JPH11242318A - Method for processing transparent silver halide color photographic sensitive material and this photographic product - Google Patents

Abstract

PROBLEM TO BE SOLVED: To alleviate occurrence of residual dye stains in imaging parts and to enable satisfactory exhibitition of printer performance and further, rapid processing and low replenished processing and low fog and to sufficiently restrain increase of fog by processing the photographic sensitive material with a processing solution containing a specified compound and then, regulation a light absorbance in nonexposed parts at a specified wavelength per an amount of residual silver in a specified range. SOLUTION: The light transmitting type silver halide color photographic sensitive material is processed with the processing solution containing at least one kind of compound selected from those represented by formulae I and II or the like, and then, the light absorbance B, at 650 nm, of the nonexposed parts is regulated to <=1.0 and a ratio of the absorbance B to the residual silver amount R (mg/m<2> ) B/R is controlled as follows; 3.0×10<-4> <=B/R<=1.50×10<-3> . In formulae I and II, Q is an atomic group necessary to form an N-containing hetero ring; R1 is an H atom or a 1-6C alkyl group or the like; each of R2 and R3 is an H atom or the like; and A is an n1 -valent heterocyclic group.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for processing a transmission type silver halide color photographic material after processing and a transmission type silver halide color photographic product. A method of processing a transmissive silver halide color photographic light-sensitive material capable of obtaining a good print without affecting the image density even if the coated silver halide remains in the silver halide color photographic product) and a transmissive silver halide color About photo products.

[0002]

2. Description of the Related Art In recent years, the London Treaty has been concluded due to the movement of protecting the global environment, and the dumping of photographic processing wastewater into the ocean has been prohibited in Japan since January 1, 1996. For this reason, there has been an effort in the photographic industry to reduce photographic processing waste to the utmost. Regarding the fixing solution, studies on low waste liquid and low replenishment have been conducted as disclosed in JP-A-8-201997.

[0003] Further, with the rapid increase in minilab stores in recent years, quick service for receiving prints by developing on the spot has been emphasized as a differentiating item. For this reason, the demand for speeding up the processing is increasing, and many studies on the speedy processing are being made.

[0004] Furthermore, the sensitivity of color films is increasing due to the rapid growth in demand for films with lenses and the spread of zoom function cameras. Generally, these high-sensitivity films have a high silver iodide ratio and a large amount of coated silver, and as a result, there is a problem that the processing step for processing a large amount of these, especially the load on the desilvering performance in the desilvering step, is problematic. Have been.

[0005] The desilvering step is a step of removing silver halide and metallic silver from the photographic material into the processing solution. If the silver halide remains as unfixed silver in the photographic material, a so-called fixing failure occurs. Cheap. These fixing defects are caused by an increase in the accumulated silver concentration due to low replenishment of the processing solution or processing of a photographic material having a large amount of silver. Further, since the fixing time is shortened in terms of speeding up the processing, the possibility that the fixing is not completed is further increased.

[0006] When a fixing failure occurs in a color negative photosensitive material, a large amount of silver remains in the photosensitive material and, along with the dye, a residual color stain is generated. When such residual color stains occur, problems such as a change in the color tone of the photosensitive material and a decrease in image quality occur, causing serious problems when printing. At present, in order to create prints from negative films, minilabs and others use the negative film under standard conditions to set the level (channel setting) for each photosensitive material in advance, and use the same type of negative film for that channel. Perform using for that reason,
The finish of the negative must always be kept constant. However, if the residual color stain occurs due to such a fixing defect, the negative density changes, so that a color print of a constant quality cannot be performed. Further, the fixing failure often occurs in an uneven manner on the film, and in this case, the print quality is significantly impaired.

On the other hand, Japanese Patent Application Laid-Open No. Hei 8-29930 discloses a processing method in which most of the applied silver remains in undeveloped areas other than the image forming area in the monochrome photosensitive material. However, in the case of monochrome light-sensitive materials, the problem of residual color stain that occurs in color light-sensitive materials as described above,
The problem of producing prints of consistent quality with a printer was unlikely to occur, so it was not a particularly serious problem.

However, as described above, in the case of a color photographic material, silver halide must be completely removed from the light-sensitive material from the viewpoint of residual color stain in order to reduce and speed up the fixing process. Until now, it was indispensable, and it was difficult and problematic to achieve low replenishment and speeding up of the fixing process of the color photographic material without any problem.

[0009]

SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to reduce the occurrence of residual color stains in an image forming section, satisfactorily exhibit printer performance, and furthermore, a transmission type which can perform rapid processing and low replenishment processing. An object of the present invention is to provide a processing method of a silver halide color photographic light-sensitive material and a transmission type silver halide color photographic product.

[0010]

[Means for Solving the Problems] After processing a transmission-type silver halide color photographic light-sensitive material with a processing solution for a silver halide color photographic light-sensitive material containing at least one compound represented by the following general formulas [I] to [V], Unexposed area 650 nm based on residual silver (mg / m ² )
A method of processing a transmission-type silver halide color photographic light-sensitive material, wherein the absorbance is within the range of the following [Formula A].

[Formula A] 3.0 × 10 ⁻⁴ ≦ ｛(absorbance at 650 nm in unexposed area) /
(Amount of residual silver (mg / m ² ))｝ ≦ 1.50 × 10 ^−3, provided that absorbance at 650 nm of unexposed portion ≦ 1.0

[0012]

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[In the formula, Q represents an atomic group necessary for forming a nitrogen-containing heterocyclic ring (including a condensed 5- to 6-membered unsaturated ring), and R ₁ represents a hydrogen atom, a carbon atom Represents an alkyl group of 1 to 6 alkyl groups, a cycloalkyl group, an aryl group, a heterocyclic group (including those in which a 5- to 6-membered unsaturated ring is condensed), or an amino group. ]

[0014]

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Wherein R ₂ and R ₃ are each a hydrogen atom,
Represents an alkyl group having 1 to 6 carbon atoms, a hydroxy group, a carboxy group, an amino group, an acyl group having 1 to 3 carbon atoms, an aryl group, or an alkenyl group.

A is-(C = X) -N (R) (R '),-
_{(CH 2) n 2 - (} C = X) -N (R) (R '), -
_{(S) m 1 - (C} = X) -N (R) (R '), - (S)
m _2- (CH ₂ ) n _3- (C = X) -N (R) (R ′),
_{- (S) m 3 - (} CH 2) n 4 -N (R) (R '), -
_{(S) m 4 -N (R} ) (R '), - (NH) n 5 - (CH
_{2) m 5 - (NH)} n 6 - (C = X) -N (R) (R '), - S
-S- (C = X) -N ( R) (R '), - SZ or n ₁
Represents a valent heterocyclic residue (including a condensed 5- to 6-membered unsaturated ring). Here, R and R ′ are R
₂ and R ₃ , X represents ＸS, ＯO, or ＮＲNR ″, and Z represents a hydrogen atom, an alkali metal atom, an ammonium group, an amino group, a nitrogen-containing heterocyclic residue, an alkyl group, or —S. -BY (R ₄ ) (R ₅ ), wherein R ″ is a hydrogen atom,
Represents an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group, an aryl group, a heterocyclic residue (including a condensed 5 to 6-membered unsaturated ring) or an amino group, and n _{1 to} n ₆ And m _{1 to} m ₅ each represent an integer of 1 to 6. B has 1 carbon atom
Represents to six alkylene group, Y is -N <, = C <or represents -CH <, R ₄ and R ₅ have the same meanings as R ₂ and R _3, respectively. However R ₄ and R ₅ may each represent -B-SZ, also R ₂ and R _3, R and R ', R ₄ and R ₅ may be bonded to each other to form a ring. ]

[0017]

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[In the formula, Q ₁ represents an atom group necessary for forming a nitrogen-containing heterocyclic ring (including a condensed 5- to 6-membered unsaturated ring), R ₁₁ ′ represents a hydrogen atom, Alkali metal atoms,

[0019]

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Or an alkyl group. However, Q 'is Q ₁
Is synonymous with ]

[0021]

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[Wherein n2, n3 and n4 represent an integer of 0-5. X represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms. Y represents a hydrogen atom, an alkyl group or an acyl group.
M represents a hydrogen atom or an alkali metal atom. R ₂₁ represents an alkyl group having 1 to 5 carbon atoms or a hydrogen atom. In addition, the disulfide dimer of this compound is also included. ]

[0023]

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[Wherein Z ₁ and Z ₂ are hydrogen atoms and have 1 to 1 carbon atoms.
3 represents an alkyl group, an amino group, a carboxyl group, a sulfonic acid group or a hydroxyl group. n5, n6, n7, n8, n9
Represents an integer of 0 to 5. ] 2. The processing solution for a silver halide color photographic light-sensitive material is a fixing processing solution, and the replenishing amount of the processing solution is 900 ml / m ^2.
2. The method for processing a transmission-type silver halide color photographic light-sensitive material as described in 1 above, wherein

3. The transmissive silver halide photographic material before processing has an aspect ratio of 5% or more of the total projected area.
As described above, tabular silver halide grains having a thickness of 0.1 to 0.3 μm, wherein 50% or more of the tabular silver halide grains have a maximum silver iodide content of the phase excluding the outermost layer of 15 mol.
less than 1%, and the silver iodide content of the outermost layer is 6 mol%
And a silver halide emulsion containing at least one silver halide emulsion containing silver halide grains which are tabular silver halide grains having five or more dislocation lines per grain. 3. The method for processing a transmission-type silver halide color photographic light-sensitive material according to item 1 or 2.

4. The weight ratio of the total lipophilic photographic material / the total weight of gelatin in the transmission type silver halide photographic material before processing is 0.50 to 0.70, and the total gelatin coating amount is 1
Processing method of transmission-type silver halide color photographic material as claimed in any one of 1 to 3, characterized in that the ^{4.0g / m 2 ~18.0g / m 2} .

