JPH11315349A - High strength wire rod excellent in delayed fracture resistance, its production, and high strength bolt - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a high strength wire rod having excellent delayed fracture resistance as well as >=1200 N/mm<2> tensile strength, a useful method for obtaining a high strength wire rod like that, and a high strength bolt having the above characteristics. SOLUTION: This wire rod is composed of a steel containing 0.5-1.0% C, and the area ratio of a pearlitic structure having a pearlite nodule size of No.7 or above by grain size number is regulated to >=80% by inhibiting the formation of structures of one or >=2 kinds among pro-eutectoid ferrite, pro-eutectoid cementite, bainite, and martensite and also strength is regulated to >=1200 N/mm<2> by means of heavy wire drawing. Moreover, the steel is heated to 800-1000 deg.C, cooled rapidly down to 520-650 deg.C, and isothermally held at the temperature, by which the formation of structures of one or >=2 kinds among pro- eutectoid ferrite, pro-eutectoid cementite, bainite, and martensite is inhibited to regulate the area ratio of a pearlitic structure having a pearlite nodule size of No.7 or above by grain size number to >=80%. Then, strength is regulated to >=1200 N/mm<2> by means of heavy wire drawing.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a high-strength wire rod suitable for bolts used for automobiles and various industrial machines, a method for producing the same, a high-strength bolt, and the like. TECHNICAL FIELD The present invention relates to a high-strength wire rod which is not less than / mm ² and excellent in delayed fracture resistance, a useful method for producing such a high-strength wire rod, and a high-strength bolt made of the high-strength wire rod.

[0002]

2. Description of the Related Art As a general high-strength bolt steel, a medium carbon alloy steel (SCM435, SCM440, SCr440) is used.
Etc.) are used, and the necessary strength is ensured by quenching and tempering. However, in general high-strength bolts used for automobiles and various industrial machines, when the tensile strength exceeds about 1200 N / mm ² , there is a risk that delayed fracture occurs, and there are restrictions on use. .

[0003] Delayed destruction can occur in a non-corrosive environment or in a corrosive environment, and it is said that the cause of occurrence is complicated by various factors.
It is generally difficult to identify the above cause. As the control factors affecting the delayed fracture as described above, tempering temperature, structure, material hardness, crystal grain size, various alloying elements and the like have been recognized for some time, but they are effective for preventing delayed fracture. In fact, no means has been established, and only various methods have been proposed by trial and error.

[0004] In order to improve the delayed fracture resistance, for example, Japanese Patent Application Laid-Open Nos. 60-114551, 2-267243 and 3-243745 have been proposed. These techniques are aimed at developing a high-strength bolt steel having excellent delayed fracture resistance even with a tensile strength of 1400 N / mm ² or more by adjusting various main alloying elements. However, these techniques do not completely eliminate the danger of delayed fracture, but their application is limited.

[0005]

SUMMARY OF THE INVENTION The present invention has been made in view of such circumstances, and has as its object to provide a high strength steel having excellent delayed fracture resistance while having a tensile strength of 1200 N / mm ² or more. An object of the present invention is to provide a high-strength wire, a useful method for obtaining such a high-strength wire, and a high-strength bolt having the above characteristics.

[0006]

The high-strength wire rod which has achieved the above object is composed of steel containing C: 0.5 to 1.0%, and comprises proeutectoid ferrite, proeutectoid cementite, bainite and martensite. Inhibits the formation of one or more types of tissues, and the pearlite nodule size is N
o. The area ratio of the pearlite structure of 7 or more is 80% or more, and 1200 N / m
The gist is that the strength is not less than m ² . Here, the pearlite nodule means a region where the crystal orientation of ferrite in the pearlite is uniform.

