5-pentyl-2-(3-fluoro-47-pentyldi
phenyl)-pyrimidine 5-pentyl-2-(3-chloro-4'-pentyldif)
phenylun-pyrimidine 5-pentyl-2-(3-bromo-4'-pentyl diph
phenyl)-pyrimidine 5-pentyl-2-(3-cyan-4'-pentyl diph
5-pentyl-2-(3'-fluoro-4'-butyl)-pyrimidine
xydiphenyl)-pyrimidine 5-pentyl-2-(3
'-chloro-4'-butyloxydiphenyl)-bi13
Sewing machine 5-pentyl-2-(3'-bromo-4'-butylene)
methyloxydiphenyl)-pyrimidine 5-pentyl-2-(3'-cyan-4'-butyloxy
cydiphenyl)-pyrimidine 5-peatyl-2-(3'-methyl-4'-butyloxy
sidiphenyl)-pyrimidine 5-pe/thiru-2-(3'-chloro-4'-zolonozeno
yloxydiphenyl)-pyrimidine 2-pentyl-5
-[2-fluoro-4-(4-pentylphenylethyl
)-phenyl]-hirimidine 2-pentyl-5-[2-chloro-4-(4-pentyl
phenylethyl)-phenyl]-hyrimidine 2-pentyl-5-[2-bromo-4-(4-pentyl
phenylethyl)-phenyltwopyrimidine 2-pentyl-5-[2-cyan-4-(4-pentyl
phenylethyl)-phenyl]-hy+)midine 5-(trans-4-pentylcyclohexyl)-2-
(2-Fluoro-4-pentylphenyl)-pyrimidine 5-()lanse-4-pentylcyclohexyl)-2-
(2-chloro-4-pentylphenyl)-pyrimidine 5-() lance-4-pentylcyclohexyl)-2-
(2-bromo-4-pentylphenyl)-pyrimidine 5-() lance-4-pentylcyclohexyl)-2-
(2-Cyan-4-pentylphenyl)-pyrimidine 5-() lance-4-pentylcyclohexyl)-2-
(2-)f-4-pentylphenyl)-pyrimidine5-()-4-pentylcyclohexyl)-2-
(3-Fluoro-4-pentylphenyl)-pyrimidine 5-(trans-4-pentylcyclohexyl)-2-
(3-chloro-4-pentylphenyl)-pyrimidine 5-(trans-4-pe/tylcyclohexyl)-2-
'(3-bromo-4-pentylphenyl)-pyrimidine 5-(trans-4-pentylcyclohexyl)-2-
(3-cyan-4-pentylphenyl)-pyrimidine 5-() lance-4-pentylcyclohexyl)-2-
(3-meIF-ru-4-pentylphenyl)-virimi
Zine 5-(trans-4-pentylcyclohexyl)-2-
(3-fluoro-4-butyloxyphenyl)-pyrimi
gin 5-() lance-4-pentylcyclohexyl)-2-
(3-70-4-butyloxyphenyl)-pyrimidine
5-() lance-4-pentylcyclohexyl)-2-
(3-'Romu-4-butyloxyphenyl)-pyrimidine
1 5-():7-pentylcyclohexyl)-2
-(3-cyan-4-butyloxyphenyl)-pyrimi
Zine 5-(trans-4-pentylcyclohexyl)-2-
(3-fluoro-4-f lobanoyloxyphenyl)-
Pyrimidine 5-() lance-4-pentylcyclohexyl)-2-
(3-chloro-4-propanoyloxyphenyl)-pi
Rimidine 5-() lance-4-pentylcyclohexyl)-2-
(3-'Romu4-zoronozonoyloxyphenyl)-
Pyrimidine s-(trans-4-pentylcyclohexyl)-2-
(3-cyan-4-pronozonoyloxyphenyl)-
Pyrimidine 2-() lance-4-pentylcyclohexyl)-5-
(2-Fluoro-4-pentylphenyl)-pyrimidine 2-(trans-4-pentylcyclo* cy/l/
)-5-(2-chloro-4-pentylphenyl)-pyri
Midine 2-() lance-4-be/tylcyclohexyl)-5-
(2-bromo-4-pentylphenyl)-pyrimidine 2-() lance-4-pentylcyclohexyl)-5-
(2-Cyan-4-pentylphenyl)-pyrimidine 2-() lance-4-pentylcyclohexyl)-5-
(2-Methyl-4-pentylphenyl)-pyrimidine 2-(trans-4-pentylcyclohexyl)-5-
(3-fluoro-4-pentylphenyl)-pyrimidi/2-()lanse-4-pentylcyclohexyl)-5-
(3-chloro-4-pentylphenyl)-pyrimidine 2-()? 4-pentylcyclohexyl)-5-
(3-':;'Romu-4-pentylphenyl)-girimi
Tay 2-(tra-7-4-pentylcyclohexyl)-5-
(3-cyan-4-pentylphenyl)-pyrimidi/2-C-tri-4-pentylcyclohexyl)-5-
(3-Methyl-4-pentylphenyl)-pyrimidine 2-() lance-4-pentylcyclohexyl)-5-
(3-fluoro-4-butyloxyphenyl)-pyrimi
2-()U/S-4-pentylcyclohexyl)-5-
(3-chloro-4-'thyloxyphenyl)-virimidium
2-() lance-4-pentylcyclohexyl)-5-
(3-bromo-4-butyloxy7enyl)-pyrimidine
2-() lance-4-pentylcyclohexyl)-5-
(3-cyan-4-butyloxyphenyl)-pyrimidine
2-() lance-4-pentylcyclohexyl)-5-
(3-fluoro-4-pronoyloxyphenyl)
-pyrimidine 2-() lance-4-pentylcyclohexyl)-5-
(3-chloro-4-propanoyloxyphenyl)-pi
Rimidine 2-(trans-4-pentylcyclohexyl)-5-
(3-bromo-4-7'lonozonoyloxyphenyl)
-pyrimidine 2-() lance-4-pentylcyclohexyl)-5-
(3-cyan-4-propanoyloxyphenyl)
Rimidine 5-(trans-4-pentylcyclohexylethyl)
-2-(2-fluoro-4d-mentylphenyl)-pyrimi
Zine 5-(trans-4-pentylcyclohexylethyl)
-2-(2-chloro-4-pentylphenyl)-pyrimi
Zin-5-()u/su-4-pentylcyclohexylethyl
)-2-(2-bromo-4-pentylphenyl)-pyri
Midine 5-() lance-4-pentylcyclohexylethyl)
-2-(2-cyan-4-pentylphenyl-bilimi)
5-() lance-4-pentylcyclohexylethyl)
-2-(2-methyl-4-pentylphenyl)-pyrimi
di1 5-() lance-4-pentylcyclohexylethyl)
-2-(3-fluoro-4-pentylphenyl)-pyri
Midine 5-() lance-4-pentylcyclohexylethyl)
-2-<3-chloro-4-pentylphenyl)-pyrimi
Zine 5-(trans-4-pentylcyclohexylethyl)
-2-(3-bromo-4-pentylphenyl)-pyrimi
Zine 5-(trans-4-pentylcyclohexylethyl)
-2-(3-cyan-4-pentylphenyl)-pyrimi
Zine 5-(trans-4-pentylcyclohexylethyl)
-2-C3-1f-4-pentylphenyl)-pyrimi
5-() lance-4-pentylcyclohexylethyl)
-2-(3-fluoro-4-butyloxyphenyl)-
Pyrimidi 1 5-() lance-4-pentylcyclohexylethyl)
-2--(3-chloro-4-butyloxyphenyl)
-pyrimidine 5-(t:lynos-4-pentylcyclohexylethyl
)-2-(3-bromo-4-f-thyloxyphenyl)
-pyrimidine 5-(trans-4-pentylcyclohexylethyl)
-2-(3-cyan-4-butyloxyphenyl)-p
Rimidine 5-(trans-4-pentylcyclohexylethyl
)-2-(3-fluoro-4-bronoyloxif)
phenyl)-pyrimidine 5-() lance-4-pentylcyclohexylethyl)
-2-(3-/Loru-4-7'lovanoyloxyphenylene
)-pyrimidine5-Ct”)7-4-pentylcyclohexylethyl
)-2-(3-bromo-4-f bromoyloxyphene)
nyl)-pyrimidine 5-()lans-4-pentylcyclohexylethyl)
-2~(3-cyan-4-2'ronozonoyloxyphene
4-pentylcyclohexylethyl)
-5-(2-fluoro-4-pentylphenyl)-pyri
Midine 2-() lance-4-pentylcyclohexylethyl)
-5-(2-chloro-4-pentylphenyl-bilimi)
gin 2-() lance-4-pentylcyclohexylethyl)
-5-(2-bromo-4-pentylphenyl)-pyrimi
2-(5y-4-pentylcyclohexylethyl)
-5-(2-cyan-4-pentylphenyl)-pyrimi
2-(): Yin-4-pentylcyclohexylethyl
)-5-(2-methyl-4-pentylphenyl)-pyri
Midine 2-(trans-4-pentylcyclohexylethyl)
-5-(3-fluoro-4-pentylphenyl)-pyri
Midi/2-(trans-4-pentylcyclohexylethyl)
-5-(3-chloro-4-pentylphenyl)-pyrimi
Zin 2-(): 7-pentylcyclohexylethyl
