JPS58112035A - Dispersing or dissolving assistant for hydrophilic substance - Google Patents
Dispersing or dissolving assistant for hydrophilic substanceInfo
- Publication number
- JPS58112035A JPS58112035A JP56208088A JP20808881A JPS58112035A JP S58112035 A JPS58112035 A JP S58112035A JP 56208088 A JP56208088 A JP 56208088A JP 20808881 A JP20808881 A JP 20808881A JP S58112035 A JPS58112035 A JP S58112035A
- Authority
- JP
- Japan
- Prior art keywords
- hydrophilic
- substance
- dispersing
- dissolving
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000126 substance Substances 0.000 title claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 7
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 7
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 6
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 6
- 125000001453 quaternary ammonium group Chemical group 0.000 claims abstract description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims abstract description 3
- 229910019142 PO4 Inorganic materials 0.000 claims abstract 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract 3
- 239000010452 phosphate Substances 0.000 claims abstract 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract 2
- 239000006185 dispersion Substances 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 2
- 229940071207 sesquicarbonate Drugs 0.000 claims description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims 1
- 235000011180 diphosphates Nutrition 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 4
- 229920001353 Dextrin Polymers 0.000 abstract description 3
- 239000004375 Dextrin Substances 0.000 abstract description 3
- 229920002472 Starch Polymers 0.000 abstract description 3
- 235000019425 dextrin Nutrition 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 235000019698 starch Nutrition 0.000 abstract description 3
- 239000008107 starch Substances 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 238000009434 installation Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 6
- 238000004090 dissolution Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 235000013312 flour Nutrition 0.000 description 3
- 229920000591 gum Polymers 0.000 description 3
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 241000981595 Zoysia japonica Species 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- SATHPVQTSSUFFW-UHFFFAOYSA-N 4-[6-[(3,5-dihydroxy-4-methoxyoxan-2-yl)oxymethyl]-3,5-dihydroxy-4-methoxyoxan-2-yl]oxy-2-(hydroxymethyl)-6-methyloxane-3,5-diol Chemical compound OC1C(OC)C(O)COC1OCC1C(O)C(OC)C(O)C(OC2C(C(CO)OC(C)C2O)O)O1 SATHPVQTSSUFFW-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 244000247812 Amorphophallus rivieri Species 0.000 description 1
- 235000001206 Amorphophallus rivieri Nutrition 0.000 description 1
- 239000001904 Arabinogalactan Substances 0.000 description 1
- 229920000189 Arabinogalactan Polymers 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- 240000008886 Ceratonia siliqua Species 0.000 description 1
- 235000013912 Ceratonia siliqua Nutrition 0.000 description 1
- 240000000745 Erythronium japonicum Species 0.000 description 1
- 235000000495 Erythronium japonicum Nutrition 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229920000569 Gum karaya Polymers 0.000 description 1
- 229920002752 Konjac Polymers 0.000 description 1
- 244000215747 Pachyrhizus erosus Species 0.000 description 1
- 235000001591 Pachyrhizus erosus Nutrition 0.000 description 1
- 235000018669 Pachyrhizus tuberosus Nutrition 0.000 description 1
- 241000934878 Sterculia Species 0.000 description 1
- 240000004584 Tamarindus indica Species 0.000 description 1
- 235000004298 Tamarindus indica Nutrition 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 229940023476 agar Drugs 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000019312 arabinogalactan Nutrition 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 239000000252 konjac Substances 0.000 description 1
