JPH1159029A - Pseudoadhesive sheet - Google Patents

Abstract

PROBLEM TO BE SOLVED: To avoid printing information from cracking or fouling, and thus raise the printing surface aesthetically by containing a toner fixation derivative substance in a pseudoadhesive layer having a specific melting point, and therefore permitting the toner to fix to the pseudoadhesive irrespective of a kind of the binder of toner. SOLUTION: The pseudoadhesive paper is formed of providing a pseudoadhesive layer 2 on at least a part of one surface of the base material sheet 1. In this instance, contained in the pseudo adhesive layer 2 is a thermoplastic substance indicating a melting point of 50 deg.C or higher, and being lower than 150 deg.C. Also, the pseudo adhesive sheet is constituted by setting a pseudoadhesive agent 2 on at least a part of one surface of the base sheet 1. In this case, contained in the pseudoadhesive layer are a thermoplastic substance indicating a melting point of 50 deg.C or higher, and being lower than 150 deg.C, organic minute grains having a grain diameter of 5 μm or lower, and inorganic minute grains having a grain diameter of 2.5 μm or lower, an oil absorption rate of 250 cc/100 g or more, and inorganic minute grains of a specific surface area of 300 m<2> /g or lower.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a pseudo-adhesive sheet having a function of temporarily adhering but easily peeling off when necessary, and more particularly to a pseudo-adhesive sheet excellent in printability in electrophotography. is there.

[0002]

2. Description of the Related Art In recent years, while the amount of information transmitted through communication means such as communication and mail has increased, communication means requiring confidentiality such as personal information have been emphasized and demanded.

Further, with the revision of the Postal Law, postcard systems having confidentiality have been put to practical use and have become widespread. With a postcard system with confidentiality, a reciprocating postcard in which various information such as personal information is folded and recorded on the inner surface is folded, pseudo-adhering the superimposed surface, concealing the information, mailing, The recipient reads the concealment information by peeling off the pseudo-adhesive part. Among these communication means requiring confidentiality, for example, there is a method in which a company notifies employees and a bank or a credit company communicates information having confidentiality to customers.

As a communication means having such confidentiality, a method using pseudo-adhesive paper has been proposed and widely used. Pseudo-adhesive paper is an adhesive consisting of a so-called non-peelable adhesive, such as natural rubber or synthetic rubber, and a particulate filler that suppresses the adhesive force of the adhesive on at least a part of one side of the base paper (hereinafter referred to as an adhesive). , A pseudo-adhesive) is provided and has a function of temporarily adhering but easily peeling off when necessary. The recipient peels off the facing face and reads the recorded information on the pseudo adhesive layer.

[0005] In recent years, with the rapid increase in demand for communication means requiring such confidentiality, it has been required to print information on pseudo-adhesive paper with high efficiency and high quality. The method of printing information on adhesive paper is shifting from printing by an impact printer combined with a computer, which has been conventionally used, to printing by electrophotography combined with a computer.

[0006]

However, when electrophotographic printing is performed on conventional pseudo-adhesive paper, a phenomenon has occurred in which toner is locally re-transferred to the opposing surface during bonding. . Such a phenomenon is not preferable because, as a result, for example, when the facing side is opened at the recipient, the printing information appears to be missing or dirty, and the aesthetic appearance of the printing side is significantly impaired.

Therefore, a main object of the present invention is to propose a pseudo adhesive sheet having excellent printability in electrophotography.

[0008]

The present inventors have conducted intensive studies on the cause of the above-mentioned retransfer of the toner, and as a result, have found the following. That is, as the binder of the toner for electrophotography, polyester type, styrene / acryl type, or epoxy type is used.
It is near 0 ° C and high. Therefore, the binder having a high melting point in the toner has poor affinity with the pseudo adhesive,
As a result, a phenomenon occurs in which the image is retransferred to the printed facing surface. On the other hand, in the case where a binder having a low melting point is used, if pressure bonding is performed within a time period after the printing until the temperature decreases, a phenomenon occurs in which the binder is re-transferred to the printed facing surface.

Therefore, in any case, it has been found that there is a limit in fixing the toner to the pseudo adhesive layer by relying on the binder of the toner.