)-5-(3-bromo-4-pentylphenyl)-pyri
Midine 2-(trans-4-pentylcyclohexylethyl)
-5-(3-cyan-4-pentylphenyl)-pyrimi
Zine 2-(trans-4-pentylcyclohexylethyl)
-5-(3-methyl-4-bentylphenyl-bilimi)
gin 2- () lance-4-pentylcyclohexylethyl
)-,5-(3-fluoro-4-butyloxyphenyl
)-pyrimidine 22(trans-4-pentylcyclohexylethyl)
-5-(3-/lo-4-1+ruoxyphenyl)-pi
Rimidine 2-(trans-4-pentylcyclohexylethyl)
-5-(3-bromo-4-butyloxyphenyl)-p
rimidine 2-() lance-4-pentylcyclohexylethyl)
-5-(3-cyan-4-butyloxyphenyl)-p
rimidine 2-() lance-4-pentylcyclohexylethyl)
-5-(3-fluoro-4-7'''lonozonoyloxy
phenyl)-pyrimidine 2-() lance-4-pentylcyclohexylethyl)
-5-(3-chloro-4-7'lonozonoyloxyphene)
pyrimidine (2-()lans-4-pentylcyclohexylethyl)
-5-(3-bromo-4-pronozonoyloxyphenylene
)-Hi IJ sewing machine 2-(trans-4-pentylcyclohexylethyl)
-5-(3-cyan-4-7'ronozonoyloxyphene
nyl)-pyrimidine 5-() lance-4-pentylcyclohexylmethoxy
)-2-(2-fluoro-4-pentylphenyl)-pi
Rimidine 5-() lance-4-pentylcyclohexylmethoxy
)-2-(2-chloro-4-pentylphenyl)-pyri
Midine 5-() lance-4-pentylcyclohexylmethoxy
)-2-(2-bromo-4-pentylphenyl)-pyri
Midine 5-()7-4-pentylcyclohexylmethoxy
) -2-(,2-cyan-4-pentylphenyl)-
Pyrimidi 1 5-() lance-4-pentylcyclohexylmethoxy
)-2-(2-methyl-4-pentylphenyl)-pi
Rimidine 5-(5-4-pentylcyclohexylmethoxy)
)-2-(3.-fluoro-4-pentylphenyl)-
Pyrimidine 5-(trans-4-pentylcyclohexylmethoxy)
)-2-(3-chloro-4-pentyl phenyl)-pi
Rimidine 5-(trans-4-pentylcyclohexylmethoxy
)-2-(3-bromo-4-pentylphenyl)-pyri
Midine 5-(trans-4-pentylcyclohexylmethoxy
)-2-(3-cyan-4-pentylphenyl)-pyri
Midine 5-() lance-4-pentylcyclohexylmethoxy
)-2-(3-methyl-4-pentylphenyl)-pyri
Midine 5-() lance-4-pentylcyclohexylmethoxy
)-2-(3-fluoro-4-butyloxyphenyl)
-pyrimidine 5-() lance-4-pentylcyclohexylmethoxy
)-2-(3-chloro-4-butyloxyphenyl)-
Pyrimidine 5-() lance-4-pentylcyclohexylmethoxy
)-2-(3-bromo-4-butyloxyphenyl)-
Pyrimidine 5-() lance-4-pentylcyclohexylmethoxy
)-2-(3-cyan-4-butyloxyphenyl)-
Pyrimidine 5-() lance-4-pentylcyclohexylmethoxy
)-2-(3-fluoro-4-bronoyloxif)
phenyl)-pyrimidine 5-(trans-4-pentylcyclohexylmethoxy
)-2-(3-chloro-4-propanoyloxyphenylene
-pyrimidine 5-(trans-4-pentylcyclohexylmethoxy
)-2-(3-bromo-4-f bromoyloxyphene)
nyl)-pyrimidine 5-() lance-4-pentylcyclohexylmethoxy
)-2-(3-cyan-4-propanoyloxyphenylene
l)-pyrimidine 2-() lance-4-pentylcyclohexylmethoxy
) -5-(2-fluoro-4-pe/tylphenyl)-
Pyrimidine 2-C trans-4-pentylcyclohexylmethoxy
)-5-(2-chloro-4-pentylphenyl)-pyri
Midine 2-() lance-4-pentylcyclohexylmethoxy
)-5-(2-bromo-4-pentylphenyl)-pyri
Midine 2-() lance-4-pentylcyclohexylmethoxy
)-5-(2-cyan-4-pentylphenyl)-pyri
Midine 2-() lance-4-pentylcyclohexylmethoxy
)-5-(2-methyl-4-pentylphenyl)-pyri
Midine 2-() lance-4-pentylcyclohexylmethoxy
)-5-(3-fluoro-4-pentylphenyl)-pi
Rimidine 2-(trans-4-pentylcyclohexylmethoxy
)-5-(3-chloro-4-pentylphenyl)-pyri
Midine 2-() lance-4-pentylcyclohexylmethoxy
)-5-(3-bromo-4-pentylphenyl)-pyri
Midine 2-(trans-4-pentylcyclohexylmethoxy
)-5-(3-cyan-4-pentylphenyl)-pyri
Midine 2-(trans-4-pentylcyclohexylmethoxy
)-5-(3-methyl-4-pentylphenyl)-pyri
Midine 2-(trans-4-pentylcyclohexylmethoxy
)-5-(3-fluoro-4-butyloxyphenyl)
-pyrimidine 2-(trans-4-pentylcyclohexylmethoxy
)-5-(3-chloro-4-butyloxyphenyl)-
Pyrimidine 2-() lance-4-pentylcyclohexylmethoxy
)-5-(3-bromo-4-butyloxyphenyl)-
Pyrimidine 2-() lance-4-pentylcyclohexylmethoxy
)-5-(3-cyan-4-butyloxyphenyl)-
Pyrimidine 2-() lance-4-pentylcyclohexylmethoxy
)-5-(3-fluoro-4-2'lovanoyloxif)
enyl)-pyrimidine 2-() lance-4-pentylcyclohexylmethoxy
)-5-(3-chloro-4-propanoyloxyphenylene
l)-pyrimidine 2-() lance-4-pentylcyclohexylmethoxy
)-S-<a-bromo-4-pro/zonoyloxyphe
pyrimidine 2-(5-4-pentylcyclohexylmethoxy)-pyrimidine
c)-5-(3-cyan-4-turonoξnoyloxif)
phenyl)-pyrimidine 2-chloro-4-propyl-4'-(4-zurobilfe
terphenyl 2-chloro-4-pentyl-4'-(4-propylphenyl)
terphenyl 2-chloro-4-pentyl-4'-(4-propylphenyl)
terphenyl 3-chloro-4-pentyl-4'-(4-propylphenyl)
terphenyl) 2-bromo-4-pentyl-4'-(4-pentylphenyl)
terphenyl 3-bromo-4-pentyl-4'-(4-pentylphenyl)
terphenyl 2-methyl-4-pentyl-4'-(4-pentylphenyl)
terphenyl 3-methyl-4-pentyl-4'-(4-pentylphenyl)
terphenyl 2-bromo-4-butyloxy-4'-(4-pentyl
phenyl)terphenyl 2-methyl-4-butyloxy-4'-(4-pentyl
phenyl)terphenyl 2-cyan-4-butyloxy, -4'-(4-pene
tylphenyl)terphenyl 2-chloro-1,4-bis(4',4'-dipentylphenyl)
phenyl) diphenyl 2-bromo-1,4-bis(4',4'-dibenthilph
2-cyan-1,4-bis(4',4'-dipentylphenyl) diphenyl
2-methyl-1,4-bis(4',4'-dipentylphenyl) diphenyl
1,4-bis(3-chloro-4-pentylphenyl)diphenyl
Phenyl 1.4-t? (3-bromo-4-pentylphenyl)
Diphenyl 1,4-bis(3-methyl-4-pentylphenyl)di
Phenyl 1-(2-chloro-4-pentyldiphenyl)-2-(
4'-pentyldiphenyl)ethane 1-(2-bromo-
4-pentyldiphenyl)-2-(4'-pentyldiphenyl)
phenyl)ethane]-(2-cyan-4-pentyldife)
(2-(4'-pentyldiphenyl)ethyl)-2-(4'-pentyldiphenyl)ethyl/1-
(2-Mef-4-pentyldiphenyl)-2-(4
'-pentyldiphenyl)ethane 1-(4'-pentyl
diphenyl)-2-[2-from(4'-) lance-pe
methylcyclohexyl)phenyl]ethane]-(4-butyloxy-3-methyldiphenyl)-2
-(3-methyl-4-(4'-) lance-pentylsic
lohexyl)phenyl]ethane 1-(4-pentyldiphenyl)-2-C2-bromo-
4-(4'-) lance-pentylcyclohexyl meth
xy)-phenyl]ethane 5-(4-pentyldipheny)
)-2-(2-riC1-4-pentylphenyl)
Pyrimidine 5-(4-pentyldiphenyl-2-(2
-bromo-4-pentylphenyl)pyrimidine 5-(4
-pentyldiphenyl)-2-(2-methyl-4-pene
tylphenyl) bi') 5-(4-pentyl diphenyl
