JPS56125212A - Production of carbon monoxide - Google Patents

Production of carbon monoxide

Info

Publication number
JPS56125212A
JPS56125212A JP2636680A JP2636680A JPS56125212A JP S56125212 A JPS56125212 A JP S56125212A JP 2636680 A JP2636680 A JP 2636680A JP 2636680 A JP2636680 A JP 2636680A JP S56125212 A JPS56125212 A JP S56125212A
Authority
JP
Japan
Prior art keywords
alkali metal
methyl formate
methanol
carbon monoxide
metal compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2636680A
Other languages
Japanese (ja)
Inventor
Kozo Sano
Hideo Igarashi
Takeo Igarashi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Gas Chemical Co Inc
Original Assignee
Mitsubishi Gas Chemical Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Gas Chemical Co Inc filed Critical Mitsubishi Gas Chemical Co Inc
Priority to JP2636680A priority Critical patent/JPS56125212A/en
Priority to US06/175,839 priority patent/US4303630A/en
Priority to GB8026302A priority patent/GB2058733B/en
Priority to FR8017968A priority patent/FR2468551A1/en
Priority to DE3030842A priority patent/DE3030842C2/en
Priority to NLAANVRAGE8004641,A priority patent/NL184360C/en
Publication of JPS56125212A publication Critical patent/JPS56125212A/en
Pending legal-status Critical Current

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  • Carbon And Carbon Compounds (AREA)

Abstract

PURPOSE: A mixture of methanol and methyl formate is brought into contact with a catalyst containing an alkali metal compound of decompose only methyl formate under specific conditions, thus producing methanol and high-purity carbon monoxide.
CONSTITUTION: A catalyst is prepared by supporting an alkali metal compound other than alkali alcoholate on a carrier such as kieselguhr or silica gel at a ratio of 0.05W3 milliatoms, as an alkali metal atom, to 1g of the carrier. The alkali metal compound is, e.g., potassium hydroxide or sodium sulfate. The catalyst is placed in the reactor and a (10W70):(90W30)(wt%) mixture of methyl formate and methanol is continuously fed a a liquid space velocity of 10W100hr-1 or at a gas-space velocity of 5,000W50,000hr-1 under conditions of 200W500°C and atmospheric pressure to 350atm. Thus, the catalytic pyrolysis of only methyl formate is selectively effected to obtain methanol and high-purity carbon monoxide.
COPYRIGHT: (C)1981,JPO&Japio
JP2636680A 1979-08-17 1980-03-03 Production of carbon monoxide Pending JPS56125212A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2636680A JPS56125212A (en) 1980-03-03 1980-03-03 Production of carbon monoxide
US06/175,839 US4303630A (en) 1979-08-17 1980-08-06 Process for the production of carbon monoxide
GB8026302A GB2058733B (en) 1979-08-17 1980-08-12 Process for the production of carbon monoxide
FR8017968A FR2468551A1 (en) 1979-08-17 1980-08-14 PROCESS FOR THE MANUFACTURE OF CARBON OXIDE
DE3030842A DE3030842C2 (en) 1979-08-17 1980-08-14 Process for the production of carbon monoxide
NLAANVRAGE8004641,A NL184360C (en) 1979-08-17 1980-08-15 PROCESS FOR PREPARING CARBON MONOXIDE.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2636680A JPS56125212A (en) 1980-03-03 1980-03-03 Production of carbon monoxide

Publications (1)

Publication Number Publication Date
JPS56125212A true JPS56125212A (en) 1981-10-01

Family

ID=12191493

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2636680A Pending JPS56125212A (en) 1979-08-17 1980-03-03 Production of carbon monoxide

Country Status (1)

Country Link
JP (1) JPS56125212A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4978766A (en) * 1987-02-17 1990-12-18 Ube Industries, Ltd. Process for producing 2-hydroxymethylene-3,3-dialkoxypropanenitrile alkali metal salt and process for obtaining alcoholic slurry of said compound from its synthetic reaction mixture
JP2002114508A (en) * 2000-09-29 2002-04-16 Mitsubishi Gas Chem Co Inc Method for producing carbon monoxide

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4978766A (en) * 1987-02-17 1990-12-18 Ube Industries, Ltd. Process for producing 2-hydroxymethylene-3,3-dialkoxypropanenitrile alkali metal salt and process for obtaining alcoholic slurry of said compound from its synthetic reaction mixture
JP2002114508A (en) * 2000-09-29 2002-04-16 Mitsubishi Gas Chem Co Inc Method for producing carbon monoxide
JP4671005B2 (en) * 2000-09-29 2011-04-13 三菱瓦斯化学株式会社 Carbon monoxide production method

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