JPH11197877A - Flux cored wire for hard build-up welding - Google Patents

Flux cored wire for hard build-up welding

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Publication number
JPH11197877A
JPH11197877A JP895898A JP895898A JPH11197877A JP H11197877 A JPH11197877 A JP H11197877A JP 895898 A JP895898 A JP 895898A JP 895898 A JP895898 A JP 895898A JP H11197877 A JPH11197877 A JP H11197877A
Authority
JP
Japan
Prior art keywords
flux
welding
deposited metal
hardness
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP895898A
Other languages
Japanese (ja)
Other versions
JP3548414B2 (en
Inventor
Hiroyuki Takeda
裕之 武田
Yasuo Murai
康生 村井
Kenji Saito
賢司 斉藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Priority to JP00895898A priority Critical patent/JP3548414B2/en
Priority to AU12174/99A priority patent/AU709342B1/en
Publication of JPH11197877A publication Critical patent/JPH11197877A/en
Application granted granted Critical
Publication of JP3548414B2 publication Critical patent/JP3548414B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To allow the member to have superior toughness and wear resistance by applying a flux cored wire to the working part of the member that receives heavy impact and that requires wear resistance. SOLUTION: This flux cored wire is one with flux packed inside the outer skin of an iron-based metal. In this case, the ratio of the components in the entire wire is designed to be as follows, by weight: 0.5<C<=1.5%, 0.6-2.1% Si, 0.6-1.8% Mn, 2.5-7.5% Cr, 0.1<=W<1.5%, 0.1<=V<1.5%, 1.0-8.0% Mo, and 0.2<B<=0.8%.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、硬化肉盛溶接用の
フラックス入りワイヤに関し、特に岩石等の破砕に用い
るコーンクラッシャのマントルライナあるいはコーンケ
ーブライナ、更にはジョークラッシャのジョープレート
等の如く、重衝撃を受け且つ耐摩耗性の要求される部材
の作用部に適用することにより、それら部材に優れた靭
性と耐摩耗性を与えることのできる硬化肉盛溶接用のフ
ラックス入りワイヤに関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a flux cored wire for hardfacing welding, and more particularly to a mantle liner or a cone cable liner of a cone crusher used for crushing rocks and the like, and a jaw plate of a jaw crusher. The present invention relates to a flux-cored wire for hardfacing welding, which is capable of imparting excellent toughness and abrasion resistance to a member subjected to heavy impact and requiring wear resistance by applying the same to an action portion of the member. .

【0002】[0002]

【従来の技術】製鉄・製鋼設備や土木建設機械などの各
種部品の耐摩耗性改善策あるいは摩耗部の補修手段とし
て、硬化肉盛溶接法が広く活用されている。中でもコー
ンクラッシャやジョークラッシャに代表される破砕機や
パワーショベル等の建設機械のシャベル先端部の如く、
高レベルの耐摩耗性と耐衝撃性が求められる部位を改質
する場合、本体に強靭な鋼材を使用し、耐摩耗性が求め
られる部位に高硬度の金属を肉盛溶接する方法がしばし
ば採用される。
2. Description of the Related Art The hardfacing welding method is widely used as a measure for improving the wear resistance of various parts such as iron and steel making facilities and civil engineering construction machines, or as a means for repairing worn parts. Above all, like the shovel tip of construction machines such as crushers and power shovels represented by cone crushers and jaw crushers,
When modifying parts where high levels of wear resistance and impact resistance are required, a method is often used in which a strong steel material is used for the body and a high hardness metal is overlaid on the parts where wear resistance is required. Is done.

【0003】こうした硬化肉盛溶接に用いられる溶接材
料としては、従来より被覆アーク溶接棒が汎用されてき
たが、溶接施工の高機能化、省力化、高性能化等の観点
から、最近ではシールドガスとして炭酸ガスを用いた自
動もしくは半自動溶接法が採用される様になってきてい
る。自動乃至半自動溶接に用いられる主な溶接材料はソ
リッドワイヤとフラックス入りワイヤであるが、ソリッ
ドワイヤを用いる方法では、ワイヤ成分そのものを高硬
度の金属素材としなければならないため、ワイヤ製造時
の伸線加工などが極めて困難であり、細径のワイヤ状に
するのが非常に難しい。
[0003] As a welding material used for such hardfacing welding, a coated arc welding rod has been widely used in the past. However, recently, from the viewpoints of higher welding performance, labor saving, and higher performance, shielded welding rods have been used. An automatic or semi-automatic welding method using carbon dioxide as a gas has been adopted. The main welding materials used for automatic or semi-automatic welding are solid wires and flux-cored wires.However, in the method using solid wires, the wire components themselves must be made of a high-hardness metal material. Processing is extremely difficult, and it is very difficult to form a thin wire.

【0004】これに対しフラックス入りワイヤであれ
ば、例えば軟鋼など伸線加工性の良好な鋼材をフープ材
として使用し、その内部に各種合金元素を粉末状にして
内包することにより肉盛溶接金属の成分を容易に調整す
ることができ、優れた伸線加工性の下で硬質の肉盛溶接
金属を与えるワイヤを生産性よく製造することができ
る。しかも必要に応じて、内包するフラックス成分中に
スラグ形成剤や脱酸剤、アーク安定剤などを含有させる
ことによって溶接作業性も改善することができるので、
好ましい硬化肉盛溶接法として推奨される。この様なフ
ラックス入りワイヤの例としては、例えば特開平2−2
41693号(高Cr系フラックス入りワイヤ)等に開
示があり、またJIS Z 3326には、各種フラッ
クス入りワイヤを用いた溶着金属の化学成分が規定され
ている。
On the other hand, in the case of a flux-cored wire, for example, a steel material having good drawability such as mild steel is used as a hoop material, and various alloying elements are contained in a powdery state in the hoop material, thereby forming a weld overlay metal. Can be easily adjusted, and a wire that gives a hard build-up weld metal under excellent drawability can be manufactured with high productivity. Moreover, if necessary, the welding workability can be improved by including a slag forming agent, a deoxidizing agent, an arc stabilizer, etc. in the contained flux component.
Recommended as the preferred hardfacing welding method. An example of such a flux-cored wire is disclosed in, for example,
No. 4,1693 (high-Cr flux-cored wire) and the like, and JIS Z 3326 defines the chemical components of the deposited metal using various flux-cored wires.