phenyl)-2-(2-iodo-4-pentylphenyl)
Pyrimidine 5-(3-ri-o-4-hentyldiphenyl
)-2-(2-ri0-4-pentyldiphenyl)-pi
Rimidine 2-(4-pentylphenyl)-5-(3'-bromo-
4/ f-thyloxydiphenyl)-pyrimidine 2-(4-pentylphenyl)-5-(3'-iodo-
4'-butyloxycyphere)-virimiji
2-(4-pentylphenyl)-5-(3'-methyl-
4'-Butyloxydiphenyl-pyrimidine 5-(4-pentylphenyl)-2-(2-bromo-4
(4'-pentylphenylethyl)-phenyl]virimi
Zin 5-() lance-4-pentylcyclohexyl)-27
(2-bromo-4-(/tyldiphenyl)-pyrimidine 5-(trans-4-pe/tylsiftetrahexyl)-2-
(2-Methyl-4-pentyldiphenyl)-pyrimidine 5-()lans-4-pentylcyclohexyl)-2-
(2-Cyan-4-pentyldiphenyl)-pyrimidine 5-(trans-4-pentylcyclohexyl)-2-
(2-Iodo-4-pentyldiphenyl)-pyrimidine 5-(trans-4-pentylcyclohexyl)-2-
(3-chloro-4-butyloxydiphenylfubilimi
gin 5-() lance-4-pentylcyclohexyl)-2-
(3-bromo-4-butyloxydiphenyl)-pyrimi
gin 5-() lance-4-pentylcyclohexyl)-2-
(3-cyan-4-butyloxydi7-functional dilupyrimidine
7-4-pentylcyclohexyl)-2-
(3-methyl-4-butyloxydiphenyl)-pyrimi
Gin 5-(57-4-pentylcyclohex'/#)
-2-(3-bromo-4-pentyldiphenyl)-biry
-midi-n5-(-)lance-4-pentylcyclohexyl)-2
-(3-cyan-4-pentyldiphenyl)-pyrimidine
5-() lance-4-pentylcyclohexyl)-2-
(3-Methyl-4-pentyldiphenyl)-pyrimidine 5-(trans-4-pentylcyclohexylethyl)
-2-(2-chloro-4-pentyldiphenyl)-pyri
Midine 5-() lance-4-pentylcyclohexylethyl)
-2-(2-bromo-4-pentyldiphenyl)-pyri
Midine 5-()ransul 4-pentylcyclohexylethyl)
-2-(2-cyan-4-pentyldiphenyl)-pyri
Midine 5-() lance-4-pentylcyclohexylethyl)
-2-(2-methyl-4-pentyldiphenyl)-pyri
2-cyano-4,4'-dipentyldiphenyl 3-cyano-4,4'-dipentyldiphenyl 3-cyano-4-butyloxy-41-pentyldiphenyl
Nyl 2-cyano-4-(4-1 lance-pentylcyclohexyl
sil)-butyloxybenzene 1-(2-cyano-4-
pentylphenyl)-2-(4-pentylphenyl)-
Nitan 2,3-dicyano-1,4-bis(4',4'
-cypentylphenyl)-benzene l-butyloxy-2,3-dicyano-4-(4'-pentylphenyl)-benzene
Benzene 1-pentyl-2,3
-dicyano-4-(4'-pentylbiphenyl)-be
1-(2,3-dicyano-4-pentylphenyl)-♀
-(4'-hentylbiphenyl)-ethane 1-(2,3-dicyano-4-butyloxyphenyl)
-2-(4'-pentylbiphenyl)-nitane 1-(2,3-dicyano-4-butyloxyphenyl)
-2-(4-(4'-) lance-pentylcyclohexy
)-phenyltoethane 1-(2,3-dicyano-4
-pentylphenyl)-2-(4-(4'-)lance-
pentylcyclohexyl)-phenyltoethane 1-(
4-pentylphenyl)-2-(4-(4'-trans
-pentylcyclohexyl)-2,3-dicyanophe
Nyl-2-ethane 1-(2,3-dicyano-4-pentyl
7 enyl)-2-(4,4'-trans, trans-pe
ethane 1-(2,3-dicyano-4-butyloxy7-butyl)
-2-(4,4'-) lance, trans-pe/chirubishi
(chlorohexyl)-ethane 2-methyl-1-pentyl-4
-(4-) lance-bentylcyclohexyl)-benze
3-methyl-1-pentyl-4-(4-trans-pentyl)
cyclohexyl)-benzene 2-methyl-1-
Nyl-4-(4-)lansubentylcyclohegycyl)
-Benzene 3-methyl-1-nonyl-4-(4-)rane
(pentylcyclohexyl)-benzene 2-methyl-
1-nonyl-4-(4-) lance-nonylcyclohexy
)-benzene 3-methyl-1-nonyl-4-(4-)lannonyl
cyclohexyl)-benzene 2-methyl-4-(4-trans-nonylcyclohexy
)-1-pentyl-benzene3-methyl-4-(4-
) lance-nonylcyclohexyl)-1-pentyl-be
l-butoxy-2-methyl-4-(4-) lance
-pentylcyclohexyl)-benzene 1-butoxy-
3-Methyl-4-(4-) lance-pentyl dichlorohex
sil)-benzene 1-butoxy-2-methyl-4-(4
-) lance-nonylcyclohexyl)-benzene 1-b
Toxy-3-methyl-4-(4-trans-nonylsic)
lohexyl)-benzene2-71ru4-(4-)la
(nonylcyclohexyl)-1-octyloxy-
Benzene 3-methyl-4-(4-)lannonylsic
qHexyl)-1-octyloxy-benzene 2-methy
-1-octyloxy-4-(4-trans-pentyl)
3-methyl-1-octyloxy-4-(4-cyclohexyl)-benzene
-bentylcyclohexylne -benzene 2-methyl-4-(4-) lance-pentylcyclohexyl
sil)-phenyl-butanoate 3-methyl-4-(4
-) lance-pentylcyclohexyl)-phenyl-b
thanoate 2-methyl-4-(4-) lance-nonyl
(chlorohexyl)-phenyl-butanoate 3-methyl-
4-(4-)lans-nonylcyclohexyl)-phenylene
rub-butanoate 2-methyl-4-(4-trans-pe
cyclohexyl)-722-octanoate 3
-Mef-4-(4-)7-supentylcyclohexy
)-phenyl-octanoate 2-methyl-4-(4
-)U7sunonylcyclohexyl)-phenyl-oc
thanoate 3-methyl-4-(4-) lance-nonyl
Chlohexyl)-phenyl-yFIIl/N-di
Tyl-2-methyl-4-(4-trans-pentylsic)
lohexyl)-aniline N-butyl-3-methyl-4-
(4-)Lance-pentylcyclohexyl)-aniline
N-butyl-2-methyl-4-(4-)lans-nonyl
Fuclohexyl)-aniline N-butyl-3-methyl-4-(4-)lans-nonyl
cyclohexyl)-aniline N-octyl-2-methyl-4-(4-) lance-pene
Tylcyclohe xyl2aniline N-octyl-3-
Methyl-4-(4-trans-pe4thylchlorhexyl)
)-Aniline N-octyl-2-methyl-4-(4-trans-noni
(cyclohexyl)-aniline N-octyl-3-methy
-4-(4-)lans-nonylcyclohexyl)-a
Nilin 1-(4-)lansubentylcyclohexyl
)-2-(2-methyl-4-pentylphenyl)-etha
1-(4-) lance-pentylcyclohexyl)-2-
(3-Methyl-4-pentylphenyl)-ethane 1-(4-) lance-pentylcyclohexyl)-2-
(2-methyl-4-nonylphenyl)-ethane
1-(1-(
4-trans-pentylcyclohexyl) -2-
-2-(3-methyl-4-)÷ruphenyl)--Nitae
Tan 1
-(-ethane
1-(1-(4-trans-nonylcyclohexyl)
) -2--2-(2-methyl-4-nonylphe
)--ethane
1-(1-(4-trans-nonylsic)
lohexyl) -2--2-(3-methyl-4-
nonylphenyl) -- ethane
1-(-ethane 4-)? /Susuntylcyclohexyl) (4-butoxy)
cy-3-methylphenyl)-4-trans-pentylcyclohexyl)(2-methyl
-4-octyloxyphenyl (4-) lance-pentylcyclohexyl) (3-methyl
-4-octyloxy7-ethane 4-)lans-nonylcyclohexyl)(4-butoxy
-2-methylphenyl)(4-trans-nonylcyclohexyl)(4-butoxy)
-3-methylphenyl)n4-)lans-nonylcyclohexyl)(2-methyl-
4-octyloxyphniethane 4-)7nonylcyclohexyl)-2-(3-methane)
tyl-4-octyloxyfuninonyl)-
Ethane 1-(4-
2-(lunonyl)-ethane-2-(ru-2-(4-N-butylamino-3-methylphenyl)
-ethane 1-(41
-(4-) lance-pentylcyclohexyl) -
2-(-2-(2-methyl-4-N-octylamino
nonyl)phenyl)-ethane
1-(41-<4-trans-pentylsic
lohexyl) -2-(-2-(3-methyl-4-
N-octylamino nonyl)phenyl)-nitane
l・−(4−2−( le”°″−”′y −2−(−