- 235000010485 konjac Nutrition 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000020183 skimmed milk Nutrition 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 235000010491 tara gum Nutrition 0.000 description 1
- 239000000213 tara gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Landscapes
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は親水性の微細な粉状物質を水に分散または溶解
する際に、その分散または溶解を容易にするために該親
水性粉状物質に添加されて用いられる添加剤に関し、−
に詳しくは、アルカリ金属、アルカリ土類金属または第
４アンモニウムの第−燐酸塩または酸性ピロＮｊ酸塩の
少くとも一種にアルカリ金属、アルカリ土類金属または
第４アンモニウムの炭酸塩、重炭酸塩またはセスキ炭酸
塩の少くとも一種を１７０．８〜１．２モルの割合で配
合してなる親水性粉状物質の水に対する分散または溶解
助剤を提供せんとするものである。日常、￥、ス水性の
物質を水に分散または溶解させる場合、その物質の水に
対する溶解度や分散性は本来は比較的太きいにも拘らず
、仲々溶解や分散し難いことが経験される。例えば、デ
ンプンやデキストリンを水に溶かす場付或いは小麦粉や
カタクリ粉を水に溶く（分散だせる）場合、溶解に非常
に長時間を要したり或いは微粉か凝集して所謂ダマを生
じたシすることが知られている。かかる難点は溶解の際
に温度を上げたシ高速度で機械的な攪拌をすること等の
方法によシ解決されることが多いが、野外における作業
等その設備のない処や親水性物質の種類によっては昇温
、攪拌等が許されないこともあり、全てのケースについ
て適用し得るものではない。DETAILED DESCRIPTION OF THE INVENTION The present invention can be used by being added to a hydrophilic fine powder substance in order to facilitate the dispersion or dissolution when the fine hydrophilic powder substance is dispersed or dissolved in water. Regarding additives, -
In particular, at least one alkali metal, alkaline earth metal or quaternary ammonium phosphate or acid pyro-Nj salt, an alkali metal, alkaline earth metal or quaternary ammonium carbonate, bicarbonate or It is an object of the present invention to provide a dispersion or solubilizing agent for a hydrophilic powdery substance in water, which contains at least one type of sesquicarbonate in a proportion of 170.8 to 1.2 moles. When dispersing or dissolving an aqueous substance in water, it is often experienced that it is difficult to dissolve or disperse it, even though the solubility and dispersibility of the substance in water is relatively high. For example, when dissolving starch or dextrin in water, or dissolving (dispersing) wheat flour or Katakuri flour in water, it may take a very long time to dissolve, or the fine particles may aggregate and form clumps. Are known. These difficulties are often solved by methods such as raising the temperature during dissolution and mechanically stirring at high speeds, but it is difficult to solve this problem in places where such equipment is not available, such as when working outdoors, or when using hydrophilic substances. Depending on the type, heating, stirring, etc. may not be allowed, so it cannot be applied to all cases.
本発明者らは特別な設備を必要とせず筒便且容易に親水
性物質を水に分散或いは溶解させる方法について種々検
討を重ねた結果、本発明を完成するに至った。The present inventors have completed the present invention as a result of various studies on a method for easily dispersing or dissolving a hydrophilic substance in water without requiring special equipment.
以下、不発明について更に詳細に説明する。Hereinafter, non-invention will be explained in more detail.
本発明の適用される親水性の粉状物質としては、第一に
は、本質的には水溶性ではあるが、そのままでは完全に
水に溶解するまでに長時間を要したシ、またはその間に
凝集固結成いは変質を招き均一な水溶液を得るのが困−
である物質であシ、その他、完全に水に溶解する訳では
ないが水に対する親和性が高く、水と混和した場合水中
に均一に分散した水性液となるが、均一な水性液を得る
に前記と同様な弊害を有する物質があげられる。尚、こ
れらの物質であってもその物理的な状態によっては、比
較的溶解が容易であったシ、水性分散液とする際、ダマ
を生じないものもあるが、当然のこと乍ら、それらにつ
いては本発明の助剤の添加は必要ないため除外される。Hydrophilic powdery substances to which the present invention is applicable include, firstly, substances that are essentially water-soluble but require a long period of time to completely dissolve in water, or Coagulation and solidification lead to deterioration and make it difficult to obtain a uniform aqueous solution.
Other substances are not completely soluble in water, but have a high affinity for water, and when mixed with water, they form an aqueous liquid that is uniformly dispersed in water, but it is difficult to obtain a uniform aqueous liquid. Substances that have the same adverse effects as those mentioned above can be mentioned. Depending on their physical state, some of these substances are relatively easy to dissolve and do not form lumps when made into an aqueous dispersion; These cases are excluded because they do not require the addition of the auxiliary agent of the present invention.
