JPH11302806A - Iron-base sintered alloy excellent in strength and toughness and its production - Google Patents
Iron-base sintered alloy excellent in strength and toughness and its productionInfo
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- JPH11302806A JPH11302806A JP12674698A JP12674698A JPH11302806A JP H11302806 A JPH11302806 A JP H11302806A JP 12674698 A JP12674698 A JP 12674698A JP 12674698 A JP12674698 A JP 12674698A JP H11302806 A JPH11302806 A JP H11302806A
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- iron
- strength
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Abstract
Description
【0001】[0001]
【発明の属する技術分野】この発明は、エンジン部品を
始めとする自動車部品およびコンプレッサー部品などの
各種機械部品の材料として使用される強度および靱性に
優れたた鉄基焼結合金およびその製造方法に関するもの
である。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an iron-based sintered alloy having excellent strength and toughness used as a material for various mechanical parts such as engine parts, automobile parts and compressor parts, and a method for producing the same. Things.
【0002】[0002]
【従来の技術】一般に、エンジン部品を始めとする自動
車部品およびコンプレッサー部品などの各種機械部品の
材料として鉄基焼結合金が用いられており、この鉄基焼
結合金の1つとして、C:0.1重量%以下、Mn:
0.08重量%以下、Cr:0.5〜3重量%、Mo:
0.1〜2重量%、S:0.01重量%以下、P:0.
01重量%以下、O:0.2重量%以下を含有し、残り
がFeおよび不可避不純物からなる組成を有する合金鋼
粉末にC:0.2〜1.2%を含有させた鉄基焼結合金
があることは知られている。2. Description of the Related Art Generally, iron-based sintered alloys are used as materials for various mechanical parts such as engine parts, automobile parts, compressor parts, and the like. One of the iron-based sintered alloys is C: 0.1% by weight or less, Mn:
0.08% by weight or less, Cr: 0.5 to 3% by weight, Mo:
0.1-2% by weight, S: 0.01% by weight or less, P: 0.
Iron-based sintering bonding in which alloy steel powder having a composition of not more than 01% by weight and O: 0.2% by weight and the balance being Fe and unavoidable impurities contains C: 0.2 to 1.2%. It is known that there is money.
【0003】[0003]
【発明が解決しようとする課題】しかし、近年、エンジ
ン部品を始めとする自動車部品およびコンプレッサー部
品などの各種機械部品の材料として一層優れた強度およ
び靱性を有する鉄基焼結合金が求められている。However, in recent years, iron-based sintered alloys having higher strength and toughness have been demanded as materials for various mechanical parts such as engine parts, automobile parts and compressor parts. .
【0004】[0004]
【課題を解決するための手段】そこで、本発明者らは、
上述のような観点から、一層優れた強度および靱性を有
する鉄基焼結合金を得るべく研究を行った結果、(a)
原料粉末として、平均粒径の大きいFe粉末にNi粉末
およびCr3 C2粉末を混合し、さらに必要に応じてC
粉末を添加して混合し、成形し、焼結すると、素地中に
フェライト相が島状に分散している組織を有する鉄基焼
結合金が得られ、この鉄基焼結合金は従来よりも強度お
よび靱性が一層向上する、(b)この鉄基焼結合金の素
地は、マルテンサイト、オーステナイトおよびパーライ
トの混合組織からなる、などの知見を得たのである。Means for Solving the Problems Accordingly, the present inventors have:
From the viewpoints described above, as a result of conducting research to obtain an iron-based sintered alloy having more excellent strength and toughness, (a)
As a raw material powder, Ni powder and Cr 3 C 2 powder are mixed with Fe powder having a large average particle size,
When powder is added, mixed, molded and sintered, an iron-based sintered alloy having a structure in which a ferrite phase is dispersed in the base material in an island shape is obtained. It has been found that the strength and toughness are further improved, and that (b) the base material of the iron-based sintered alloy has a mixed structure of martensite, austenite and pearlite.