【0005】上記の様な用途に用いられる硬化肉盛溶接
材料のうち代表的なものは、マルテンサイト系と高Cr
鉄系の肉盛溶接材料であるが、マルテンサイト系の肉盛
溶接材料では、溶着金属の内部に高硬度の炭化物が含ま
れないため、一般に高Cr鉄系溶接材料を用いた場合に
比べて硬化肉盛溶接金属の耐摩耗性が不十分であり、満
足のいく摩耗寿命が得られ難い。一方高Cr鉄系溶接材
料は、高硬度の炭化物等を相当量含んでいるためマルテ
ンサイト系溶接材料に比べると、特に激しい土砂摩耗な
どに対する耐摩耗性には優れている反面、耐摩耗性と引
き替えに溶着金属の伸びや靭性が乏しくなって割れを生
じ易くなる傾向があり、硬化肉盛部が使用中に欠けや剥
離を生じて使用し得なくなることがあり、破砕機械等本
体の損傷を招く恐れも生じてくる。こうした欠けや剥離
は、高Cr鉄系肉盛溶着金属の耐割れ性不足が最大の原
因と考えられる。
[0005] Among the hardfacing welding materials used for the above applications, typical ones are martensitic and high Cr.
Although it is an iron-based build-up welding material, the martensite-based build-up welding material does not contain high-hardness carbide inside the deposited metal, so it is generally compared to the case of using a high-Cr iron-based welding material. The wear resistance of the hardfacing weld metal is insufficient, and it is difficult to obtain a satisfactory wear life. On the other hand, high-Cr iron-based welding consumables contain a considerable amount of high-hardness carbide, etc., and are therefore superior to martensite-based welding consumables, particularly in terms of wear resistance to severe earth and sand wear. In exchange, there is a tendency for the weld metal to have poor elongation and toughness and tend to crack, and the hardfacing part may become chipped or peeled during use, making it unusable. There is also a fear of inviting. It is considered that such chipping or peeling is mainly caused by insufficient cracking resistance of the high Cr iron-based overlay welding metal.

【0006】即ち硬化肉盛溶接部に発生する割れは、当
該摩耗部品が稼働中に受ける応力によって進展し、つい
には肉盛溶着金属の欠落や剥離を生じ、耐用寿命を却っ
て短くするのである。従って、特に激しい衝撃に曝され
る摩耗部材については、耐摩耗性を確保するための前提
として、耐割れ性の改善が強く望まれている。
That is, the cracks generated in the hardfacing welded portion are developed by the stress applied to the wear part during operation, and eventually, the build-up deposited metal is dropped or peeled, thereby shortening the service life. Therefore, for wear members that are particularly exposed to severe impact, improvement of crack resistance is strongly desired as a precondition for ensuring wear resistance.

【0007】[0007]

【発明が解決しようとする課題】本発明は上記の様な事
情に着目してなされたものであって、その目的は、高硬
度で優れた耐摩耗性を有し、しかも優れた耐割れ性を示
す肉盛溶着金属を与える硬化肉盛溶接用のフラックス入
りワイヤを提供しようとするものである。
SUMMARY OF THE INVENTION The present invention has been made in view of the above circumstances, and has as its object to have high hardness, excellent wear resistance, and excellent crack resistance. It is an object of the present invention to provide a flux-cored wire for hardfacing welding, which gives a build-up deposited metal having the following characteristics.

【0008】[0008]

【課題を解決するための手段】上記課題を解決すること
のできた本発明に係る硬化肉盛溶接用フラックス入りワ
イヤとは、鉄基金属外皮内にフラックスが充填された硬
化肉盛溶接用のフラックス入りワイヤであって、該ワイ
ヤ全量中に占める比率が C :0.5%超1.5%以下、 Si:0.6〜2.1%、 Mn:0.6〜1.8%、 Cr:2.5〜7.5%、 W :0.1%以上1.5%未満、 V :0.1%以上1.5%未満、 Mo:1.0〜8.0%、 B :0.2%超0.8%以下、 であるところに特徴を有している。
The flux-cored wire for hardfacing welding according to the present invention, which can solve the above-mentioned problems, is a flux for hardfacing welding in which a flux is filled in an iron-based metal sheath. In a cored wire, the ratio of the total wire amount to C: more than 0.5% and 1.5% or less, Si: 0.6 to 2.1%, Mn: 0.6 to 1.8%, Cr : 2.5 to 7.5%, W: 0.1% to less than 1.5%, V: 0.1% to less than 1.5%, Mo: 1.0 to 8.0%, B: 0 It is characterized by being more than 0.2% and 0.8% or less.

【0009】上記フラックス入りワイヤ中に含まれる元
素の中でも特に重要なのはMoであり、そのより好まし
い含有量は、2.0%以上、更に好ましくは3.0%以
上、最も好ましくは4.0%超である。
Among the elements contained in the flux-cored wire, Mo is particularly important, and its content is more preferably 2.0% or more, further preferably 3.0% or more, and most preferably 4.0%. It is super.

【0010】また上記フラックス入りワイヤにおいて、
金属外皮内に充填されるフラックス成分は、肉盛溶接に
より金属外皮と溶融一体化して溶着金属を構成する前記
各元素のみからなるものであっても勿論構わないが、そ
れらの元素に加えて、溶接作業性などの向上を期して、
溶着金属成分中には取り込まれない成分、例えばアーク
安定剤、スラグ形成剤、ガス発生剤等を、金属外皮内に
充填させることも有効である。
In the above flux-cored wire,
The flux component to be filled in the metal shell may be composed of only each of the above-described elements constituting the weld metal by being fused and integrated with the metal shell by overlay welding, but in addition to those elements, In order to improve welding workability,
It is also effective to fill the metal outer shell with components that are not incorporated into the deposited metal component, such as an arc stabilizer, a slag forming agent, and a gas generating agent.

【0011】[0011]

【発明の実施の形態】本発明者らは、前述した様な従来
技術に指摘される問題点の改良を期して、特に、硬化肉
盛溶接された溶着金属の硬度と耐割れ性に影響を及ぼす
因子を、溶着金属の化学成分の観点から検討を重ねてき
た。その結果、炭化物の生成は溶着金属の硬度向上に有
効である反面、耐割れ性を極端に悪化させることをつき
とめた。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The present inventors have made an effort to improve the problems pointed out in the prior art as described above, and in particular, to influence the hardness and crack resistance of a weld metal welded by hardfacing. Factors to be exerted have been studied in terms of the chemical composition of the deposited metal. As a result, it has been found that the formation of carbides is effective in improving the hardness of the deposited metal, but extremely deteriorates the crack resistance.

【0012】ところが耐割れ性を高めるべく炭化物の生
成を制御すると、溶着金属の硬度が低下して満足のいく
耐摩耗性が得られなくなる。そこで溶着金属の硬度を高
めると共に、耐割れ性も向上させることのできる溶着金
属成分を見出すべく検討を重ねた。その結果、溶着金属
中のCr,W,V,Mo,Bの各含有量、とりわけMo
とBの含有量を適切に制御し、溶着金属組織を鋼のマル
テンサイトと硼化物からなる複合組織としてやれば、溶
着金属の硬度が高められると共に、溶着金属組織が微細
化されて耐割れ性も向上し、従来材に比べて格段に優れ
た耐摩耗性を有する表面硬化部材が得られることをつき
とめた。
However, if the generation of carbides is controlled in order to increase the crack resistance, the hardness of the deposited metal decreases, and satisfactory wear resistance cannot be obtained. Therefore, studies were repeated to find a weld metal component that can increase the hardness of the weld metal and also improve the crack resistance. As a result, each content of Cr, W, V, Mo, and B in the deposited metal, in particular, Mo
And the content of B are appropriately controlled, and the weld metal structure is formed as a composite structure composed of martensite and boride in steel, thereby increasing the hardness of the weld metal and miniaturizing the weld metal structure to improve crack resistance. It was also found that a surface-hardened member having much better wear resistance than conventional materials could be obtained.

