JPS5781444A - Preparation of n-alkyl-substituted aromatic amino compound - Google Patents
Preparation of n-alkyl-substituted aromatic amino compoundInfo
- Publication number
- JPS5781444A JPS5781444A JP55157095A JP15709580A JPS5781444A JP S5781444 A JPS5781444 A JP S5781444A JP 55157095 A JP55157095 A JP 55157095A JP 15709580 A JP15709580 A JP 15709580A JP S5781444 A JPS5781444 A JP S5781444A
- Authority
- JP
- Japan
- Prior art keywords
- hydrogen
- aromatic amino
- compound
- amino compound
- aldehyde compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To prepare the titled compound useful as an intermediate of dyes, pharmaceuticals, pesticides, etc., in a short time, by the reductive alkylation of an aromatic amino compound in the presence of a noble metal catalyst and hydrogen in an organic solvent under the controlled rate of feeding of an aldehyde compound.
CONSTITUTION: An aromatic amino compound (e.g. o-toluidine, 2-aminophenol, etc.) is alkylated with an aldehyde compound (e.g. formaldehyde, benzaldehyde, etc.) as the alkylating agent, in an organic solvent, in the presence of a noble metal catalyst (e.g. palladium-activated charcoal, platinum-activated charcoal, etc.) and hydrogen. The aldehyde compound is supplied to the reaction system corresponding to the consumption of hydrogen excepting the induction period. The reaction is carried out at normal temp. W150°C, pref. 50W100°C under atmospheric pressure or positive pressure (usually ≤10atm.) controlled with hydrogen.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55157095A JPS5781444A (en) | 1980-11-10 | 1980-11-10 | Preparation of n-alkyl-substituted aromatic amino compound |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55157095A JPS5781444A (en) | 1980-11-10 | 1980-11-10 | Preparation of n-alkyl-substituted aromatic amino compound |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5781444A true JPS5781444A (en) | 1982-05-21 |
Family
ID=15642133
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP55157095A Pending JPS5781444A (en) | 1980-11-10 | 1980-11-10 | Preparation of n-alkyl-substituted aromatic amino compound |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5781444A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60130551A (en) * | 1983-12-16 | 1985-07-12 | Kao Corp | Preparation of tertiary amine |
KR980009227A (en) * | 1996-07-24 | 1998-04-30 | 성재갑 | Preparation of alkyl substituted dialkyl aniline derivatives |
US6014905A (en) * | 1995-05-10 | 2000-01-18 | Marposs Societa' Per Azioni | Measuring apparatus with an analog-digital display unit |
CN103933973A (en) * | 2014-04-28 | 2014-07-23 | 河南师范大学 | Preparation method of supported nano palladium/carbon catalyst |
-
1980
- 1980-11-10 JP JP55157095A patent/JPS5781444A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60130551A (en) * | 1983-12-16 | 1985-07-12 | Kao Corp | Preparation of tertiary amine |
JPH0533214B2 (en) * | 1983-12-16 | 1993-05-19 | Kao Corp | |
US6014905A (en) * | 1995-05-10 | 2000-01-18 | Marposs Societa' Per Azioni | Measuring apparatus with an analog-digital display unit |
KR980009227A (en) * | 1996-07-24 | 1998-04-30 | 성재갑 | Preparation of alkyl substituted dialkyl aniline derivatives |
CN103933973A (en) * | 2014-04-28 | 2014-07-23 | 河南师范大学 | Preparation method of supported nano palladium/carbon catalyst |
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