【0005】この発明は、かかる知見にもとづいて成さ
れたものであって、(1)Cr:0.2〜5重量%、N
i:1〜6重量%、C:0.1〜1.0重量%を含有
し、残りがFeおよび不可避不純物からなる組成を有
し、かつ素地中にフェライト相が島状に分散している組
織を有する強度および靱性に優れた鉄基焼結合金、
(2)前記素地は、マルテンサイト、オーステナイトお
よびパーライトの混合組織からなる前記(1)記載の強
度および靱性に優れた鉄基焼結合金、(3)Fe粉末、
Ni粉末およびCr3 C2 粉末を混合し、成形し、焼結
する前記(1)または(2)記載の強度および靱性に優
れた鉄基焼結合金の製造方法,(4)Fe粉末、Ni粉
末、Cr3 C2 粉末およびC粉末を混合し、成形し、焼
結する(1)または(2)記載の強度および靱性に優れ
た鉄基焼結合金の製造方法、に特徴を有するものであ
る。The present invention has been made based on this finding, and (1) Cr: 0.2 to 5% by weight;
i: 1 to 6% by weight, C: 0.1 to 1.0% by weight, the remainder has a composition consisting of Fe and unavoidable impurities, and the ferrite phase is dispersed in an island shape in the base material. Iron-based sintered alloy with structure and strength and toughness,
(2) The iron-based sintered alloy having excellent strength and toughness according to (1), wherein the base comprises a mixed structure of martensite, austenite, and pearlite; (3) Fe powder;
The method for producing an iron-based sintered alloy having excellent strength and toughness according to the above (1) or (2), wherein the Ni powder and the Cr 3 C 2 powder are mixed, molded and sintered, (4) Fe powder, Ni Powder, Cr 3 C 2 powder and C powder are mixed, molded and sintered, and the method is characterized by (1) or (2), a method for producing an iron-based sintered alloy having excellent strength and toughness. is there.
【0006】Fe粉末にNi粉末およびCr3 C2 粉末
を混合し、成形し、焼結すると、マルテンサイト、オー
ステナイトおよびパーライトの混合組織からなる素地中
にフェライト相が島状に分散している組織を有する強度
および靱性に優れた鉄基焼結合金が得られるメカニズム
は、下記の理由によるものと考えられる。When Ni powder and Cr 3 C 2 powder are mixed with Fe powder, molded, and sintered, a structure in which a ferrite phase is dispersed in an island shape in a matrix composed of a mixed structure of martensite, austenite, and pearlite. The mechanism for obtaining an iron-based sintered alloy having excellent strength and toughness having the following is considered to be due to the following reasons.
【0007】すなわち、Fe粉末、Ni粉末およびCr
3 C2 粉末を混合し、成形し、焼結すると、焼結中に大
部分のNi、CrおよびCはFe粉末に拡散してFeを
主成分とするFe−Cr−Ni−C合金相となり、この
Fe−Cr−Ni−C合金相はマルテンサイト、オース
テナイトおよびパーライトの混合組織となって合金の素
地を形成する。しかし、Fe粉末の平均粒径が大きい
と、Fe粉末、Ni粉末およびCr3 C2 粉末からなる
混合粉末を焼結しても、大きな平均粒径を有するFe粉
末の中央部までNi、CrおよびCが十分に拡散せず、
Fe粉末の中央部はFe粉末本来の組織であるフェライ
ト相がそのまま残り、大きな粒径のFe粉末の周囲はF
e−Cr−Ni−C合金相となってマルテンサイト、オ
ーステナイトおよびパーライトに変態し素地を形成す
る。That is, Fe powder, Ni powder and Cr
When 3 C 2 powder is mixed, molded and sintered, most of the Ni, Cr and C diffuse into the Fe powder during sintering to form an Fe-Cr-Ni-C alloy phase containing Fe as a main component. The Fe-Cr-Ni-C alloy phase has a mixed structure of martensite, austenite and pearlite to form a base material of the alloy. However, when the average particle diameter of the Fe powder is large, even if the mixed powder composed of the Fe powder, the Ni powder and the Cr 3 C 2 powder is sintered, the Ni, Cr and C does not diffuse enough,
At the center of the Fe powder, the ferrite phase, which is the original structure of the Fe powder, remains as it is.
It becomes an e-Cr-Ni-C alloy phase and transforms into martensite, austenite and pearlite to form a matrix.
【0008】このようにして得られたマルテンサイト、
オーステナイトおよびパーライトの混合組織からなる素
地中にフェライト相が島状に分散している組織を有する
鉄基焼結合金は、高強度のマルテンサイト、オーステナ
イトおよびパーライトの混合組織からなる素地を有する
鉄基焼結合金に破壊が発生しても柔らかいフェライト相
で破壊の進行が阻害され、靱性が向上するものと考えら
れる。The martensite thus obtained,
An iron-based sintered alloy having a structure in which a ferrite phase is dispersed in the form of islands in a body having a mixed structure of austenite and pearlite is an iron-based sintered alloy having a base having a mixed structure of high-strength martensite, austenite and pearlite. It is considered that even if a fracture occurs in the sintered alloy, the progress of the fracture is hindered by the soft ferrite phase, and the toughness is improved.
