JPS55162740A - Preparation of cyclobranol organic acid ester - Google Patents
Preparation of cyclobranol organic acid esterInfo
- Publication number
- JPS55162740A JPS55162740A JP6994479A JP6994479A JPS55162740A JP S55162740 A JPS55162740 A JP S55162740A JP 6994479 A JP6994479 A JP 6994479A JP 6994479 A JP6994479 A JP 6994479A JP S55162740 A JPS55162740 A JP S55162740A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- ester
- organic acid
- methylenecycloaltanol
- iodine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Medicines Containing Plant Substances (AREA)
- Steroid Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
PURPOSE: To prepare the titled compound useful as a medicine for autonomic imbalance, etc., easily, in high yield, by the heat isomerization of a 24-methylenecycloaltanol organic acid ester or a composition containing the ester using iodine, etc. as a catalyst.
CONSTITUTION: 24-Methylenecycloaltanol organic acid ester containing 24-methylenecycloaltanol ferulic acid ester which is a distillation residue of rice bran oil, or a composition containing the ester, is dissolved or dispersed in an organic solvent, and isomerized at 46W110°C in the presence of 0.1W300%, based on the raw material, of iodine or a mixture of iodine and an iodide. The objective compound is obtained in 30W80% yield. The organic acid is, e.g. acetic acid, butyric acid, isobutyric acid, palmitic acid, benzoic acid, etc.
EFFECT: The scission of the cyclopropane ring and the decomposition of the ester at high temperature inherent to the conventional acid catalyst process can be avoided.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP54069944A JPS5843400B2 (en) | 1979-06-06 | 1979-06-06 | Method for producing cyclobranol organic acid ester |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP54069944A JPS5843400B2 (en) | 1979-06-06 | 1979-06-06 | Method for producing cyclobranol organic acid ester |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS55162740A true JPS55162740A (en) | 1980-12-18 |
JPS5843400B2 JPS5843400B2 (en) | 1983-09-27 |
Family
ID=13417262
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP54069944A Expired JPS5843400B2 (en) | 1979-06-06 | 1979-06-06 | Method for producing cyclobranol organic acid ester |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5843400B2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5983015U (en) * | 1982-11-25 | 1984-06-05 | 株式会社タムラ製作所 | small transformer |
JPS59142219U (en) * | 1982-11-25 | 1984-09-22 | 林 光夫 | Truck loading platform for construction work |
JPS60258198A (en) * | 1984-06-04 | 1985-12-20 | Amano Pharmaceut Co Ltd | Triterpene alcohol organic acid ester and its preparation |
-
1979
- 1979-06-06 JP JP54069944A patent/JPS5843400B2/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5983015U (en) * | 1982-11-25 | 1984-06-05 | 株式会社タムラ製作所 | small transformer |
JPS59142219U (en) * | 1982-11-25 | 1984-09-22 | 林 光夫 | Truck loading platform for construction work |
JPS6314414Y2 (en) * | 1982-11-25 | 1988-04-22 | ||
JPS60258198A (en) * | 1984-06-04 | 1985-12-20 | Amano Pharmaceut Co Ltd | Triterpene alcohol organic acid ester and its preparation |
JPH0140040B2 (en) * | 1984-06-04 | 1989-08-24 | Amano Pharma Co Ltd |
Also Published As
Publication number | Publication date |
---|---|
JPS5843400B2 (en) | 1983-09-27 |
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