The high-strength wire rod of the present invention may, if necessary, (1) Si: 2.0% or less (excluding 0%) and / or Co: 0.5% or less (excluding 0%). ),
(2) One or more selected from the group consisting of Cr, Mo, Ti, Nb, V and W in a total of 0.01 to 0.05.
%, (3) Ai: 0.01 to 0.05%, etc. is also effective.

[0008] In producing the high-strength wire as described above, the rolling or forging end temperature of the steel is 800 to 100.
After hot rolling or hot forging to 0 ° C,
The average cooling rate V is set to 40 so as to satisfy the following equation (1).
By cooling to 0 ° C. and subsequently allowing to cool, the formation of one or more types of proeutectoid ferrite, proeutectoid cementite, bainite and martensite is suppressed,
The pearlite nodule size is No. in the particle size number. The area ratio of the pearlite structure of 7 or more may be set to 80% or more, and then the strength may be increased to 1200 N / mm ² or more by strong drawing. 166 × (wire diameter) ^-1.4 ≦ V ≦ 288 × (wire diameter) ^-1.4 … (1)

[0009] The high-strength wire of the present invention comprises a steel material of 800
After heating to about 1000 ° C., it is rapidly cooled to a temperature of 520 to 650 ° C. and maintained at that temperature to form one or more types of microstructures of proeutectoid ferrite, proeutectoid cementite, bainite and martensite. Restrain,
The pearlite nodule size is No. in the particle size number. It can also be manufactured by setting the area ratio of the pearlite structure of 7 or more to 80% or more, and thereafter making the strength of 1200 N / mm ² or more by strong drawing.

Further, the high-strength wire of the present invention is subjected to hot rolling or hot forging so that the rolling or forging end temperature of the steel is 800 to 1000 ° C., and then the average cooling rate of 5 ° C./sec or more. To a temperature of 520 to 750 ° C., holding at that temperature at an average cooling rate of 1.0 ° C./sec or less for 200 seconds or more, and then allowing to cool to obtain proeutectoid ferrite, proeutectoid cementite, bainite and martensite. The formation of one or more types of tissue at the site is suppressed, and the pearlite nodule size is No. in particle size number. It can also be manufactured by setting the area ratio of the pearlite structure of 7 or more to 80% or more, and thereafter making the strength of 1200 N / mm ² or more by strong drawing.

On the other hand, after using the high-strength wire of the present invention as a material and cutting it to a predetermined length, (1) threading or threading the both ends by threading or cutting (to form stud bolts); Or (2) forming a bolt head at one end by warm forging, and threading the other end before or after warm forging by thread rolling or cutting to provide excellent delayed fracture resistance. A high-strength bolt that can be used is obtained.

[0012]

BEST MODE FOR CARRYING OUT THE INVENTION The present inventors have studied from various angles the cause of the inferior delayed fracture resistance of conventional high strength steel for bolts. As a result, in the conventional improvement method, the structure has been tempered martensite, and the delayed fracture resistance has been supplemented by avoiding the tempered embrittlement region, reducing the grain boundary segregation elements, and refining the crystal grains. It has been found that there is a limit in improving the delayed fracture resistance of high-strength steel.

The inventors of the present invention have conducted intensive studies to further improve the delayed fracture resistance. As a result, the structure was changed to a structure mainly composed of pearlite having a certain restriction, and 1200 N / mm ² or more was formed by strong drawing. It has been found that if the strength is set as above, the delayed fracture resistance is improved, and the present invention has been completed.

As described above, the high-strength wire of the present invention suppresses the formation of one or more types of pro-eutectoid ferrite, pro-eutectoid cementite, bainite and martensite,
The pearlite nodule size is No. in the particle size number. The area ratio of the pearlite structure of 7 or more needs to be 80% or more. When a large amount of pro-eutectoid ferrite and pro-eutectoid cementite is formed in the above-mentioned structure, longitudinal cracks are caused at the time of drawing and the drawing cannot be performed, and 1200 N / mm ² is obtained by strong drawing.
Cannot be obtained. In addition, proeutectoid cementite and martensite cause disconnection during wire drawing, and thus need to be reduced. Further, since the amount of work hardening of bainite is smaller than that of pearlite, it is not possible to expect an increase in strength due to strong wire drawing.