5. The processing solution containing the compounds represented by the general formulas [I] to [V] is at least one selected from a processing solution having a bleaching ability, a processing solution having a fixing ability, and a processing solution for stabilization. Any one of 1 to 4
The method for processing a transmissive silver halide photographic light-sensitive material described in the above item.

6. The amount of the compound represented by the general formulas [I] to [V] added to the treatment liquid is 0.000.
6. The processing method for a transmission-type silver halide photographic material as described in any one of 1 to 5, wherein the processing amount is 1 to 0.1 mol / L.

7. After processing a transmissive silver halide color photographic light-sensitive material with a processing solution for a silver halide color photographic light-sensitive material containing at least one of the compounds represented by formulas (I) to (V), Residual silver (mg
/ M ² ), wherein the absorbance of the unexposed portion at 650 nm is within the range of the above [Formula A].

That is, as a result of intensive studies, the present inventor has achieved the stabilization of unfixed silver and positively caused silver halide to remain in the light-sensitive material by the constitution of the present invention. It has succeeded in achieving low replenishment and rapid processing. Surprisingly, even if silver salts remain in the processed photographic material, it is possible to obtain a good print without any influence on transmitted light. It has been found that it is possible to simultaneously solve the above-mentioned problem of uneven fixing failure.

Until now, Japanese Patent Application Laid-Open No. HEI 9-204566 discloses a processing method for leaving a large amount of coated silver in undeveloped portions other than an image forming portion in a transmission-type silver halide monochrome photographic light-sensitive material (hereinafter referred to as a monochrome light-sensitive material). No. 8-29930. However, in the monochrome light-sensitive material, the problem of the residual color stain which occurs in the color light-sensitive material as described above and the problem of subsequently producing a print of a constant quality by a printer hardly occur, which is completely different from the present invention. .

Hereinafter, the present invention will be described in detail.

The "transmission type silver halide color photographic product" in the present invention is a transmission type color photographic product obtained by developing a transmission type silver halide color photographic light-sensitive material. This is a transmission type color photographic product used when printing a color image on photographic paper by applying light, or a transmission type color photographic product which is viewed by applying transmitted light.

The “transmissive silver halide color photographic light-sensitive material” used in the present invention refers to the following:
The above-mentioned "transmission type silver halide color photographic product", that is, a silver halide photographic material which provides a transmission type color photographic product.

The "color light-sensitive material" in the present invention is a light-sensitive material which forms an image using a dye image instead of a silver image.

The absorbance at 650 nm as referred to in the present invention refers to a spectrophotometer manufactured by Shimadzu without reference, which is obtained by cutting an unexposed portion of a processed transmissive photosensitive material to 3 × 4.5 cm, setting the film in a film holder, and without reference. It is measured by UV-160A.

The amount of silver remaining in the light-sensitive material was measured using a fluorescent X-ray analyzer manufactured by Rigaku Corporation.

In the transmission type silver halide color photographic light-sensitive material and the processing method of the transmission type silver halide color photographic light-sensitive material of the present invention, the transmission type silver halide color photographic light-sensitive material of the present invention after processing (transmission type halogenation) The silver color photographic product) has a value of {(absorbance at 650 nm of unexposed area) / (residual silver amount (mg / m ² ))} of 3.0 × 10 ^{−4 to} 1.5.
0 × 10 ^-3 , more preferably 3.5 × 10 ^{-3
−4 to} 1.00 × 10 ⁻³ . The unexposed portion 6
The absorbance at 50 nm needs to be 1.0 or less.

The compounds represented by the general formulas [I] to [V] essential for the present invention (hereinafter, also referred to as compounds of the present invention) will be described.

Specific compounds of the general formulas [I] to [V] are shown below, but the compounds of the present invention are not limited to these.

[0041]

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[0042]

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[0043]

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[0044]

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[0045]

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[0046]

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[0047]

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V-1 HO—CH ₂ CH ₂ —S—CH ₂ CH ₂ —S—CH ₂ CH ₂ —OH V-2 HOOC—CH ₂ CH ₂ —S—CH ₂ CH ₂ —S—CH ₂ CH _{2 -COOH V-3 CH 3 CH} 2 -S-CH 2 CH 2 -S-CH 2 CH 3 V-4 CH 3 -CH 2 CH 2 -S-CH 2 CH 2 -S-CH 2 CH 2 -CH _{3 V-5 NH 2 -CH 2} CH 2 -S-CH 2 CH 2 -S-CH 2 CH 2 -SO 3 H V-6 HO-CH 2 CH 2 -S-CH 2 CH 2 -S-CH 2 _{CH 2 -S-CH 2 C H} 2 -OH V-7 HO-CH 2 CH 2 CH 2 -S-CH 2 CH 2 -S-CH 2 CH 2 -OH V-8 HO-CH 2 CH 2 -S among _{-CH 2 CH 2 CH 2 -S-} CH 2 CH 2 -OH the above compound, the objective compounds preferably used from the present invention I-2, II-2 The compound represented by formula III, IV-1, IV-3, the compound of the general formula V are mentioned, is among the compounds represented by the general formula III III-
Among the compounds represented by 9, III-10, III-13, III-22, III-23 and the general formula V, V-1 and V-2 are preferably used. II is particularly preferably used.
I-10, III-13, III-23 and V-1. These compounds may be used alone or in combination of two or more. Further, in order to further exert the effects of the present invention, it is preferable to add them to two or more kinds of processing solutions. When adding to two or more types of processing solutions, different types of additives may be used.

The compound of the present invention has a sulfur atom and has a strong adsorptive power with silver halide to form a complex compound with silver halide or to promote an exchange reaction with a dye in a light-sensitive material. Even if silver is present, the dye component can be effectively removed.
Therefore, the transmitted light is not affected at all and a good print can be obtained.

In the present invention, the processing solution to which the compound of the present invention is added may be any processing solution used for processing a silver halide photographic light-sensitive material, but may be added to the latter processing solution. Preferably, a processing solution having bleaching ability,
A processing solution having a fixing ability, a processing solution having the compound of the present invention added to any of the stabilizing processing solutions or a bleaching ability,
Processing solution having a fixing ability, more preferably added to all of the stabilization processing solution, further processing solution having a fixing ability,
Most preferably, the compound of the present invention is added to any of the stabilizing treatment solutions.

When the compound of the present invention is used in a processing solution having bleaching ability, the amount of the compound of the present invention may be 0.0001 to 0.1 mol / mol from the viewpoint of the effect of the present invention and the precipitation property.
L is preferable, and 0.005 to
It is more preferably in the range of 0.07 mol / L,
Most preferably, it is in the range of 0.01 to 0.05 mol / L.

When the compound of the present invention is used in a processing solution having a fixing ability, the amount of the compound of the present invention is preferably 0.0001 to 0.1 mol from the viewpoint of the effect of the present invention and the precipitation property.
/ L, more preferably 0.001 to
It is more preferably in the range of 0.05 mol / L,
The most preferred range is 0.005 to 0.03 mol / L.

When the compound of the present invention is added to the treatment solution for stabilization, the amount of the compound of the present invention is 0.0001 to 0.1 mol / L from the viewpoint of the effect of the present invention and the precipitation property.
Is preferably in the range of 0.0005 to 0.0005.
It is more preferably in the range of 0.03 mol / L,
The most preferred range is from 0.001 to 0.01 mol / L.

Furthermore, in order to make the effect of the compound of the present invention more remarkable, the following general formula (F-1)
It is preferable that at least one of the compounds represented by (F-3) is contained. These compounds may be used in combination.

[0055]

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[Wherein A _{1 to} A ₄ represent a hydrogen atom, an alkyl group, an alkenyl group, or a pyridyl group. l represents 0 or 1. ]

[0057]

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[Wherein, Z ₄ represents an atom group necessary for forming a hydrocarbon ring or a hetero ring, X ₁ represents an aldehyde group,

[0059]

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Wherein R ₄₁ and R ₄₂ each represent a lower alkyl group, and n represents an integer of 1 to 4. ]

[0061]

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[Wherein X ₂ , X ₃ , X ₄ and X ₅ are each-
_{NR 6 O -, = N -} , - O -, - S -, - CR 61 R
_{62 -, = CR 63 -,} - CO- or -C (= NR ₆₄₎ - represents a represents _{R 60, R 61, R 62} , R 63 and R ₆₄ are each a hydrogen atom or a substituent. Z ₅ and Z ₆ represents a nonmetallic atomic group necessary for each form a 4-8 membered ring. Examples of the salt of the compound represented by formula (F-1) include inorganic salts such as hydrochloride, sulfate and nitrate, organic acid salts such as phenol salt, double or complex salts with metal salts, and hydrated salts. And internal salts.

The compound represented by the general formula (F-1) is specifically described in Beilsteins: Handbuch der.
Organischen Hemy (Beilsteins H
andbuch der Organishen Ch
emie), Volume II, Vol. 26, pp. 200-212. Among them, those soluble in water are preferred in the present invention. The following are representative examples.

[0064]

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[0065]

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[0066]

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[0067]

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[0068]

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[0069]

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[0070]

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The addition amount of the compound represented by formula (F-1) is preferably 0.1 to 20 g per liter of the treatment liquid.

