JPS57130939A - Synthetic method of alkane polyol - Google Patents

Synthetic method of alkane polyol

Info

Publication number
JPS57130939A
JPS57130939A JP56014364A JP1436481A JPS57130939A JP S57130939 A JPS57130939 A JP S57130939A JP 56014364 A JP56014364 A JP 56014364A JP 1436481 A JP1436481 A JP 1436481A JP S57130939 A JPS57130939 A JP S57130939A
Authority
JP
Japan
Prior art keywords
compound
ruthenium
alkane polyol
thenium
complexed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP56014364A
Other languages
Japanese (ja)
Inventor
Masahide Tanaka
Yoshihisa Kiso
Kenji Saeki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Petrochemical Industries Ltd
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Priority to JP56014364A priority Critical patent/JPS57130939A/en
Publication of JPS57130939A publication Critical patent/JPS57130939A/en
Pending legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To obtain an alkane polyol, particularly ethylene glycol, in high selectivity and high yield even under a relatively low pressure, by reacting CO with H2 in the presence of a catalytic system consisting of a ruthenium compound, a rhenium compound and a specific co-catalyst.
CONSTITUTION: CO is reacted with H2 in the presence of a catalytic system consisting of a ruthenium compound, a rhenium compound and one or more selected from an alkali metal, alkaline earth metallic compound, NH3, a quaternary ammonium compound and organic amine compound as a co-catalyst preferably in an organic solvent at 150W300°C and 300kg/cm2G for 0.1W24hr to give an alkane polyol. A ruthenium and thenium compounds complexed with CO or complexed with CO and further H2 or one or more organic ligands are preferred as the ruthenium and thenium compounds. An alkali metallic iodide is preferred as the co-cotalyst.
COPYRIGHT: (C)1982,JPO&Japio
JP56014364A 1981-02-04 1981-02-04 Synthetic method of alkane polyol Pending JPS57130939A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56014364A JPS57130939A (en) 1981-02-04 1981-02-04 Synthetic method of alkane polyol

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56014364A JPS57130939A (en) 1981-02-04 1981-02-04 Synthetic method of alkane polyol

Publications (1)

Publication Number Publication Date
JPS57130939A true JPS57130939A (en) 1982-08-13

Family

ID=11858997

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56014364A Pending JPS57130939A (en) 1981-02-04 1981-02-04 Synthetic method of alkane polyol

Country Status (1)

Country Link
JP (1) JPS57130939A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2508438A1 (en) * 1981-06-26 1982-12-31 Texaco Development Corp PREPARATION OF ALKANOLS FROM SYNTHESIS GAS
CN1067972C (en) * 1996-06-27 2001-07-04 中国石化齐鲁石油化工公司 Method for producing terliary butyl alcohol by using iso-butylene from mixed carbon 4 or raffinate oil carbon 4

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2508438A1 (en) * 1981-06-26 1982-12-31 Texaco Development Corp PREPARATION OF ALKANOLS FROM SYNTHESIS GAS
CN1067972C (en) * 1996-06-27 2001-07-04 中国石化齐鲁石油化工公司 Method for producing terliary butyl alcohol by using iso-butylene from mixed carbon 4 or raffinate oil carbon 4

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