Therefore, according to the present invention, if the pseudo-adhesive layer contains a substance which induces the fixation of the toner in advance, the toner is suitably fixed to the pseudo-adhesive layer regardless of the type of the binder of the toner. It has been found that the danger of retransfer is eliminated.

That is, according to the first aspect of the present invention, in a pseudo-adhesive sheet having a pseudo-adhesive layer provided on at least a part of one side of a base sheet, the pseudo-adhesive layer has a melting point of 50%. A pseudo-adhesive sheet comprising a thermoplastic material having a temperature of not less than 150 ° C. and less than 150 ° C.

In this case, in a pseudo-adhesive sheet having a pseudo-adhesive layer provided on at least a part of one side of a base sheet, the pseudo-adhesive layer has a melting point of 50.degree.
Thermoplastic organic material having a temperature of less than 5 ° C., organic fine particles having a particle size of 5 μm or less, a particle size of 2.5 μm or less, and an oil absorption of 250 cc.
/ 100 g or more and inorganic fine particles having a specific surface area of 300 m ² / g or less can be obtained.

[0013]

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, a pseudo adhesive sheet according to the present invention will be described in detail. 1 to 4 show application examples of the pseudo adhesive sheet according to the present invention. In the folding pseudo-adhesive supply envelope shown in FIG. 1, a pseudo-adhesive layer 2 is provided on the surface of the base paper 1, and after feeding information is printed on the pseudo-adhesive layer 2, as shown in FIG. The information printing surface 3 is folded into two valleys from the center line in the printing surface printing direction on the inner surface, and is pressure-bonded. Address information 4 and the like are printed on the back surface.

In the tri-fold postcard shown in FIG. 2, pseudo-adhesive layers 2 and 2 are formed on the front and back surfaces of the base paper 1, and concealment information 3, communication information and address information 4 are printed on the front surface thereof. B) As shown in the figure, folding and pressure bonding are performed so that the address printing surface is the front surface.

The two-fold postcard shown in FIG. 3 and the partially folded postcard shown in FIG. 4 form a pseudo-adhesive layer on the inner side of the fold of the base paper 1, print information, fold and press-bond. In each case, the pseudo adhesives are overlapped with each other and pressure-bonded.

The pseudo-adhesive sheet of the present invention is widely and suitably used for various postcards, postcards and reports in addition to those listed in these examples. It is also possible to facilitate the re-peeling by applying the coating only to a part of the coating or by providing a non-coating part. Pseudo-adhesive sheet of the present invention is a multi-fold pseudo-adhesive sheet, overlapping pseudo-adhesive sheet, other confidential information concealing paper, confidential postcard,
It can be suitably used for all forms such as a confidential envelope.

The substrate of the pseudo-adhesive sheet according to the present invention is not particularly limited, and may be high quality paper, art paper,
It may be so-called coated paper such as coated paper or lightweight coated paper, gravure paper, or synthetic paper or plastic film.

[0018] substrate, the case of using paper, its bulk density is 0.85 g / cm ³ or less, is suitable especially 0.80~0.70g / cm ^3. In such a tension range, the cushioning property is imparted to the base paper itself, and only the pressure applied to the unfixed toner or the like at the time of bonding decreases, so that even when the printing is performed by the electrophotographic method, It is possible to prevent the toner from being retransferred while maintaining the pseudo adhesive force at a normal level.

In the present invention, the base of the pseudo-adhesive may be any latex, specifically, any of those used in conventional general pseudo-adhesives such as natural rubber, synthetic rubber and synthetic resin. In particular, natural rubber latex obtained by subjecting natural rubber to sulfur-free vulcanization and mixing with methyl methacrylate, and natural rubber latex obtained by graft polymerization of methyl methacrylate onto natural rubber An acrylic-modified rubber latex, or a mixture of a rubber latex and a protective colloid-based acrylic copolymer emulsion is suitable in terms of blocking resistance, aging resistance, ink adhesion, and the like.

In the pseudo-adhesive layer of the present invention and / or an upper layer described later (the upper layer also functions as the pseudo-adhesive layer of the present invention), the adhesive force of the pseudo-adhesive layer is suppressed, or the surface has irregularities. Contains fine particles for forming. As the fine particles, regular fine particles and / or irregular fine particles can be used.