【0013】そこで本発明では、こうした適正且つ微細
な金属組織を有する硬化肉盛溶着金属を確実に与え得る
様なフラックス入りワイヤを提供するものである。
Accordingly, the present invention provides a flux-cored wire capable of reliably providing a hardfacing weld metal having such an appropriate and fine metal structure.

【0014】以下、本発明において硬化肉盛溶接用フラ
ックス入りワイヤの化学成分を定めた理由を詳細に説明
する。
Hereinafter, the reason why the chemical composition of the flux-cored wire for hardfacing welding in the present invention is determined will be described in detail.

【0015】C:0.5%超1.5%以下 Cは、Fe主体のマトリックス中に固溶して鋼をマルテ
ンサイト化する主要元素であり、ワイヤ中のC含有量が
0.5%以下では、硬化肉盛により形成される溶着金属
内部のFeへのC固溶量が不足気味となってマトリック
スが硬度不足となり、後述する如くマトリックスの周囲
に高硬度の硼化物が生成したとしても溶着金属全体とし
ての硬度が十分に上がらなくなる。一方C含有量が1.
5%を超えると、溶着金属のFeマトリックスの一部が
マルテンサイトとならずにオーステナイトとして残存す
る。オーステナイトは硬度が低いため、溶着金属全体の
硬度を低下させるばかりでなく、熱膨張係数がマルテン
サイトや硼化物と大きく異なっているため、その収縮量
の違いに由来して溶着金属が割れを起こし易くなる。こ
うしたCの利害得失を考慮してより好ましいC量の下限
値は0.55%以上、更に好ましくは0.7%以上、C
量のより好ましい上限値は1.3%以下である。
C: more than 0.5% and 1.5% or less C is a main element that forms a martensitic steel by forming a solid solution in a matrix mainly composed of Fe, and has a C content of 0.5% in the wire. In the following, the amount of C dissolved in Fe inside the weld metal formed by the hardfacing tends to be insufficient and the matrix becomes insufficient in hardness, and even if high hardness boride is generated around the matrix as described later. The hardness of the deposited metal as a whole cannot be sufficiently increased. On the other hand, when the C content is 1.
If it exceeds 5%, part of the Fe matrix of the deposited metal remains as austenite without becoming martensite. Because austenite has low hardness, it not only lowers the hardness of the entire weld metal, but also has a coefficient of thermal expansion that is significantly different from that of martensite or boride. It will be easier. In view of the advantages and disadvantages of C, the lower limit of the C content is more preferably 0.55% or more, still more preferably 0.7% or more.
A more preferred upper limit of the amount is 1.3% or less.

【0016】尚、肉盛溶着金属中の好ましいC含有率は
0.2〜0.9%程度であるが、Cは溶接時に一部が燃
焼して消費されるので、溶接時の歩留りを考慮してワイ
ヤ中のC含有量はこれよりやや多めの上記範囲に定めて
いる。
The preferred C content in the build-up deposited metal is about 0.2 to 0.9%. However, since C is partially burned and consumed during welding, the yield during welding is taken into consideration. The C content in the wire is set in the above range, which is slightly larger than the above.

【0017】Si:0.6〜2.1% Siは脱酸作用を有しており、溶着金属の清浄化に寄与
する。こうした作用を有効に発揮させるには0.6%以
上、より好ましくは0.7%以上含有させるべきである
が、多過ぎるとFeマトリックス中のSi固溶量が増大
して靭性が低下し、耐割れ性に悪影響が表われてくるの
で2.1%以下、より好ましくは2.0%以下に抑えな
ければならない。尚、肉盛溶着金属中の好ましいSi含
有量は0.6〜1.9%程度であるが、Siは溶接時に
脱酸剤あるいはスラグ形成剤として作用してSiO2
なり一部が消費されるので、その消費量を考慮してワイ
ヤ中のSi量は若干多めの上記範囲に規定している。
Si: 0.6 to 2.1% Si has a deoxidizing effect and contributes to cleaning of the deposited metal. In order to effectively exhibit such an effect, the content should be 0.6% or more, more preferably 0.7% or more. However, if it is too much, the amount of Si solid solution in the Fe matrix increases, and the toughness decreases. Since the crack resistance has an adverse effect, it must be suppressed to 2.1% or less, more preferably 2.0% or less. The preferable Si content in the build-up deposited metal is about 0.6 to 1.9%. However, Si acts as a deoxidizing agent or a slag forming agent at the time of welding to become SiO 2 and partly consumed. Therefore, in consideration of the consumption, the amount of Si in the wire is specified in the slightly larger range.

【0018】Mn:0.6〜1.8% 上記Siと同様に脱酸作用を有し溶着金属の清浄化に寄
与する元素であり、その効果を有効に発揮させるには
0.6%以上、より好ましくは0.8%以上含有させな
ければならないが、多過ぎると溶着金属中にオーステナ
イトが生成し易くなり、硬度や耐割れ性に悪影響を及ぼ
す様になるので、1.8%以下、より好ましくは1.6
%以下に抑えなければならない。該Mnの肉盛溶着金属
中の好ましい含有量は0.6〜1.6%程度であるが、
Mnも溶接時に脱酸剤あるいはスラグ形成剤として作用
してMnO2 となり一部が消費されるので、その消費量
を考慮してワイヤ中のMn量は上記の様にやや多めの上
記範囲に規定している。
Mn: 0.6 to 1.8% An element which has a deoxidizing effect and contributes to the cleaning of the deposited metal similarly to the above-mentioned Si, and 0.6% or more is required to exert its effect effectively. , More preferably 0.8% or more. However, if it is too much, austenite is liable to be formed in the deposited metal and adversely affects hardness and crack resistance. More preferably 1.6
% Or less. The preferred content of the Mn in the build-up deposited metal is about 0.6 to 1.6%,
Mn also acts as a deoxidizing agent or a slag forming agent during welding to form MnO 2 and partially consume it. Therefore, the amount of Mn in the wire is specified in a slightly larger range as described above in consideration of the consumed amount. doing.

【0019】Cr:2.5〜7.5% CrはBと結合して硼化物を生成し、溶着金属の高硬度
化に寄与する重要な元素であり、その効果を有効に発揮
させるには2.5%以上、より好ましくは3.0%以上
含有させるべきである。反面Cr量が多くなり過ぎる
と、溶着金属が凝固する際に高温割れを生じ易くなるの
で7.5%以下、より好ましくは6.8%以下に抑えな
ければならない。尚、肉盛溶接時のCrの酸化消費は殆
んどなく、その殆んどは肉盛溶着金属内へ取り込まれ
る。
Cr: 2.5 to 7.5% Cr is an important element that combines with B to form borides and contributes to increasing the hardness of the deposited metal. It should be contained at least 2.5%, more preferably at least 3.0%. On the other hand, if the Cr content is too large, high temperature cracking is likely to occur when the deposited metal solidifies, so it must be suppressed to 7.5% or less, more preferably 6.8% or less. It should be noted that there is almost no oxidation consumption of Cr during overlay welding, and most of the Cr is taken into the overlay weld metal.