On the other hand, the remaining pearlite structure has the effect of trapping hydrogen at the interface between cementite and ferrite and reducing the amount of hydrogen accumulated at grain boundaries. From these facts, one of proeutectoid ferrite, proeutectoid cementite, bainite and martensite
The formation of the seed or two or more kinds of tissues is suppressed as much as possible (ie, less than 20%), and the area ratio of the pearlite structure is reduced to 8%.
Must be 0% or more. The area ratio of the pearlite structure is preferably 90% or more, and more preferably 100% pearlite structure.

The pearlite structure has a pearlite nodule size of No. in particle size number. It is necessary to be 7 or more. The pearlite nodule size is No. in the particle size number. If it is less than 7, the breaking reduction value becomes low, and subsequent cold drawing becomes difficult, and the required strength cannot be obtained. On the other hand, when the pearlite nodule size is reduced, the stress applied to the grain boundary is reduced, and the grain boundary strength is increased. As a result, grain boundary destruction observed when delayed fracture occurs is suppressed, and delayed fracture resistance is improved. Further, by reducing the pearlite nodule size, ductility and toughness are improved, and from this viewpoint, delayed fracture resistance is also improved. That is, at least one of the microstructures such as proeutectoid ferrite, proeutectoid cementite, bainite, and martensite is reduced as much as possible, and the total area ratio is less than 20%. By setting the area ratio of the pearlite structure of 7 or more to 80% or more, excellent delayed fracture resistance is achieved. The pearlite nodule size is No. in the particle size number. No. 8 or more, more preferably No. It is good to be 10 or more.

In the wire rod of the present invention, required dimensional accuracy cannot be obtained as it is as rolled or forged.
Since it becomes difficult to obtain a strength of 0 N / mm ² or more,
Strong wire drawing is required. In addition, cementite in some pearlite is finely dispersed by strong wire drawing to improve the hydrogen trapping ability, and the structure is arranged along the wire drawing direction to reduce the crack propagation resistance (the crack propagation direction is Perpendicular to the drawing direction).

In the high-strength wire rod of the present invention, C is set to 0.5 to 1.0.
The medium carbon steel containing 0% is assumed, but the reason for limiting the range of the C content is as follows.

C: 0.5 to 1.0% C is a necessary and economical element for securing the strength of steel.
The strength increases as the C content increases. In order to secure the target strength, C needs to be contained at 0.5% or more. However, when the C content exceeds 1.0%, the precipitation amount of proeutectoid cementite increases, so that the toughness and ductility are significantly reduced and the wire drawing workability is deteriorated. A preferred lower limit of the C content is 0.65%, more preferably 0.1%.
7%. A preferable upper limit of the C content is 0.95.
%, More preferably 0.9%.

The high-strength wire of the present invention can be prepared by adding various elements (Si, Co, Mn, Cu, Ni, Cr, Mo,
Ti, Nb, V, W, Al, B, etc.) may of course be contained, but in particular, containing a predetermined amount of Si or Co is effective in suppressing the precipitation of proeutectoid cementite. In addition, Cr, Mo, Ti, Nb, V, W, and Al are effective for refining crystal grains to reduce the pearlite nodule size. The reasons for limiting each element to be added as necessary are as follows.

Si: 2.0% or less (excluding 0%) Si has the effect of improving the hardenability of steel wire and suppressing the precipitation of proeutectoid cementite. In addition, it is expected to act as a deoxidizing agent, and exhibits a remarkable solid solution strengthening effect by being dissolved in ferrite. These effects increase as the content increases, but an excessive Si content reduces the ductility of the drawn steel wire, so the upper limit is 2.0%. The preferred upper limit of the Si content is 1.0%, more preferably 0.5%.