As the former fixed fine particles, all of the fine particles generally used conventionally can be used. Specifically, calcite-based precipitated calcium carbonate forming primary or secondary aggregates, aragonite-based precipitated calcium carbonate forming primary or secondary aggregates, styrene beads, cereal starch, modified starch And silica, synthetic fine particles, ordinary calcium, oxides, hydroxides, carbonates or silicates of metals such as zinc, magnesium, aluminum and titanium, and mixtures thereof. White carbon composed of a porous secondary aggregate can also be used.

As the latter irregular fine particles, natural fibers such as pulp cellulose powder, other animal / vegetable fibers, or particles obtained by fibrillating chemical fibers can be used. When pulp cellulose powder is used, it is 20 to 100 μm when observed by a microscope of itself.
Are obtained by adjusting the surface roughness of the base material to randomly form irregularities having a surface roughness of about 0.4 to 25 μm after coating. In a printing sheet containing such irregular fine particles in a pseudo-adhesive layer, the surface thereof contains fine fibrous projections fibrillated on the surface thereof, for example, on the surface of the pseudo-adhesive layer or on the surface of the surface layer. It has an irregular stitch structure.

It is desirable that such fine particles be contained in an amount of 10% or more, preferably 20 to 100%, based on the pseudo adhesive layer material.

When applying the pseudo-adhesive, the base of the pseudo-adhesive is dissolved in a solvent, and the fixed fine particles and / or the irregular fine particles are mixed and stirred. Apply. As this coating method, coating by a coating / printing method such as an air knife coater, a blade coater, a curtain coater, a bar coater, flexographic printing, and screen printing is preferable.

In addition to providing a pseudo adhesive layer on the substrate,
One or more surface layers can be provided. As this surface layer, two or more layers can be provided. The surface layer is a layer formed with one or more functional agents that further enhance the function as a pseudo-adhesive sheet.

There are many functional agents. For example, typically, the above-mentioned irregular fine particles, antioxidants, ultraviolet absorbers, tackifiers, lubricants, pigments, antislip agents, buffers, antistatic agents, surfactants, thickeners , An antifoaming agent, a release agent, an anti-blocking agent, and a printer toner fixing agent.

When the application of the pseudo adhesive layer is completed or when the surface layer is provided, the surface is pressurized at about 1 to 10 kg / cm ² when the application is completed, and the surface is excessively protruded. Is preferably adjusted to have a surface roughness of 30 to 5 μm.

The adhesive strength of the sheet in the present invention is as follows.
Depending on the application, the type of the base of the pseudo-adhesive, the type of fine particles, the type of additive, or can be adjusted by selecting the compounding ratio of these, preferably, when pressed with a commercially available sealer, The peel strength at a width of 25 mm is preferably 25 g or more.

The thickness of each surface layer is desirably 2 μm or less. When several layers are provided, the total thickness is desirably 5 μm or less. If the thickness is more than 5 μm, the adhesive strength may be significantly reduced. It is necessary to increase the surface roughness of the material or to provide a pseudo adhesive layer having a stronger adhesive force.

The pseudo adhesive sheet according to the present invention is excellent in printability in electrophotography, and the electrophotographic method is not limited to a positive toner developing method and a negative toner developing method. .

(Regarding the material according to the present invention) In the present invention, in order to prevent the above-mentioned retransfer, a thermoplastic material having a melting point of 50 ° C. or more and less than 150 ° C. , A fixing inducer). More preferably, the fixing inducer has a melting point of from 80 to 12.
It is at 0 ° C. Having such a melting point, it has been found that fixation can be promoted irrespective of the type of fixation inducing substance. If the melting point is high, there is no fixation inducing effect,
On the other hand, if the melting point is excessively low, there arises a problem that a fixing inducing substance adheres to the electrophotographic printing drum.