【0009】したがって、この発明の強度および靱性に
優れた鉄基焼結合金の製造には、平均粒径の大きなFe
粉末を用いることが必要であり、さらに還元が難しいC
rをCr3 C2 中のCにより容易に還元し、Fe中へ拡
散しやすくするためにCr3C2 粉末を用いることが必
要である。この場合、C含有量を調整するためにCr 3
C2 粉末と共にC粉末を添加しても良い。Therefore, the strength and toughness of the present invention
For the production of excellent iron-based sintered alloys, Fe
It is necessary to use powder and it is difficult to reduce C
r for CrThreeCTwoEasily reduced by C in the steel and expanded into Fe
Cr for easy dispersalThreeCTwoIt is necessary to use powder
It is important. In this case, to adjust the C content, Three
CTwoC powder may be added together with the powder.
【0010】前述のごとく、この発明の強度および靱性
に優れた鉄基焼結合金の製造には、平均粒径の大きなF
e粉末を用いることが必要であり、そのFe粉末の平均
粒径は30〜90μmの範囲内にあることが好ましく、
このFe粉末に対して添加するNi粉末、Cr3 C2 粉
末およびC粉末の平均粒径はそれぞれNi粉末:1〜8
μm、Cr3 C2 粉末:0.5〜15μmおよびC粉
末:1〜25μmの範囲内にあることが好ましい。As described above, in order to produce the iron-based sintered alloy having excellent strength and toughness according to the present invention, it is necessary to use F
It is necessary to use e powder, and the average particle diameter of the Fe powder is preferably in the range of 30 to 90 μm,
The average particle diameters of the Ni powder, Cr 3 C 2 powder and C powder added to the Fe powder are Ni powder: 1 to 8 respectively.
μm, Cr 3 C 2 powder: 0.5 to 15 μm and C powder: preferably 1 to 25 μm.
【0011】この発明の強度および靱性に優れた鉄基焼
結合金の製造方法を一層具体的に述べると、原料粉末と
して、Fe粉末、Ni粉末、Cr3 C2 粉末および黒鉛
粉末を用意し、これら原料粉末を金型成形時の潤滑剤で
あるステアリン酸亜鉛粉末またはエチレンビスステアラ
ミドとともにダブルコーンミキサーで混合し、プレス成
形して圧粉体を作製し、圧粉体を水素を含む窒素雰囲気
中、温度:1000〜1200℃で焼結する。焼結温度
は1110〜1150℃が一層好ましい。温度:110
0〜1150℃で焼結すると、平均粒径:30〜90μ
mを有するFe粉末の内でも粒径の大きい60μm以上
のFe粉末の中央部までNi、CrおよびCが十分に拡
散せず、靱性に富むFe粉末本来のフェライト相を維持
できる。The method for producing an iron-based sintered alloy having excellent strength and toughness according to the present invention will be described in more detail. Fe powder, Ni powder, Cr 3 C 2 powder and graphite powder are prepared as raw material powders. These raw material powders are mixed with a zinc stearate powder or ethylene bisstearamide, which is a lubricant at the time of molding, by a double cone mixer, and pressed to produce a green compact. Medium, sintering at a temperature of 1000-1200 ° C. The sintering temperature is more preferably 1110 to 1150 ° C. Temperature: 110
When sintered at 0 to 1150 ° C., the average particle size is 30 to 90 μm.
Even among the Fe powders having m, Ni, Cr and C are not sufficiently diffused to the central portion of the Fe powder having a large particle diameter of 60 μm or more, and the original ferrite phase of the tough Fe powder can be maintained.
【0012】つぎに、この発明の強度および靱性に優れ
た鉄基焼結合金の成分組成を上記のごとく限定した理由
について説明する。 (a)Cr Crは、靱性を低下させることなく強度を向上させる効
果があるが、その含有量が0.2重量%未満ではその効
果が十分でなく、一方、5重量%を越えてもそれ以上の
効果が望めない。したがって、Crの含有量は0.2〜
5重量%に定めた。Crの含有量の一層好ましい範囲は
2〜4重量%である。Next, the reason why the component composition of the iron-based sintered alloy having excellent strength and toughness of the present invention is limited as described above will be described. (A) Cr Cr has the effect of improving the strength without lowering the toughness. However, if its content is less than 0.2% by weight, its effect is not sufficient. The above effects cannot be expected. Therefore, the content of Cr is 0.2 to
It was determined to be 5% by weight. A more preferable range of the Cr content is 2 to 4% by weight.
