JPS57182305A - Polymerization and copolymerization of branched alpha-olefin - Google Patents

Polymerization and copolymerization of branched alpha-olefin

Info

Publication number
JPS57182305A
JPS57182305A JP6872481A JP6872481A JPS57182305A JP S57182305 A JPS57182305 A JP S57182305A JP 6872481 A JP6872481 A JP 6872481A JP 6872481 A JP6872481 A JP 6872481A JP S57182305 A JPS57182305 A JP S57182305A
Authority
JP
Japan
Prior art keywords
olefin
trichloride
aluminum trichloride
branching
titanium trichloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6872481A
Other languages
Japanese (ja)
Inventor
Takayuki Otsu
Kiyoji Endou
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Petrochemical Co Ltd
Original Assignee
Mitsubishi Petrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Petrochemical Co Ltd filed Critical Mitsubishi Petrochemical Co Ltd
Priority to JP6872481A priority Critical patent/JPS57182305A/en
Publication of JPS57182305A publication Critical patent/JPS57182305A/en
Pending legal-status Critical Current

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  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

PURPOSE: To produce an α-olefin polymer extremely excellent in heat resistance, by using a catalyst consisting of an organoaluminum compound and a titanium trichloride-containing solid subtantially free of aluminum trichloride.
CONSTITUTION: In polymerizing an α-olefin having a branching at the C atom in position 3 (e.g., 3-methylbutene-1) or coplymerizing such an olefin with a different olefin (e.g., ethylene), use is made of a catalyst prepared by combining an organoaluminum compound wit a titanium trichloride-containing solid completely free of aluminum trichloride or containing aluminum trichloride in an amount corresponding to a mol ratio to titanium trichloride of below 0.1. According to this process, an α-olefin having a branching at the C atom in position 3 can be polymerized at a rate several times higher than those in conventional processes and, therefore, a high-m.p. polymer is obtained in high yields. Accordingly, this process is useful.
COPYRIGHT: (C)1982,JPO&Japio
JP6872481A 1981-05-07 1981-05-07 Polymerization and copolymerization of branched alpha-olefin Pending JPS57182305A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6872481A JPS57182305A (en) 1981-05-07 1981-05-07 Polymerization and copolymerization of branched alpha-olefin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6872481A JPS57182305A (en) 1981-05-07 1981-05-07 Polymerization and copolymerization of branched alpha-olefin

Publications (1)

Publication Number Publication Date
JPS57182305A true JPS57182305A (en) 1982-11-10

Family

ID=13382025

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6872481A Pending JPS57182305A (en) 1981-05-07 1981-05-07 Polymerization and copolymerization of branched alpha-olefin

Country Status (1)

Country Link
JP (1) JPS57182305A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1986000316A1 (en) * 1984-06-22 1986-01-16 Mitsubishi Chemical Industries Limited 3-methylbutene-1 polymer composition, and process for its preparation
JP2021143214A (en) * 2020-03-10 2021-09-24 日本化薬株式会社 Olefin resin, curable resin composition and cured product thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1986000316A1 (en) * 1984-06-22 1986-01-16 Mitsubishi Chemical Industries Limited 3-methylbutene-1 polymer composition, and process for its preparation
US4645797A (en) * 1984-06-22 1987-02-24 Mitsubishi Chemical Industries Ltd. 3-Methylbutene-1 polymer composition and process for its production
JP2021143214A (en) * 2020-03-10 2021-09-24 日本化薬株式会社 Olefin resin, curable resin composition and cured product thereof

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