JPS57200371A - Preparation of triallyl isocyanurate in high purity - Google Patents

Preparation of triallyl isocyanurate in high purity

Info

Publication number
JPS57200371A
JPS57200371A JP8549881A JP8549881A JPS57200371A JP S57200371 A JPS57200371 A JP S57200371A JP 8549881 A JP8549881 A JP 8549881A JP 8549881 A JP8549881 A JP 8549881A JP S57200371 A JPS57200371 A JP S57200371A
Authority
JP
Japan
Prior art keywords
organic layer
solvent
resultant
cyanuric acid
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP8549881A
Other languages
Japanese (ja)
Other versions
JPH0138112B2 (en
Inventor
Ikuo Kawakami
Yoshiharu Mori
Tomoyuki Sato
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissan Chemical Corp
Original Assignee
Nissan Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Chemical Corp filed Critical Nissan Chemical Corp
Priority to JP8549881A priority Critical patent/JPS57200371A/en
Publication of JPS57200371A publication Critical patent/JPS57200371A/en
Publication of JPH0138112B2 publication Critical patent/JPH0138112B2/ja
Granted legal-status Critical Current

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  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To obtain the titled compound which is a modifier for synthetic resins, in high yield and purity, by reacting isocyanuric acid with allyl chloride in the presence of tri-n-propylamine, washing the resultant product in a given order, distilling off the solvent, and finally rectifying the product.
CONSTITUTION: Cyanuric acid and tri-n-propylamine at a molar ratio of 1:(3W 3.9) are added to o-dichlorobenzene solvent, and 3W3.9 moles, based on one mole cyanuric acid, allyl chloride is added thereto while keeping the solution at 105°C or above with stirring. The reaction mixture is heated to react 95% or more cyanuric acid at 180°C or below. The resultant reaction solution is cooled and washed with water to recover the organic layer, which is then similarly washed with dilute hydrochloric acid, dilute aqueous solution of sodium carbonate, and water in the order to recover the organic layer. The washing and recovery operations are repeated. The solvent is distilled from the resultant organic layer, and the recovered crude product is rectified to give the aimed triallyl isocyanurate ≥99.9%.
COPYRIGHT: (C)1982,JPO&Japio
JP8549881A 1981-06-03 1981-06-03 Preparation of triallyl isocyanurate in high purity Granted JPS57200371A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8549881A JPS57200371A (en) 1981-06-03 1981-06-03 Preparation of triallyl isocyanurate in high purity

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8549881A JPS57200371A (en) 1981-06-03 1981-06-03 Preparation of triallyl isocyanurate in high purity

Publications (2)

Publication Number Publication Date
JPS57200371A true JPS57200371A (en) 1982-12-08
JPH0138112B2 JPH0138112B2 (en) 1989-08-11

Family

ID=13860592

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8549881A Granted JPS57200371A (en) 1981-06-03 1981-06-03 Preparation of triallyl isocyanurate in high purity

Country Status (1)

Country Link
JP (1) JPS57200371A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005112740A (en) * 2003-10-03 2005-04-28 Kaneka Corp Curing agent, curable composition and cured material prepared by curing the same
JP2005112925A (en) * 2003-10-03 2005-04-28 Kaneka Corp Curable composition
EP2270103A2 (en) 2000-12-27 2011-01-05 Kaneka Corporation Curing agent, curable compositions, compositions for optical materials, optical materials, their production, and liquid crystal displays and LED's made by using the materials
DE102012021134B3 (en) * 2012-10-27 2013-03-28 Alzchem Ag Preparing triallylisocyanurate, useful as crosslinker for plastic, comprises reacting cyanuric acid with allyl halide in aqueous solution, and in presence of catalyst comprising copper salt and complex ligand comprising polyvalent alcohols
JP2015166462A (en) * 2015-04-16 2015-09-24 日本化成株式会社 Crosslinking agent and sealant
CN106810505A (en) * 2017-03-02 2017-06-09 江苏华星新材料科技股份有限公司 The technique that a kind of isocyanuric acid prepares Triallyl isocyanurate
JP2017165741A (en) * 2017-04-13 2017-09-21 日本化成株式会社 Triallyl isocyanurate
CN112500399A (en) * 2020-12-02 2021-03-16 黄山华惠科技有限公司 Low-chlorine ECH-residue-free TGIC curing agent and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104211651A (en) * 2014-09-02 2014-12-17 江苏科利新材料有限公司 Method for preparing high-quality cross-linking agent

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2270103A2 (en) 2000-12-27 2011-01-05 Kaneka Corporation Curing agent, curable compositions, compositions for optical materials, optical materials, their production, and liquid crystal displays and LED's made by using the materials
JP2005112740A (en) * 2003-10-03 2005-04-28 Kaneka Corp Curing agent, curable composition and cured material prepared by curing the same
JP2005112925A (en) * 2003-10-03 2005-04-28 Kaneka Corp Curable composition
DE102012021134B3 (en) * 2012-10-27 2013-03-28 Alzchem Ag Preparing triallylisocyanurate, useful as crosslinker for plastic, comprises reacting cyanuric acid with allyl halide in aqueous solution, and in presence of catalyst comprising copper salt and complex ligand comprising polyvalent alcohols
WO2014064170A1 (en) 2012-10-27 2014-05-01 Alzchem Ag Method for producing triallyl isocyanurate
JP2015166462A (en) * 2015-04-16 2015-09-24 日本化成株式会社 Crosslinking agent and sealant
CN106810505A (en) * 2017-03-02 2017-06-09 江苏华星新材料科技股份有限公司 The technique that a kind of isocyanuric acid prepares Triallyl isocyanurate
JP2017165741A (en) * 2017-04-13 2017-09-21 日本化成株式会社 Triallyl isocyanurate
CN112500399A (en) * 2020-12-02 2021-03-16 黄山华惠科技有限公司 Low-chlorine ECH-residue-free TGIC curing agent and preparation method thereof
CN112500399B (en) * 2020-12-02 2024-03-12 黄山华惠科技有限公司 Low-chlorine ECH-residue-free TGIC curing agent and preparation method thereof

Also Published As

Publication number Publication date
JPH0138112B2 (en) 1989-08-11

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