【0020】W:0.1%以上1.5%未満 WもBと結合して硼化物を形成し溶着金属の高硬度化に
寄与する他、溶着金属に伸びを与えて収縮割れを抑え耐
割れ性を高める作用も有している。こうした効果を有効
に発揮させるには0.1%以上、より好ましくは0.2
%以上、更に好ましくは0.4%以上含有させるべきで
あるが、含有量が多くなり過ぎると耐割れ性を却って悪
化させる傾向が生じてくるので、1.5%以下、より好
ましくは1.45%以下、更に好ましくは1.3%以下
に抑えるべきである。尚、肉盛溶接時のWの酸化消費も
殆んどなく、その殆んどは肉盛溶着金属内へ取り込まれ
る。
W: 0.1% or more and less than 1.5% W also combines with B to form a boride, thereby contributing to an increase in the hardness of the deposited metal, and also provides elongation to the deposited metal to suppress shrinkage cracking and to withstand resistance. It also has the effect of increasing cracking. In order to exert such effects effectively, 0.1% or more, more preferably 0.2%
%, More preferably 0.4% or more. However, if the content is too large, the crack resistance tends to be rather deteriorated. Therefore, 1.5% or less, more preferably 1.% or more. It should be kept below 45%, more preferably below 1.3%. In addition, there is almost no oxidation consumption of W during overlay welding, and almost all of it is taken into the overlay weld metal.

【0021】V:0.1%以上1.5%未満 VもBと結合して硼化物を形成し溶着金属の高硬度化に
寄与する他、溶着金属が凝固する際の高温割れ防止にも
有効に作用する。こうした作用は、0.1%以上、より
好ましくは0.2%以上、更に好ましくは0.3%以上
含有させることによって有効に発揮されるが、多過ぎる
と耐割れ性を却って悪化させるので、1.5%以下、よ
り好ましくは1.4%以下、更に好ましくは1.2%以
下、最も好ましくは1.0%以下に抑えるべきである。
尚、肉盛溶接時のVの酸化消費も殆んどなく、その殆ん
どは肉盛溶着金属内へ取り込まれる。
V: 0.1% or more and less than 1.5% V also combines with B to form a boride, thereby contributing to increase the hardness of the deposited metal, and also to prevent hot cracking when the deposited metal solidifies. Works effectively. Such an effect can be effectively exhibited by containing 0.1% or more, more preferably 0.2% or more, and still more preferably 0.3% or more. It should be kept below 1.5%, more preferably below 1.4%, even more preferably below 1.2%, most preferably below 1.0%.
In addition, there is almost no oxidation consumption of V during the overlay welding, and most of the V is taken into the overlay welding metal.

【0022】Mo:1.0〜8.0% MoはBと結合して硼化物を形成し、溶着金属の高硬度
化に寄与する主要元素であり、且つ硼化物の形成に寄与
した以外のMoは、Feマトリックス中に固溶して溶着
金属の焼入れ性を高める作用も発揮する。こうした効果
を有効に発揮させるには、1.0%以上含有させなけれ
ばならない。より好ましいMoの含有量は2.0%以
上、更に好ましくは3.0%以上、最も好ましくは4.
0%超であるが、多くなり過ぎると溶着金属の靭性を低
下させて耐割れ性を阻害する傾向が表われてくるので、
8.0%以下、より好ましくは7.0%以下に抑えなけ
ればならない。尚、肉盛溶接時のMoの酸化消費も殆ん
どなく、その殆んどは肉盛溶着金属内へ取り込まれる。
Mo: 1.0 to 8.0% Mo is a main element that combines with B to form a boride and contributes to increase the hardness of the deposited metal, and also contributes to the formation of the boride. Mo also exerts an effect of forming a solid solution in the Fe matrix to enhance the hardenability of the deposited metal. In order to effectively exhibit these effects, the content must be 1.0% or more. A more preferred Mo content is 2.0% or more, still more preferably 3.0% or more, and most preferably 4.0% or more.
Although it is more than 0%, if it becomes too large, the toughness of the deposited metal tends to be reduced and the crack resistance tends to be impaired.
It must be kept at 8.0% or less, more preferably at 7.0% or less. It should be noted that there is almost no oxidation consumption of Mo during overlay welding, and most of the Mo is taken into the overlay weld metal.

【0023】B:0.2%超0.8%以下 Bは硼化物の形成に欠くことのできない元素であり、
0.2%を超えて含有させなければ溶着金属中に十分な
量の硼化物が生成せず、満足のいく硬度が得られないば
かりでなく、金属組織も粗大となって十分な耐割れ性も
得られ難くなる。但し含有量が多くなり過ぎると粒界脆
化を起こして溶着金属の靭性を低下させ、却って耐割れ
性に悪影響が表われてくるので、0.8%以下、より好
ましくは0.7%以下、更に好ましくは0.6%以下に
抑えるべきである。尚、肉盛溶接時のBの酸化消費も殆
んどなく、その殆んどは肉盛溶着金属内へ取り込まれ
る。
B: more than 0.2% and 0.8% or less B is an element indispensable for boride formation,
If the content is not more than 0.2%, a sufficient amount of boride will not be formed in the deposited metal, not only a satisfactory hardness will not be obtained, but also the metal structure will be coarse and sufficient crack resistance will be obtained. Is also difficult to obtain. However, if the content is too large, it causes grain boundary embrittlement and lowers the toughness of the deposited metal, which adversely affects the cracking resistance. Therefore, 0.8% or less, more preferably 0.7% or less. , More preferably 0.6% or less. In addition, there is almost no oxidation consumption of B during the overlay welding, and most of the B is taken into the overlay welding metal.

【0024】本発明のフラックス入りワイヤを構成する
成分元素は上記の通りであり、残部成分は実質的にFe
であり、その他の元素としてP,S,N,O等あるいは
更に他の元素が混入してくることがあるが、それらも不
可避不純物量である限り許容される。またフラックス入
りワイヤにおいては、金属外皮内へ充填されるフラック
ス成分として、肉盛される溶着金属の化学成分には影響
を与えない(即ち溶着金属中に取り込まれない)成分で
あって、肉盛溶接作業性などを高める作用を有する成
分、例えばスラグ形成剤、アーク安定剤、ガス発生剤な
どを適量含有させることも有効である。但しこれらの成
分は、溶着金属中には実質的に混入してこない成分であ
るから、それらの含有量は、前記フラックス入りワイヤ
の化学成分を設定するに当たっては考慮に入れないもの
とする。
The constituent elements constituting the flux-cored wire of the present invention are as described above, and the remaining components are substantially Fe
And other elements such as P, S, N, O, etc. or other elements may be mixed therein, but these elements are also allowed as long as they are inevitable impurity amounts. Further, in the flux-cored wire, the flux component to be filled into the metal sheath is a component which does not affect the chemical component of the deposited metal to be deposited (that is, is not taken into the deposited metal), and It is also effective to include an appropriate amount of a component having an effect of improving welding workability, such as a slag forming agent, an arc stabilizer, and a gas generating agent. However, since these components are components that are not substantially mixed into the deposited metal, their contents are not taken into account when setting the chemical components of the flux-cored wire.

