JPS54106414A - Acyloxylation of 1,3-butadiene - Google Patents

Acyloxylation of 1,3-butadiene

Info

Publication number
JPS54106414A
JPS54106414A JP1296878A JP1296878A JPS54106414A JP S54106414 A JPS54106414 A JP S54106414A JP 1296878 A JP1296878 A JP 1296878A JP 1296878 A JP1296878 A JP 1296878A JP S54106414 A JPS54106414 A JP S54106414A
Authority
JP
Japan
Prior art keywords
butadiene
acyloxylation
catalyst
reaction
butenediol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP1296878A
Other languages
Japanese (ja)
Other versions
JPS6319500B2 (en
Inventor
Nobuhiro Tamura
Masanori Ikeda
Masanori Tanabe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd
Priority to JP1296878A priority Critical patent/JPS54106414A/en
Publication of JPS54106414A publication Critical patent/JPS54106414A/en
Publication of JPS6319500B2 publication Critical patent/JPS6319500B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To improve the yield of acyloxylation reaction of 1,3-butadiene with carboxylic acid and molecular oxygen based on the weight of Pd used as the catalyst, by addition of selenic acid salt to the expensive conventional Pd catalyst.
CONSTITUTION: Ester of butenediol is prepared by the acyloxylation of 1,3-butadiene with carboxylic acid and molecular oxygen, using a mixed catalyst comprising Pd, preferably supported on active carbon, and 0.1W5 mol of selenic acid salt (K2SeO4, Na2SeO4, etc.) per 1 gram atom of Pd. The reaction is preferably carried out in liquid phase, and the amount of Pd is preferably 0.5W100g per 1l of reaction solution.
USE: Raw materials of plasticizers, polymers, etc. are obtained by the hydrogenation and hydrolysis of the butenediol ester.
COPYRIGHT: (C)1979,JPO&Japio
JP1296878A 1978-02-09 1978-02-09 Acyloxylation of 1,3-butadiene Granted JPS54106414A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1296878A JPS54106414A (en) 1978-02-09 1978-02-09 Acyloxylation of 1,3-butadiene

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1296878A JPS54106414A (en) 1978-02-09 1978-02-09 Acyloxylation of 1,3-butadiene

Publications (2)

Publication Number Publication Date
JPS54106414A true JPS54106414A (en) 1979-08-21
JPS6319500B2 JPS6319500B2 (en) 1988-04-22

Family

ID=11820031

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1296878A Granted JPS54106414A (en) 1978-02-09 1978-02-09 Acyloxylation of 1,3-butadiene

Country Status (1)

Country Link
JP (1) JPS54106414A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008062120A (en) * 2006-09-04 2008-03-21 Mitsubishi Chemicals Corp Method for preparing transition metal catalyst, and catalyst composition liquid

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008062120A (en) * 2006-09-04 2008-03-21 Mitsubishi Chemicals Corp Method for preparing transition metal catalyst, and catalyst composition liquid

Also Published As

Publication number Publication date
JPS6319500B2 (en) 1988-04-22

Similar Documents

Publication Publication Date Title
JPS523030A (en) Process for manufacturing high purity terephthalic acid
NZ240009A (en) Process for preparation of carboxylic acid anhydrides by reaction of co with a carboxylic acid ester or alkyl ether
IE41093L (en) Production of carbonic acid esters.
JPS55162743A (en) Asymmetric hydrogenation of alpha-ketoester
JPS54106414A (en) Acyloxylation of 1,3-butadiene
ES463559A1 (en) Process for preparing terephthalic acid
JPS5382720A (en) Preparation of unsaturated carboxylic acids and their esters
JPS53105421A (en) Preparation of optical active alpha-hydroxycarboxylic acid esters acid esters
JPS55153741A (en) Improved preparation of carboxylic acid ester
Harrison et al. Oxidative cleavage of ethers
JPS5424818A (en) Preparation of high purity maleic acid monoalcohol ester
IE44251L (en) Manufacture of butenediol diesters and their secondary¹products
JPS5559122A (en) Preparation of diol
ES8101033A1 (en) Process for the preparation of vinyl acetate.
JPS527909A (en) Process for preparation of butanediol or butenediol
JPS5384932A (en) Preparation of terephthalic acid
JPS53105471A (en) Preparation of cyclic ethers
JPS6485940A (en) Production of allyl alcohol
JPS54106413A (en) Selective preparation of 1,4-diacyloxybutene
JPS5657723A (en) Preparation of m-phenoxybenzyl alcohol and/or m-phenoxybenzaldehyde
JPS54112811A (en) Acyloxylation of 1,3-butadiene
JPS5461109A (en) Preparation of 1,4-butanediol and/or 1,4-butenediol
JPS52133942A (en) Treatment of reaction mother liquor
JPS5365841A (en) Preparation of terephthalic acid
JPS532414A (en) Preparation of diacetoxybutene