JPS572248A - Preparation of anthraquinone type intermediate - Google Patents
Preparation of anthraquinone type intermediateInfo
- Publication number
- JPS572248A JPS572248A JP7531880A JP7531880A JPS572248A JP S572248 A JPS572248 A JP S572248A JP 7531880 A JP7531880 A JP 7531880A JP 7531880 A JP7531880 A JP 7531880A JP S572248 A JPS572248 A JP S572248A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- aminoanthraquinone
- dibromination
- preparation
- sulfuric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain the titled compound useful as an intermediate for dye, containing no by-product, in high quality and in high yield, by subjecting 1-aminoanthraquinone to dibromination in sulfuric acid in the presence of a specific amount of fatty monocarboxylic acid.
CONSTITUTION: 1-Aminoanthraquinone is subjected to dibromination in ≥50wt% sulfuric acid or ≤10wt% fuming sulfuric acid in the presence of a fatty monocarboxylic acid (e.g., acetic acid, propionic acid, butyric acid, etc.) in a molar ratio of the monocarboxylic acid to 1-aminoanthraquinone 0.05W1.5, to give 1-amino- 2,4-dibromoanthraquinone. The dibromination is carried out at 50W150°C, preferably 60W130°C using a brominating agent, e.g., bromine, etc. in a molar ratio of the brominating agent to 1-aminoanthraquinone 1.0W3.0.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7531880A JPS572248A (en) | 1980-06-03 | 1980-06-03 | Preparation of anthraquinone type intermediate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7531880A JPS572248A (en) | 1980-06-03 | 1980-06-03 | Preparation of anthraquinone type intermediate |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS572248A true JPS572248A (en) | 1982-01-07 |
JPS6261020B2 JPS6261020B2 (en) | 1987-12-18 |
Family
ID=13572782
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7531880A Granted JPS572248A (en) | 1980-06-03 | 1980-06-03 | Preparation of anthraquinone type intermediate |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS572248A (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS53133230A (en) * | 1977-04-25 | 1978-11-20 | Sumitomo Chem Co Ltd | Preparation of anthraquinone intermediate |
-
1980
- 1980-06-03 JP JP7531880A patent/JPS572248A/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS53133230A (en) * | 1977-04-25 | 1978-11-20 | Sumitomo Chem Co Ltd | Preparation of anthraquinone intermediate |
Also Published As
Publication number | Publication date |
---|---|
JPS6261020B2 (en) | 1987-12-18 |
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