【0025】次に、上記化学成分を特定することによっ
て、高硬度で且つ耐割れ性が共に高められた溶着金属が
得られる理由について説明する。
Next, the reason why by specifying the above chemical components, it is possible to obtain a deposited metal having high hardness and improved crack resistance will be described.

【0026】まずBは、マトリックス粒界に偏析し易
く、且つCr,Mo,W,V等と結合して硼化物を形成
する特性を有している。そしてこれらの元素との反応に
よって生成する硼化物は、溶着金属内でマトリックス粒
界に沿って網目状に生成し、マトリックスの粒成長を抑
制して結晶粒を微細化する特性を発揮し、溶着金属の靭
性を高めて耐割れ性を向上させる。しかも生成した硼化
物は高硬度であり、溶着金属の硬度上昇にも寄与する。
First, B has the property of easily segregating at the matrix grain boundaries and forming borides by combining with Cr, Mo, W, V and the like. Borides generated by the reaction with these elements are formed in a network along the matrix grain boundaries in the deposited metal, exhibiting the characteristic of suppressing the growth of the matrix grains and refining the crystal grains. Increases the toughness of metal and improves crack resistance. Moreover, the generated boride has a high hardness and contributes to an increase in the hardness of the deposited metal.

【0027】一方、Cr,Mo,W,VはCとも反応し
易いことが確認されているが、系中にBが存在するとそ
の多くは硼化物となるため、溶着金属中の炭化物の生成
量は極めて少なくなる。その結果、溶着金属中に含まれ
ている殆んどのCはFeマトリックス中に固溶すること
となり、Feのマルテンサイト化に寄与する。一般にマ
ルテンサイトは、Fe中のC固溶量が多くなるほど高硬
度化することが知られており、溶着金属中のCが炭化物
の生成に利用されずその殆んどがマトリックス中に固溶
すると、マルテンサイトからなるマトリックスの硬度も
高くなり、溶着金属全体が高硬度化してくる。
On the other hand, it has been confirmed that Cr, Mo, W and V also easily react with C. However, when B is present in the system, most of them become borides, so that the amount of carbides generated in the deposited metal is increased. Is extremely small. As a result, most of C contained in the deposited metal forms a solid solution in the Fe matrix, which contributes to the formation of Fe into martensite. In general, it is known that martensite increases in hardness as the amount of C solid solution in Fe increases, and when C in the deposited metal is not used for forming carbides and most of the solid solution forms in the matrix. As a result, the hardness of the matrix composed of martensite increases, and the hardness of the entire deposited metal increases.

【0028】この様に炭化物が生成し難くなることによ
る効果は、マルテンサイトの高硬度化に止まらない。即
ち炭化物は極めて脆弱であるため、炭化物が生成すると
溶着金属の靭性が低下して耐割れ性に悪影響を及ぼす様
になるが、前述の如くB,Cr,Mo,W,V等の含有
量を調整した成分系では、溶着金属内部の炭化物量が極
めて少なくなり、耐割れ性の向上にも好影響をもたらす
ものと考えられる。
The effect of making the formation of carbides difficult is not limited to increasing the hardness of martensite. That is, since carbides are extremely brittle, the formation of carbides reduces the toughness of the deposited metal and adversely affects the cracking resistance. However, as described above, the content of B, Cr, Mo, W, V, etc. is reduced. In the adjusted component system, it is considered that the amount of carbide inside the deposited metal is extremely small, and this also has a favorable effect on the improvement of crack resistance.

【0029】この様にBの添加効果は、硼化物の生成と
マトリックス硬度の上昇による溶着金属の高硬度化のみ
ならず、結晶粒の微細化ならびに脆弱な炭化物の生成抑
制による溶着金属の耐割れ性向上にも寄与し、それらの
効果が相まって、溶着金属の高硬度化と耐割れ性の向上
に顕著な効果を奏するのである。
As described above, the effect of adding B is not only to increase the hardness of the deposited metal due to the formation of borides and increase the matrix hardness, but also to reduce the size of crystal grains and suppress the cracking of the deposited metal by suppressing the formation of brittle carbides. It also contributes to the improvement of the weldability, and together with these effects, it has a remarkable effect on increasing the hardness of the deposited metal and improving the crack resistance.

【0030】また、前述の如く溶着金属の高硬度化には
マトリックスをマルテンサイト化することが重要とな
る。そして、マトリックスを安定してマルテンサイト化
するには、溶着金属の焼入れ性を向上させることが有効
であり、焼入れ性の向上にはMoが顕著な影響を及ぼ
す。しかもMoは、前述の如く硼化物を生成して溶着金
属の硬度向上にも寄与するので、含有元素の中でもMo
は極めて重要な元素として位置付けられる。そしてこう
したMoの焼入れ性向上と硼化物生成による複合効果を
有効に発揮させるには、前述の如くフラックス入りワイ
ヤ中のMo含有量を1.0%以上、より好ましくは2.
0%以上、更に好ましくは3.0%以上、最も好ましく
は4.0%超とすべきであり、Mo量が1.0%未満で
は、Moの殆んどが硼化物となって消費され、マトリッ
クス中に固溶するMoが実質的に存在し得なくなる為、
溶着金属の焼入れ性を高める効果が有効に発揮されず、
マトリックス硬度の低下、ひいては溶着金属の硬度低下
を惹起する。尚こうしたMoの効果は約4〜5%程度で
飽和し、8.0%を超えて過度に含まれるときは溶着金
属の靭性が低下し、満足な耐割れ性を確保できなくな
る。
As described above, it is important to make the matrix martensite in order to increase the hardness of the deposited metal. In order to stably transform the matrix into martensite, it is effective to improve the hardenability of the deposited metal, and Mo has a significant effect on the improvement of the hardenability. In addition, Mo generates boride as described above and contributes to the improvement of the hardness of the deposited metal.
Is positioned as a very important element. In order to improve the quenchability of Mo and effectively exhibit the combined effect of boride generation, the Mo content in the flux-cored wire is 1.0% or more, more preferably 2.%.
It should be 0% or more, more preferably 3.0% or more, and most preferably more than 4.0%. When the Mo content is less than 1.0%, most of Mo is consumed as boride. , Since Mo dissolved in the matrix cannot substantially exist,
The effect of increasing the hardenability of the deposited metal is not effectively exhibited,
This causes a decrease in the matrix hardness and, consequently, a decrease in the hardness of the deposited metal. The effect of Mo saturates at about 4 to 5%, and when the Mo content exceeds 8.0% excessively, the toughness of the deposited metal decreases, and satisfactory crack resistance cannot be secured.