Co: 0.5% or less (excluding 0%) Co has the effect of suppressing the precipitation of pro-eutectoid cementite like Si, and the high-strength additive of the present invention for reducing pro-eutectoid cementite. This is particularly effective. These effects increase as the content increases,
If the content exceeds 0.5%, the effect is saturated and uneconomical, so the upper limit is made 0.5%. The preferred range of the Co content is 0.05 to 0.3%, and more preferably, the lower limit is 0.1% and the upper limit is 0.2%.

From Cr, Mo, Ti, Nb, V and W
One or more selected from the group consisting of: 0.01 to 0.5 in total
% These elements form fine carbon / nitride and contribute to the improvement of delayed fracture resistance. These carbides and nitrides are also effective in reducing the pearlite nodule size. In order to exert such effects, it is necessary to contain a total of 0.01% or more, but if it is contained excessively, the delayed fracture resistance and toughness are impaired, so it is necessary to make the total 0.5% or less. . The preferable lower limit of the content of these elements is 0.02% in total, and more preferably 0.03%. A preferable upper limit is 0.3% in total, and more preferably 0.1%.

Al: 0.01 to 0.05% Al captures N in steel to form AlN, and contributes to improvement in delayed fracture resistance by reducing the size of pearlite nodules. For this purpose, the content must be 0.01% or more. However, if it exceeds 0.05%, nitride-based inclusions or oxide-based inclusions are formed, and the wire drawing property is reduced. It must be: The preferred lower limit of the Al content is 0.025%, and the preferred upper limit is 0.035%.

Mn: 0.2 to 1.0% Mn exerts an effect as a deoxidizing agent and an effect of improving the hardenability of the steel wire and improving the uniformity of the structure of the steel wire. In order to exert these effects, it is necessary to contain 0.2% or more. However, when the Mn content becomes excessive, M
Since a supercooled structure such as martensite or bainite is formed in the segregated portion of n to deteriorate the drawability, the upper limit is 1.0%. The preferred lower limit of the Mn content is 0.40%.
And more preferably 0.45%. Further, a preferable upper limit of the Mn content is 0.70%, and more preferably 0.55%.

Cu: 0.5% or less (excluding 0%) Cu is an element that contributes to increasing the strength of a steel wire by a precipitation hardening action. However, if added excessively, it causes grain boundary embrittlement and deteriorates delayed fracture resistance.
The upper limit is 0.5%. The lower limit of the Cu content is preferably 0.05%, and more preferably 0.1%. The preferable upper limit of the Cu content is 0.3%, more preferably 0.2%.

Ni: 1.0% or less (excluding 0%) Ni does not significantly contribute to the increase in the strength of the steel wire, but has the effect of increasing the toughness of the drawn wire. However, if the Ni content is excessive, the transformation end temperature becomes too long, which leads to an excessively large facility and a deterioration in productivity. Therefore, the upper limit is 1.0%. The lower limit of the Ni content is preferably 0.05%, and more preferably 0.1%. Also Ni
A preferred upper limit of the content is 0.5%, and more preferably 0.3%.

B: 0.0005% to 0.003% B is added for improving the hardenability of steel, but in order to exhibit the effect, it is necessary to contain 0.0005% or more. However, if the content exceeds 0.003%, the toughness is rather hindered. The preferred lower limit of the B content is 0.0010%, and the preferred upper limit is 0.0010%.
25%.

N: 0.015% or less (excluding 0%) N forms a nitride such as AlN or TiN, and thereby has a favorable effect on the refinement of crystal grains and the improvement in delayed fracture resistance. However, if the N content is excessive, not only does the nitride excessively increase and adversely affect drawability, but also solute N promotes aging during drawing, so
Must be 5% or less. The upper limit of the N content is preferably 0.007%, and more preferably 0.005% or less.