In the general formula (F-2), Z ₄ represents an atom group necessary for forming a substituted or unsubstituted carbocyclic ring or a substituted or unsubstituted heterocyclic ring. Or a condensed ring, and preferably, Z ₄ is an aromatic carbon ring or a hetero ring having a substituent. The substituent of Z ₄ is an aldehyde group,
A hydroxyl group, an alkyl group (eg, methyl, ethyl, methoxyethyl, benzyl, carboxymethyl, sulfopropyl, etc.), an aralkyl group, an alkoxy group (eg, methoxy, ethoxy, methoxyethoxy, etc.), a halogen atom,
Nitro group, sulfo group, carboxy group, amino group (for example, N, N-dimethylamino, N-ethylamino, N-
Phenylamino, etc.), hydroxyalkyl group, aryl group (eg, phenyl, p-methoxyphenyl, etc.), cyano group, aryloxy group (eg, phenoxy, p-
Carboxylphenyl), acyloxy group, acylamino group, sulfonamide group, sulfamoyl group (for example, N
-Ethylsulfamoyl, N, N-dimethylsulfamoyl, etc.), carbamoyl group (for example, carbamoyl, N
-Methylcarbamoyl, N, N-tetramethylenecarbamoyl, etc.) or a sulfonyl group (for example, methanesulfonyl, ethanesulfonyl, benzenesulfonyl, p-toluenesulfonyl, etc.) is preferred.

The carbon ring represented by Z ₄ is preferably a benzene ring, and the hetero ring represented by Z ₄ is preferably a 5- or 6-membered heterocyclic ring. For example, the 5-membered ring may be thiophene, pyrrole, Furan, thiazole,
Examples thereof include imidazole, pyrazole, succinimide, triazole, and tetrazole. Examples of the six-membered ring include pyridine, pyrimidine, triazine, and thiadiazine.

Examples of the condensed ring include naphthalene, benzofuran, indole, thionaphthalene, benzimidazole, benzotriazole, quinoline and the like.

Preferred examples of the compound represented by formula (F-2) are shown below.

[0076]

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Exemplified compounds (F-2-1) to (F-2-7)
7) is obtained by inserting various substituents into 1 to 6 in the above formula as follows.

[0078]

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[0079]

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[0080]

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[0081]

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[0082]

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Among the specific examples of the compound represented by the formula (F-2), a more preferred compound is (F-2)
-2), (F-2-3), (F-2-4), (F-2-
6), (F-2-23), (F-2-24), (F-2
-52), and most preferably (F-2-
3).

The compound represented by formula (F-2) can be easily obtained as a commercial product.

The addition amount of the compound represented by the formula (F-2) is preferably 0.05 to 20 g, more preferably 0.1 to 15 g, particularly preferably 0.5 to 15 g per liter of the stabilizing solution. The range is from 10 to 10 g.

In formula (F-3), at least one of Z ₅ and Z ₆ is a nitrogen atom or X _{2 in} formula (F-3).
And X ₃ or a nitrogen atom, X ₄ and X ₅ are preferably non-metallic atoms necessary to form a ring capable of forming an aromatic ring as an aromatic ring or a tautomer. Z ₅ is a group of nonmetallic atoms necessary to form a nitrogen atom, X ₂ and X ₃ together with X ₂ and X _{3 in the} general formula (F-3) to form a ring capable of forming an aromatic ring as an aromatic ring or a tautomer. And Z ₆ is more preferably a group of non-metallic atoms necessary for forming a non-aromatic ring together with a nitrogen atom, X ₄ and X ₅ . As the aromatic ring or tautomer formed by Z ₅ , a five-membered ring is preferable as a ring on which an aromatic ring can be formally formed, and more preferably a pyrazole ring, a triazole ring (1,2,4-triazole ring and 1 , 2,3-triazole ring) and urazole ring. As the aromatic ring formed by Z ₆ , a pyrrolidine ring, a piperidine ring, a morpholine ring and a piperazine ring are preferable.

The following are specific examples of the compound represented by formula (F-3).

[0088]

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[0089]

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[0090]

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[0091]

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[0092]

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[0093]

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In the present invention, in the light-sensitive material after processing, an amount of silver in which the absorbance at 650 nm of the unexposed portion relative to the amount of residual silver (mg / m ² ) falls within the range of the following [formula A] is defined as unfixed silver. Will remain.

[Formula A] 3.0 × 10 ⁻⁴ ≦ Δ (absorbance at 650 nm in unexposed area) /
(Amount of residual silver (mg / m ² ))｝ ≦ 1.50 × 10 ⁻³ where absorbance at 650 nm of unexposed area ≦ 1.0 Silver halide, silver chlorobromide and silver halide are applied to the photosensitive material to be processed. , Silver bromide, silver iodobromide, silver iodochloride and the like. In order to exert the effect of the present invention, the content of silver iodide in the photographic light-sensitive material is 1% or more of the total silver halide.
% Of the light-sensitive material is preferred. Further, it is more preferable that the light-sensitive material has a silver iodide content of 2% to 10% of the total silver halide. Further, a magnetic recording layer may be provided.

Preferred specific processing steps of the processing method according to the present invention are shown below.

(1) Color development → bleaching → fixing → washing (2) Color developing → bleaching → fixing → washing → stable (3) Color developing → bleaching → fixing → stable (4) Color developing → bleaching → fixing → first Stable → second stable (5) color development → bleach → bleach-fix → washing (6) color development → bleach → bleach-fix → washing → stable (7) color development → bleach → bleach-fix → stable (8) color development → bleaching → Bleaching and fixing → First stable → Second stable (9) Color development → Bleaching → Bleaching and fixing → Fixing → Washing → Stable (10) Color developing → Bleaching → Bleaching and fixing → Fixing → First stable →
Second stability (11) Color development → bleach-fix → stable (12) Color development → bleach → first fix → second fix → stable (13) Color development → bleach → fix → first stable → second stable →
Third stable Among these steps, (3), (4), (7), (1)
0), (12) and (13) are preferable, and particularly (3),
(4) and (13) are preferred.

In the present invention, the replenishment rate of the processing step having a fixing ability is 900 ml / m ² or less, since the amount of accumulated silver increases due to the reduction in replenishment and residual silver is easily generated in the photographic material. It is preferable for exhibiting the effect.

Furthermore, in the present invention, it is preferable to introduce the processing solution pumped out of the stabilization tank into the processing tank immediately before the stabilization step, not only from the viewpoint of reducing the replenishment amount but also from the viewpoint of improving image storability.

The processing time of the step having a fixing ability is preferably 10 seconds or more and 4 minutes or less, from the viewpoint that unfixed silver is likely to be generated due to rapid processing, in order to achieve the effect of the present invention more favorably. It is preferably from one second to one minute.

In carrying out the present invention, the color developing step, the step having a bleaching ability, the step having a fixing ability, and the stabilizing step may be constituted according to a usual method. For example, the color developing step is described in JP-A-5-224373, the step having bleaching ability is described in JP-A-9-90579, the step having fixing ability, and the stabilizing step is described in JP-A-8-201997. No.

The tabular silver halide (hereinafter also referred to as “tabular grain”) in the present invention refers to a circle having two parallel principal planes and a diameter equivalent to the circle of the principal plane (the circle having the principal plane and the projected area). Is the ratio of the distance between the main planes (i.e., the thickness of the particles), that is, particles having an aspect ratio of 5 or more.

In the rapid development processing, it is preferable that 50% or more of the total projected area of all the tabular grains of the present invention are tabular grains having an aspect ratio of 5 or more, and more preferably 8 or more.

The diameter of the tabular grains of the present invention is preferably from 0.3 to 10 μm, more preferably from 0.5 to 5.0 μm, even more preferably from 0.5 to 5.0 μm in order to obtain a desired sensitivity.
2.0 μm. The particle thickness is preferably 0.05 to
0.8 μm, more preferably 0.1 to 0.3 μm
It is. It has been found that the surface area range according to the diameter and the particle thickness is suitable for rapid development processing.

The measurement of the particle diameter and the particle thickness in the present invention can be obtained by the method described in US Pat. No. 4,434,226.

The size distribution of the tabular grains of the present invention is obtained by dividing the coefficient of variation of the circle-converted diameter of the main plane (the diameter of a circle having the same projected area as the main plane) by dividing the standard deviation of the diameter distribution by the average diameter. ) Is preferably 30% or less, and 20%
It is more preferred that:

The intergranular distribution of the silver iodide content of the silver halide grains of the present invention is obtained by dividing the coefficient of variation of the silver iodide content (the standard deviation of the silver iodide content grain distribution by the average silver iodide content). Is preferably 30% or less, more preferably 20% or less.

Although the tabular grains of the present invention have at least two or more phases having different halogen compositions inside the grains, the layer having the largest silver iodide content except for the outermost layer has a silver iodide content of 3%. It is from mol% to less than 15 mol%, preferably from 3 mol% to less than 10 mol%, more preferably from 5 mol% to less than 8 mol%. Further, the volume fraction of the phase in the particles is preferably 30% or more and 90% or less, more preferably 30% or more and 60% or less.

The outermost layer of the tabular grains of the present invention preferably has a silver iodide content of 6 mol% or more and a solid solution limit or less. If it is less than 6 mol%, the storage stability of the adsorption of the sensitizing dye is undesirably reduced.

The outermost layer in the present invention is a region including the surface area of the particles, but it is not always necessary to completely cover the inner phase. Further, the outermost layer in the present invention refers to a region having a thickness of at least 10 atomic layers or more.

In the present invention, the silver iodide content on the grain surface refers to a value measured by the XPS method or a value measured by the ISS method, and either may be used.

The surface silver iodide content according to the XPS method of the present invention can be determined as follows. The sample was cooled to −115 ° C. or less in an ultra-high vacuum of 1 × 10 ⁻⁸ torr or less, and irradiated with MgKα as a probe X-ray at an X-ray source voltage of 15 kV and an X-ray source current of 40 mA, and Ag3d5 / 2 and Br3d. , I3
It measures about d3 / 2 electron. The integrated intensity of the measured peak is corrected by a sensitivity factor, and the halide composition on the surface is determined from the intensity ratio.

The structure relating to the halogen composition in the grains is represented by X
It can be examined by a line diffraction method, a composition analysis method using EMPA, or the like.

The maximum silver iodide-containing phase excluding the outermost layer in the present invention does not include a high iodine localization region generated by an operation described later performed for forming dislocation lines.