【0013】(b)Ni Niは、Fe合金相の強度および靱性を向上させる作用
があるが、その含有量が1重量%未満ではその効果が十
分でなく、一方6重量%を越えて含有してもそれ以上の
効果が少ない。したがって、Niの含有量は1〜6重量
%に定めた。Niの含有量の一層好ましい範囲は3〜5
重量%である。(B) Ni Ni has the effect of improving the strength and toughness of the Fe alloy phase, but if its content is less than 1% by weight, its effect is not sufficient, while its content exceeds 6% by weight. Even so, there is little effect. Therefore, the content of Ni is set to 1 to 6% by weight. A more preferred range for the Ni content is 3-5.
% By weight.
【0014】(c)C Cは、強度を向上させまた硬さを向上させる作用がある
が、その含有量が0.1重量%未満では強度向上効果が
十分でなく、一方、1.0重量%を越えて含有する靱性
を低下させるので好ましくない。したがって、Cの含有
量は0.1〜1.0重量%に定めた。Cの含有量の一層
好ましい範囲は0.3〜0.8重量%である。(C) C C has the effect of improving the strength and the hardness, but if its content is less than 0.1% by weight, the effect of improving the strength is not sufficient. % Is not preferred because the toughness contained in excess of% is reduced. Therefore, the content of C is set to 0.1 to 1.0% by weight. A more preferable range of the content of C is 0.3 to 0.8% by weight.
【0015】[0015]
【発明の実施の形態】実施例1 原料粉末として、平均粒径:55μmのFe粉末、平均
粒径:5μmのNi粉末、平均粒径:10μmのCr3
C2 粉末および平均粒径:17μmのC粉末を用意し、
これら原料粉末を表1〜表2に示される配合組成となる
ように配合し、さらに金型成形時の潤滑剤であるステア
リン酸亜鉛粉末またはエチレンビスステアラミド粉末を
外掛けで0.8重量%に当たる量だけ添加し、ダブルコ
ーンミキサーで混合し、プレス成形して30mm×12
mm×6mmの寸法を有する抗折試験片形状および55
mm×10mm×10mmの寸法を有するシャルピー衝
撃試験片形状の圧粉体を作製した。なお、ステアリン酸
亜鉛粉末を潤滑剤として用いる場合は常温で、エチレン
ビスステアラミド粉末を潤滑剤として用いる場合は、混
合する粉末および金型の温度を135℃としてプレス成
形した。得られた圧粉体をN2 −5%H2 の混合雰囲気
中、温度:1150℃、20分保持の条件で焼結したの
ち、0.5℃/secの冷却速度で冷却し、表1〜表2
に示される成分組成の本発明焼結合金1〜7および比較
焼結合金1〜6からなる抗折試験片およびシャルピー衝
撃試験片を作製した。DESCRIPTION OF THE PREFERRED EMBODIMENTS Example 1 As a raw material powder, an Fe powder having an average particle size of 55 μm, a Ni powder having an average particle size of 5 μm, and a Cr 3 having an average particle size of 10 μm were used.
C 2 powder and C powder having an average particle size of 17 μm were prepared,
These raw material powders are blended so as to have a blending composition shown in Tables 1 and 2, and zinc stearate powder or ethylenebisstearamide powder which is a lubricant at the time of molding is 0.8% by weight. , And mixed with a double cone mixer, press-molded to 30 mm x 12
Form of bending test specimen having dimensions of mm × 6 mm and 55 mm
A compact having a shape of a Charpy impact test specimen having a size of mm × 10 mm × 10 mm was prepared. In addition, when zinc stearate powder was used as a lubricant, press molding was performed at room temperature, and when ethylene bisstearamide powder was used as a lubricant, the temperature of the mixed powder and the mold was set at 135 ° C. to perform press molding. The obtained compact was sintered in a mixed atmosphere of N 2 -5% H 2 at a temperature of 1150 ° C. for 20 minutes and then cooled at a cooling rate of 0.5 ° C./sec. ~ Table 2
The bending test pieces and the Charpy impact test pieces were prepared from the sintered alloys 1 to 7 of the present invention and the comparative sintered alloys 1 to 6 having the component compositions shown in FIG.