In the high-strength wire rod of the present invention, other than the above components (the rest) is basically made of iron, but may contain trace components in addition to these components. It is included in the technical scope of the present invention. From the viewpoint of further improving the characteristics, P, S and O are preferably suppressed as follows. Furthermore, although the high-strength wire of the present invention inevitably contains impurities, they are permissible as long as the effects of the present invention are not impaired.

P: 0.03% or less (including 0%) P is an element that causes grain boundary segregation and deteriorates delayed fracture resistance. Therefore, by setting the P content to 0.03% or less, delayed fracture resistance can be improved. The P content is
It is preferably reduced to 0.015% or less, and more preferably 0.005% or less.

S: 0.03% or less (including 0%) S forms MnS in steel, and when stress is applied, M
nS is the stress concentration point. Therefore, in order to improve the delayed fracture resistance, it is necessary to reduce the S content as much as possible, and the S content is preferably set to 0.03% or less. The S content is
It is preferably reduced to 0.01% or less, more preferably 0.005% or less.

O: 0.005% or less (including 0%) O hardly forms a solid solution with steel at room temperature, exists as hard oxide-based inclusions, and causes wire breakage during drawing. Therefore, the O content should be as low as possible, and should be suppressed to at least 0.005% or less.
The O content is preferably reduced to 0.003% or less, and more preferably to 0.002% or less.

The high-strength wire rod of the present invention can be manufactured by each of the above-mentioned manufacturing methods, and the operation of each method is as follows. First, a steel material having the above chemical composition is used, and the rolling or forging end temperature of the steel material is 8
After hot rolling or hot forging is performed so that the temperature becomes 00 to 1000 ° C., the temperature is cooled to 400 ° C. so that the average cooling rate V satisfies the following formula (1), and then the product is allowed to cool. 166 × (wire diameter) ^-1.4 ≦ V ≦ 288 × (wire diameter) ^-1.4 … (1)

By this step, a more uniform pearlite structure can be obtained than in a normal rolled material, and the strength before drawing can be increased. If the rolling or forging end temperature is too high, the austenite grain size becomes coarse, causing the pearlite nodule size to become coarse. Conversely, if the end temperature is too low, austenitization becomes insufficient and a homogeneous pearlite structure cannot be obtained. From such a viewpoint, the end temperature is 800
１０００1000 ° C. The preferred range of the heating temperature is about 850 to 950 ° C, more preferably about 850 to 900 ° C.

The average cooling rate V is 166 × (wire diameter)
^When it is smaller than ^-1.4, not only a homogeneous pearlite structure cannot be obtained, but also proeutectoid ferrite and proeutectoid cementite are easily formed. The average cooling rate V is 288 ×
(Wire diameter) When it is larger than ^-1.4 , bainite and martensite are easily generated.

The high-strength wire of the present invention uses a steel having the chemical composition as described above,
After being heated to 000 ° C., it is rapidly cooled to a temperature of 520 to 650 ° C., and is kept at that temperature (patenting treatment) to obtain a pearlite structure that is more homogeneous than a normal rolled material, and to increase the strength before drawing. Can be achieved.

In this method, the specified range of the steel material heating temperature must be 800 to 1000 ° C. for the same reason as the above-mentioned rolling or forging end temperature. The preferred range of the heating temperature is the same as described above. In the patenting process, it is desirable to use a salt bath, lead, a fluidized bed, or the like to rapidly cool the heated wire at a temperature as fast as possible.
In order to obtain a homogeneous pearlite structure, 520 to 650 is required.
It is necessary to carry out isothermal transformation at ℃. The preferred temperature range of the isothermal transformation temperature is 550 to 600 ° C., and the most preferred isothermal holding temperature is a temperature near the pearlite nose in the TTT diagram.