As a method for producing tabular grains, methods known in the art can be appropriately combined. For example, Japanese Patent Application Laid-Open Nos. 61-6643, 61-146305, and 6
2-157024, 62-18556, 63-
No. 92942, No. 63-151618, No. 63-16
No. 3451, No. 63-220238, No. 63-311
A known method such as that described in Japanese Patent No. 244/244 can be referred to. For example, a double jet method, a double jet method, a so-called controlled double jet method which maintains a constant pAg in a liquid phase in which silver halide is formed, which is one type of the double jet method, and a soluble silver halide having a different composition, A triple jet method, which is independently added, can also be used. A forward mixing method can be used, and a method of forming grains in the presence of excess silver ions (a so-called reverse mixing method) can also be used. If necessary, a silver halide solvent can be used. Silver halide solvents often used include ammonia, thioethers and thioureas. Regarding thioethers, U.S. Patent Nos. 3,271,157 and 3,790,387
No. 3,574,628 and the like. The mixing method is not particularly limited, and a neutral method using no ammonia, an ammonia method, an acidic method, or the like can be used. However, in order to reduce fog of silver halide grains, it is preferable to use a pH (hydrogen) method. The logarithmic value of the reciprocal of the ion concentration) is 5.5 or less, more preferably 4.5 or less.

The silver halide grains of the present invention contain iodide ions. In this case, the method of adding iodide ions in the grain growth is not particularly limited, and they may be added as an ion solution such as potassium iodide. Further, for example, it may be added as silver iodide fine particles. Grain formation using silver halide fine grains is described in JP-A-1-183417 and 1-18.
The grains may be grown using only silver halide fine particles in the same manner as in the grains disclosed in JP-A Nos. 3644 and 1-183645, but at least one of the halogen elements is supplied by the silver halide fine particles. I just need. In this case, the iodide ions are preferably supplied by silver halide fine particles. As claimed in Japanese Patent Application No. 3-218608, two or more silver halide fine grains are used for grain growth, at least one of which is one.
It may be composed of only different kinds of halogen elements.

An emulsion containing silver halide grains grown in the presence of silver halide grains having a lower solubility than the growing silver halide grains as described in the claims of JP-A-2-16737. It is particularly preferable to use silver iodide as the silver halide grain having a small solubility product.

The dislocation of tabular grains is described, for example, in J. Am. F. Ha
Milton, Photo. Sci. Eng. , 11
(1967), 57; Shiozawa, Jou.
ofPhoto. Sci. Japan, 35 (197
2) Observation can be performed by the method described in 213, that is, a direct method using a transmission electron microscope at a low temperature. That is, silver halide grains taken out so as not to apply enough pressure from the emulsion to generate dislocations on the grains are placed on a mesh for an electron microscope to prevent damage (printout, etc.) by an electron beam. Observation is performed by a transmission method while the sample is cooled. At this time, the thicker the particle, the more difficult it is for the electron beam to pass therethrough.
The use of an electron microscope (200 kV) for a thickness of 5 μm allows more clear observation. From the grain photograph obtained by such a method, the position and number of dislocations for each grain when viewed from a direction perpendicular to the main plane can be determined.

The position of the dislocation of the grains of the present invention does not necessarily have to be a specific location, but preferably exists at the fringe portion of the tabular grains. It may be present both in the fringe portion of the particle and inside the particle.

The fringe portion of the tabular grains referred to in the present invention refers to the outer periphery of the tabular grains. More specifically, the fringe portion is defined by a perpendicular line dropped from the center of gravity of the tabular grain projected surface as viewed from the main plane to each side of the grains. Outside of 50% of the length of the perpendicular (side), preferably outside of 70%, more preferably 8
It means a region outside 0%.

The number of dislocations in the tabular grains of the present invention is preferably such that grains containing 5 or more dislocations account for 50% or more of the projected area of all silver halide grains in the emulsion.
It is particularly preferred that it is 0% or more. Further, the number of dislocations is more preferably 10 or more. In the present invention, the presence of dislocation lines has an advantageous effect on high sensitivity, pressure resistance, and processing stability. When the number of dislocation lines is less than 5, the effect is small, and the number of dislocation lines is preferably large and there is no upper limit.

In the case where dislocation lines exist between the inside of the grain and the fringe portion, it is preferable that five or more dislocation lines exist inside the grain, and it is more preferable that there are five or more dislocation lines both inside the fringe portion and inside the grain.

The method for introducing dislocation lines according to the present invention is not particularly limited, but a method of adding an aqueous solution of an iodide ion such as potassium iodide and a water-soluble silver salt solution by double jet at the position where the dislocation is to be introduced, or A method of adding silver halide fine particles, a method of adding only an iodine ion solution,
The method can be carried out by a method using an iodide ion releasing agent as described in No. 11781. A method of adding an aqueous iodide ion solution and a water-soluble silver salt solution by a double jet,
A method of adding silver iodide fine particles and a method of using an iodide ion releasing agent are preferable, and a method of using silver iodide fine particles is more preferable. The aqueous solution of iodide ions is preferably an aqueous solution of an alkali iodide, and the aqueous solution of a water-soluble silver salt is preferably an aqueous solution of silver nitrate.

It is preferable that the dislocation is introduced after the formation of the maximum silver iodide-containing phase inside the grain, and more preferably after the formation of the phase and before the formation of the adjacent phase. Further, in relation to the position of the whole grain, it is preferable that the silver is introduced in an amount corresponding to 50 to 95% of the silver amount of the whole grain, and it is more preferable that the silver is introduced in a proportion of less than 60 to 80%.

The lipophilic photographic material in the present invention refers to a substantially water-insoluble material, and specifically includes a so-called high-boiling solvent and the same as the high-boiling solvent to be added to a photographic light-sensitive material. At the same time or at the same time. For example, an emulsified dispersion to be added to a hydrophilic colloid binder such as an ultraviolet absorber, an anti-turbidity agent, an antioxidant, an anti-stain agent, and an oil-soluble coupler or a DIR coupler is also included.

As the organic high boiling point compound, those having a boiling point at normal pressure of 180 ° C. or more and less than 350 ° C. are generally used.

In the present invention, any known method can be used to add a lipophilic photographic material. Typical methods include, for example, one or more of the above-mentioned organic high-boiling compounds and the like. Is dissolved with a photographic additive as described below, if necessary, and, if necessary, methyl acetate, ethyl acetate, propyl acetate, butyl acetate, butyl propionate, cyclohexanol, dimethylene glycol. Dissolve in low boiling solvents such as monoacetate, nitromethane, carbon tetrachloride, chloroform, cyclohexanetetrahydrofuran, methyl alcohol, ethyl alcohol, propyl alcohol, fluorinated alcohol, acetonitrile, dimethylformamide, dioxane, acetone, methyl ethyl ketone, methyl isobutyl ketone ( The boiling solvent may be used alone or as a mixture.) Anionic surfactants such as alkylbenzenesulfonic acid and alkylnaphthalenesulfonic acid and / or nonionic surfactants such as sorbitan sesquioleate and sorbitan monolaurate. The mixture is mixed with an aqueous solution containing a hydrophilic colloid substance such as gelatin containing an emulsifying agent, and emulsified and dispersed by a high-speed rotary mixer, a colloid mill or an ultrasonic dispersing device, and the obtained dispersion is applied to a coating liquid containing a hydrophilic colloid substance. It may be added and coated on a support or on a silver halide emulsion layer or the like coated on the support. The compound capable of forming a certain kind of oil droplet may be dissolved, for example, in the above-mentioned low-boiling organic solvent, and the solution may be directly added to a coating liquid containing a hydrophilic colloid substance. The low-boiling organic solvent used at this time evaporates after coating and drying, and hardly exists in the binder.

The oil-soluble couplers include a yellow coupler, a magenta coupler, and a cyan coupler which form a color image by color development.

As the couplers that can be used in the present invention, the compounds described in the following patents are representatively included.

Among these, benzoylacetoanilide type, pivaloylacetoanilide type, and yellow coupler are exemplified.
Alternatively, it is a 2-equivalent yellow coupler in which the carbon atom at the coupling position is substituted with a substituent capable of leaving during the coupling reaction (a so-called split-off group). As the magenta coupler, 5-pyrazolone,
A pyrazolotriazole-based, pyrazolino-benzimidazole-based, indazolone-based, or 2-equivalent magenta coupler having a split-off group.

Further, the cyan coupler is a phenol-based, naphthol-based or 2-equivalent cyan coupler having a split-off group.

Further, as a preferable example of the coupler contained in the oil droplet in the present invention, a so-called Weiss coupler which is oil-soluble and does not form a colored dye by reacting with an oxidized form of the developing agent is also mentioned.

The lipophilic photographic material in the non-photosensitive layer contains a color turbidity preventive. Examples of the color turbidity inhibitor include compounds described in Japanese Patent Application No. 4-19048, which react with an oxidized form of a color developing agent and do not impart image density.
Specifically, hydroquinone-based compounds (Japanese Patent Application No. 4-19 / 1992)
No. 048 H-1 to H-18), pyrogallol-based compounds, catechol-based compounds (Japanese Patent Application No. 4-19084, P1 to P1)
6), sulfonylamino compounds (Japanese Patent Application No. 4-1904)
No. 8 S-1 to S-19), coupling type compound (CP
-1 to CP-23) and a hydrazine compound (HZ-1)
To HZ-14).

In the present invention, the weight ratio of total lipophilic photographic material / gelatin is preferably 0.50 to 0.70, more preferably 0.50 to 0.65. The preferred gelatin coating amount is 14.0 to 18.0 g / m ² , and more preferably 15.0 to 17.0 g / m ² .