【0016】さらに比較のために、C:0.8重量%、
Mn:0.04重量%、Cr:1.03重量%、Mo:
0.92重量%、S:0.005重量%、P:0.00
4重量%、O:0.08重量%を含有し、残りがFeお
よび不可避不純物からなる従来焼結合金を用意した。こ
の従来焼結合金からなる抗折試験片およびシャルピー衝
撃試験片を作製した。For further comparison, C: 0.8% by weight,
Mn: 0.04% by weight, Cr: 1.03% by weight, Mo:
0.92% by weight, S: 0.005% by weight, P: 0.00
A conventional sintered alloy containing 4% by weight and 0.08% by weight of O and the balance of Fe and inevitable impurities was prepared. A bending test piece and a Charpy impact test piece made of this conventional sintered alloy were produced.
【0017】さらにこれら本発明焼結合金1〜7、比較
焼結合金1〜6および従来焼結合金の密度を測定してそ
の値を表3に示した後、ISO3325に基づき、支点
間距離25mmで抗折試験を行うことにより抗折力を測
定し、またJIS Z2242NI準じてノッチなしの
シャルピー衝撃試験片を用いてシャルピー衝撃を測定
し、その結果を表3に示した。Further, the densities of these sintered alloys 1 to 7 of the present invention, comparative sintered alloys 1 to 6 and conventional sintered alloys were measured and the values are shown in Table 3. Based on ISO3325, the distance between fulcrums was 25 mm. The bending force was measured by performing a bending test in Table 1. The Charpy impact was measured using a notched Charpy impact test piece according to JIS Z2242NI. The results are shown in Table 3.
【0018】この発明の強度および靱性に優れた鉄基焼
結合金の組織を一層理解しやすくするために、表1に示
される本発明焼結合金3を切断し、研磨し、金属顕微鏡
による組織写真を取り、その組織写真を図1に示した。
図2は本発明焼結合金3の金属組織の写生図である。図
1および図2において黒く見える部分は空孔3であり、
1は素地、2はフェライト相である。図1の組織写真お
よび図2金属組織の写生図から明らかなように、本発明
焼結合金3の素地はマルテンサイト、オーステナイトお
よびパーライトの混合組織からなり、素地1の中にフェ
ライト相2が島状に分散していることが分かる。In order to make it easier to understand the structure of the iron-based sintered alloy having excellent strength and toughness of the present invention, the sintered alloy 3 of the present invention shown in Table 1 was cut, polished, and examined by a metallographic microscope. A photograph was taken and a photograph of the structure is shown in FIG.
FIG. 2 is a sketch of the metal structure of the sintered alloy 3 of the present invention. In FIG. 1 and FIG.
1 is a base and 2 is a ferrite phase. As is clear from the structure photograph of FIG. 1 and the sketch of the metal structure in FIG. 2, the base material of the sintered alloy 3 of the present invention is composed of a mixed structure of martensite, austenite and pearlite. It can be seen that they are dispersed in a shape.
【0019】さらに、前記本発明焼結合金3の組織の素
地1およびフェライト相2の部分の成分含有量をEPM
Aにより測定した結果、素地1はNi、CrおよびCは
Fe粉末に拡散してFeを主成分とするFe−Cr−N
i−C合金相となり、このFe−Cr−Ni−C合金相
はマルテンサイト、オーステナイトおよびパーライトの
混合組織となっているが、この素地の中に島状に分散し
ているフェライト相2にはNi、CrおよびCがほとん
ど含まれないことを確認した。Further, the component contents of the base material 1 and the ferrite phase 2 of the structure of the sintered alloy 3 of the present invention were determined by EPM.
As a result of measurement by A, the base material 1 was Ni, Cr and C were diffused into Fe powder, and Fe—Cr—N containing Fe as a main component.
The Fe-Cr-Ni-C alloy phase has a mixed structure of martensite, austenite, and pearlite, and the ferrite phase 2 dispersed in the form of islands in the matrix has an i-C alloy phase. It was confirmed that Ni, Cr and C were hardly contained.
【0020】[0020]
【表1】 [Table 1]
【0021】[0021]
【表2】 [Table 2]
【0022】[0022]
【表3】 [Table 3]
【0023】表1〜表3に示される結果から、本発明焼
結合金1〜7と従来焼結合金を比較すると、本発明焼結
合金1〜7は従来焼結合金と比べて、抗折力および衝撃
値が優れていることが分かる。しかし、この発明の範囲
から外れている成分組成を有する比較焼結合金1〜6
は、抗折力および衝撃値のうちの少なくともいずれかが
劣ることが分かる。From the results shown in Tables 1 to 3, when the sintered alloys 1 to 7 of the present invention are compared with the conventional sintered alloys, the sintered alloys 1 to 7 of the present invention are more deflected than the conventional sintered alloys. It can be seen that the force and impact values are excellent. However, comparative sintered alloys 1 to 6 having a component composition outside the scope of the present invention.
