JPS562925A - Preparation of ketone - Google Patents

Preparation of ketone

Info

Publication number
JPS562925A
JPS562925A JP6469079A JP6469079A JPS562925A JP S562925 A JPS562925 A JP S562925A JP 6469079 A JP6469079 A JP 6469079A JP 6469079 A JP6469079 A JP 6469079A JP S562925 A JPS562925 A JP S562925A
Authority
JP
Japan
Prior art keywords
formula
organometallic compound
organic halide
desired ketone
ketone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6469079A
Other languages
Japanese (ja)
Other versions
JPS6045606B2 (en
Inventor
Masato Tanaka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Institute of Advanced Industrial Science and Technology AIST
Original Assignee
Agency of Industrial Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology
Priority to JP54064690A priority Critical patent/JPS6045606B2/en
Publication of JPS562925A publication Critical patent/JPS562925A/en
Publication of JPS6045606B2 publication Critical patent/JPS6045606B2/en
Expired legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To obtain the desired ketone simply in high yield without using a reactive raw material and troublesome procedures, by acylating an organic halide with CO and an organometallic compound in the presence of a palladium catalyst.
CONSTITUTION: An organic halide, e.g. iodobenzene, of the formula R1X (R1 is alkyl, aryl, aralkyl, cycloalkyl, alkenyl, alkynyl or heterocyclic group; X is halogen) is reacted with an organometallic compound of the formula Rm 2MYn (R2 is R1; Y is electro-negative group, H or R1, M is metallic atom; m and n are integers; plural R2;s or Y;s may be the same or different and M and Rm 2 may form a cyclic structure), e.g. tetrabutyltin, and CO in the presence of a metallic palladium or its complex as a catalyst in the presence of absence of a solvent, preferably at 50W150°C and a partial pressure of CO of 1W50atm to give the desired ketone, e.g. Ph-CO-n- C4H9.
COPYRIGHT: (C)1981,JPO&Japio
JP54064690A 1979-05-25 1979-05-25 Method for producing ketones Expired JPS6045606B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP54064690A JPS6045606B2 (en) 1979-05-25 1979-05-25 Method for producing ketones

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP54064690A JPS6045606B2 (en) 1979-05-25 1979-05-25 Method for producing ketones

Publications (2)

Publication Number Publication Date
JPS562925A true JPS562925A (en) 1981-01-13
JPS6045606B2 JPS6045606B2 (en) 1985-10-11

Family

ID=13265391

Family Applications (1)

Application Number Title Priority Date Filing Date
JP54064690A Expired JPS6045606B2 (en) 1979-05-25 1979-05-25 Method for producing ketones

Country Status (1)

Country Link
JP (1) JPS6045606B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4849545A (en) * 1987-03-21 1989-07-18 Bp Chemicals Limited Process for the production of aliphatic ketones
JP2004501877A (en) * 2000-06-26 2004-01-22 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー Catalysis using phosphine oxide compounds and sulfoxide compounds

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4849545A (en) * 1987-03-21 1989-07-18 Bp Chemicals Limited Process for the production of aliphatic ketones
JP2004501877A (en) * 2000-06-26 2004-01-22 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー Catalysis using phosphine oxide compounds and sulfoxide compounds

Also Published As

Publication number Publication date
JPS6045606B2 (en) 1985-10-11

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