The non-photosensitive layer according to the invention is a layer containing no photosensitive silver halide, but may contain a non-photosensitive silver halide. The non-light-sensitive intermediate layer located between the light-sensitive layers may be the same color-sensitive layer or a different color-sensitive layer, and the weight ratio of at least one lipophilic photographic material / gelatin weight of the non-light-sensitive intermediate layer Is preferably from 0.30 to 0.90, more preferably from 0.35 to 0.70. In the present invention, the weight ratio of lipophilic photographic material / gelatin in the non-light-sensitive intermediate layer is 0.1%.
It is preferably from 30 to 0.90, and more preferably from 0.
It is 35 or more and 0.70 or less. If it is more than 0.90, the adhesion of the coating film will decrease and sweating will occur, and if it is less than 0.30, the effect of improving the pressure resistance of the present invention will be small.

In the present invention, the photosensitive layer and the non-photosensitive layer adjacent to each other may be above or below the photosensitive layer as viewed from the support, and all the parent layers of the adjacent photosensitive layer and non-photosensitive layer may be used. Oil-based photographic material weight / gelatin weight ratio difference between 0 and 0.5
It is preferably 0 or less, more preferably 0 or more and 0.40 or less. If it is larger than 0.50, the adhesiveness of the coating film is inferior and the stability over time is also reduced. Further, all the layers adjacent to each other may be photosensitive layers, non-photosensitive layers, or a photosensitive layer and a non-photosensitive layer. The difference in gelatin weight ratio is preferably 0 or more and 0.60 or less, more preferably 0 or more and 0.50 or less.

The silver halide color light-sensitive material of the present invention has a good balance with the coated amount of gelatin even though the weight ratio of lipophilic photographic material / gelatin is higher than that of conventional light-sensitive materials, Lipophilic photographic material weight /
An excellent effect is exhibited due to a small difference in gelatin weight ratio.

The photographic constituent layer of the light-sensitive material of the present invention preferably has a calcium content of 50 ppm or less, particularly preferably 4 ppm or less.
It is preferably at most 0 ppm, more preferably at most 30 ppm. If the calcium content is too high, the film will peel off or devitrify during rapid development, making it impractical.

The calcium in the gelatin forming the photographic constituent layer is derived from the raw materials. To obtain the gelatin having the calcium content of the present invention, the selection of the raw materials, the selection of the production conditions, the ion exchange treatment, etc. May be appropriately combined.

In the ion exchange treatment, gelatin may be extracted from raw materials such as beef bone and pig skin, and then ion exchanged using an ion exchange resin (for example, IRA type manufactured by Rohm and Haas Company).

The calcium ion content after the ion-exchange treatment may be determined according to the method described in the sixth edition of the photographic gelatin test method (abbreviation: Bagii method) established by the Joint Committee for Gelatin Test Methods.

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EXAMPLES Hereinafter, the present invention will be described in detail with reference to examples, but embodiments of the present invention are not limited thereto.

Example 1 (Preparation of photosensitive material) A seed crystal emulsion was prepared as follows.

JP-B-58-58288, 58-58
No. 289, a silver nitrate aqueous solution (1.161 mol) was added to the following solution A1 adjusted to 35 ° C.
And a mixed aqueous solution of potassium bromide and potassium iodide (potassium iodide 2 mol%) while maintaining the silver potential (measured with a silver ion selective electrode using a saturated silver-silver chloride electrode as a reference electrode) at 0 mV. For 2 minutes to form nuclei. Subsequently, the temperature of the solution was raised to 60 ° C. over a period of 60 minutes, adjusted to pH 5.0 with an aqueous sodium carbonate solution, and then mixed with an aqueous solution of silver nitrate (5.902 mol) and potassium bromide and potassium iodide. A mixed aqueous solution (2 mol% of potassium iodide) was added over 42 minutes by a double jet method while keeping the silver potential at 9 mV. After the addition was completed, the temperature was lowered to 40 ° C., and desalting and washing were immediately performed using a normal flocculation method.

The resulting seed crystal emulsion had an average sphere-equivalent diameter of 0.24 μm, an average aspect ratio of 4.8, and a maximum side ratio of 1.0% or more of 90% or more of the total projected area of silver halide grains.
~ 2.0 hexagonal tabular grains. This emulsion is referred to as seed emulsion-1.

[Solution A1] Ossein gelatin 24.2 g Potassium bromide 10.8 g HO (CH ₂ CH ₂ O) _m {CH (CH ₃ ) CH ₂ O} _19.8 (CH ₂ CH ₂ O) _n H (m + n = 9.77) (10% ethanol solution) 6.78 ml 10% nitric acid 114 ml H ₂ O 9657 ml Preparation of silver iodide fine grain emulsion SMC-1 6.0% by weight gelatin aqueous solution containing 0.06 mol of potassium iodide While stirring 5 liters vigorously, 7.06
2 liters of an aqueous silver nitrate solution and 2 liters of a 7.06 mol aqueous potassium iodide solution were added over 10 minutes. During this time, the pH was controlled at 2.0 using nitric acid, and the temperature was controlled at 40 ° C. After the particles are prepared, the pH is adjusted using an aqueous sodium carbonate solution.
Was adjusted to 5.0. The average particle size of the obtained silver iodide fine particles was 0.05 μm. This emulsion is designated as SMC-1.

Preparation of Emulsion Em-1 0.178 moles of seed crystal emulsion-1 and HO (CH ₂ CH ₂
O) _m {CH (CH ₃ ) CH ₂ O} _19.8 (CH ₂ CH ₂ O) _n
H (m + n = 9.77) in 10% ethanol solution 0.5
4.5% by weight of an aqueous inert gelatin solution 70
0 ml at 75 ° C., pAg 8.9, pH 5.0.
Then, particles were formed by the simultaneous mixing method with vigorous stirring according to the following procedure.

1) 2.1 mol silver nitrate aqueous solution and 0.19
5 mol of SMC-1 and an aqueous solution of potassium bromide were added to pA
g was maintained at 8.9 and the pH was maintained at 5.0.

2) Subsequently, a 1.028 mol aqueous solution of silver nitrate, 0.032 mol of SMC-1 and an aqueous solution of potassium bromide were added while maintaining the pAg at 8.9 and the pH at 5.0.

Each solution was added at an optimum rate throughout the particle formation so as to prevent the formation of new nuclei and the Ostwald ripening between particles from proceeding. After completion of the addition, the resultant was subjected to a water washing treatment at 40 ° C. using a normal flocculation method, and then gelatin was added and redispersed to adjust the pAg to 8.1 and the pH to 5.8.

The obtained emulsion had a particle size (cubic 1 of the same volume).
This emulsion was composed of tabular grains having a side length of 0.65 μm and an average aspect ratio of 7.2 and a halogen composition shown in Table 7 below. When the surface silver iodide content was measured by the method described in this specification, the surface silver iodide content was 4.5.
Mole%.

Sensitizing dyes SD-5 and S were added to the above emulsion Em-1.
D-6 and SD-7 were added, and sodium thiosulfate, chloroauric acid, potassium thiocyanate, and selenium sensitizer b were further added.
-1 was added, and chemical sensitization was performed according to a conventional method so as to optimize the fog-sensitivity relationship.

After completion of the chemical sensitization, a stabilizer ST-1 was added to each emulsion.
And an antifoggant AF-1. The amount of ST-1 added was 1 g per mol of silver halide, and the amount of AF-1 was 15 mg per mol of silver halide.

Thus, a chemically sensitized emulsion Em-A corresponding to Em-1 was prepared.

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<< Preparation of Multilayer Color Photographic Material Sample >> On a triacetylcellulose film support provided with an undercoat layer, each layer having the following composition was sequentially formed from the support side to form a multilayer color photographic material sample 101 Was prepared. In the fifth, tenth and fourteenth layers, the emulsion Em-
A was used.

Unless otherwise specified, the amount added is the number of grams per 1 m ² . Further, silver halide and colloidal silver are shown in terms of silver, and sensitizing dyes are shown in moles per mole of silver.

