JPS55143988A - Preparation of thienodiazepin-2-one derivative containing novel diamine derivative and novel diazepin derivative - Google Patents
Preparation of thienodiazepin-2-one derivative containing novel diamine derivative and novel diazepin derivativeInfo
- Publication number
- JPS55143988A JPS55143988A JP5178379A JP5178379A JPS55143988A JP S55143988 A JPS55143988 A JP S55143988A JP 5178379 A JP5178379 A JP 5178379A JP 5178379 A JP5178379 A JP 5178379A JP S55143988 A JPS55143988 A JP S55143988A
- Authority
- JP
- Japan
- Prior art keywords
- derivative
- formula
- compound
- novel
- diamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Heterocyclic Compounds Containing Sulfur Atoms (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Abstract
PURPOSE: To prepare the title compound having tranquillizing activity, etc., economically, in high yield, from N-thiophene diamine through a novel diamine derivative and a 2-halogenomethyl-thienoazepin derivative.
CONSTITUTION: An N-thiophene diamine of formula I (R1,2 are H, alkyl, halogen, etc.; R3 is H, alkyl, lower alkoxy, etc.) is reacted with a compound of formula II (R4 is H, halogen, NO2, etc.; when the bond between C and Z is double bond, Z is NH and X is lower alkoxyl, or Z is O and X is halogen, etc., and when the bond is triple bond, Z is N) to afford a diamine derivative of formula III (Y is NH or O), which is subjected to intramolecular cyclization to obtain a compound of formula IV (X1 is Cl or Br). The substitution group X1 of the compound IV is converted to various groups by conventional method to obtain novel thienodiazepin derivatives of formula V. The objective compound of formula VI can be prepared by treating the compound V with a proper oxidizing agent in the presence of an inert solvent.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5178379A JPS55143988A (en) | 1979-04-26 | 1979-04-26 | Preparation of thienodiazepin-2-one derivative containing novel diamine derivative and novel diazepin derivative |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5178379A JPS55143988A (en) | 1979-04-26 | 1979-04-26 | Preparation of thienodiazepin-2-one derivative containing novel diamine derivative and novel diazepin derivative |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS55143988A true JPS55143988A (en) | 1980-11-10 |
Family
ID=12896534
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5178379A Pending JPS55143988A (en) | 1979-04-26 | 1979-04-26 | Preparation of thienodiazepin-2-one derivative containing novel diamine derivative and novel diazepin derivative |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS55143988A (en) |
-
1979
- 1979-04-26 JP JP5178379A patent/JPS55143988A/en active Pending
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