Preferred examples of the fixing inducing substance include the following.・ Fatty acid amides such as stearic acid amide, stearic acid bisamide, oleic acid amide, palmitic acid amide (melting point: 50 to 150 ° C.) ・ Waxes such as paraffin, polyester, styrene, polystyrene wax (melting point: 50 to 150 ° C.) ・ 1 , 2-bis (3-methylphenoxy) ethane, triphenylmethane, 1,2-diphenoxyethane, 1,2
-Bis (4-methoxyphenylthio) ethane, 1-phenoxy-2- (4-chlorophenoxy) ethane, 1-phenoxy-2- (4-methoxyphenoxy) ethane, 1
-(2-methylphenoxy) -2- (4-methylphenoxy) ethane, 1,2-bis (4-methylphenoxy)
Ethane, 1,2-bis (4-methoxyphenoxy) propane, 1,4-diphenoxybutane, 1,4-diphenoxy-2-butene, 1,4-dimethoxynaphthalene,
1,4-diethoxynaphthalene, 1,4-dibenzyloxynaphthalene, diphenyl carbonate, p-benzylbiphenyl, m-terphenyl, dibenzoylmethane,
Dibenzoyloxymethane, dibenzoyloxypropane, dibenzyl oxalate, di (4-methylbenzyl) oxalate, di (4-chlorobenzyl) oxalate, dibenzyl terephthalate, dimethyl terephthalate, 2,2′-bis (4 -Methoxyphenoxy) diethyl ether, bis (4-methoxyphenyl) ether, 2-naphthylbenzyl ether, ethylene glycol-m-tolyl ether, benzyl-4-methylthiophenyl ether, 1,
1′-diphenylethanol, 1,1′-diphenylpropanol, p-benzyloxybenzyl alcohol,
On the other hand, in the pseudo adhesive layer, organic fine particles having a particle size of 5 μm or less, a particle size of 2.5 μm or less, and an oil absorption of 250 cc / 100 g.
As described above, the inclusion of the inorganic fine particles having a specific surface area of 300 m ² / g or less further enhances the fixing of the toner.

As the organic fine particles, various types of starch,
Examples include cellulose powder and styrene particles. Examples of the inorganic fine particles include silica.

[0034]

EXAMPLES Next, experimental examples of the pseudo adhesive sheet according to the present invention will be shown to clarify the effects of the present invention. <Experimental example> The tension was 0.0 in the range of 0.6 to 0.9 g / cm ^3.
Base paper slid in 5 g / cm ³ increments of 10,000 each
A paper was made, and a natural rubber latex obtained by mixing sulfur-free vulcanization of natural rubber and methyl methacrylate as a pseudo-adhesive was added to these base papers, and synthetic fine-particle silica was added as a fine-particle filler. Apply the pseudo adhesive,
A pseudo adhesive sheet was produced. Here, those with and without the addition of various thermoplastic materials were produced. Then
Test printing was performed on the surface of the pseudo-adhesive layer of the pseudo-adhesive sheet of each of these strengths using an electrophotographic copying machine (type 6700) manufactured by Fuji Xerox Co., Ltd., and the pseudo-adhesive machine (adhesion pressure; 50 kg / cm ² )
After the pseudo-adhesive sheet folded in two such that the pseudo-adhesive layers face each other was adhered, the pseudo-adhesive sheet was peeled off, and the state of retransfer of the toner was observed. The retransfer condition of the toner is indicated by ◎: very excellent effect of preventing retransfer, ○: excellent in effect of preventing retransfer, ×
.. Are poor in retransfer prevention effect.

Further, Table 1 shows that Japanese Patent Application Laid-Open No. 7-292329
The results of the measurement of the adhesion of the pseudo-adhesive sheet performed in accordance with Experimental Example 1 of the Publication No. 3 (three-level evaluation of ◎: excellent in adhesion,…: excellent in adhesion, ×: inferior in adhesion) are also shown.

[0036]

[Table 1]

From these results, it is understood that retransfer can be prevented by adding the thermoplastic substance according to the present invention. Although the adhesive strength of Examples 2 and 3 is inferior, in this case, it is possible to increase the adhesive strength by adopting the adhesive strength increasing means.

[0038]

As described above, according to the present invention, even when printing is performed by electrophotography, it is possible to prevent the toner from being retransferred to the opposing surface at the time of bonding, and thus the electrophotographic method can be used. It becomes a pseudo adhesive sheet excellent in printability.

[Brief description of the drawings]

FIG. 1 is an explanatory diagram of a folded pay envelope.

FIG. 2 is an explanatory diagram of a tri-fold postcard.

FIG. 3 is an explanatory diagram of a two-fold postcard.

FIG. 4 is an explanatory diagram of a partially folded postcard.