。一般に微細な粉状物の場合に難水溶性、帷分散性とな
るものが多く、これらに適用された場合、最もその特徴
が発揮される。具体的に例を示せば、例えば、アラビア
ゴム、アルギン酸塩、ガテイーガム、カラギーナン、カ
ラヤガム、寒天、キサンタンガム、グアーガム、コンニ
ャク粉、タマリンドガム、タラガム、デキストリン、テ
ンプン、トラガントガム、ファーセラン、ベクチンミヤ
マイモ、ローカストビーンガム、アラビノガラクタン、
・Ｃ，Ｍ、 Ｃ，、脱脂粉乳、小麦粉等の天然高分子
物質の粉末が掲げられる０
使用量については厳密な制限はないが、一般に親水性物
質に対して５〜５０重量％の範囲で用いるのが適当であ
シ、必要に応じて増減することができる。. In general, fine powders are often poorly water-soluble and widely dispersible, and their characteristics are best exhibited when applied to these. Specific examples include gum arabic, alginate, gatei gum, carrageenan, karaya gum, agar, xanthan gum, guar gum, konjac powder, tamarind gum, tara gum, dextrin, starch, gum tragacanth, farcelan, vectin yam, and locust bean. gum, arabinogalactan,
・Powders of natural polymer substances such as C, M, C, skim milk powder, and wheat flour are listed. There are no strict restrictions on the amount used, but it is generally in the range of 5 to 50% by weight based on the hydrophilic substance. It is appropriate to use it, and it can be increased or decreased as necessary.
以下、本発明の実施態様、及び効果について代表的な実
施例を示し更に具体的に説明するが、これらは本発明に
ついての理解を容易にするための単なる例示であり、従
って本発明はこれによって何ら制限されないことは言う
までもない。尚、実施例、中の部は重量部である。Hereinafter, typical examples and effects of the present invention will be shown and explained in more detail, but these are merely illustrative examples to facilitate understanding of the present invention, and therefore, the present invention will be explained in more detail. Needless to say, there are no restrictions. In the examples, the middle parts are parts by weight.
実施例 １
第１表に示す遅溶解性親水性物質２０部に、本発明によ
る第２表の溶解助剤を所定量混合し、これを混合剤に対
して４０重量倍の１８℃の水に投入して、約３分間攪拌
した結果、親水性物質の溶解性は第１表に示すごとく極
めて良好であった。Example 1 20 parts of the slow-dissolving hydrophilic substance shown in Table 1 was mixed with a predetermined amount of the solubilizing agent shown in Table 2 according to the present invention, and this was added to water at 18° C. that was 40 times the weight of the mixture. As a result of stirring for about 3 minutes, the solubility of the hydrophilic substance was found to be extremely good as shown in Table 1.
これに対し、本発明による溶解助剤を使用することなく
、第１表に示す親水性物質を、該物質に対して４０重量
倍の１８℃の水に投入して、約３分間攪拌した結果、第
１表に示すごとく殆んどがダマになって、水に均一に溶
解させることは困難であった。In contrast, the results were obtained by adding the hydrophilic substances shown in Table 1 to 18°C water of 40 times the weight of the substance and stirring for about 3 minutes without using the solubilizing agent according to the present invention. However, as shown in Table 1, most of the mixture became lumps, making it difficult to dissolve them uniformly in water.