First layer: Antihalation layer Black colloidal silver 0.16 Ultraviolet absorber (UV-1) 0.20 High boiling organic solvent (Oil-1) 0.07 Gelatin 1.53 Second layer: Intermediate layer Antifouling agent (SC-1) 0.06 High-boiling organic solvent (Oil-2) 0.08 Gelatin 0.80 Third layer: low-sensitivity red-sensitive layer Silver iodobromide emulsion (average particle size 0.38 μm, iodine Silver iodide bromide emulsion (average grain size: 0.27 μm, silver iodide content: 2.0 mol%) 0.18 Sensitizing dye (SD-1) 8 × 10 ^-4 sensitizing dye (SD-2) 1.9 × 10 ^-4 sensitizing dye (SD-3) 1.9 × 10 ^-4 sensitizing dye (SD-4) 1.0 × 10 ^-4 Cyan coupler (C-1) 0.56 Colored cyan coupler (CC-1) 0.021 DIR compound (D-1) 0.025 Boiling point solvent (Oil-1) 0.49 Gelatin 1.14 Fourth layer: middle-sensitivity red-sensitive layer Silver iodobromide emulsion (average particle size 0.52 μm, silver iodide content 8.0 mol%) 0.89 Silver iodobromide emulsion (average grain size 0.38 μm, silver iodide content 8.0 mol%) 0.22 sensitizing dye (SD-1) 2.3 × 10 ^-4 sensitizing dye (SD-2) 1.2 × 10 ^-4 sensitizing dye (SD-3) 1.6 × 10 ^-4 cyan coupler (C-1) 0.45 colored cyan coupler (CC-1) 0.038 DIR compound (D-1) 0.017 High boiling point solvent (Oil-1) 0.39 Gelatin 1.01 Fifth layer: Highly sensitive red-sensitive layer Emulsion Em-A 1.27 Sensitizing dye (SD-1) 1.3 × 10 ^-4 increase sensitive dye (SD-2) 1.3 × 10 -4 sensitizing dye (SD-3) 1.6 × 10 -4 cyan coupler (C-2) 0.20 colored Uncoupler (CC-1) 0.034 DIR compound (D-3) 0.001 High boiling point solvent (Oil-1) 0.37 Gelatin 1.10 6th layer: Intermediate layer Color stain inhibitor (SC-1) 0.075 High boiling point solvent (Oil-2) 0.095 Gelatin 1.00 Seventh layer: Intermediate layer Gelatin 0.45 Eighth layer: Low-sensitivity green-sensitive layer Silver iodobromide emulsion (average particle size 0.38 μm, (Silver iodide content: 8.0 mol%) 0.68 Silver iodobromide emulsion (average grain size: 0.27 μm, silver iodide content: 2.0 mol%) 0.18 Sensitizing dye (SD-4) 7 0.4 × 10 ^-4 sensitizing dye (SD-5) 6.6 × 10 ^-4 Magenta coupler (M-1) 0.19 Magenta coupler (M-2) 0.49 Colored magenta coupler (CM-1) 0 .12 High boiling solvent (Oil-2) 0.31 Gelatin 1.89 Ninth layer: Neutral Green-sensitive layer Silver iodobromide emulsion (average grain size 0.59 .mu.m, a silver iodide content of 8.0 mol%) 0.76 Sensitizing dye (SD-6) 1.5 × 10 -4 Sensitizing dye (SD -7) 1.6 × 10 ^-4 sensitizing dye (SD-8) 1.5 × 10 ^-4 magenta coupler (M-1) 0.043 Magenta coupler (M-2) 0.10 Colored magenta coupler (CM) -2) 0.039 DIR compound (D-2) 0.021 DIR compound (D-3) 0.002 High boiling point solvent (Oil-2) 0.17 Gelatin 0.76 10th layer: Highly sensitive green-sensitive layer Emulsion Em-A 1.46 Magenta coupler (M-1) 0.08 Magenta coupler (M-2) 0.133 Colored magenta coupler (CM-2) 0.014 High boiling solvent (Oil-1) 0.15 High Boiling point solvent (Oil-2) 0.22 Gelatin 1.0 8 11th layer: Yellow filter layer Yellow colloidal silver 0.07 Color stain inhibitor (SC-1) 0.18 Formalin scavenger (HS-1) 0.14 High boiling solvent (Oil-2) 0.11 Gelatin 0. 73 th twelfth layer: middle layer formalin scavenger (HS-1) 0.18 gelatin 0.60 thirteenth layer: low-sensitivity blue-sensitive layer silver iodobromide emulsion (average grain size 0.59 μm, silver iodide content 8. 0 mol%) 0.075 Silver iodobromide emulsion (average grain size 0.38 μm, silver iodide content 3.0 mol%) 0.15 Silver iodobromide emulsion (average grain size 0.27 μm, silver iodide) 0.20 Sensitizing dye (SD-9) 2.1 × 10 ^-4 Sensitizing dye (SD-10) 2.8 × 10 ^-4 Yellow coupler (Y-1) 89 DIR compound (D-4) 0.008 High boiling point solvent (Oil-2) 0.27 gelatin 1.51 14th layer: high-sensitivity blue-sensitive layer Emulsion Em-A 0.95 sensitizing dye (SD-9) 7.3 × 10 ^-4 sensitizing dye (SD-10) 2.8 × 10 ^-4 Yellow coupler (Y-1) 0.16 High boiling solvent (Oil-2) 0.093 Gelatin 0.80 15th layer: 1st protective layer Silver iodobromide emulsion (average particle size 0.05 μm, iodine 0.30 UV absorber (UV-1) 0.094 UV absorber (UV-2) 0.10 Formalin scavenger (HS-1) 0.38 High boiling point solvent (Oil) -1) 0.05 gelatin 1.44 16th layer: 2nd protective layer Alkali-soluble matting agent PM-1 (average particle size 2 μm) 0.15 polymethyl methacrylate (average particle size 3 μm) 0.04 Slip agent (WAX) -1) 0.02 gelatin 0.55 In addition to the serial composition, coating aids SU-1, SU-
2, SU-3, dispersing aid SU-4, viscosity modifier V-1,
Stabilizer ST-1, dyes AI-1, AI-2, antifoggant AF-1, two kinds of polyvinylpyrrolidone (AF-2) having a weight average molecular weight of 10,000 and a weight average molecular weight of 100,000, Membrane agents H-1, H-2 and preservative DI
-1 was added. The amount of DI-1 added was 9.4 mg / m ^2.
Met. The structure of the compound used in the above sample is shown below.

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(Automatic Developing Machine) A color negative film processor CL-KP-50QA (manufactured by Konica Corporation) modified so as to double the transport speed was used.

(Processing Step) Processing Time Processing Temperature Replenishment Color Development 97 seconds 41 ° C. 520 ml / m ² Bleaching 22 seconds 38 ° C. 100 ml / m ² Fixing-1 22 seconds 38 ° C. Fixing-2 22 seconds 38 ° C. 550 ml / m ² Stable-1 10 seconds 38 ° C Stable-2 10 seconds 38 ° C Stable-3 10 seconds 38 ° C 860 ml / m ² Drying 40 seconds 65 ° C (Formulation of processing solution) Color developer: solution used per liter Replenisher Sodium sulfite 5. 0 g 8.0 g Potassium carbonate 45.0 g 45.0 g Diethylenetriaminepentasodium pentasodium 4.0 g 4.0 g Hydroxylamine sulfate 3.0 g 5.0 g Carbium bromide 1.5 g 0.3 g 2-methylbenzimidazole 0.1 g 0 .15 g polyvinylpyrrolidone K-17 2.0 g 2.0 g potassium iodide 2.0 mg-4-amino-3-methyl -N-Ethyl-N- (β-hydroxyethyl) aniline sulfate 10.2 g 11.5 g pH 10.30 10.65 Add water to make each 1 L, and adjust the pH with potassium hydroxide or 50% sulfuric acid did.

Bleach solution: per liter Use solution Replenisher solution 1,3-Propylenediaminetetraacetic acid ferric ammonium 133 g 190 g 1,3-Propylenediaminetetraacetic acid 5 g 7 g Ammonium bromide 60 g 90 g Maleic acid 40 g 60 g Imidazole 10 g 15 g pH 3 0.02.5 Each was added with water to make 1 L, and the pH was adjusted using ammonia water or 50% sulfuric acid.

Fixing solution: per liter Working solution = replenishing solution Ammonium thiosulfate 180 g Sodium thiosulfate 20 g Sodium sulfite 18 g Disodium ethylenediaminetetraacetate 2 g Compound shown in Table 1 0.01 mol pH 7.5 The pH was adjusted using aqueous ammonia or 50% sulfuric acid.

Stabilizing solution: per liter Working solution = replenisher m-hydroxybenzaldehyde (Exemplified compound F-2-3) 1.5 g Disodium ethylenediaminetetraacetate 0.6 g β-cyclodextrin 0.2 g Potassium carbonate 0.2 g pH 8.0 Water was added to make up to 1 L, and the pH was adjusted using potassium hydroxide or 50% sulfuric acid.

Each processing solution was put into the automatic developing machine described above,
The Konica Corporation LV400 color negative film was processed until the triple replenisher in the fixing processing tank (10 L) was renewed to prepare a processing liquid in a converged state. The multilayer color photographic light-sensitive material sample 101 prepared as described above was subjected to under, normal,
After the scene was photographed under the over condition, it was processed with the processing liquid in the converged state created as described above. Sample No. was used as a reference negative (completely desilvered negative). After processing the first negative, the negative was treated again with a fixing solution at 38 ° C. for 90 seconds, and then washed with running water for 3 minutes and dried. Using this reference negative, the level of the negative channel of the printer processor of the NPS-858JA system manufactured by Konica Corporation was set. In other words, a print of the same quality can be performed from a negative having the same processing level as that of the reference negative. Using these channels, prints were prepared from the light-sensitive materials processed with the respective processing liquids in a convergent state. If the print levels do not match, perform the level correction and then correct the YMC
The concentrations are shown in Table 1. Generally, it is considered that there is no problem if the level correction is within 10%.

In addition, the residual silver amount of the negative after the processing was 650 n
The transmission density at m was also measured.

Further, the photographic material after each processing was re-fixed, re-washed and re-dried as in the case of the reference negative, and the difference in RMS granularity (ΔRMS) before and after the re-processing was measured. RMS
The granularity is determined by measuring the density of the portion to be measured of the sample by an opening scanning area of 750 μm.
Scan with a microdensitometer of m ² (slit width 10 μm, slit length 75 μm), and measure the standard deviation 1000
The doubled value was determined, and Comparative Sample No. The values are shown as relative values with 1 being 1.00. The smaller the ΔRMS, the better the performance.

Table 1 shows the above results.

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[Table 1]

Sample No. In Nos. 1 to 3, the amount of liquid circulating in the fixing tank of the automatic developing machine was changed to adjust the amount of silver remaining in the photosensitive material (Sample 1 = 5 L / min, Sample 2 = 2.5 L / mi).
n, sample 3 = 10 L / min). Everything else is 5L /
min.

As is clear from the results shown in Table 1, the light-sensitive material having the relationship between the amount of residual silver and the absorbance at 650 nm within the range of the present invention (the constitution of the first and seventh aspects of the present invention) is the same as the standard negative. Even if the channel is used, a certain print quality can be obtained, and there is no problem in the granularity even when compared with the reference negative. As described above, according to the present invention, it is possible to produce a photosensitive material that can satisfy print quality even in a state in which desilvering is not completely completed (there is silver remaining in the impression). Configuration).

