JPS5576826A - Pretreatment of raw material for adamantane - Google Patents
Pretreatment of raw material for adamantaneInfo
- Publication number
- JPS5576826A JPS5576826A JP14864478A JP14864478A JPS5576826A JP S5576826 A JPS5576826 A JP S5576826A JP 14864478 A JP14864478 A JP 14864478A JP 14864478 A JP14864478 A JP 14864478A JP S5576826 A JPS5576826 A JP S5576826A
- Authority
- JP
- Japan
- Prior art keywords
- raw material
- heavy fraction
- isomerization
- distillation
- adsorption
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To prolong greatly the life of the solid acid catalyst in isomerization and improve the quality of the adamantanes produced, by pretreating and removing the heavy fraction contained in a ≥10C tricyclic saturated hydrocarbon (raw material) with distillation or adsorption.
CONSTITUTION: The heavy fraction, e.g. trimer or tetramer of cyclopentadiene, contained in a ≥10C tricyclic saturated hydrocarbon, e.g. preferably endo-trimethylene-norbornane obtained by complete hydrogenation of dicyclopentadiene, is removed in advance with distillation or adsorption, in producing adamantanes by isomerization of the above-mentioned hydrocarbon in the pressure of the known solid acid catalyst. The remaining heavy fraction in the raw material is 300ppm or less preferably 250ppm or less, and the deteriorating speed of the isomerizing catalyst is 0.1 conversion/hour or below, to maintain the catalytic activity for a long term and obtain the object compound or high quality and purity.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14864478A JPS5576826A (en) | 1978-12-02 | 1978-12-02 | Pretreatment of raw material for adamantane |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14864478A JPS5576826A (en) | 1978-12-02 | 1978-12-02 | Pretreatment of raw material for adamantane |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5576826A true JPS5576826A (en) | 1980-06-10 |
Family
ID=15457397
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP14864478A Pending JPS5576826A (en) | 1978-12-02 | 1978-12-02 | Pretreatment of raw material for adamantane |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5576826A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007129665A1 (en) * | 2006-05-10 | 2007-11-15 | Idemitsu Kosan Co., Ltd. | Method for production of adamantane |
-
1978
- 1978-12-02 JP JP14864478A patent/JPS5576826A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007129665A1 (en) * | 2006-05-10 | 2007-11-15 | Idemitsu Kosan Co., Ltd. | Method for production of adamantane |
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