JPH11131184A - Case hardening steel minimal in heat treatment strain - Google Patents

Case hardening steel minimal in heat treatment strain

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Publication number
JPH11131184A
JPH11131184A JP29137997A JP29137997A JPH11131184A JP H11131184 A JPH11131184 A JP H11131184A JP 29137997 A JP29137997 A JP 29137997A JP 29137997 A JP29137997 A JP 29137997A JP H11131184 A JPH11131184 A JP H11131184A
Authority
JP
Japan
Prior art keywords
less
center
cross
section
quenching
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP29137997A
Other languages
Japanese (ja)
Other versions
JP3409275B2 (en
Inventor
Sumie Suda
澄恵 須田
Yoshitake Matsushima
義武 松島
Takashi Matsunaga
崇 松永
Naoya Kondo
直哉 近藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
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Filing date
Publication date
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Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Priority to JP29137997A priority Critical patent/JP3409275B2/en
Publication of JPH11131184A publication Critical patent/JPH11131184A/en
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Abstract

PROBLEM TO BE SOLVED: To provide a case hardening steel minimal in the occurrence of heat treatment strain due to carburizing and quenching even without constraining of parts at the time of carburizing and correcting the shape after carburizing and quenching, etc. SOLUTION: In the cross section of a rod-like rolled stock, the region occupied by equiaxed crystals is regulated to <=30% by area ratio. It is desirable to regulate the value of a/D to <=0.05 when (a) represent the distance between the center of a central segregation zone in the cross section of the rod-like rolled stock and the center of the cross section and also D represents the diameter of the rolled stock. Further, it is desirable to regulate the value of b/D to <=0.05 when (b) represents the distance between the center of an equiaxed crystal region in the cross section of the rod-like rolled stock and the center of the cross section.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は熱処理歪の少ない肌
焼鋼に関し、詳細には浸炭焼入れによる部品の形状変化
が少なく、寸法のばらつきの小さい肌焼鋼に関するもの
である。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a case hardening steel having a small heat treatment distortion, and more particularly, to a case hardening steel having a small change in shape of a part due to carburizing and quenching and a small dimensional variation.

【0002】[0002]

【従来の技術】歯車やシャフト等の鋼部品には、使用中
に曲げ応力や高い面圧が繰り返しかかることから、耐疲
労性及び耐摩耗性に優れることが要求される。そこで靭
性に優れた低炭素鋼を用いることで耐疲労性を確保する
と共に、上記低炭素鋼に浸炭焼入れを施すことにより表
面を硬化し耐摩耗性を向上する方法が採用されている。
但し、浸炭焼入れは高温で加熱した後に急冷を行う処理
であるので、冷却工程において部品の表層部と内部の温
度差に起因する熱応力が発生すると共に、相変態に伴う
体積変化により変態応力が発生して熱処理歪が不可避的
に発生する。例えば、ギア等の略円筒型部品やスリーブ
等のリング型部品の場合には、外径の真円度や端面の平
坦度が悪くなったり、シャフト等の軸型部品の場合には
曲がりが生じたりする。しかも浸炭焼入れは部品の最終
加工段階で行われることが一般的であることから、発生
した熱処理歪はそのまま部品に残されることとなり、特
定の位置だけに高い圧力がかかって、耐久性の低下を招
いたり、或いは騒音や振動を発生させる等、部品の性能
に直接影響を及ぼすものである。
2. Description of the Related Art Steel parts such as gears and shafts are required to be excellent in fatigue resistance and wear resistance because bending stress and high surface pressure are repeatedly applied during use. Therefore, a method has been adopted in which fatigue resistance is ensured by using low-carbon steel having excellent toughness, and the surface is hardened by carburizing and quenching the low-carbon steel to improve wear resistance.
However, carburizing and quenching is a process of quenching after heating at a high temperature, so that in the cooling step, thermal stress occurs due to the temperature difference between the surface layer and the inside of the part, and the transformation stress due to the volume change accompanying the phase transformation. And heat treatment distortion is inevitably generated. For example, in the case of a substantially cylindrical part such as a gear or a ring part such as a sleeve, the roundness of the outer diameter and the flatness of the end face are deteriorated, and in the case of a shaft part such as a shaft, bending occurs. Or In addition, since carburizing and quenching are generally performed at the final processing stage of a part, the generated heat treatment distortion is left on the part as it is, and high pressure is applied only to specific positions, reducing the durability. It directly affects the performance of components, such as inviting or generating noise or vibration.