On the other hand, the steel material is hot-rolled or hot-forged so as to have a temperature of 800 to 1000 ° C. after completion of the rolling or forging, and then 520 to 750 at an average cooling rate of 5 ° C./sec or more.
C., cooled to a temperature of 1 ° C./second or less at an average cooling rate of 200 ° C. or more, and then allowed to cool to obtain a more uniform pearlite structure than a normal rolled material. The previous strength can be increased. The operation in each step when such a method is adopted is as follows.

First, the specified range of the temperature after the completion of rolling or forging is set to 800 to 800 for the same reason as the above-mentioned steel material heating temperature.
It was determined to be 1000 ° C. The preferred range of this temperature is
Same as above. If the cooling rate after hot rolling or hot forging is too slow, ferrite transformation may occur during cooling, and it is preferable to cool at a cooling rate as high as possible. Therefore, the cooling rate at this time was specified to be 5 ° C./sec or more. The preferred range of this cooling rate is 10 ° C.
/ Sec or more, more preferably 30 ° C / sec or more. It is necessary to cool down to 520 to 750 ° C. by this cooling.
If the temperature exceeds 50 ° C., a structure other than pearlite is likely to be generated by subsequent slow cooling.

After the above cooling, the temperature (520 to 750 ° C.) is obtained from the viewpoint of obtaining a homogeneous pearlite structure.
(Temperature: slow cooling start temperature), it is necessary to hold for 200 seconds or more while cooling (slow cooling) at an average cooling rate of 1 ° C./sec or less. If the average cooling rate at this time is higher than 1 ° C./sec or the holding time is less than 200 seconds, the material is left to cool before transforming to a pearlite structure, and bainite and martensite are easily generated. The preferred range of the cooling rate is 0.5 ° C./sec or less, more preferably 0.2 ° C./sec.
C./sec or less is preferable. A preferred range of the holding time is 300 seconds or more, more preferably 600 seconds.
It is good to be more than seconds. It is most preferable to keep the temperature near the pearlite nose in the TTT diagram for a long time.

After using the high-strength wire obtained as described above and cutting it to a predetermined length, (1) threading or thread-cutting both ends (to form stud bolts); Or (2) a bolt head is formed at one end by warm forging, and the other end is threaded by thread rolling or cutting before or after warm forging, and the like, so that excellent delayed fracture resistance and A bolt exhibiting strength is obtained.
In the above method (2), the use of the warm forging method when forming the bolt head is because the strength of the wire is high and it is difficult to form the bolt into a predetermined bolt shape by ordinary cold forging. It is.

Hereinafter, the present invention will be described in more detail with reference to Examples. However, the following Examples are not intended to limit the present invention. Included in the technical scope.

[0044]

Example 1 Using a test steel having the chemical composition shown in Table 1 below, hot rolling was performed to a wire diameter of 11 mm or 14 mm so that the rolling end temperature would be about 930 ° C., and then the average cooling rate V was subjected to blast cooling in a range of 4.1 to 12.3 ° C./sec (Table 2 below). Thereafter, the wire was drawn to a wire diameter of 7.06 mm (drawing ratio: 59% .75%).

[0045]

[Table 1]

Using the obtained various wire rods, M8 shown in FIG.
A stud bolt of × P1.25 was prepared, and a delayed fracture test was performed. In the delayed fracture test, a bolt was immersed in an acid (15% HCl × 30 minutes), washed with water and dried, and subjected to a stress load in air (load stress was 90% of the tensile strength). The presence or absence was evaluated. In addition, pro-eutectoid ferrite, pro-eutectoid cementite, bainite, martensite or pearlite structures were classified by the following method to determine the area ratio of each structure. Furthermore, perlite nodule size,
It was measured by the following method. At this time, for the purpose of comparison, a delayed fracture test was performed on some of the alloys that had been quenched and tempered to have a 100% tempered martensite structure (No. 19 in Table 2 below).