Example 2 Sample No. 1 of Example 1 In Examples 1 and 7, an experiment was performed in the same manner as in Example 1 except that the replenishment amount of the fixing solution at the time of preparing the astringent solution was changed as shown in Table 2, and a print was prepared to correct the print. Further, ΔRMS was also measured, and Comparative Sample No. 1-1-1 was represented by a relative value with 1.00. The results are summarized in Table 2.

[0181]

[Table 2]

As is evident from the results in Table 2, the effect of the present invention is remarkably exhibited when the replenishment rate of the fixing solution is 900 ml / m ² or less (the structure of the invention described in claim 2).

Example 3 Additives were added to the processing solution at the addition concentrations shown in Table 3,
The same experiment as in Example 1 was performed, and the print level was evaluated in the same manner as in Example 1 except that the processing time was changed as described below. Further, the prepared materials were left under conditions of 65 ° C. and a relative humidity of 80% for 7 days, after which similar prints were prepared and the print level was evaluated.

Table 3 summarizes the results.

For print correction, only the C density was described. In addition, a sample subjected to wedge exposure by an ordinary method was prepared, and the Dmax-Red density was measured when the sample was processed in the same manner. Here, N1, N2, N3, and N4 in the table indicate a color developing solution, a bleaching solution, a fixing solution, and a stabilizing solution, respectively.
The amount of addition was shown in parentheses immediately below the compound name.

[0186] Table 3 summarizes the above results.

[0187]

[Table 3]

As is clear from the results in Table 3, the photographic processing solution to which the compound of the present invention is added is a processing solution having a bleaching ability or a processing solution having a fixing ability.
Alternatively, the effect of the present invention is more remarkably exhibited by using a processing solution for stabilization (the configuration of the invention described in claim 5).

Example 4 Sample No. 3 of Example 3 The same experiment was performed except that the concentration of the additive to be added to the bleaching solution was changed to the amount shown in Table 4 and the replenishment amount of the bleaching solution was changed to 90 ml / m ² in 3-3. (M, C concentrations). Also,
It was visually evaluated whether or not streaks had occurred on the unexposed portion of the negative, and a print was prepared so as to have a density of 0.8 and confirmed on the print.

4... No streak is observed on the negative or on the print 3... Slightly confirmed on the negative but not problematic on the print 2... Confirmed on the negative and slightly on the paper 1... It was clearly confirmed on the negative, and also clearly on the paper.

Table 4 shows the above results.

[0192]

[Table 4]

As is evident from the results in Table 4, the amount of the compound of the present invention is 0.0001 mol / L to 0.1 mol / L from the viewpoint of print correction and the occurrence of streaks.
mol / L (the structure of the invention according to claim 6), and more preferably 0.005 mol / L to 0.1 mol / L.
The range is more preferably from 07 mol / L, most preferably from 0.01 mol / L to 0.05 mol / L.
Range.

Example 5 Sample No. 3 of Example 3 The same experiment was performed except that the concentration of the additive added to the fixing solution was changed to the amount shown in Table 5 and the replenishment amount of the fixing solution was changed to 450 ml / m ² in 3-4, and print correction (Y, (M, C concentrations). In addition, evaluation was made on the occurrence of streaks on the negative of the unexposed portion in the same manner.

Table 5 summarizes the results.

[0196]

[Table 5]

As is evident from the results in Table 5, the amount of the compound of the present invention was 0.0001 mol / L to 0.1 m from the viewpoints of print correction and occurrence of streaks.
ol / L (the structure of the invention according to claim 6), and more preferably 0.001 mol / L to 0.01 mol / L.
The range is more preferably 5 mol / L, most preferably 0.005 mol / L to 0.03 mol / L.
Range.

Example 6 Sample No. 3 of Example 3 The same experiment was performed except that the concentration of the additive to be added to the stabilizer was changed to the amount shown in Table 6 and the replenishment amount of the stabilizer was changed to 800 ml / m ² in 3-5. (M, C concentrations). In addition, evaluation was made on the occurrence of streaks on the negative of the unexposed portion in the same manner.

The results are summarized in Table 6.

[0200]

[Table 6]

As is clear from the results in Table 6, the amount of the compound of the present invention is 0.0001 mol / L to 0.1 mol from the viewpoints of print correction and the occurrence of streaking.
It is preferably in the range of 1 / L (the configuration of the invention according to claim 6), and more preferably 0.0005 mol / L to 0.0.
The range is more preferably 3 mol / L, most preferably 0.001 mol / L to 0.01 mol / L.
Range.

Example 7 Emulsions Em-2 to Em-6 used in place of the emulsion Em-1 of the light-sensitive material used in Example 1 were prepared by the following method.

Preparation of Emulsion Em-2 In the preparation of Emulsion Em-1, after the completion of the step 2).
Em-2 was prepared in the same manner as Em-1, except that 004 mol of SMC-1 was added and aged for 16 minutes.

The obtained emulsion had a particle size (cubic 1 of the same volume).
The emulsion was a tabular grain having a halogen composition shown in Table 7 having a side length of 0.65 μm and an average aspect ratio of 7.0. The surface silver iodide content was 12.5 mol%.

Preparation of Emulsion Em-3 0.178 mol of seed crystal emulsion-1 and HO (CH ₂ CH ₂
O) m ｛CH (CH ₃ ) CH ₂ O｝ 19.8 (CH ₂ CH ₂
O) 700 ml of a 4.5% by weight aqueous solution of inert gelatin containing 0.5 ml of a 10% ethanol solution of nH (m + n = 9.77) was kept at 75 ° C., the pAg was 8.9 and the pH was 5.0. After adjustment, particles were formed by the simultaneous mixing method with vigorous stirring according to the following procedure.

1) 2.1 mol silver nitrate aqueous solution and 0.19
5 mol of SMC-1 and an aqueous solution of potassium bromide were added to pA
g was maintained at 8.9 and the pH was maintained at 5.0.

2) Subsequently, the solution was cooled to 60 ° C.
Was adjusted to 9.8. Then, 0.071 mol of SMC
-1 was added and aging was performed for 2 minutes (introduction of dislocation lines).

3) 0.959 mol silver nitrate aqueous solution and 0.1 mol
030 mol of SMC-1 and an aqueous solution of potassium bromide,
The pAg was added while maintaining the pH at 9.8 and the pH at 5.0.

Each solution was added at an optimum rate throughout the particle formation so as to prevent formation of new nuclei and Ostwald ripening between particles. After completion of the addition, the resultant was subjected to a water washing treatment at 40 ° C. using a normal flocculation method, and gelatin was added to redisperse the mixture. The pAg was adjusted to 8.1 and the pH was adjusted to 5.5.

The obtained emulsion had a particle size (cubic 1 of the same volume).
The emulsion was a tabular grain having a halogen composition shown in Table 7 having a side length of 0.65 μm and an average aspect ratio of 7.2. When this emulsion was observed with an electron microscope, five or more dislocation lines were observed both in the fringe portion and in the inside of the grain in 60% or more of the total projected area of the grain in the emulsion. The surface silver iodide content was 6.3 mol%.

Preparation of Emulsion Em-4 Em-3 was prepared except that the amount of silver nitrate added in step 2) was 0.91 mol and the amount of SMC-1 was 0.069 mol in the preparation of emulsion Em-3. Emulsion Em-4 was prepared in the same manner as described above.

The resulting emulsion had a particle size (cubic 1 of the same volume).
This emulsion was composed of tabular grains having a side length of 0.65 μm and an average aspect ratio of 6.5 and having a halogen composition shown in Table 7. When this emulsion was observed with an electron microscope, five or more dislocation lines were observed both in the fringe portion and in the inside of the grain in 60% or more of the total projected area of the grain in the emulsion. The surface silver iodide content was 11.5 mol%.

Preparation of Emulsion Em-5 0.178 mol of seed crystal emulsion-1 and polyisoprene
4.5% by weight containing 0.5 ml of a 10% ethanol solution of polyethylene oxydisuccinate sodium salt
Of inert gelatin aqueous solution at 75 ° C.
After adjusting the Ag to 8.9 and the pH to 5.0, particles were formed by the simultaneous mixing method with vigorous stirring by the following procedure.

1) 0.692 mol of silver nitrate aqueous solution and 0.1 mol
297 moles of SMC-1 and potassium bromide aqueous solution
The pAg was added while keeping the pH at 8.9 and the pH at 5.0.

2) Subsequently, a 2.295 mol aqueous solution of silver nitrate, 0.071 mol of SMC-1 and an aqueous solution of potassium bromide were added while maintaining the pAg at 8.9 and the pH at 5.0.

3) After completion of the step 2), 0.004 mol of SMC-1 was added and the mixture was aged for 15 minutes.

Each solution was added at an optimum rate throughout the particle formation so as to prevent the formation of new nuclei and the Ostwald ripening between particles from proceeding. After the above step 3), after performing a water washing treatment at 40 ° C. using a normal flocculation method,
Gelatin was added for redispersion, and the pAg was adjusted to 8.1 and the pH was adjusted to 6.0.

The emulsion obtained had a particle size (cubic 1 of the same volume).
This emulsion was composed of tabular grains having a halogen composition shown in Table 7 having a side length of 0.65 μm and an average aspect ratio of 4.1. Observation of this emulsion with an electron microscope revealed that there were no grains having dislocation lines. The surface silver iodide content is 1
1.7 mol%.

Preparation of Emulsion Em-6 Em-6 described in Examples of JP-A-7-92594
In accordance with the production method of Comparative Example 4, Comparative Emulsion Em-6 was prepared.

Emulsions Em-2 to-
Table 7 shows the content of Em-6, including Em-1 produced in Example 1.

[0221]

[Table 7]

1) The silver iodide content (mol%) of each phase is shown. X indicates a dislocation line introduction position.

2) The aspect ratio at 50% of the total projected area of the silver halide grains in each emulsion.

3) The mark → indicates that the iodine composition was continuously changed in the formulation.