Indicates that at least one of the bending force and the impact value is inferior.
【0024】[0024]
【発明の効果】上述のように、この発明の鉄基焼結合金
は、抗折力および衝撃値が高い値を示し、さらに強度お
よび靱性に優れ、自動車部品およびコンプレッサー部品
などの各種機械部品の材料として適しており、機械産業
の発展に大いに貢献し得るものである。As described above, the iron-based sintered alloy of the present invention exhibits high values of the transverse rupture strength and the impact value, and also has excellent strength and toughness, and is suitable for various mechanical parts such as automobile parts and compressor parts. It is suitable as a material and can greatly contribute to the development of the machinery industry.
【図1】この発明の強度および靱性に優れた鉄基焼結合
金の金属顕微鏡による組織写真である。FIG. 1 is a micrograph of a structure of an iron-based sintered alloy having excellent strength and toughness according to the present invention, taken by a metallurgical microscope.
【図2】この発明の強度および靱性に優れた鉄基焼結合
金の組織の写生図である。FIG. 2 is a sketch of the structure of an iron-based sintered alloy having excellent strength and toughness according to the present invention.
1 素地 2 フェライト相 3 空孔 1 base 2 ferrite phase 3 vacancy
Claims (4)
重量%、C:0.1〜1.0重量%を含有し、残りがF
eおよび不可避不純物からなる組成を有し、かつ素地中
にフェライト相が島状に分散している組織を有すること
を特徴とする強度および靱性に優れた鉄基焼結合金。1. Cr: 0.2 to 5% by weight, Ni: 1 to 6
% By weight, C: 0.1 to 1.0% by weight, the balance being F
An iron-based sintered alloy excellent in strength and toughness, characterized by having a composition comprising e and unavoidable impurities and having a structure in which a ferrite phase is dispersed in an island shape in a base material.
ナイトおよびパーライトの混合組織からなることを特徴
とする請求項1記載の強度および靱性に優れた鉄基焼結
合金。2. The iron-based sintered alloy having excellent strength and toughness according to claim 1, wherein the base comprises a mixed structure of martensite, austenite and pearlite.
末を混合し、成形し、焼結することを特徴とする請求項
1または2記載の強度および靱性に優れた鉄基焼結合金
の製造方法。3. The iron-based sintered alloy having excellent strength and toughness according to claim 1, wherein Fe powder, Ni powder and Cr 3 C 2 powder are mixed, molded and sintered. Production method.
よびC粉末を混合し、成形し、焼結することを特徴とす
る請求項1または2記載の強度および靱性に優れた鉄基
焼結合金の製造方法。4. The iron-based sintering excellent in strength and toughness according to claim 1, wherein Fe powder, Ni powder, Cr 3 C 2 powder and C powder are mixed, molded and sintered. Manufacturing method of bonded gold.
Priority Applications (1)
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JP12674698A JP3341675B2 (en) | 1998-04-21 | 1998-04-21 | Iron-based sintered alloy excellent in strength and toughness and method for producing the same |
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Application Number | Priority Date | Filing Date | Title |
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JP12674698A JP3341675B2 (en) | 1998-04-21 | 1998-04-21 | Iron-based sintered alloy excellent in strength and toughness and method for producing the same |
Publications (2)
Publication Number | Publication Date |
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JPH11302806A true JPH11302806A (en) | 1999-11-02 |
JP3341675B2 JP3341675B2 (en) | 2002-11-05 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1347067A1 (en) * | 2002-03-12 | 2003-09-24 | Kabushiki Kaisha Riken | Iron-based sintered alloy for use as valve seat and its production method |
-
1998
- 1998-04-21 JP JP12674698A patent/JP3341675B2/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1347067A1 (en) * | 2002-03-12 | 2003-09-24 | Kabushiki Kaisha Riken | Iron-based sintered alloy for use as valve seat and its production method |
US6802883B2 (en) | 2002-03-12 | 2004-10-12 | Kabushiki Kaisha Riken | Iron-based sintered alloy for use as valve seat and its production method |
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JP3341675B2 (en) | 2002-11-05 |
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