【0003】そこで浸炭焼入れ時に発生する熱処理歪を
できるだけ小さくすることを目的として、浸炭焼入れの
際に拘束治具を用いて鋼材を拘束する方法や、浸炭焼入
れ後に部品形状を修正するような方法等が行われている
が、いずれの方法も多大の費用と労力を要するという問
題点がある。特開平2−240249号公報には、浸炭
焼入れ時に部品の拘束を行ったり、浸炭焼入れ後に形状
の修正を行わなくても、熱処理歪の発生を少なくできる
浸炭部品の製造方法が開示されている。但し、この方法
では特定成分の機械構造用鋼を用いて浸炭処理した後、
特定の焼入剤を用いて焼入れを行う必要があった。
For the purpose of minimizing the heat treatment distortion generated during carburizing and quenching, a method of restraining a steel material using a restraining jig during carburizing and quenching, a method of correcting the shape of a part after carburizing and quenching, etc. However, there is a problem that both methods require a great deal of cost and labor. JP-A-2-240249 discloses a method for manufacturing a carburized component that can reduce the occurrence of heat treatment distortion without restraining the component during carburizing and quenching or correcting the shape after carburizing and quenching. However, in this method, after carburizing using a specific structural steel for machine structure,
It was necessary to perform quenching using a specific quenching agent.

【0004】[0004]

【発明が解決しようとする課題】本発明は上記事情に着
目してなされたものであり、浸炭焼入れ時に部品の拘束
を行ったり、浸炭焼入れ後に形状の修正を行う等しなく
ても浸炭焼入れによる熱処理歪を少なくすることのでき
る肌焼鋼であって、しかも焼入時に特定の焼入剤等を必
要としない肌焼鋼を提供しようとするものである。
SUMMARY OF THE INVENTION The present invention has been made in view of the above circumstances, and is based on carburizing and quenching without constraining parts at the time of carburizing and quenching without modifying the shape after carburizing and quenching. An object of the present invention is to provide a case hardened steel that can reduce heat treatment distortion and that does not require a specific quenching agent or the like during quenching.

【0005】[0005]

【課題を解決するための手段】上記課題を解決した本発
明の肌焼鋼とは、棒状圧延材の横断面において等軸晶の
占める領域が面積率で30%以下であることを要旨とす
るものであり、また棒状圧延材の横断面における中心偏
析帯の中心と前記横断面の中心との距離をa、圧延材の
直径をDとする時、a/Dの値が0.05以下であるこ
とが望ましく、更に棒状圧延材の横断面における等軸晶
域の中心と前記横断面の中心との距離をbとする時、b
/Dの値が0.05以下であることが望ましい。
The case-hardened steel of the present invention which has solved the above-mentioned problems is characterized in that the area occupied by equiaxed crystals in the cross section of the rod-shaped rolled material is 30% or less in area ratio. When the distance between the center of the center segregation zone and the center of the cross section in the cross section of the rod-shaped rolled material is a and the diameter of the rolled material is D, the value of a / D is 0.05 or less. It is desirable that the distance between the center of the equiaxed crystal region in the cross section of the rod-shaped rolled material and the center of the cross section be b.
It is desirable that the value of / D be 0.05 or less.

【0006】尚、本発明において、等軸晶域の面積率を
算出するにあたり、等軸晶と柱状晶が混在する分岐柱状
晶の領域が存在する場合には、上記分岐柱状晶域は等軸
晶域に含めて面積率を算出することとする。
In the present invention, when calculating the area ratio of the equiaxed crystal region, when there is a region of the branched columnar crystal in which the equiaxed crystal and the columnar crystal are mixed, the above-mentioned branched columnar crystal region is not equiaxed. The area ratio is calculated to be included in the crystal region.