第 １ 表
◎：急速完全溶解（分散） ：ダマが残る○：完全溶解
（分散）×：ダマが多量に残る第 ２ 表
特許出願人 昭和電工株式会社
三光化学工業株式会社
手続補正書（方式）
昭和左り年 す月２ｒ日
特許庁長官 島田春樹殿
１、事件の表示
昭和聞年特許願第２０８０８８号
２発明の名称
親水性物質の分散または溶解助剤
３、補正をする者
事件との関係 特許出願人
住所 東京都港区芝大門−丁目１３番９号名称 （２０
０）昭和電工株式会社
他１名
４、代理人〒１０５
居所 東京都港区芝大門−丁目１３番９号昭和５７年４
月９日（発送日 同年４月ｎ日）ｌ）願書の発明の名称
の欄を 親水性物質の分散または溶解助剤 と訂正し、
別紙の通り訂正願書を提出する。Table 1 ◎: Rapid complete dissolution (dispersion): Clumps remain ○: Complete dissolution (dispersion) ×: A large amount of lumps remain Table 2 Patent applicant Showa Denko Co., Ltd. Sanko Chemical Industries Co., Ltd. Procedural amendment (method) Haruki Shimada, Commissioner of the Japan Patent Office, February 2, 19391, Indication of the case, Showa Era Patent Application No. 208088, 2 Name of the invention, Dispersion or solubilizing agent for hydrophilic substances, 3, Person making the amendment, Relationship with the case Patent applicant address: Shiba Daimon-chome 13-9, Minato-ku, Tokyo Name (20
0) Showa Denko Co., Ltd. and 1 other person 4, agent 105 Address 13-9 Shiba Daimon-chome, Minato-ku, Tokyo 1984 4
April 9th (shipment date: April nth of the same year) 1) The title of the invention in the application was corrected to Dispersion or solubilizing agent for hydrophilic substances.
Submit the correction application as shown in the attached sheet.
２）明細書の発明の名称の欄を 親水性物質の分散また
は溶解助剤 と訂正する。2) The title of the invention column in the description should be corrected to "Dispersion or solubilizing agent for hydrophilic substances."
３）別紙の通り委任状を提出する。3) Submit a power of attorney as shown in the attached document.
８、添付書類 １）訂正願書 １通−２’8. Attached documents 1) Correction application 1 copy - 2'
Claims (1)
ピロ燐酸塩の少くとも一種にアルカリ金属、アルカリ土
類金属または第４アンモニウムの炭酸塩、重炭酸塩また
はセスキ炭酸塩の少くとも一種をｉ：ｏ、ｓ〜１．２モ
ルの割合で配合してなる親水性粉状物質の水に対する分
散または溶解助剤。[Scope of Claims] At least one primary phosphate or acid pyrophosphate of an alkali metal, alkaline earth metal or quaternary ammonium, carbonate or bicarbonate of an alkali metal, alkaline earth metal or quaternary ammonium Or, a dispersion or solubilizing agent for water of a hydrophilic powdery substance, which contains at least one type of sesquicarbonate in a ratio of i:o,s to 1.2 moles.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56208088A JPS58112035A (en) | 1981-12-24 | 1981-12-24 | Dispersing or dissolving assistant for hydrophilic substance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56208088A JPS58112035A (en) | 1981-12-24 | 1981-12-24 | Dispersing or dissolving assistant for hydrophilic substance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS58112035A true JPS58112035A (en) | 1983-07-04 |
Family
ID=16550434
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56208088A Pending JPS58112035A (en) | 1981-12-24 | 1981-12-24 | Dispersing or dissolving assistant for hydrophilic substance |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58112035A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5234945A (en) * | 1975-08-01 | 1977-03-17 | Merck & Co Inc | Artificial food and method of producing same |
| JPS5356174A (en) * | 1976-11-02 | 1978-05-22 | Kyowa Kagaku Kougiyou Kk | Calcium hydrogen phosphateecalcium carbonate compound structure and the manufacture |
| JPS56144735A (en) * | 1980-04-11 | 1981-11-11 | San Ei Chem Ind Ltd | Stabilization of oil in water type emulsion |
-
1981
- 1981-12-24 JP JP56208088A patent/JPS58112035A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5234945A (en) * | 1975-08-01 | 1977-03-17 | Merck & Co Inc | Artificial food and method of producing same |
| JPS5356174A (en) * | 1976-11-02 | 1978-05-22 | Kyowa Kagaku Kougiyou Kk | Calcium hydrogen phosphateecalcium carbonate compound structure and the manufacture |
| JPS56144735A (en) * | 1980-04-11 | 1981-11-11 | San Ei Chem Ind Ltd | Stabilization of oil in water type emulsion |
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