JPS5692244A - Preparation of 4-oxocyclohexylacetic acid - Google Patents
Preparation of 4-oxocyclohexylacetic acidInfo
- Publication number
- JPS5692244A JPS5692244A JP16929379A JP16929379A JPS5692244A JP S5692244 A JPS5692244 A JP S5692244A JP 16929379 A JP16929379 A JP 16929379A JP 16929379 A JP16929379 A JP 16929379A JP S5692244 A JPS5692244 A JP S5692244A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- water
- hydrogenating
- catalyst
- hydroxyphenylacetic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To prepare the titled compound useful as a raw material of carbazole-type or steroid-type antiphlogistic analgesic agent or a remedy for arthritis, in high yield and conversion, by hydrogenating 4-hydroxyphenylacetic acid in the presence of water and a Pd catalyst.
CONSTITUTION: 4-Oxocyclohexylacetic acid is prepared by hydrogenating 4-hydroxyphenylacetic acid in the presence of a Pd catalyst using water. 4-Hydroxyphenylacetic acid is obtained easily, e.g. by hydrogenating 4-hydroxymandelic acid. The Pd catalyst is pref. obtained by supporting 0.1W10wt% of metallic Pd on a carrier such as activated charcoal, silica gel, etc. The amount of water is pref. 0.5W20 liters per 1mol of 4-hydroxyphenylacetic acid. The presence of water gives the conversion and the yield of as high as 97W100% and 90W94%, respectively, in contrast with those of 25W33% and 18W21% attained by using an organic solvent.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16929379A JPS5692244A (en) | 1979-12-27 | 1979-12-27 | Preparation of 4-oxocyclohexylacetic acid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16929379A JPS5692244A (en) | 1979-12-27 | 1979-12-27 | Preparation of 4-oxocyclohexylacetic acid |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5692244A true JPS5692244A (en) | 1981-07-25 |
Family
ID=15883823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP16929379A Pending JPS5692244A (en) | 1979-12-27 | 1979-12-27 | Preparation of 4-oxocyclohexylacetic acid |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5692244A (en) |
-
1979
- 1979-12-27 JP JP16929379A patent/JPS5692244A/en active Pending
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