(Method of Classifying Each Tissue) The cross section of the wire is embedded, polished, and then immersed in a 5% alcoholic picric acid solution.
After immersion for 30 seconds to corrode, the structure of D / 4 (D: diameter) was observed by scanning electron microscope (SEM). After photographing 5 to 10 visual fields at 1000 to 3000 times and determining the pearlite tissue portion, the area ratio of each tissue was determined by an image analyzer. For the bainite structure and the proeutectoid ferrite structure, which are hard to distinguish from the pearlite structure, the structure shown in FIG. 2 (micrograph as a substitute for a drawing) is defined as a bainite structure, and the structure as shown in FIG. 3 (micrograph as a substitute for a drawing). Was determined to be a proeutectoid ferrite structure. As a tendency of these structures, proeutectoid ferrite and proeutectoid cementite are:
Needle-like precipitates were formed along the former austenite crystal grain boundaries, and martensite was precipitated in bulk.

(Measurement method of pearlite nodule size) After embedding the cross section of the wire, polishing and immersing it in a 1-2% nital solution for 2 to 10 seconds, the D / 4 (D is a diameter) portion was observed with an optical microscope. The tissue was observed. The particle size number of perlite nodule is JIS G0551 or JIS
It was defined in the same unit (grain number) as the austenite grain size or ferrite grain size of SG0552.

The structure of each wire is shown in Table 2 below together with the average cooling rate V, and the result of the delayed fracture test is shown in Table 3 below together with the drawing conditions and mechanical properties. The appropriate range of the average cooling rate V [the range satisfying the above equation (1)] is as follows.
4.12 ≦ V ≦ 7.16 (° C./sec) when m
When the wire diameter is 11 mm, 5.78 ≦ V ≦ 10.03 (° C.
/ Sec).

[0050]

[Table 2]

[0051]

[Table 3]

Example 2 Using the test steel C shown in Table 1 above, hot rolling was performed so that the rolling end temperature was about 930 ° C. to a wire diameter of 11 mmφ, followed by rapid cooling. Patenting treatment (heating temperature: 750-935 ° C., constant temperature transformation: 495-6)
(65 ° C. × 4 minutes). Thereafter, the wire was drawn to a wire diameter of 7.06 mm (drawing ratio: 59%).

[0053]

[Table 4]

Using the obtained various wire rods, an M8 × P1.25 stud bolt shown in FIG. 1 was prepared, and a delayed fracture test was performed in the same manner as in Example 1. The structure of each wire is also shown in Table 4 above, and the results of the delayed fracture test are shown in Table 5 below together with the drawing conditions and mechanical properties.

[0055]

[Table 5]

Example 3 The test steel C shown in Table 1 was hot-rolled to a wire diameter of 11 mmφ under the rolling conditions shown in Table 6 below. afterwards,
The wire was drawn to a diameter of 7.06 mm (drawing ratio: 59%).

[0057]

[Table 6]

Using the obtained various wire rods, M8 × P1.25 stud bolts shown in FIG. 1 were produced, and a delayed fracture test was performed in the same manner as in Example 1. The structure of each wire is shown in Table 7 below, and the results of the delayed fracture test are shown in Table 8 below together with the drawing conditions and mechanical properties.

[0059]

[Table 7]

[0060]

[Table 8]

As is apparent from these results, the bolt satisfying the requirements of the steel of the present invention has a tensile strength of 1200 N /
It can be seen that even if it is not less than mm ² , it has excellent delayed fracture resistance.

[0062]

The steel for bolts according to the present invention is constituted as described above, and has a tensile strength of 1200 N / mm ² or more and is excellent in delayed fracture resistance, and such a high-strength wire. And a high-strength bolt having the above-mentioned characteristics.

[Brief description of the drawings]

FIG. 1 is a schematic explanatory view showing a shape of a bolt subjected to a delayed fracture test in an example.

FIG. 2 is a drawing-substituting micrograph showing a bainite structure.

FIG. 3 is a drawing-substituting micrograph showing a proeutectoid ferrite structure.