【0031】本発明で定める上記ワイヤの化学成分は、
金属外皮とその内部に充填されるフラックス成分によっ
て調整する。通常は、金属外皮として軟鋼やCr鋼など
を使用し、それら外皮金属に不足する元素をフラックス
成分として内部に充填することにより、フラックス入り
ワイヤ全体としての化学成分が前述した範囲となる様に
調整すればよい。従って、外皮成分が制限されないこと
は言うまでもないが、フラックス入りワイヤ製造時の伸
線加工性などを考えると、金属外皮材としては伸線加工
性に優れた素材を使用することが好ましく、従って、金
属外皮の硬度を高める様な元素、例えばSi,C,B,
Mo,W等は極力フラックス成分として金属外皮内に充
填して成分調整することが望ましい。
The chemical components of the wire defined in the present invention are:
Adjustment is made according to the metal shell and the flux components filled therein. Normally, mild steel or Cr steel is used as the metal sheath, and the elements that are lacking in the skin metal are filled into the inside as flux components, so that the chemical composition of the flux-cored wire as a whole falls within the range described above. do it. Therefore, it goes without saying that the outer shell component is not limited, but in view of the drawability at the time of producing a flux-cored wire, it is preferable to use a material excellent in the drawability as the metal sheath material, Elements that increase the hardness of the metal shell, such as Si, C, B,
Mo, W, and the like are desirably filled as flux components as much as possible in the metal outer cover to adjust the components.

【0032】尚、金属外皮内に充填して成分調整に用い
られる前記各元素のうちC,Si,Mn,B,Cr,
W,V,Mo,等は夫々の金属粉として供給してもよい
が、Fe等との合金として供給してもよい。
In addition, among the above-mentioned elements used for adjusting the components by filling the inside of the metal sheath, C, Si, Mn, B, Cr,
W, V, Mo, etc. may be supplied as respective metal powders, or may be supplied as an alloy with Fe or the like.

【0033】尚フラックス入りワイヤの断面形状や寸
法、フラックス充填率等も特に制限がなく、採用する溶
接法や肉盛溶接位置などを考慮して任意に決めればよ
い。
The cross-sectional shape and size of the flux-cored wire, the flux filling rate, and the like are not particularly limited, and may be arbitrarily determined in consideration of the welding method to be used and the overlay welding position.

【0034】本発明のフラックス入りワイヤを用いた硬
化肉盛溶接法あるいは溶接条件等には一切制限がなく、
最も一般的な炭酸ガスアーク溶接法の他、シールドガス
としてAr等の不活性ガスを混入させたガスアーク溶接
法(MIG溶接、MAG溶接、TIG溶接など)、サブ
マージドアーク溶接法、セルフシールドアーク溶接法な
どが非限定的に例示される。
The hardfacing welding method or welding conditions using the flux-cored wire of the present invention are not limited at all.
In addition to the most common carbon dioxide gas arc welding method, gas arc welding method (MIG welding, MAG welding, TIG welding, etc.) mixed with inert gas such as Ar as shielding gas, submerged arc welding method, self-shielded arc welding method And the like are non-limiting examples.

【0035】また硬化肉盛溶着金属層が形成される母材
の種類は、前記硬化肉盛層の支持層として使用時の応力
に耐え得る強度と靭性を有する素材であればその種類は
特に制限されないが、強度特性や前記溶着金属層に対す
る接着性、コスト等を総合的に考慮して最も実用性の高
いのは軟鋼や低合金鋼などの鋼材である。
The type of the base material on which the hardfacing welded metal layer is formed is not particularly limited as long as it is a material having strength and toughness that can withstand stress during use as a support layer of the hardfacing overlay. However, steel materials such as mild steel and low alloy steel are most practical in consideration of strength characteristics, adhesion to the deposited metal layer, cost, and the like.

【0036】上記の様に、本発明のフラックス入りワイ
ヤを用いて肉盛溶接された溶着金属は、高硬度で且つ優
れた耐割れ性を有しており、重衝撃を受ける部位に適用
したときでも卓越した靭性と耐摩耗性を発揮するので、
特に破砕機や粉砕機など、具体的にはコーンクラッシャ
やジョークラッシャ、ローラミル、インパクトクラッシ
ャ等に幅広く適用することができる。また破砕・粉砕以
外の分野でも、例えば製鉄所の原料搬送部品、鉄鉱石等
の原料貯留施設に設けられる各種取扱い部品、圧延ロー
ル等の各種耐摩耗性部品、更にはパワーショベル等の建
設機械部品、鉱山、石炭等の採掘に用いられる鉱山機械
部品などに広く活用することができる。
As described above, the deposited metal welded by overlay welding using the flux-cored wire of the present invention has high hardness and excellent crack resistance, and when applied to a portion that is subjected to heavy impact. But it demonstrates outstanding toughness and wear resistance,
In particular, the present invention can be widely applied to a crusher, a crusher, and the like, specifically, a cone crusher, a jaw crusher, a roller mill, an impact crusher, and the like. In fields other than crushing and crushing, for example, raw material transport parts of ironworks, various handling parts provided in raw material storage facilities such as iron ore, various wear-resistant parts such as rolling rolls, and construction machine parts such as power shovels. Can be widely used for mining machinery parts used for mining, mining, coal and the like.

【0037】[0037]

【実施例】次に本発明の実施例を示すが、本発明はもと
より下記実施例によって制限を受けるものではなく、前
・後記の趣旨に適合し得る範囲で適当に変更を加えて実
施することも勿論可能であり、それらはいずれも本発明
の技術的範囲に含まれる。
EXAMPLES Next, examples of the present invention will be described. However, the present invention is not limited by the following examples, and the present invention should be practiced with appropriate modifications within a range that can be adapted to the gist of the preceding and the following. Of course, these are also possible, and all of them are included in the technical scope of the present invention.

【0038】実施例1 金属外皮材として軟鋼を使用し、充填フラックスの成分
と充填量を調整することにより、下記表1に示す化学成
分のフラックス入りワイヤを製造した。尚フラックスの
充填率は15〜35%、ワイヤ径は1.2〜1.6mm
(直径)の範囲とした。
Example 1 Flux-cored wires having the chemical components shown in Table 1 below were produced by using mild steel as the metal sheath material and adjusting the components of the filling flux and the filling amount. The filling rate of the flux is 15 to 35%, and the wire diameter is 1.2 to 1.6 mm.
(Diameter).

【0039】得られた各フラックス入りワイヤを使用
し、軟鋼製母材(厚さ50mm×幅150mm×長さ2
00mm)の表面に、図1(1は母材、2は溶着金属を
表わす)に示す如く硬化肉盛溶接を行なって溶着金属層
を形成した。尚肉盛溶接条件は下記の通りとした。 (溶接条件) 溶接電流:200A,溶接速度:35cm/分,溶接電
圧:33V,シールドガス:CO2 100%,ワイヤ
突き出し長さ:20mm,予熱・パス間温度:200〜
350℃ 肉盛溶着金属厚さ:10mm(3層盛り)
Using each of the obtained flux-cored wires, a mild steel base material (thickness 50 mm × width 150 mm × length 2)
As shown in FIG. 1 (1 represents a base material and 2 represents a deposited metal), a hardfacing weld was formed on the surface of the (00 mm) surface to form a deposited metal layer. The build-up welding conditions were as follows. (Welding conditions) Welding current: 200 A, welding speed: 35 cm / min, welding voltage: 33 V, shielding gas: 100% CO 2 , wire protrusion length: 20 mm, preheating / interpass temperature: 200 to
350 ° C overlay metal thickness: 10mm (three layers)

【0040】得られた各肉盛溶接材について、溶着金属
成分を調べると共に、その硬度(荷重30kgfでのビ
ッカース硬さ)と割れの状態(溶着金属表面のカラーチ
ェック)を調べ、表1,2に示す結果を得た。
For each of the overlay welding materials obtained, the weld metal components were examined, and the hardness (Vickers hardness under a load of 30 kgf) and the state of cracks (color check of the surface of the weld metal) were examined. Were obtained.

