JPS5658981A - Production of hexaorganoditin compound - Google Patents
Production of hexaorganoditin compoundInfo
- Publication number
- JPS5658981A JPS5658981A JP13476879A JP13476879A JPS5658981A JP S5658981 A JPS5658981 A JP S5658981A JP 13476879 A JP13476879 A JP 13476879A JP 13476879 A JP13476879 A JP 13476879A JP S5658981 A JPS5658981 A JP S5658981A
- Authority
- JP
- Japan
- Prior art keywords
- triorganotin
- hexaorganoditin
- compound
- organic solvent
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
PURPOSE: To obtain hexaorganoditin compound of high purity at a high yield by electrolyzing specific triorganotin formate in the presence of an organic solvent.
CONSTITUTION: The triorganotin formate expressed by the formula I is obtained by the dehydration reaction of triorganohydroxide or bis(triorganotin) oxide and formic acid or the desodium-halide reaction of triorganotin halide and sodium formate. This is electrolyzed in the presence of an organic solvent. The organic solvent is preferably, for example, dimethylformamide, 2-ethoxy ethanol, etc. which have no moisture content. The quantity of electricity necessary for the electrolysis is about 1W4 Faraday (equiv.) and electric efficiency is about ≥20%. The reaction is performed at room temp., and the evolution of carbonic acid gas and hydrogen is admitted during reaction progress. The product is straightly filtered if it is solid, and is fractionally distilled if liquid. This yields the hexaorganoditin compound of the formula II.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13476879A JPS5658981A (en) | 1979-10-18 | 1979-10-18 | Production of hexaorganoditin compound |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13476879A JPS5658981A (en) | 1979-10-18 | 1979-10-18 | Production of hexaorganoditin compound |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5658981A true JPS5658981A (en) | 1981-05-22 |
JPS5727941B2 JPS5727941B2 (en) | 1982-06-14 |
Family
ID=15136103
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP13476879A Granted JPS5658981A (en) | 1979-10-18 | 1979-10-18 | Production of hexaorganoditin compound |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5658981A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6072629U (en) * | 1983-10-26 | 1985-05-22 | コンビ株式会社 | carrying child |
JPS60187659U (en) * | 1984-05-23 | 1985-12-12 | コンビ株式会社 | foldable backpack |
-
1979
- 1979-10-18 JP JP13476879A patent/JPS5658981A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS5727941B2 (en) | 1982-06-14 |
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