2-methyl-4-N-octylamino)-ethane-trans-nonylcyclohexyl) 3-methyl-4-N-octylamino)-ethane-trans-pentylcyclohexyl) 4-butanoyl
oxy-2-methyl (7-ethane-trans-bentylcyclohexyl) 4-butameyl
oxy-3-methyl2ethane-trans-pentylcyclohexyl)2-methyl-4
-octanoyloxy)-ethane-trans-pentylcyclohexyl)3-methyl-4
-octanoyloxy1-(4-)lans-nonylcyclohexyl)-2-(
4-Butanoyloxy-2-methyl7enyl)-ethane1-(4-)lans-nonylcyclohexyl)-2-(
4-Butanoyloxy-3-methylphenyl)-ethane]-(4-)lans-nonylcyclohexyl)-2-(
2-Methyl-4-octanoyloxyphenyl)-nitha
1-(4-trans-nonylcyclohexyl)-2-(
3-Methyl-4-octanoyloxyphenyl)-etha
(4-) lance-pentylcyclohexylmethyl)-(
2-me? (4-pentylphenyl)-ether (4-) lance-pentylcyclohexylmethyk)-<
3-Methyl-4-pentylphenyl)-ether (4-) lance-pentylcyclohexylmethy/')-
(4-bu)xy-2-methylphenyl)-ether (4-)/Funsupentylcyclohexylmethy/L'
)-(4-phth*cy-3-meth-ruphenyl)-ether
(4-thora;/supentylcyclohexylmethyl)-
(4-N-butylamino-2-methylphenyl)-A
Tel(4-trans-pentylcyclohexylmethyl)-(
4-N-butylamino-3-methylphenyl)-ether
(4-) lance-pentylcyclohexylmethyl)-(
2-Methyl-4-octanoyloxyphenyl)-A
Ter(4-)ranspentylcyclohexylmethyl (
3-Methyl-4-octanoyloxyphenyl)-A
4-(4-) lance-pentylcyclohexyl)-2-
) If syl-'-pentyl-biphenyl 4-(4-) la
(pentylcyclohexyl)-3-meth? Lou 4'-
Pentyl biphenyl 4-(4-) lance-pentyl biphenyl
(chlorohexyl)-2-methyl-4'-octanoyloxy
C-biphenyl 4-(4-) lance-pentylcyclohexyl)-3-
Methyl-4'-octanoyloxy-biphenyl4'-butoxy-4-(4-trans-pentylcyclo
hexyl)-2-methyl-biphenyl4'-butoxy-
4-(4-) lance-pentylcyclohexyl)-3-
Methyl-biphenyl 4'-N-butylamino-4-(4
-trans-pentylcyclohexyl)-2-methyl-
biphenyl 4'-N-butylamino-4-(4-) lance-penter
cyclohexyl)-3-methyl-biphenyl4-(4-)lans-pentylcyclohexyl)-3,
3'-dimethyl-4'-benthylbiphenyl 4-(4-trans-pentylcyclohexyl)-3,
3'-dimethyl-4'-octanoyloxy-biphenylene
4'-N-butylamino-4-(4-trans-pentyl)
cyclohexyl)-3,3'-dimethyl-biphenyl4'-butoxy-4-(4-)lans-pentylcyclo
hexyl) 3 + 3') l f ruhi
Phenyl 1-(4-(4-) lance-pentylcyclohexyl)
-2-methylphenyl)-2-(4-benthylphenyl)
-ethane 1-(4-(4-1 lance-pentylcyclohexyl)
-3-methylphenyl)-2-(4-pentylphenyl)
)-nitane 1-(4-(4-) lance-pentylcyclohexyl)
-2-methylphenyl) = 2-(4-butoxyphenyl)
)-ethane 1-(4-(4-) lance-pentylcyclohexyl)
-3-methylphenyl)-2-(4-butoxyphenyl
)-ethane]-(4-(4-1 lance-pentylcyclohexyl)
-2-methylphenyl) -2-(4-N-butylamide
nophenyl)-etha/1-(4-(4-trans-pentylcyclohexyl)
-3-methylphenyl)-2-(4-N-butylamino
phenyl)-etha/1-(4-(4-) lance-pentylcyclohexyl)
-2-methylphenyl)-2-(4-octanonylphenyl)
nyl)-ethane 1-(4-(4-) lance-pentylcyclohexyl)
-3-methylphenyl)-2-(4-octanoyl phenyl)
nyl)-ethane 1-(4-(4'-) lance-pentylcyclohexyl
)-2-methylphenyl)-2-(2-methyl-4-pe
ethyl phenyl)-eth/1=(4-(4-trans-
pentylcyclohexyl)-3-methylphenyl)-2
-(2-methyl-4-pentylphenyl)-ethane 1-
(4-(4-trans-pentylcyclohexyl)-2
-methylphenyl)-2-(3-methyl-4-pentyl
phenyl)-ethane 1-(4-(4-) lance-pliers
(cyclohexyl)-3-methylphenyl)-2-(3
-Methyl-4-pentylphenyl)-ethane 1-(4-
(4-) lance-pentylcyclohexyl)-2-methy
(ruphenyl)-2-(4-butoxy-2-methylphenylphenyl)
) to ethane 1-(4-(4-) lance-pentylsic)
lohexyl)-3-methylphenyl)-2-(4-buto
xy-2-methylphenyl)-ethane 1-(4-(4-
trans-pentylcyclohexyl)-2-methylphene
2-(4-butoxy-3-methylphenyl)-2-(4-butoxy-3-methylphenyl)
Ethane 1-(4-(4-) lance-pentylcyclohexyl
sil)-3-methylphenyl)-'2-(4-butoxy
-3-methylphenyl)-ethane 1-(4-(4-)ra
(pentylcyclohexyl)-2-methylphenyl
)-2-(4-N--jfruamino-2-methylphenylene
)-ethane 1-(4-(4-trans-pentylcyclohexyl))
-3-methylphenyl)-2-(4-N-sof-#7mi
/-2-,)'tylphenyl)-ethane 1-(4-(4-trans-pentylcyclohexyl)
-2-methylphenyl)-2-(4-N-butylamino
-3-, >1 tylphenyl)-nitane 1-(4-(4-) lance-pentylcyclohexicine
-3-methylphenyl)-2-(4-N-ifruami/
-3-Me'F-ruphenyl)-nitane]-(4-(4-t:7nesupentylcyclohexyl)
)-2-methylphenyl)-2-(2-methyl-4-o
ctanoyloxyphenyl)-ethane 1-(4-(4-1 lance-pentylcyclohexyl)
-3-methylphenyl)-2-(2-methyl-4-oc
tanoyloxyphenyl)-ethane 1-(4-C4-4 lance-pentylcyclohexyl)
-・2-methylphenyl)-2-(3-methyl-4-o
ctanoyloxyphenyl)-ethane 1-(4-C4-trans-pentylcyclohexyl)
-3-methylphenyl)-2-(3-methyl-4-oc
tanoyloxyphenyl)-ethane 1-(3,3'-dimethyl-4'-pentylbiphenyl
-4-yl)-2-(4-) lance-pentylcyclohe
xyl)-ethane 1-(3,3'-dimethyl-4'-octanoyloxy
biphenyl-4-(l)-2-(4-trans-pentyl)
cyclohexyl)-nitane 1-(4'-butoxy-3
,3'-dimethylbiphenyl-4-yl)-2-(4-
) lance-pentylcyclohexyl)-technique 1-(4'-N-butylamino-3,3'-dimethylvinyl
phenyl-4-yl)-2-(4-) lance-pentyl
Cyclohexylune-ethane (3,3'-dimethyl-47
-pentyl)-biphenyl-4-1ru(4-)lance
-pentylcyclohexyl)-methyl-ether (3,
3'-dimethyl-4'-octanoyloxy)-bife
Nyl-4-yl-(4-trans-pentylcyclohexyl)
-if syl--ter(4'-butoxy-3,3'-dimethyl)-biphenyl
-4-yl-<4-thora7supentylcyclohexyl
)-methyl-ether (4'-N-butylamino-3,
31-dimethyl)-biphenyl-4-1ru(4-thora)
pentylcyclohexyl)-meth-fk-2-? 1,4-bis-(4-) lance-propylcyclohexy
)-2-)thyl-benzene 1.4-(4-trans-nonylcyclohexy)
)-2-)thyl-benzene1-(4-)lans-nonylcyclohexyl)-4-(
4-trans-zorobylcyclohexyl)-2-methyl
-benzene 1-(4-trans-nonylcyclohexyl)-4-(
4-trans-zolobylcyclohexyl)-3-methyl
-benzene 1-(4-) lance-propylcyclohexyl)-2-
(4-(4-) lance-propylcyclohexyl)-2
-methylphenyl)-nitane 1-(4-trans-pro
Pyrcyclohexyl)-2-(4-(4-)lansuzo
robylcyclohexyl)-3-methylphenyl)-etha
1-(4-)lansuzolovircyclohexyl)-2
-(4-(4-)lans-nonylcyclohexyl)-2
-methylphenyl)-nitane 1- (4-) lance-p
lopylcyclohexyl)-2-(4-(4-)lance-
