JPS57113350A - Determination of chlorine dioxide by ultraviolet spectrophotometery - Google Patents
Determination of chlorine dioxide by ultraviolet spectrophotometeryInfo
- Publication number
- JPS57113350A JPS57113350A JP7181A JP7181A JPS57113350A JP S57113350 A JPS57113350 A JP S57113350A JP 7181 A JP7181 A JP 7181A JP 7181 A JP7181 A JP 7181A JP S57113350 A JPS57113350 A JP S57113350A
- Authority
- JP
- Japan
- Prior art keywords
- chlorine dioxide
- mixed
- mixture
- liberate
- ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title abstract 22
- 239000004155 Chlorine dioxide Substances 0.000 title abstract 11
- 235000019398 chlorine dioxide Nutrition 0.000 title abstract 11
- 239000007789 gas Substances 0.000 abstract 2
- 239000011261 inert gas Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 abstract 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000000872 buffer Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000002347 injection Methods 0.000 abstract 1
- 239000007924 injection Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000006174 pH buffer Substances 0.000 abstract 1
- 230000000717 retained effect Effects 0.000 abstract 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 abstract 1
- 229960002167 sodium tartrate Drugs 0.000 abstract 1
- 239000001433 sodium tartrate Substances 0.000 abstract 1
- 235000011004 sodium tartrates Nutrition 0.000 abstract 1
- 238000002798 spectrophotometry method Methods 0.000 abstract 1
- 235000002906 tartaric acid Nutrition 0.000 abstract 1
- 239000011975 tartaric acid Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/33—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using ultraviolet light
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Abstract
PURPOSE:To enable continuous determination of chlorine dioxide by a method wherein a pH buffer agent is mixed into an aqueous solution of chlorine dioxide to liberate chlorine dioxide, and the gas contg. chlorine dioxide voltalized from the aq. soln. by passing an inert gas is determined by an ultraviolet ray spectrophotometry method. CONSTITUTION:A water solution 1 of chlorine dioxide and a normal solution comprising tartaric acid and sodium tartrate at a ratio of 1/10 each are mixed at the ratio by volume of 1:20. The mixture is mixed with a buffer liquid 2 of pH4.2 at an equal flow rate and fed into a chlorine dioxide generation tank 4 at a weak acidity of pH5.0+ or -1.0. The mixture is retained at a temperature of 50 deg.C to liberate chlorine dioxide while air is blown thereinto from an air injection pipe 5 provided on the bottom of the tank 4 to make chlorine dioxide fugacious. After cooled to 20 deg.C with a cooling tube 6, a gas thus obtained is sent to a detector 7. An inert gas containing chlorine dioxide with separated entrainment is measured by a peak wavelength 360nm of absorptivity for chlorine dioxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7181A JPS57113350A (en) | 1981-01-06 | 1981-01-06 | Determination of chlorine dioxide by ultraviolet spectrophotometery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7181A JPS57113350A (en) | 1981-01-06 | 1981-01-06 | Determination of chlorine dioxide by ultraviolet spectrophotometery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57113350A true JPS57113350A (en) | 1982-07-14 |
| JPS6156944B2 JPS6156944B2 (en) | 1986-12-04 |
Family
ID=11463942
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7181A Granted JPS57113350A (en) | 1981-01-06 | 1981-01-06 | Determination of chlorine dioxide by ultraviolet spectrophotometery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57113350A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2783050A1 (en) * | 1998-09-09 | 2000-03-10 | Atochem Elf Sa | AQUEOUS SOLUTION BASED ON AN AZO DYE, ITS MANUFACTURING METHOD AND ITS USE |
| CN102735640A (en) * | 2012-07-05 | 2012-10-17 | 四川久大制盐有限责任公司 | Method for determining content of ferrous tartrate |
| RU2495404C1 (en) * | 2012-04-20 | 2013-10-10 | Российская Федерация, от имени которой выступает Министерство промышленности и торговли Российской Федерации (Минпромторг России) | Method for spectrophotometric determination of concentration of chlorine dioxide and chlorite ions in drinking water |
| CN105699310A (en) * | 2016-01-22 | 2016-06-22 | 青岛科技大学 | Wide-range chlorine dioxide gas concentration detection method |
| WO2024023320A1 (en) * | 2022-07-29 | 2024-02-01 | Hemera | Gas-phase physico-chemical analysis method |
-
1981
- 1981-01-06 JP JP7181A patent/JPS57113350A/en active Granted
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2783050A1 (en) * | 1998-09-09 | 2000-03-10 | Atochem Elf Sa | AQUEOUS SOLUTION BASED ON AN AZO DYE, ITS MANUFACTURING METHOD AND ITS USE |
| EP0985929A1 (en) * | 1998-09-09 | 2000-03-15 | Elf Atochem S.A. | Aqueous solution with azo-dye, its manufacturing method and utilization |
| WO2000014530A1 (en) * | 1998-09-09 | 2000-03-16 | Atofina | Azo dye aqueous solution, preparation method and use |
| US6777242B1 (en) | 1998-09-09 | 2004-08-17 | Atofina | Aqueous solution based on an azo dye, process for its manufacture and use thereof |
| RU2495404C1 (en) * | 2012-04-20 | 2013-10-10 | Российская Федерация, от имени которой выступает Министерство промышленности и торговли Российской Федерации (Минпромторг России) | Method for spectrophotometric determination of concentration of chlorine dioxide and chlorite ions in drinking water |
| CN102735640A (en) * | 2012-07-05 | 2012-10-17 | 四川久大制盐有限责任公司 | Method for determining content of ferrous tartrate |
| CN105699310A (en) * | 2016-01-22 | 2016-06-22 | 青岛科技大学 | Wide-range chlorine dioxide gas concentration detection method |
| WO2024023320A1 (en) * | 2022-07-29 | 2024-02-01 | Hemera | Gas-phase physico-chemical analysis method |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6156944B2 (en) | 1986-12-04 |
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