To each of the above emulsions Em-2 to Em-6, sensitizing dyes SD-5, SD-6 and SD-7 were added, and sodium thiosulfate, chloroauric acid, potassium thiocyanate and selenium sensitizer b were added. -1 was added, and chemical sensitization was performed according to a conventional method so as to optimize the fog-sensitivity relationship.

After completion of the chemical sensitization, a stabilizer ST-1 was added to each emulsion.
And an antifoggant AF-1. The amount of ST-1 was 1 g per mol of silver halide, and the amount of AF-1 was 15 mg per mol of silver halide.

The emulsion Em-1 was prepared as described above.
In the same manner as in the case where the chemically sensitized emulsion Em-A was prepared from the above, chemically sensitized emulsions Em-B to Em-F corresponding to the emulsions Em-2 to Em-6 were prepared.

The fifth and first samples 101 of the sample 101 used in the first embodiment were used.
Samples 102 to 106 were prepared by replacing the emulsion Em-A of the 0th and 14th layers with the emulsions Em-BF.

The sample No. of Example 1 was used. The sample prepared as described above was processed under the same processing conditions except that the temperature of the fixing solution was changed to 35 ° C. using the fixing solution used in 7, and the print performance of the negative sample after processing was evaluated. did. Also, ΔR
MS was also measured and shown as a relative value with Comparative Sample 7-1 being 1.00.

Table 8 shows the results.

[0231]

[Table 8]

From the results shown in Table 8, it was found that the silver halide photographic light-sensitive material had an aspect ratio of 5 or more in 50% or more of the pre-projected area.
A tabular silver halide having a thickness of 0.1 μm or more and 0.3 μm or less, wherein 50% or more of the tabular silver halide has a maximum silver iodide content of less than 15 mol% of the phase excluding the outermost layer. Wherein the outermost layer has a silver iodide content of at least 6 mol% and contains at least one silver halide emulsion having at least five dislocation lines per grain (the invention according to claim 3). It is apparent that the effect of the present invention can be further exerted by the above configuration.

Example 8 In the sample 101 of Example 1, the high boiling solvent O
The amounts of il-1 and Oil-2 were increased at the same ratio, and the ratio of total lipophilic photographic material weight / total gelatin weight (O / G ratio) in the light-sensitive material was as shown in Table 9, and A light-sensitive material was prepared so that the total amount of gelatin applied was as shown in Table 9. Thereafter, the sample No. of Example 1 was used. Using the fixing solution prepared in No. 7, processing was performed under the same processing conditions except that the circulation amount of the fixing solution was changed to 3 L / min, and the sample prepared as described above was processed. Was evaluated for print performance. Further, ΔRMS was also measured, and Comparative Sample 8 was measured.
The relative value was set to 1.00 when -1 was set to 1.00.

The results are shown in the table.

[0235]

[Table 9]

As is clear from the results in Table 9, the weight ratio of total lipophilic photographic material / weight of total gelatin in the silver halide photographic light-sensitive material was 0.50 or more and 0.70 or less, and the total gelatin coating amount was effect of the present invention by 14.0 g / m ² or more 18.0 g / m ² or less (the structure of the invention according to claim 4) can be exhibited more effectively.

As described above, according to the present invention, even if the silver halide applied to the light-sensitive material remains in the light-sensitive material, no residual color stains or streaks are generated in the image, and good print quality is obtained without deteriorating the image quality. It can be seen that it becomes possible to obtain

[0238]

According to the present invention, the occurrence of residual color stain in the image forming portion can be reduced, and the printer performance can be sufficiently exhibited.
Furthermore, a processing method of a transmission type silver halide color photographic light-sensitive material capable of rapid processing and low replenishment processing, and a transmission type silver halide color photographic product could be provided.

──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. ⁶ Identification code FI G03C 7/00 510 G03C 7/00 510 7/44 7/44

Claims (7)

[Claims] 1. A transmission type silver halide color photographic light-sensitive material is treated with a processing solution for a silver halide color photographic light-sensitive material containing at least one compound represented by the following general formulas [I] to [V]. , The amount of silver remaining in the photosensitive material (mg /
A process for processing a transmissive silver halide color photographic light-sensitive material, wherein the absorbance at 650 nm of the unexposed portion with respect to m ² ) is within the range of the following [formula A]. [Formula A] 3.0 × 10 ⁻⁴ ≦ ｛(absorbance at 650 nm in unexposed area) /
(Residual silver amount (mg / m ² ))｝ ≦ 1.50 × 10 ⁻³ where absorbance at 650 nm of unexposed portion ≦ 1.0 [In the formula, Q represents an atomic group necessary for forming a nitrogen-containing heterocyclic ring (including a condensed 5- to 6-membered unsaturated ring), and R ₁ represents a hydrogen atom, a carbon atom number of 1 to 1. 6 alkyl groups, cycloalkyl groups, aryl groups, heterocyclic groups (5 to
A 6-membered unsaturated ring is condensed) or an amino group. [Chemical formula 2] [Wherein, R ₂ and R ₃ each represent a hydrogen atom and a carbon atom 1
Represents an alkyl group, a hydroxy group, a carboxy group, an amino group, an acyl group having 1 to 3 carbon atoms, an aryl group, or an alkenyl group. A is-(C = X) -N (R)
(R '), - (CH 2) n 2 - (C = X) -N (R)
(R '), - (S ) m 1 - (C = X) -N (R)
(R '), - (S ) m 2 - (CH 2) n 3 - (C = X) -
N (R) (R ') , - (S) m 3 - (CH 2) n 4 -N
(R) (R '), - (S) m 4 -N (R) (R'), -
_{(NH) n 5 - (CH} 2) m 5 - (NH) n 6 - (C = X)
-N (R) (R '), -SS- (C = X) -N (R)
(R ′), —SZ, or n ₁ -valent heterocyclic residue (including a condensed 5- to 6-membered unsaturated ring). Here, R and R 'are the same as R ₂ and R ₃ , respectively, and X is =
S, ＯO, or ＮＲNR ″, Z represents a hydrogen atom, an alkali metal atom, an ammonium group, an amino group, a nitrogen-containing heterocyclic residue, an alkyl group, or —S—B—Y (R ₄ ) (R ₅ )
R ″ represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group, an aryl group, a heterocyclic residue (5
A 6 to 6-membered unsaturated ring is condensed) or an amino group, and n _{1 to} n ₆ and m _{1 to} m ₅ each represent an integer of 1 to 6. B represents the number 1-6 alkylene group with a carbon, Y is -N <, = C <or represents -CH <, R ₄ and R ₅ have the same meanings as R ₂ and R _3, respectively. Where R ₄ and R
₅ may each represent -B-SZ, also R ₂ and R _3, R and R ', R ₄ and R ₅ may be bonded to each other to form a ring. [Chemical formula 3] [In the formula, Q ₁ represents an atomic group necessary for forming a nitrogen-containing heterocyclic ring (including a condensed 5- to 6-membered unsaturated ring), and R ₁₁ ′ represents a hydrogen atom, an alkali metal atom. , Or an alkyl group. However, Q 'has the same meaning as that of Q _1. [Chemical formula 5] [In the formula, n2, n3, and n4 represent an integer of 0 to 5. X represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms. Y represents a hydrogen atom, an alkyl group or an acyl group. M represents a hydrogen atom or an alkali metal atom. R ₂₁ represents an alkyl group having 1 to 5 carbon atoms or a hydrogen atom. In addition, the disulfide dimer of this compound is also included. [Formula 6] [In the formula, Z ₁ and Z ₂ represent a hydrogen atom, an alkyl group having 1 to 3 carbon atoms, an amino group, a carboxyl group, a sulfonic acid group or a hydroxyl group. n5, n6, n7, n8, and n9 represent an integer of 0 to 5. ] 2. The processing solution for a silver halide color photographic light-sensitive material is a fixing processing solution, and the replenishment amount of the processing solution is 900.
^{2. The} method for processing a transmission-type silver halide color photographic light-sensitive material according to claim 1, wherein the amount is not more than ml / m < ² >. 3. The transmission type silver halide photographic material before processing is tabular silver halide grains having an aspect ratio of 5 or more and a thickness of 0.1 to 0.3 μm in 50% or more of the total projected area. And at least 50% of the tabular silver halide grains are
The maximum silver iodide content of the phase excluding the outermost layer is 15 mol%
Silver halide emulsion containing silver halide grains, which are tabular silver halide grains having a silver iodide content of 6 mol% or more in the outermost layer and having 5 or more dislocation lines per grain. 3. The method according to claim 1, wherein at least one layer contains at least one of the following. 4. The weight ratio of the total lipophilic photographic material to the total gelatin in the transmissive silver halide light-sensitive material before processing is 0.
13. 50 to 0.70, and the total gelatin coverage is 14.
Processing method of transmission-type silver halide color photographic material according to claim 1, characterized in that the ^{0g / m 2 ~18.0g / m 2} . 5. A processing solution containing a compound represented by any one of the general formulas [I] to [V], wherein the processing solution has at least one selected from a processing solution having a bleaching ability, a processing solution having a fixing ability, and a processing solution for stabilization. 5. The processing method for a transmission-type silver halide photographic material according to claim 1, wherein: 6. The amount of the compound represented by the general formulas [I] to [V] added to the treatment liquid is 0.000.
The amount is 1 to 0.1 mol / L.
6. The method for processing a transmission-type silver halide photographic material as described in any one of items 1 to 5. 7. A transmission type silver halide color photographic light-sensitive material is treated with a processing solution for a silver halide color photographic light-sensitive material containing at least one of the compounds represented by formulas [I] to [V]. , The amount of silver remaining in the photosensitive material (mg /
A transmission-type silver halide color photographic product, wherein the absorbance at 650 nm of the unexposed portion with respect to m ² ) is within the range of the above [Formula A].