nonylcyclohexyl)-3-methylphenyl)-etha
/]-(4-):ysunonylcyclohexyl)-2
-(4-(4-trans-propylcyclohexyl)-
2-methylphenyl)-ethane 1-(4-) suit
Nylcyclohexyl)-2-(4-(4-) lancep
Lopylcyclohexyl)-3-19-ruphenyl)-e
Tan 1-(4-)lans-nonylcyclohexyl)-2
-(4-(4-trans-nonylcyclohexyl)-2
-methylphenyl)-etha/1-(4-):7suno
nylcyclohexyl)-2-(4-(4-)lans-no
Nylcyclo*sil)-3-methylphenyl)-ethane
(4-trans-zolobylcyclohexyl)-methyl-
(4-(4-) lance-propylcyclohexyl)-2
-Methyl)-phenyl-ether (4-)lansuzolovircyclohexyl)-meth? Roux
(4-(4-) lance-zorobylcyclohexyl)-3
-methyl)-722-ether (4-trans-zorobylcyclohexyl)-methyl-
(4-(4-)lans-nonylcyclohexyl)-2-
1-tyl)-phenyl-ether (4-trans-brobi)
cyclohairacyl)-methyl-(4-(4-trans-
nonylcyclohexyl)-3-)5-l)-phenyl-
Ether (4-) lance-nonylcyclohexyl)-methyl-(
4-(4-trans-zolobylcyclohexyl)-2-
methyl)-phenyl-ether (4-) lance-nonylcyclohexyl)-methyl-(
4-(4-trans-zolobylcyclohexyl)-3
-)-thyl)-phenyl-ether (4-trans-nonylcyclohexyl)-m+ru(
4-(4-nonylcyclohexyl)-2-methyl)-ph
phenyl-ether (4-thora/sutonylcyclohexyl)-methyl-(
4-(4-)trans-nonylcyclohexyl)-3-butylene
thyl)-phenyl-ether 1,4-bis-(2-(4
-) lanosuzolovircyclohexyl)-ethyl)-2
-Methyl-benzene 1,4-bis-(2-(4-trans-nonylcyclohexyl)
xyl)-ethyl)-2-methyl-benzene 1-(2-(4-)lans-nonylcyclohexyl)-
ethyl)-4-(2-(4-)lansuclovircyclo
hexyl)-ethyl)-2-methyl-7ase/1-(2-(4-)lans-nonylcyclohexyl)-
Ethyl-4-(2-(4-) lance-zolopylcyclohe
xyl)-ethyl-3-methyl-benzene], 4-bis-(2-(4-)lansucrovircyclo
hexyl)-ethyl)-2,3-dimethyl-benzene 1,4-bis-(2-(4-trans-nonylcyclohexyl)
xyl)-ethyl)-2,3-di/thyl:pe/zine 1-(2-(4-1 lance-nonylcyclohexyl)-
Ethyl-4-(2-(4-trans-clobylcyclohe)
xyl)-ethyl)-2,3-dimethyl-benzene 1-(4'-)trans-pentyl-trans-bicyclo
hex-4-yl)-2-methyl-4-benzeneruben
Zen 1-(4'-) lance-pentyl-trans-bicyclo
Hex-4-yl-3-methyl-4-benzeneruben
zen1-(4'-1lansupebutyl-trans-bicyclo
hex-4-yl)-4-butoxy-2-methyl-ben
Zen 1-(4'-trans-benzyl-trans-bicyclo
hex-4-yl)-4-butoxy-3-methyl-ben
Zen 1-(4'-) lance-pentyl-trans-bicyclo
(hex-4-yl) -4-N-butylamino-2-methyl
thyl-benzene 1-(4'-trans-benzene-trans-bicyclo
hex-4-yl)-4-N-butylamino-3-methy
Rubenzene 1-(4'-trans-pentyl-trans-bicyclo
hex-4-yl)-2-,7'? Lou 4-Octanoy
1-(4'-trans-pentyl-trans-bicyclo)
hex-4-1-3-methyl-4-octanoyl
xy-benzene 1-(4'-trans-benzene-trans-rubicyclo
hex-4-yl)-2-(2-methyl-4-pentyl
phenyl)-ethane 1-(4'-trans-pentyl-trans-bicyclo
hex-4-yl)-2-(3-methyl-4-pentyl
phenyl)-ethane 1-(4'-trans-pentyl-trans-bicyclo
hex-4-yl)-2-(4-butoxy-2-methyl
phenyl)-ethane 1-(4'-1 lance-benzyltrans-bicyclo
hex-4-yl)-2-(4-butoxy-3-methyl
phenyl)-nitane 1-(4'-1 lance-benzyltrans-bicyclo
hex-4-yl)-2-< 4-N-butylamino-
2-methylphenyl)-p71-(4'-)lance-
pentyl-trans-bicyclohex-4-yl)-2
-(4-N-butylamino-3-methylphenyl)-et
Tan 1-(4'-trans-pentyl-trans-bicy)
Chlohex-4-yl)-2-(2-methyl-4-oc
Tanoyloxyphenyl)-2] -(4”-)
trans-benzene-trans-bicyclohex-4-yl
)-2-(3-methyl-4-octanoyloxyphenylene)
)-ethane(4'-trans-pentyl-trans-bicyclohexyl)
cy-4-yl)-methyl-(2-methyl-4-pentyl
)-phenyl-ether (4'-trans-pentyl-
trans-bicyclohex-4-yl)-mefk-(3
-Me? (4-pentyl)-phenyl-ether < 4
/ ) lance-pentyl-trans-bicyclohexy
-4-yl)-methyl-(2-methyl-4-octanoy
(4'-trans-pentyl-trans-bicyclohexyl)-phenyl-ether (4'-trans-pentyl-trans-bicyclohexyl)
(4-yl)-methyl-(3-methyl-4-octano
yloxy)-phenyl-ether (4'-trans-benzyl-trans-bicyclohexyl)
(4-yl)-methyl-(4=but)xy-2-methyl
)-phenyl-ether (4'-5-subenyl)
trans-bicyclohex-4-yl)-methyl=(4
-butoxy-3-1 thyl)-phenyl-ether (4'
-) Lance-pe/Til-trans-bicyclohexy-4
-yl)-methyl-(4-N-butylamino-2-methyl
)-phenyl-ether (4'-)trans-pentyl-trans-bicyclohexyl
(4-yl)-methyl-(4-N-butylamino-3
-methyl)-phenyl-ether 5-(4-(4-trans-pentylcyclohexyl)
-2-methylphenyl)-2-hephthylpyrimidine 5-(4-(4-trans-pentylcyclohexyl)
-3-methylphenyl)-2-hectylpyrimidine 2-(4-(4-):lyn supentylcyclohexy
)-2-methylphenyl)-5-hebutyl-pyrimidine
-2-(4-(4-trans-pentylcyclohexyl)
-3-methylphenyl)-5-hephthylpyrimidine 2-(4-(4-trans-pentylcyclohexyl)
-2-) tylphenyl) -5-7' toxic pyrimidine
2-(4-(4-) lance-pentylcyclohexyl)
-3-methylphenyl)-5-cytoxy-pyrimidine 5-(4-(2-(4-)lansuzolovircyclohexyl)
sil)-ethyl)-2-methylphenyl)-2-zolobi
rubirimidine 5-(4-(2-(4-)lansuzolovircyclohexyl)
sil)-ethyl)-3-methyl7enyl)-2-zolobi
rubirimidine 5-(4-(2-(4-) lance-zorobylcyclohexyl
sil)-ethyl)-2-methylphenyl)-2-nonyl
-pyrimidine 5-(4-(2-(4-trans-propylcyclohe-
xyl)-ethyl)-3-methyl7enyl)-2-noni
-pyrimidine 5-(4-(2-(4'-trans-7ylcyclohexyl)
sil)-ethyl)-2-methylphenyl)-2-propy
l-pyrimidine 5-(4-(2-(4-1 lance-nonylcyclohexy
)-ethyl)-3-methylphenyl)-2-zorobyl
-Birimidine 5- (4-(2-(4-trans-nonylcyclohexyl)
sil)-ethyl-2-methylphenyl)-2-nonyl-
Pyrimidine 5-(4-(2-(4-) lance-nonylcyclohexy
)-ethyl)-3-, )'tylphenyl)-2-noni
L-pyrimidine 5-(4-(4-)lansuzolovircyclohexylme
Toxy)-2-methylphenyl)-2-zorobyl-pyri
Midine 5-(4-(4-)9nsuzolobylcyclohexylme
Toxy)-3-methylphenyl)-2-zorobyl-pyri
Midine 5-(4-(4-4 lance-propylcyclohexylmethane)
Toxy)-2-methylphenyl)-2-nonyl-pyrimi
Zine 5-(4-(4-)trans-propylcyclo-II'
sylmethoxy)-3-methylphenyl)-2=nonyl-
Pyrimidine 5-(4-(4-)lans-nonylcyclohexylmeth)
xy)-2-methylphenyl)-2-zorobyrubirimi
5-(4-(4-)lans-nonylcyclohexylmeth)
xy)-3-methylphenyl)-2-propyl-pyrimi
5-(4-(4-)lans-nonylcyclohexylmeth)
xy)-2-methylphenyl)-2-nonyl-pyrimidine
5-(4-(4-)trans-nonylcyclohexylmeth)
xy)-3-methylphenyl)-2-nonyl-pyrimidine
