JPS5615804A - Semipermeable composite membrane having stable selective separation capacity - Google Patents
Semipermeable composite membrane having stable selective separation capacityInfo
- Publication number
- JPS5615804A JPS5615804A JP9149879A JP9149879A JPS5615804A JP S5615804 A JPS5615804 A JP S5615804A JP 9149879 A JP9149879 A JP 9149879A JP 9149879 A JP9149879 A JP 9149879A JP S5615804 A JPS5615804 A JP S5615804A
- Authority
- JP
- Japan
- Prior art keywords
- film layer
- composite membrane
- barrier film
- solvent resistance
- separation capacity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012528 membrane Substances 0.000 title abstract 4
- 239000002131 composite material Substances 0.000 title abstract 3
- 238000000926 separation method Methods 0.000 title abstract 2
- 239000010410 layer Substances 0.000 abstract 4
- 230000004888 barrier function Effects 0.000 abstract 3
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- 239000000758 substrate Substances 0.000 abstract 2
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229920006037 cross link polymer Polymers 0.000 abstract 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 230000003204 osmotic effect Effects 0.000 abstract 1
- 229920002492 poly(sulfone) Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 1
- 239000011118 polyvinyl acetate Substances 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 239000011241 protective layer Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
- B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/025—Reverse osmosis; Hyperfiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1216—Three or more layers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Nanotechnology (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE:To obtain a reverse osmotic membrane excellent in durability, strength, and solvent resistance by superposing a barrier film layer of a crosslinked polymer polymerized by an acid catalyst and a protective film layer of a composite membrane consisting of a partially saponified product on a porous substrate. CONSTITUTION:On the surface of the anisotropic porous substrate of polysulfone, polyvinyl chloride, etc., a thickness of approx. 0.01-0.1mu of the barrier film layer of a bridged polymer composed primarily of a compound with an acid-polymerizable isocyanurate main chain and/or furfuryl alcohol is formed, and then on the barrier film layer, a protective layer with an optical interference stripe, having high water insolubility and high solvent resistance, composed of the partially saponified products of polyvinyl alcohol and/or polyvinyl acetate is formed. The semipermeable composite membrane thus obtained has high resistance to mechanical damage, highly stable separation capacity for a long period of time, and high solvent resistance.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9149879A JPS5615804A (en) | 1979-07-20 | 1979-07-20 | Semipermeable composite membrane having stable selective separation capacity |
PCT/JP1980/000165 WO1981000217A1 (en) | 1979-07-20 | 1980-07-21 | Process for selectively separating water-soluble valuable materials from an aqueous solution containing same |
EP80901335A EP0044872B1 (en) | 1979-07-20 | 1980-07-21 | Process for selectively separating water-soluble valuable materials from an aqueous solution containing same |
AT80901335T ATE15607T1 (en) | 1979-07-20 | 1980-07-21 | PROCESS FOR SELECTIVE SEPARATION OF WATER-SOLUBLE, VALUABLE MATERIALS FROM AQUEOUS SOLUTIONS. |
DE8080901335T DE3071096D1 (en) | 1979-07-20 | 1980-07-21 | Process for selectively separating water-soluble valuable materials from an aqueous solution containing same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9149879A JPS5615804A (en) | 1979-07-20 | 1979-07-20 | Semipermeable composite membrane having stable selective separation capacity |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5615804A true JPS5615804A (en) | 1981-02-16 |
JPS6211881B2 JPS6211881B2 (en) | 1987-03-16 |
Family
ID=14028069
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP9149879A Granted JPS5615804A (en) | 1979-07-20 | 1979-07-20 | Semipermeable composite membrane having stable selective separation capacity |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5615804A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5814908A (en) * | 1981-07-15 | 1983-01-28 | Nitto Electric Ind Co Ltd | Preparation of composite semi-permeable membrane |
WO1983000443A1 (en) * | 1981-08-03 | 1983-02-17 | Kawaguchi, Takeyuki | Composite semipermeable membrane, process for its production, and methode of its use |
JPS5892402A (en) * | 1981-11-27 | 1983-06-01 | Teijin Ltd | Preparation of composite membrane having selective permeability of organic substance |
JPS602946A (en) * | 1983-06-20 | 1985-01-09 | Fujitsu Ltd | Positive type resist material |
JPS61186329A (en) * | 1985-02-15 | 1986-08-20 | Agency Of Ind Science & Technol | Separation of aqueous solution of organic acid |
JP2010201303A (en) * | 2009-03-02 | 2010-09-16 | Toray Ind Inc | Composite semipermeable membrane |
-
1979
- 1979-07-20 JP JP9149879A patent/JPS5615804A/en active Granted
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5814908A (en) * | 1981-07-15 | 1983-01-28 | Nitto Electric Ind Co Ltd | Preparation of composite semi-permeable membrane |
JPH0221292B2 (en) * | 1981-07-15 | 1990-05-14 | Nitto Denko Corp | |
WO1983000443A1 (en) * | 1981-08-03 | 1983-02-17 | Kawaguchi, Takeyuki | Composite semipermeable membrane, process for its production, and methode of its use |
JPS5892402A (en) * | 1981-11-27 | 1983-06-01 | Teijin Ltd | Preparation of composite membrane having selective permeability of organic substance |
JPH0114801B2 (en) * | 1981-11-27 | 1989-03-14 | Teijin Ltd | |
JPS602946A (en) * | 1983-06-20 | 1985-01-09 | Fujitsu Ltd | Positive type resist material |
JPH0377986B2 (en) * | 1983-06-20 | 1991-12-12 | Fujitsu Ltd | |
JPS61186329A (en) * | 1985-02-15 | 1986-08-20 | Agency Of Ind Science & Technol | Separation of aqueous solution of organic acid |
JPH0528691B2 (en) * | 1985-02-15 | 1993-04-27 | Kogyo Gijutsuin | |
JP2010201303A (en) * | 2009-03-02 | 2010-09-16 | Toray Ind Inc | Composite semipermeable membrane |
Also Published As
Publication number | Publication date |
---|---|
JPS6211881B2 (en) | 1987-03-16 |
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