[Explanation of symbols]

DESCRIPTION OF SYMBOLS 1 ... Base paper, 2 ... Pseudo-adhesive layer, 3 ... Information printing surface, 4 ...
Address information.

────────────────────────────────────────────────── ───

[Procedure amendment]

[Submission date] March 25, 1998

[Procedure amendment 1]

[Document name to be amended] Statement

[Correction target item name] 0014

[Correction method] Change

[Correction contents]

In the tri-fold postcard shown in FIG. 2, pseudo adhesive layers 2 and 2 are formed on the front and back surfaces of a base paper 1 and a concealing information is formed on the front surface.
After printing the information , the communication information, and the address information 4, as shown in FIG. 3B, the address print surface is folded and pressure-bonded so that the address print surface becomes the front surface.

[Procedure amendment 2]

[Document name to be amended] Statement

[Correction target item name] 0015

[Correction method] Change

[Correction contents]

The two-fold postcard shown in FIG. 3 and the partially folded postcard shown in FIG. 4 form a pseudo-adhesive layer 2 on the inner side of the fold of the base paper 1, print information, fold and press. In each case, the pseudo-adhesive layers 2 are overlapped with each other and pressure-bonded.

[Procedure amendment 3]

[Document name to be amended] Statement

[Correction target item name] 0019

[Correction method] Change

[Correction contents]

In the present invention, the base of the pseudo-adhesive may be any latex, specifically, any of those used in conventional general pseudo-adhesives such as natural rubber, synthetic rubber and synthetic resin. it can be selected and used, in particular, natural rubber and non-sulfur vulcanizable natural rubber latex was mixed with methyl methacrylate, natural rubber in the natural rubber methyl methacrylate obtained by graft copolymerization Latex, acryl-modified rubber latex, and a mixture of rubber latex and a protective colloid-based acrylic copolymer emulsion are suitable in terms of blocking resistance, aging resistance, ink adhesion, and the like.

[Procedure amendment 4]

[Document name to be amended] Statement

[Correction target item name] 0023

[Correction method] Change

[Correction contents]

[0023] The kind of the fine particles is 10% or more against the pseudo adhesive layer, preferably a desirably contained 20-100%.

[Procedure amendment 5]

[Document name to be amended] Statement

[Correction target item name] 0034

[Correction method] Change

[Correction contents]

[0034]

EXAMPLES Next, experimental examples of the pseudo adhesive sheet according to the present invention will be shown to clarify the effects of the present invention. <Experimental example> The tension was 0.0 in the range of 0.6 to 0.9 g / cm ^3.
Base paper slid in 5 g / cm ³ increments of 10,000 each
A paper was made, and a natural rubber latex obtained by mixing sulfur-free vulcanization of natural rubber and methyl methacrylate as a pseudo-adhesive was added to these base papers, and synthetic fine-particle silica was added as a fine-particle filler. Apply the pseudo adhesive,
A pseudo adhesive sheet was produced. Here, those with and without the addition of various thermoplastic materials were produced. Then
Test printing was performed on the surface of the pseudo-adhesive layer of the pseudo-adhesive sheet of each of these strengths using an electrophotographic copying machine (type 6700) manufactured by Fuji Xerox Co., Ltd., and the pseudo-adhesive machine (adhesion pressure; 50 kg / cm ² )
After the pseudo-adhesive sheet folded in two such that the pseudo-adhesive layers face each other was adhered, the pseudo-adhesive sheet was peeled off, and the state of retransfer of the toner was observed. The retransfer condition of the toner is indicated by ◎: very excellent effect of preventing retransfer, ○: excellent in effect of preventing retransfer, ×
.. Are poor in retransfer prevention effect.

[Procedure amendment 6]

[Document name to be amended] Drawing

[Correction target item name] Fig. 1

[Correction method] Change

[Correction contents]

FIG.

 ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Yoshiaki Murakami 5-1 Kamiyacho, Iyo Mishima City, Ehime Prefecture Daio Paper Co., Ltd.

Claims (1)

[Claims] 1. A pseudo-adhesive paper having a pseudo-adhesive layer provided on at least a part of at least one surface of a substrate sheet, wherein a thermoplastic substance having a melting point of 50 ° C. or more and less than 150 ° C. is contained in the pseudo-adhesive layer. A pseudo-adhesive sheet characterized by containing.