JPS5651496A - Cobalt carbonyl-isoquinoline complex, its preparation and a catalyst for hydroesterification consisting of said complex - Google Patents

Cobalt carbonyl-isoquinoline complex, its preparation and a catalyst for hydroesterification consisting of said complex

Info

Publication number
JPS5651496A
JPS5651496A JP12789779A JP12789779A JPS5651496A JP S5651496 A JPS5651496 A JP S5651496A JP 12789779 A JP12789779 A JP 12789779A JP 12789779 A JP12789779 A JP 12789779A JP S5651496 A JPS5651496 A JP S5651496A
Authority
JP
Japan
Prior art keywords
complex
isoquinoline
hydroesterification
catalyst
cobalt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP12789779A
Other languages
Japanese (ja)
Other versions
JPS6230996B2 (en
Inventor
Akio Matsuda
Kazutaro Koike
Tadashi Sasuga
Masahiro Matsuno
Chihiro Yazawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ihara Chemical Industry Co Ltd
National Institute of Advanced Industrial Science and Technology AIST
Original Assignee
Agency of Industrial Science and Technology
Ihara Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agency of Industrial Science and Technology, Ihara Chemical Industry Co Ltd filed Critical Agency of Industrial Science and Technology
Priority to JP12789779A priority Critical patent/JPS5651496A/en
Publication of JPS5651496A publication Critical patent/JPS5651496A/en
Publication of JPS6230996B2 publication Critical patent/JPS6230996B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

NEW MATERIAL:Cobalt carbonyl-isoquinoline complex. EXAMPLE:The compound of the formula (iQ is isoquinoline). USE:A catalyst for hydroesterification having improved thermal stability without deteriorating the catalytic activity even on dehydration by the azeotropic method, capable of suppressing the hydrocarboxylation in the presence of water and readily separable after the reaction. PROCESS:A cobalt compound, e.g. hydroxide, carbonate, oxide or a salt with an organic acid, is reacted with carbon monoxide and isoquinoline, preferably at 120- 160 deg.C and 100-250kg/cm<2> for 3-5hr, to give the titled complex. The molar amount of the isoquinoline is 8-12 times that of the cobalt.
JP12789779A 1979-10-05 1979-10-05 Cobalt carbonyl-isoquinoline complex, its preparation and a catalyst for hydroesterification consisting of said complex Granted JPS5651496A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12789779A JPS5651496A (en) 1979-10-05 1979-10-05 Cobalt carbonyl-isoquinoline complex, its preparation and a catalyst for hydroesterification consisting of said complex

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12789779A JPS5651496A (en) 1979-10-05 1979-10-05 Cobalt carbonyl-isoquinoline complex, its preparation and a catalyst for hydroesterification consisting of said complex

Publications (2)

Publication Number Publication Date
JPS5651496A true JPS5651496A (en) 1981-05-09
JPS6230996B2 JPS6230996B2 (en) 1987-07-06

Family

ID=14971359

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12789779A Granted JPS5651496A (en) 1979-10-05 1979-10-05 Cobalt carbonyl-isoquinoline complex, its preparation and a catalyst for hydroesterification consisting of said complex

Country Status (1)

Country Link
JP (1) JPS5651496A (en)

Also Published As

Publication number Publication date
JPS6230996B2 (en) 1987-07-06

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