2-(4-(2-(4-)lansuzolovircyclohexyl)
sil)-ethyl)-2-methylphenyl)-5-chlorobi
Ru'pyrimidine 2-(4-(2-(4-trans-zolopylcyclohexyl)
sil)-ethyl)-3-methylphenyl)-5-propy
-pyrimidine 2-(4-(2-(4-trans-zolopylcyclohexyl)
sil)-ethyl)-2-methylphenyl)-5-nonyl
-pyrimidine 2-(4-(2-(4-trans-zolobylcyclohexyl)
sil)-ethyl)-3-methylphenyl)-5-nonyl
-pyrimidine 2-(4-(2-(4-)lansuzolobylcyclohexyl)
sil)-ethyl)-2-7'tylphenyl)-5-buto
xy-pyrimidine 2-(4-(2-(4-trans-zolobylcyclohexyl)
sil)-ethyl)-3-)'fru7-butyl)-5-buto
xypyrimidine 2-(4-(2-(4-trans-zorobylcyclohexyl)
sil)-ethyl)-2-methyl 7enylrune-5-octyl
2-(4-(2-(4-trans)
-Zorobylcyclohexyl)-ethyl)-3-methylphenyl
phenyl)-5-octyloxy-pyrimidine 2-(4-
(2-(4-)lans-nonylcyclohexyl)-ethyl
)-2-methylphenyl)-s-71″ lobiroupyri
Midine 2-(4-(2-(4-trans-nonylcyclohexy)
)-ethyl)-3-methylphenyl)-5-zorovir
-Birimidine 2-(4-(2-(4-1 lance-nonylcyclohexy
)-ethyl)-2-/? birenyl)-5-nonyl-
Pyrimidine 2-(4-(2-(4-transnonylcyclohexy)
(ethyl)-3-methylphenyl-5-nonyl-
Pyrimidine 2-(4-(2-(4-trans-nonylcyclohexy)
)-ethyl)-2-methylphenyl)-5-butoxy
-pyrimidine 2-(4-(2-(4-) lance-nonylcyclohexy
)-ethyl)-3-methylphenyl)-5'-buto-
Cypyrimidine 2-(4-(2-(4-trans-nonylcyclohexy)
)-ethyl)-2-methylphenyl)-5-octyl
Oxy-pyrimidine 2-(4-(2-(4-trans-nonylcyclohexy)
]-ethyl)-3-, )'tylphenyl)-5-oc
Tyloxy-pyrimidine 2- (4-(4-)lansuzolobylcyclohexyl
methoxy)-2-methylphenyl)-5-propyl-pi
rimidine 2-(4-C4-to5-suzolobylcyclohexylme)
Toxy)-3-methylphenyl)-5=propyl-pyri
Midine 2-(4-(4-trans-propylcyclohexyl)
Toxy)-2-methylphenyl)-5-nonyl-pyrimi
2-(4-(4-trans-zorobylcyclohexylme)
Toxy)-3-methylphenyl)-5-nonyl-pyrimi
2-(4-(4-)Lance-propylcyclohexylmethane)
Toxy)-2-methylphenyl)-5-butoxy-pyri
Midi/2-(4-(4-trans-zolobylcyclohexyl)
methoxy)-3-methylphenyl)-5-butoxy-pi
rimidiy 2-(4-(4-trans-propylcyclohexylmethane)
Toxy)-2-methylphenyl)-5-octyl-pyri
Midi/2- (4-(4-) lance-zorobylcyclohexyl
methoxy)-,3-methylphenyl)-5-octyl
Oxy-pyrimidine 2-C4-(4-trans-nonylcyclohexylmeth)
xy)-2-methylphenyl)-5-propyl-pyrimi
2-(4-(4-)lans-nonylcyclohexylmeth)
xy)-3-methylphenyl)-5-zoroby-pyrimi
2-(4-(4-)lans-nonylcyclohexylmeth)
xy)-2-, )'tylphenyl)-5-nonyl-pyri
Midine 2-'(4-(4-)lans-nonylcyclohexylme
Toxy)-3-methylphenyl)-5-nonyl-pyrimi
Dine 2-(4-(4-)lansononylcyclohexylVkmeth)
=IF-”/)-2-,7'tylphenyl)-5-buto
xy-pyrimidine 2-(4-(4-)lans-nonylcyclohetosilmeth)
xy)-3-methylphenyl)-5-butoxy-pyrimi
2-(4-(4-)lans-nonylcyclohexylmeth)
xy)-2-methylphenyl)-5-octyl-pyrimi
2-(4-(4-trans-nonylcyclohexylmeth)
xy)-3-methylphenyl)-5-octyloxy-
Pyrimidine 4.4'-bis-(4-trans-propylcyclohexyl)
sil)-2-methyl-biphenyl4,4'-bis-(4
-trans-zorobylcyclohexyl)-3-methyl-
Hyphenyl 4.4'-bis-(4-trans-zolovir)
cyclohexyl) -3,3'-shime'fk -bifu
phenyl 4.4'-bis-(4-trans-zolobylcyclohexyl
sil)-2,3'-dimethyl-biphenyl4,4'-bis-(4-trans-nonylcyclohexy
)-2-methyl-biphenyl4.4'-bis-(4-
trans-nonylcyclohexyl)-3-1f Lupif
enyl 4.4'-bis-(4-trans-nonylcyclo
hexyl)-2,3'-dimethyl-biphenyl4,4'-bis-(4-trans-nonylcyclohexyl)
)-3,3'-dimethyl-biphenyl4-(4-)lanosonylcyclohexyl)-4'-
(4-)U/'Sugzolorcyclohexyl)-2-Me
thyl-biphenyl 4-' (4-) lance-nonylcyclohexyl)-4'
-(4-), F nosuprovircyclohexyl)-3-
Methyl-biphenyl 4-(4-)lans-nonylcyclohexyl)-4'-
(4-trans-zolobylcyclohexyl)-21-mer
Thyl-biphenyl 4-(4-t,5-nonylcyclohexyl)-4'
-(4-trans-zolobylcyclohexyl)-3'-
Methyl-biphenyl 4-(4-)lans-nonylcyclohexyl)-4'-
(4-)lansuzolovircyclohexyl)-2,3'
-17methyl-biphenyl 4-(4-trans-nonyl
cyclohexyl)-4'-(4-to5-nosuprovir
cyclohexyl)-2',3-dimethyl-biphenyl4
-(4-trans-nonylcyclohexyl)-4'-(
4-1 lance-fa cyclohexyl)-3,3'-
Dimethyl-biphenyl 4.4'-bis-(2-(4-)
Lance-propylcyclohexylene-ethyl)-2,3
'-dimethyl-biphenyl 4.4/-bis-(2-(4-) lance-propyl sic
lohexyl)-ethyl)-3,3'-dimethyl-bife
Nyl4,4'-bis-(2-(4-transnonylcyclo
hexylune-ethyl)-2,3'-dimethyl-biphenylene
4.4'-bis-(2-(4-) lance-nonylcyclo
hexyl)-ethyl)-3,3'-dimethyl-biphenylene
4-(2-(4-1 lance-nonylcyclohexyl)-
ethyl)-4'-(2-(4-trans-propylsic)
lohexyl)-ethyl)-2゜31-dimethyl-bife
Nyl 4-(2-(4-):ysunonylcyclohexyl)
-ethyl)-4'-(2-(4-trans-71J Robi)
(cyclohexyl)-ethyl)-2',3-dimethyl-
biphenyl 4-(2-(4-thora/sutonylcyclohexyl)-
ethyl)-4'-(2-(4-1)
lohexyl)-ethyl)-3゜3'-dimethyl-bife
4,4'-bis-(4-trans-propyl shift
silmethoxy)-2,3'-dimethyl-biphenyl4,4'-bis-(4-trans-zolopylcyclohexyl
silmethoxy)-3,3'-dimethyl-biphenyl4.4/-bis-(4-trans-nonylcyclohexy
4,4'-bis-(4-trans-nonylcyclohexy)-2,3'-dimethyl-biphenyl
3,3'-dimethyl-biphenyl 4-(4-transnoni, cyclohexylmethoxy)
)-4'-(4-) lance-propylcyclohexylme
(4-(4-)lans-nonylcyclohexylmethoxy)-2,3'-dimethyl-biphenyl)
-4'-(4-trans-propylcyclohexylmeth)
xy-2', 3-17methyl-biphenyl 4-(4-trans-nonylcyclohexylmethoxy)
-4'-(4-) lance-propylcyclohexylmeth
xy)-3,3'-dimethyl-biphenyl 4-(4'-trans-benzyl-trans-bicyclo
hex-4-yl)-2,3'-dimethyl-4'-ben
H, rubiphenyl 4-(4'-)trans-pentyl-trans-bicyclo
hex-4-yl)-2',3-dimethyl-4/-pen
thyl-biphenyl 4-(4'-trans-pentyl-trans-bicyclo
hex-4-yl) ~3,3'-dimethyl-47'+
HENTYL-BIPHENYL 4-(4'-TRANS-PENTI)
Le-trans-bicyclohex-4-yl> + 47
-ptoxy2.3'-dimethyl-biphenyl4-(4'-trans-pentyl-trans-bicyclo
hex-4-yl)-4'-butoxy-2',3-dime
thyl-biphenyl 4-(4'-trans-pentyl-trans-bicyclo
hex-4-yl)-4'-butoxy-3,3'-dime
thyl-biphenyl 4-(4'-)trans-pentyl-trans-bicyclo
hex-4-yl)-4'-N-butylamino2.3
'-dimethyl-biphenyl 4-(4'-) lance-pene