【0041】また上記と同じフラックス入りワイヤと溶
接条件を採用し、図2に略示する耐摩耗性評価試験装置
[図中、3は上型基材(軟鋼)、4は下型基材(軟
鋼)、5は硬化肉盛溶着金属層、6は被破砕石、7は上
部原料シュート、8は下部原料シュート、9は荷重検出
装置(ロードセル)、10はアクチュエータ、11は強
化ガラスを夫々示している]における上型基材3および
下型基材4の作用面に硬化肉盛溶着金属層5を夫々形成
し、各試験材を試験装置に装着して、上部原料シュート
からチャート岩石を連続的に装入して下記の条件で破砕
を行ない、試験前後の試験材の重量を測定して重量減少
(試験材4個の合計)により耐摩耗性を調べた。なお試
験材の重量減少は、破砕に供された岩石の重量(投入
量)に影響を受けると予測されるため、比摩耗量(試験
材の重量減少/破砕した岩石の重量)で評価した。結果
を表2に示す。 (破砕条件) 破砕原料:チャート岩石、投入サイズ 2〜5mm、出
口サイズ:2.5±1mm 破砕時の周波数:2Hz 平均破砕荷重 :5kN 繰り返し回数 :約8000回
Further, the same flux-cored wire and welding conditions as those described above were employed, and a wear resistance evaluation test apparatus schematically shown in FIG. 2 [in the figure, 3 is an upper mold base material (mild steel), 4 is a lower mold base material ( Mild steel), 5 is a hardfacing deposited metal layer, 6 is a crushed stone, 7 is an upper material chute, 8 is a lower material chute, 9 is a load detector (load cell), 10 is an actuator, and 11 is tempered glass. In this case, a hardfacing welded metal layer 5 is formed on each of the working surfaces of the upper mold base 3 and the lower mold base 4, each test material is mounted on a test apparatus, and the chart rock is continuously fed from the upper raw material chute. The sample was charged and crushed under the following conditions, the weight of the test material before and after the test was measured, and the wear resistance was examined by weight reduction (total of four test materials). Since the weight loss of the test material is expected to be affected by the weight (input amount) of the rock subjected to crushing, the specific wear amount (weight loss of test material / weight of crushed rock) was evaluated. Table 2 shows the results. (Crushing conditions) Crushing raw material: Chert rock, input size 2-5 mm, outlet size: 2.5 ± 1 mm Frequency at crushing: 2 Hz Average crushing load: 5 kN Number of repetitions: about 8,000

【0042】[0042]

【表1】 [Table 1]

【0043】[0043]

【表2】 [Table 2]

【0044】表1,2より次の様に考えることができ
る。No.11〜18は本発明の規定要件を全て満たす
実施例であり、いずれの溶着金属もビッカース硬度が8
00を超えており、且つ溶着金属の表面および内部のい
ずれにも割れは認められない。但し溶着金属の硬度につ
いては、Mo添加量の影響が認められ、本発明の規定範
囲内であっても、Mo量が多くなるほど硬度は高くなる
傾向が伺われる。しかし、その傾向はMo量が4%を超
えた辺りでほぼ飽和している。
From Tables 1 and 2, the following can be considered. No. Nos. 11 to 18 are examples satisfying all the requirements of the present invention.
It is more than 00, and no crack is recognized on both the surface and the inside of the deposited metal. However, the hardness of the deposited metal is affected by the amount of Mo added, and even within the range specified in the present invention, the hardness tends to increase as the amount of Mo increases. However, the tendency is almost saturated when the Mo amount exceeds 4%.

【0045】これらの実施例に対し、No.1〜10
は、本発明で規定するいずれかの要件を欠く比較例であ
り、下記の如く硬度か耐割れ性のいずれかに問題があ
る。
In contrast to these examples, 1 to 10
Is a comparative example lacking any of the requirements specified in the present invention, and has a problem in either hardness or crack resistance as described below.

【0046】No.1:ワイヤ中のC量が不足するため
溶着金属の硬度が低く、しかもVが含まれていないため
溶着金属に高温割れが発生している。
No. 1: The hardness of the deposited metal was low due to the insufficient amount of C in the wire, and the deposited metal was hot cracked because it did not contain V.

【0047】No.2:Mn量が多過ぎるため溶着金属
に低温割れが発生しており、またMn量が多く且つCr
量が不足しているため溶着金属の硬度も低く耐摩耗性に
欠ける。
No. 2: Low temperature cracking occurred in the deposited metal due to too much Mn, and a large amount of Mn and Cr
Since the amount is insufficient, the hardness of the deposited metal is low and the wear resistance is poor.

【0048】No.3:溶着金属の硬度や耐割れ性に問
題はないが、SiとMn量が不足するため溶着金属内に
ブローホールが発生している。 No.4:Mo量が不足するため溶着金属の硬度が不足
する。
No. 3: There is no problem in the hardness and crack resistance of the deposited metal, but blow holes are generated in the deposited metal due to insufficient amounts of Si and Mn. No. 4: Since the Mo content is insufficient, the hardness of the deposited metal is insufficient.

【0049】No.5:WおよびB量が多過ぎるため耐
割れ性が低下し、割れが発生している。 No.6:Cr量が多過ぎるため高温割れが発生してお
り、且つB量も不足するため硬度が低くまた低温割れを
生じている。
No. 5: The cracking resistance was reduced due to excessive amounts of W and B, and cracking occurred. No. 6: Hot cracking has occurred due to too much Cr content, and hardness is low and cold cracking has occurred due to insufficient B content.

【0050】No.7:W量が不足するため硬度が低
く、またSi量が多過ぎるため耐割れ性が悪く低温割れ
を生じている。 No.8:C量が多過ぎるため、硬度が低く且つ低温割
れも見られる。 No.9:Mo量が多過ぎるため耐割れ性が低下し、低
温割れを生じている。 No.10:V量が多過ぎるため耐割れ性が低下し、溶
着金属に低温割れが生じている。
No. 7: Hardness was low due to insufficient W content, and cracking resistance was poor due to too much Si content, causing low temperature cracking. No. 8: Since the C content is too large, the hardness is low and low-temperature cracking is also observed. No. 9: The cracking resistance was lowered due to too much Mo content, and low-temperature cracking occurred. No. 10: The cracking resistance was reduced due to too much V content, and the deposited metal was cracked at low temperature.