──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. ⁶ Identification code FI C22C 38/10 C22C 38/10 38/30 38/30 F16B 35/00 F16B 35/00 J (72) Inventor Hiroshi Ieguchi Kobe 1-5-5 Takatsukadai, Nishi-ku, Kobe Steel Works, Kobe Research Institute

Claims (9)

[Claims] C: 0.5 to 1.0% (meaning by mass%,
The same shall apply hereinafter), which suppresses the formation of one or more types of pro-eutectoid ferrite, pro-eutectoid cementite, bainite and martensite, and has a pearlite nodule size of No. 1 in particle size number. The area ratio of the pearlite structure of 7 or more is 80% or more, and the strength is 1200 N / mm ² or more and the delayed fracture resistance is excellent by strong drawing. High strength wire with excellent delayed fracture resistance. 2. Si: 2.0% or less (excluding 0%)
And / or Co: 0.5% or less (excluding 0%)
The high-strength wire according to claim 1, which comprises: 3. One or more kinds selected from the group consisting of Cr, Mo, Ti, Nb, V and W in a total amount of 0.01 to
The high-strength wire according to claim 1 or 2, which contains 0.5%. 4. The high-strength wire according to claim 1, which contains 0.01 to 0.05% of Al. 5. High strength according to claim 1.
In producing wire rods, the temperature at which steel is rolled or forged
Hot rolling or hot so that the temperature is 800-1000 ° C
After forging, the average cooling rate V satisfies the following formula (1).
Cool to 400 ° C and then allow to cool
Proeutectoid ferrite, proeutectoid cementite, bay
One or more sets of knight and martensite
Suppresses weaving and reduces perlite nodule size
No. by number. 80% area ratio of pearlite structure of 7 or more
After that, 1200 N / mm by strong wire drawing
^Two Excellent in delayed fracture resistance characterized by having the above strength
Manufacturing method of high strength wire rod. 166 x (wire diameter)^-1.4≦ V ≦ 288 × (wire diameter)^-1.4 … (1) 6. In producing the high-strength wire according to claim 1, the steel is heated to 800 to 1000 ° C., rapidly cooled to a temperature of 520 to 650 ° C., and kept at that temperature. By suppressing the formation of one or more types of proeutectoid ferrite, proeutectoid cementite, bainite and martensite, the pearlite nodule size becomes No. 1 in particle size number. A method for producing a high-strength wire excellent in delayed fracture resistance, characterized in that an area ratio of a pearlite structure of 7 or more is 80% or more, and thereafter, a strength of 1200 N / mm ² or more is obtained by strong drawing. 7. In producing the high-strength wire according to any one of claims 1 to 4, hot rolling or hot forging is performed so that the rolling or forging end temperature of the steel is 800 to 1000 ° C. Thereafter, at an average cooling rate of 5 ° C./sec or more, 52
It is cooled to a temperature of 0 to 750 ° C, and at that temperature, 1.0 ° C /
By holding for 200 seconds or more at an average cooling rate of 2 seconds or less, and then allowing to cool, the formation of one or more types of pro-eutectoid ferrite, pro-eutectoid cementite, bainite and martensite is suppressed, and the pearlite nodule size is reduced. Is the particle size number and No. The area ratio of the pearlite structure of 7 or more was set to 80% or more, and then 1200 mm by strong wire drawing.
A method for producing a high-strength wire excellent in delayed fracture resistance, characterized by having a strength of N / mm ² or more. 8. A high-strength bolt excellent in delayed fracture resistance, obtained by using the high-strength wire rod according to claim 1 and cutting both ends by thread rolling or cutting after cutting. . 9. A bolt head is formed at one end by warm forging after cutting using the high-strength wire rod according to claim 1, and the other end before or after warm forging. High-strength bolt with excellent delayed fracture resistance, which is made by thread rolling or cutting.