tyl-trans-bicyclohex-4-yl)-4'-
N-butylamino-2',3-dimethyl-biphenyl4
-(4'-trans-pentyl-trans-bicyclohetyl)
(x-4-yl)-4'-N-1+ruamino-3,3'
-dimethyl-biphenyl 4-(4'-) lance-pliers
(ru-trans-bicyclohex-4-yl)-2,3'
-dimethyl-47-ophthalyloxy-biphenyl 4
-(4'-)trans-pentyl-trans-bicyclohe
x-4-yl)-2',3-dimethyl-4'-octa
Noyloxy-biphenyl 4-(4'-) lance-pene
thyl-trans-bicyclohex-4-yl)-3,3
'-dimethyl-4'-octanoyloxy-biphenyl
4-(4'-1 lance-pentyl-trans-bicyclo
hex-4-yl)-2-1thyl-4'-pentyl-bi
Phenyl 4-(4'-)trans-benzyltrans-bicyclo
hex-4-yl)-3-19-4'-pentyl-bi
phenyl 4-(4'-1 lance-benzyltrans-bicyclo
Hexy-4-(l)-2-methyl-4'-octanoyl
Oxy-biphenyl 4-(4'-trans-pentyl-trans-bicyclo
hex-4-yl)-3-methyl-4'-octanoyl
Oxy-biphenyl 4-(4'-)trans-pentyl-trans-bicyclo
hex-4-yl)-4'-butoxy-2-methyl-bi
Phenyl 4-(4'-trans-benzyl-trans-bicyclo
hex-4-yl) 4/-butoxy-3-methyl-
biphenyl 4-(4'-), F-subpentyl-transubisic
lohex-4-yl)-4'-N-butyloxy-2-
Methyl-biphenyl 4-(4'-)trans-pentyl-trans-bicyclo
hex-4-yl)-4'-N-butyloxy-3-methyl
thyl-biphenyl 1-(4'-trans-benzyl-trans-bicyclo
hex-4-yl)-2-(2-methyl-4'-hen
tylbiphenyl-4-(l)-ethane]-(4'-)trans-pentyl-trans-bicyclo
hex-4-yl)-2-(3-methyl-4'4-ethyl
biphenyl(4-1)-ethane(4'-)trans-pentyl-trans-bicyclo
hex-4-yl)-2-(2,3'-dimethyl-4'
-hairtylbiphenyl-4-yl)-ethane 1-(4'-trans-benzyl-trans-bicyclo
hex-4-yl)-2-(2', 3-zume5-ru4
/-h/tylbiphenyl-4-yl)-ethane 1-(4'-) lance-benzyltrans-bicyclo
hex-4-yl)-2-(3,3'-dimethyl-4'
-pentylbiphenyl-4・-yl)-ethane 1-(4'-trans-pentyl-trans-bicyclo
hex-4-yl)-2-(4'-butoxy-2-methy
rubiphenyl-4-(l)-etha/1-(4'-)trans-pentyl-trans-bicyclo
hex-4-yl)-2-(4'-butoxy-3-methy
ruphenyl-4-1-ethane 1-(4'-)trans-pentyl-trans-bicyclo
hex-4-yl)-2-(4'-butoxy-2,3'
-dimethylbiphenyl-4-yl)-ethane 1-(4'-trans-pentyl-trans-bicyclo
hex-4-yl)-2-(4'-butoxy-2/,3
-dimethylbiphenyl-4-yl)-ethane 1-(4'-)trans-pentyl-trans-bicyclo
hex-4-yl)-2-(4'-butoxy-3,3'
-dimethylbiphenyl-4-yl)-ethane 1-(4'-trans-pentyl-trans-bicyclo
hex-4-yl)-2-(4'-N-butylamino-
2-methylbiphenyl-4-yl)-ethane 1-(4'-trans-pentyl-trans-bicyclo
hex-4-yl)-2-(4'-N-butylamino-
3-methylbiphenyl-4-yl)-ethane]-(4'-)trans-pentyl-trans-bicyclo
hex-4-yl)-2-(4'-N-butylamino-
2,31-dimethylbiphenyl-4-yltuethane 1-(4'-)trans-pentyl-trans-bicyclo
hex-4-yl)-2-(4'-N-butylamino)
-2',3-dimethylbi722-4-yl)-nitane 1-(4'-)trans-pentyl-trans-bicyclo
hex-4-yl)-2-(4'-N-butylamino-
3,3'-dimethy, enyl-4-yl)-ethane 1-(4'-) lance-pentyl-trans-bicyclo
hex-4-yl)-2-(2-methyl-4'-octa
Noyloxybiphenyl-4-yl)-ethane 1-(4'-)trans-pentyl-trans-bicyclo
hex-4-yl)-2-(3-methyl-4'-octa
Noyloxybiphenyl-4-yl)-ethane 1-(4'-trans-pentyl-trans-bicyclo
hex-4-yl)-2-(2,3'-dimethyl-41
-octanoyloxybiphenyl-4-yl)-nitane 1-(4'-)trans-pentyl-trans-bicyclo
hex-4-yl)-2-(2',3-dimethyl-4'
-octanoyloxybiphenyl-4-yl)-ethane 1-(,4'-)trans-pentyl-trans-bisic
lohex-4-yl)-2-(3,3'-dimethyl-4
'-octanoyloxybiphenyl-4-yl)-etha
(4'-trans-benzene-trans-bicyclohexyl)
(4-yl)-methyl-(2-methyl-4'-pene)
(4'-trans-pentyl-trans-bicyclohexyl)
(4-yl)-methyl-(3-methyl-4'-pentyl)
)-biphenyl-4-(k-ether (4'-trans-pentyl-trans-bicyclohexyl)
(4-yl)-methyl-(2,3'-di)f-4
' -hentyl) -k'phenyl-4-yl-ether
(4'-)trans-pentyl-trans-bicyclohexyl
(4-yl)-methyl-(2', 3-di)If sil
-/-/leltin)-biphenyl-4-yl-ether
(4'-trans-pentyl-trans-bicyclohexyl)
(4-yl)-methyl-(3,3'-dimethyl-4'
-pentyl)-biphenyl-4-yl-ether
(4-yl)-methyl-(4'-butoxy-2-methy
)-bienyl-4-1-ether (4'-trans-pentyl-trans-bicyclohexyl)
(4-yl)-methyl-(4'-butoxy-3-methy
)-piphenyl-4-1-ether (4'-trans-pentyl-trans-bicyclohexyl)
(4-yl)-methyl-(4'-butoxy-2,3'
-dimethyl)-biphenyl-4-yl-ether (4'-trans-pentyl-trans-bicyclohexyl)
(4-yl)-1+ru(4'-butoxy-2',3
-dimethyl)-biphenyl-4-yl-ether (4'-)trans-pentyl-trans-bicyclohexyl
cy-4-yl)-methyl-(4'-butoxy-3,3'
-dimethyl)-biphenyl-4-yl-ether (4'-)lan-subenyl-transupicyclohexyl
(4-yl)-methyl-(4'-N-butylamino-
2-Methyl)-biphenyl-4-yl-ether (4'-)trans-pentyl-trans-bicyclohexyl
(4-yl)-methyl-(4'-N-butylamino-
3-Methyl)-biphenyl-4-yl-ether (4'-)supe/thyl-trans-bicyclohexyl
C-4-yl)-methyl-(4'-N-butylaC)-
2,31-dimethyl)-biphenyl-4-yl-ether
(4'-trans-pentyl-trans-bicyclohexyl)
(4-yl)-methyl-(4'-N-butylamino-
2',3-dimethyl)-biphenyl-4-yl-ether
C4'-t57 Supentyl-trans-bicyclohexyl
4-yl)-methyl-(4'-N-butylamino-
3,3'-dimethyl)-bi7-di-4-yl ether
(4'-trans-pentyl-trans-bicyclohexyl)
(4-yl)-methyl-(2-methyl-4'-octa
(noyloxy)-biphenyl-4-yl-ether (4'-)trans-pentyl-trans-bicyclohexyl
(4-yl)-methyl-(3-methyl-4'-octa
noyloxy)-biphenyl-4-yl-ether (4'-trans-pentyl-trans-bicyclohexyl)
(4-yl)-methyl-(2,3'-dimethyl-4'
-octanoyloxy)-biphenyl-4-yl-A
Ter(4'-1 lance-benzyl-trans-bicyclohexyl)
(4-yl)-methyl-(2', 3-dimethyl-4
'-octanoyloxy)-biphenyl-4-yl-e
-ter(4'-)trans-pentyl-trans-bicyclohexyl
(4-yl)-methyl-(3,3'-dimethyl-4'
-octanoyloxy)-biphenyl-4-yl-A
Continuation of Tel page 1■Int, C1,3 identification code Office serial number C0
7C87/32 7118-4H
871507118-4H 1211507731-4H 121/60 7731-4H1
21/75 7731-4HC0
7D 239/26 7431-
4CCO9K 3/34 102 72
29-4HIG 02 F 1/13
7448-2HG 09 F 9100
6865-5C priority claim 019
May 4, 1982 ■ Switzerland (CH) ■ 2725/82-7 0 Inventor Majed A. Ottoman Switzerland
-Rich Lerchenline 1

Claims (1)

