JPS57113352A - Analyzer for isotope composition - Google Patents
Analyzer for isotope compositionInfo
- Publication number
- JPS57113352A JPS57113352A JP4781A JP4781A JPS57113352A JP S57113352 A JPS57113352 A JP S57113352A JP 4781 A JP4781 A JP 4781A JP 4781 A JP4781 A JP 4781A JP S57113352 A JPS57113352 A JP S57113352A
- Authority
- JP
- Japan
- Prior art keywords
- gas
- analyzed
- hydrogen
- oxidizing device
- infrared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- 239000007789 gas Substances 0.000 abstract 5
- 230000001590 oxidative effect Effects 0.000 abstract 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 230000003197 catalytic effect Effects 0.000 abstract 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000005751 Copper oxide Substances 0.000 abstract 1
- UFHFLCQGNIYNRP-VVKOMZTBSA-N Dideuterium Chemical compound [2H][2H] UFHFLCQGNIYNRP-VVKOMZTBSA-N 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 238000000862 absorption spectrum Methods 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 abstract 1
- 239000012159 carrier gas Substances 0.000 abstract 1
- 229910000431 copper oxide Inorganic materials 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 238000005070 sampling Methods 0.000 abstract 1
- 238000004611 spectroscopical analysis Methods 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N21/3504—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Abstract
PURPOSE:To analyze an isotope composition of a hydrogen gas by measuring an infrared absorption spectrum of a vapor of a gas to be analyzed after it is vaporized with a catalytic oxidizing device. CONSTITUTION:A mixed hydrogen gas of hydrogen H and heavy hydrogen D in the process 1 is introduced into an analyzer from a sampling tube 2. At the same time, a carrier gas containing oxygen is introduced into a catalyst oxidizing device 5 from a cylinder 4 mixed with a gas to be analyzed. For example, the catalytic oxidizing device 5 uses a copper oxide catalyst and an alumina- carried platinum catalyst. The hydrogen gas being analyzed in the gas mixture flown into the catalytic oxidizing device 6 is all converted into steam and then, sent to an infrared spectroscopic cell 11. Infrared active molecules in the gas to be introduced into the cell 11 are H2O, HDO and D2O generated by the oxidation of the gas to be analyzed. These three moleculars having an intrinsic absorption wavelength undergoes a spectroscopic analysis with a diffraction grating 19 and the intensity of infrared rays is recorded on a recorder 23.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4781A JPS57113352A (en) | 1981-01-05 | 1981-01-05 | Analyzer for isotope composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4781A JPS57113352A (en) | 1981-01-05 | 1981-01-05 | Analyzer for isotope composition |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS57113352A true JPS57113352A (en) | 1982-07-14 |
Family
ID=11463354
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP4781A Pending JPS57113352A (en) | 1981-01-05 | 1981-01-05 | Analyzer for isotope composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57113352A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59222746A (en) * | 1983-06-01 | 1984-12-14 | Sagami Chem Res Center | Method and apparatus for measuring stable isotope |
JP2006520458A (en) * | 2003-03-13 | 2006-09-07 | トラスティーズ オブ プリンストン ユニバーシティ | Apparatus and method for measuring impurity concentration level in input gas stream, apparatus and method for measuring oxygen concentration level in input gas stream |
JP2020071121A (en) * | 2018-10-31 | 2020-05-07 | 大陽日酸株式会社 | Hydrogen isotope ratio measurement method and device |
-
1981
- 1981-01-05 JP JP4781A patent/JPS57113352A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59222746A (en) * | 1983-06-01 | 1984-12-14 | Sagami Chem Res Center | Method and apparatus for measuring stable isotope |
JP2006520458A (en) * | 2003-03-13 | 2006-09-07 | トラスティーズ オブ プリンストン ユニバーシティ | Apparatus and method for measuring impurity concentration level in input gas stream, apparatus and method for measuring oxygen concentration level in input gas stream |
JP2011149954A (en) * | 2003-03-13 | 2011-08-04 | Trustees Of Princeton Univ | Apparatus and method for measuring concentration level of impurity in input gas stream, and apparatus and method for measuring concentration level of oxygen in input gas stream |
JP4744152B2 (en) * | 2003-03-13 | 2011-08-10 | トラスティーズ オブ プリンストン ユニバーシティ | Apparatus and method for measuring impurity concentration level in input gas stream, apparatus and method for measuring oxygen concentration level in input gas stream |
JP2020071121A (en) * | 2018-10-31 | 2020-05-07 | 大陽日酸株式会社 | Hydrogen isotope ratio measurement method and device |
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