【0051】またNo.11〜18(実施例)とNo.
1〜10(比較例)を全体的に比較すると、溶着金属の
比摩耗量は前者の方が格段に優れており優れた耐摩耗性
を有していることが分かる。即ち、本発明で定める前記
規定要件のうち1つでも欠如する比較例では、得られる
溶着金属の表面硬度が低く、あるいは溶着金属層の表層
または内部に割れやブローホール等の欠陥が生じ、該欠
陥部からの欠けや剥離を起こすため比摩耗量が多くなっ
ている。また溶着金属の硬度と耐摩耗性については、M
o含有量依存性が認められ、Mo含有量が多くなるほど
硬度が高くなって耐摩耗性は良好となる傾向が認められ
る。しかしその傾向は、Mo含有量が約4%でほぼ飽和
することを確認できる。
No. Nos. 11 to 18 (Example) and
Comparing 1 to 10 (Comparative Examples) as a whole, it can be seen that the specific wear amount of the deposited metal is much better in the former case and has excellent wear resistance. That is, in the comparative example in which even one of the above-mentioned prescribed requirements defined in the present invention is not obtained, the surface hardness of the obtained deposited metal is low, or defects such as cracks and blow holes occur in the surface layer or inside of the deposited metal layer. The specific wear amount is increased due to chipping or peeling from the defective portion. For the hardness and wear resistance of the deposited metal,
The o content dependency is recognized, and the higher the Mo content, the higher the hardness and the better the abrasion resistance. However, it can be confirmed that the tendency is almost saturated when the Mo content is about 4%.

【0052】[0052]

【発明の効果】本発明は以上の様に構成されており、フ
ラックス入りワイヤ中の含有元素のうち特に、C,B,
Cr,Mo,W,V等の含有量を規定することによっ
て、高硬度で且つ耐割れ性に優れ、重衝撃を受ける破砕
・粉砕条件下に曝されたときでも卓越した耐摩耗性を示
す肉盛溶着金属を与える肉盛溶接用フラックス入りワイ
ヤを得ることができる。
The present invention is constituted as described above, and among the elements contained in the flux-cored wire, C, B, and
By specifying the content of Cr, Mo, W, V, etc., the meat has high hardness, excellent crack resistance, and excellent wear resistance even when exposed to crushing / crushing conditions subjected to heavy impact. It is possible to obtain a flux-cored wire for build-up welding that gives a build-up weld metal.

【図面の簡単な説明】[Brief description of the drawings]

【図1】実験で採用した硬化肉盛溶接法を示す見取り図
である。
FIG. 1 is a sketch showing a hardfacing welding method adopted in an experiment.

【図2】フラックス入りワイヤを用いて形成した硬化肉
盛溶着金属層の耐摩耗性を評価するための岩石破砕試験
法を示す概略断面説明図である。
FIG. 2 is a schematic sectional explanatory view showing a rock crushing test method for evaluating the wear resistance of a hardfacing welded metal layer formed using a flux-cored wire.

【符号の説明】[Explanation of symbols]

1 母材(基材) 2 溶着金属 3 上型基材(軟鋼) 4 下型基材(軟鋼) 5 硬化肉盛溶着金属層 6 被破砕石 7 上部原料シュート 8 下部原料シュート 9 荷重検出装置(ロードセル) 10 アクチュエータ 11 強化ガラス Reference Signs List 1 base material (base material) 2 weld metal 3 upper die base material (mild steel) 4 lower die base material (mild steel) 5 hardfacing deposited metal layer 6 crushed stone 7 upper raw material chute 8 lower raw material chute 9 load detector ( Load cell) 10 Actuator 11 Tempered glass

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 鉄基金属外皮内にフラックスが充填され
た硬化肉盛溶接用のフラックス入りワイヤであって、該
ワイヤ全量中に占める比率が C :0.5%超1.5%(質量%を意味する、以下同
じ)以下、 Si:0.6〜2.1%、 Mn:0.6〜1.8%、 Cr:2.5〜7.5%、 W :0.1%以上1.5%未満、 V :0.1%以上1.5%未満、 Mo:1.0〜8.0%、 B :0.2%超0.8%以下、 であることを特徴とする硬化肉盛溶接用フラックス入り
ワイヤ。
1. A flux-cored wire for hardfacing welding in which a flux is filled in an iron-based metal sheath, wherein a ratio of C: more than 0.5% to 1.5% (mass) in the total amount of the wire. %; The same applies hereinafter), Si: 0.6 to 2.1%, Mn: 0.6 to 1.8%, Cr: 2.5 to 7.5%, W: 0.1% or more Less than 1.5%, V: 0.1% or more and less than 1.5%, Mo: 1.0-8.0%, B: more than 0.2% and 0.8% or less. Flux-cored wire for hardfacing welding.
【請求項2】 Mo含有量が4.0%超8.0%以下で
ある請求項1記載の硬化肉盛溶接用フラックス入りワイ
ヤ。
2. The flux-cored wire for hardfacing welding according to claim 1, wherein the Mo content is more than 4.0% and not more than 8.0%.
【請求項3】 請求項1または2の成分に加えて、フラ
ックス成分としてアーク安定剤、スラグ形成剤およびガ
ス発生剤の少なくとも1種が含まれていることを特徴と
する硬化肉盛溶接用フラックス入りワイヤ。
3. A flux for hardfacing welding, characterized in that the flux contains at least one of an arc stabilizer, a slag forming agent and a gas generating agent as a flux component in addition to the components of claim 1 or 2. Cored wire.
JP00895898A 1998-01-20 1998-01-20 Flux-cored wire for hardfacing welding Expired - Lifetime JP3548414B2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP00895898A JP3548414B2 (en) 1998-01-20 1998-01-20 Flux-cored wire for hardfacing welding
AU12174/99A AU709342B1 (en) 1998-01-20 1999-01-20 Surface hardened member, deposited metal, and flux cored wire for hardfacing by welding

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP00895898A JP3548414B2 (en) 1998-01-20 1998-01-20 Flux-cored wire for hardfacing welding

Publications (2)

Publication Number Publication Date
JPH11197877A true JPH11197877A (en) 1999-07-27
JP3548414B2 JP3548414B2 (en) 2004-07-28

Family

ID=11707192

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP3548414B2 (en)

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Publication number Priority date Publication date Assignee Title
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EP2322315A1 (en) * 2009-11-17 2011-05-18 Kabushiki Kaisha Kobe Seiko Sho Hardfacing mig-arc welding wire and hardfacing mig-arc welding process
US20110114606A1 (en) * 2009-11-17 2011-05-19 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Hardfacing mig-arc welding wire and hardfacing mig-arc welding process
CN104139254A (en) * 2014-08-06 2014-11-12 广东省工业技术研究院(广州有色金属研究院) Bead-weld flux-cored welding wire
JP5840746B1 (en) * 2014-09-11 2016-01-06 東海溶業株式会社 TIG welding wire for overlaying
CN112122819A (en) * 2020-09-29 2020-12-25 天津市永昌焊丝有限公司 Low-dilution high-hardness surfacing flux-cored wire
CN112122819B (en) * 2020-09-29 2022-04-22 天津市永昌焊丝有限公司 Low-dilution high-hardness surfacing flux-cored wire
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