[Claims] 1. Formula (1): [wherein, human is the formula αG-Q2: Qo 01] (represents a cyclic group t- represented by one of 12, 2 is a single bond, the group -OH OHm-, methyleneoxy group or oxymethylene group, n is 1 or 2, p is 0 or 1 or a2.r is 0 or it-, and X is a fluorine atom, chlorine atom, bromine atom or iodine atom or a nitrile group or a methyl group, R1 and R represent a hydrogen atom, each an alkyl group, an alkoxy group, an alkanoyloxy group, or an alkyl group having 1 to 12 carbon atoms in the alkyl group; : In the case of , the alkyl group may be linear or branched and chiral, or 2〇J~06= a3 α4 α5 (2) (In the above formula, Bl~R is a hydrogen atom, an alkyl group, an alkoxy group, an alkanoyloxy group or an alkylamino group each having 1 to 12 carbon atoms in the furkyl group t-
In this case, the alkyl group may be linear or branched and chiral, and 23-2.
The following is an example of t-representation and X% p and r represent a cyclic group shown in the above t-representation. 01
), Q3゜For any of the aromatic groups (b) or (g), the methyleneoxy group or the oxymethylene group is one of the skeleton groups.
(B) Only one of the groups 1 and B represents a cyclic group of formula (2) or (t), or neither of them represents the cyclic group t, and When a person has the formula (b) and the bridge member zl or 2@ represents a single bond t-,
an anisotropic compound having a nematic phase, at least one of which is a butterfly methyl group; 2, 5, @: (wherein, Rly" eXtzeI) and n represents the above-mentioned toi-). Compound according to claim 1. &Formula ga: (wherein, R1, R'', X, Z, n and r are represented by t- as defined above. A compound according to claim 1. 4. The compound according to claim 1, which is represented by the formula: (wherein R'', R, X, Z, r and n are the above-mentioned t-). 5 Formula @ 6. The compound according to claim 1, which is represented by the formula (wherein, R1, R-in-law, Z, X, and n represent the above-mentioned t-).寞vn” * Z * Z” sA t X
2. The compound according to claim 1, wherein a p and n are as defined above. 2 Formula @: (wherein R", R', Z, Z', A, X, n and r
2. A compound according to claim 1, which is represented by the above-mentioned t-. a The compound according to claim 1, which is represented by the formula @: (wherein R'', R1, Z, Z, #A @ @: (In the formula, R1, R., Z, Z'', A, x and Hina represent the above). A compound according to claim 1 of IPF. 10. Formula gQ: (wherein R'', R'', Z, Z'', A, X, m and p represent the above-mentioned t-), Claim 1
Compounds described in Section. 11. Formula clη: (wherein R'', R', Z, Z', A, X
, n and Ur represent the above-mentioned compounds. 12, 2@: (in the formula, % R', R', Z, Z', A, X, a and r are the same as above). *Claims No. 1
Compounds described in Section. 1'A, a compound of the formula QII: (wherein R1, R'', Z, Z., A, X and U n h) according to claim 1. 14. Claims W!J where X or methyl group t-represents
tIIE The compound according to any one of Items 1 to 13. 15. The compound according to any one of claims 1 to 13, wherein X represents a valve leaflet atom, a chlorine atom, a bromine atom, or an iodine atom. 16, Formula (1): [In the formula, A represents a cyclic group represented by one of the formulas αO to Q2=, 2 is a single bond, and the group -O
H, OH, -, methyleneoxy group or oxymethylene group? : Representation, n is 1 or 2, p is O or 1 or 2. r is 0 or 1t-; R1 and R3 are hydrogen atoms, each having 1 to 12 atoms in the alkyl group
represents an alkyl group, an alkoxy group, an alkanoyloxy group or an alkylaz) group having ) ~ @: Q3 Q41 (In the above formula, R''-R@a represents a hydrogen atom, an alkyl group, an alkoxy group, an alkanoyloxy group, or an alkylamino group each having 1 to 12 carbon atoms in the alkyl group; In this case, the alkyl group may be linear or branched and may be chiral, Z1%Z.
represents the one listed above, and X t p and r represent the above-mentioned cyclic group, provided that in this case, condition (A) is the formula (t) o in the molecule? F is "tru type Q (1,
Ql), Qa. (B) Only one of the groups R1 and Bl has the formula or (g) represents a cyclic group, or neither of them represents the cyclic group, and the person has formula (2) and the bridge member zi or z6
When represents a single bond, it is represented by formula 1 (satisfying that at least one of Mixture. lz A compound represented by the formula @: (wherein, R1, R", X, Z, p and 1 represent the above), A compound represented by the formula (goods): (wherein R", R", X, Z, r and n represent the above), A compound represented by the formula @: (in the formula, b "tR" * z * x and n have the same meanings as above), formula (7): (in the formula, R" t R" s Z I" t Ay X
t P and Teng represent the above-mentioned compounds. A compound represented by the formula: (wherein, R', Z, Z', A, Z, Z', A, X, n and r represent the above), a compound represented by the formula:
represents the above), a compound represented by formula (7): (wherein R'', R'', Z, Z'', A, X
, n and hip are as defined above), 2aD: (in the formula %R', R', Z, Z', A, X,
1K and r represent the above), a compound represented by the formula (to): (wherein R', R@, Z, Z', A, X, +n and r represent the above) The scope of the patent terminal is characterized by at least one of the compounds shown and the formula @: (wherein R", R', Z, Z", A, The mixture according to item 16.