【0007】本発明の肌焼鋼の化学成分としては、C:
0.01〜0.50%(質量%の意味、以下同じ)、S
i:2.0%以下(0%を含まない)、Mn:0.20
〜2.5%、Al:0.01〜1.0%、N:0.00
3〜0.03%を含有し、残部Feおよび不可避的不純
物からなることが望ましく、さらに他の元素としてT
i:0.005〜0.3%を含有しても良い。
[0007] The case hardening steel of the present invention contains C:
0.01 to 0.50% (meaning by mass%, the same applies hereinafter), S
i: 2.0% or less (excluding 0%), Mn: 0.20
-2.5%, Al: 0.01-1.0%, N: 0.00
It is desirable to contain 3 to 0.03%, the balance being Fe and unavoidable impurities.
i: 0.005 to 0.3% may be contained.

【0008】また本発明の肌焼鋼の化学成分としては、
C:0.01〜0.50%、Si:2.0%以下(0%
を含まない)、Mn:0.20〜2.5%、Al:0.
01〜1.0%、B:0.01%以下(0%を含まな
い)、Ti:0.005〜0.3%、N:0.002〜
0.01%を含有し、残部Feおよび不可避的不純物か
らなるものであっても良い。
The chemical components of the case hardening steel of the present invention include:
C: 0.01 to 0.50%, Si: 2.0% or less (0%
), Mn: 0.20-2.5%, Al: 0.
01 to 1.0%, B: 0.01% or less (excluding 0%), Ti: 0.005 to 0.3%, N: 0.002 to
It may contain 0.01%, with the balance being Fe and unavoidable impurities.

【0009】さらに焼入性の向上を目的としてNi:
0.2〜4.5%、Cr:0.2〜6.0%、Mo:
0.05〜1.0%、Cu:0.2〜1.0%よりなる
群から選択される1種以上を含有させてもよく、また靭
性の向上を目的としてV:0.03〜1.5%及び/又
はNb:0.005〜1.5%を含有させてもよく、さ
らに被削性の向上を目的として、S:0.02〜0.3
%、Ca:0.0003〜0.01%、Pb:0.3%
以下(0%を含まない)、Te:0.1%以下(0%を
含まない)、Zr:0.1%以下(0%を含まない)よ
りなる群から選択される1種以上を含有させてもよい。
In order to further improve hardenability, Ni:
0.2 to 4.5%, Cr: 0.2 to 6.0%, Mo:
One or more selected from the group consisting of 0.05 to 1.0% and Cu: 0.2 to 1.0% may be contained, and V: 0.03 to 1 for the purpose of improving toughness. 0.5% and / or Nb: 0.005 to 1.5%, and for the purpose of improving machinability, S: 0.02 to 0.3%
%, Ca: 0.0003 to 0.01%, Pb: 0.3%
The following (excluding 0%), Te: 0.1% or less (excluding 0%), Zr: 0.1% or less (excluding 0%), containing one or more selected from the group consisting of May be.

【0010】[0010]

【発明の実施の形態】本発明者らは後記する実施例を含
む多くの実験データに基づいて、上記圧延材横断面中の
等軸晶(分岐柱状晶域を含む)の面積率が浸炭焼入れ時
の熱処理歪に及ぼす影響を調べたところ、図1に示した
グラフの通り、圧延材横断面中の等軸晶域の面積率が小
さくなるほど焼入歪量が少なくなるとの知見を得た。具
体的には、面積率が30%を超えると歪発生量が極端に
悪くなっており、等軸晶域の割合を30%以下に抑える
必要があることが分かった。
BEST MODE FOR CARRYING OUT THE INVENTION Based on many experimental data including the examples described later, the present inventors have determined that the area ratio of equiaxed crystals (including branched columnar regions) in the cross section of the rolled material is carburized and quenched. As a result of examining the effect on the heat treatment strain at the time, as shown in the graph of FIG. 1, it was found that the smaller the area ratio of the equiaxed crystal region in the cross section of the rolled material, the smaller the amount of quenching strain. Specifically, it was found that when the area ratio exceeded 30%, the amount of strain generation was extremely poor, and it was found that the proportion of the equiaxed crystal region had to be suppressed to 30% or less.

【0011】この様に、本発明者らは機械構造用鋼の熱
処理歪に及ぼす鋳造組織の影響について様々な角度から
研究を重ねた結果、鋳造時に生成する鋳造組織と熱処理
歪の間に非常に大きな相関があることを見出し本発明に
想到したものであり、本発明では棒状圧延材の横断面に
おいて、等軸晶域(分岐柱状晶域を含む)を面積率で3
0%以下に抑えることにより、浸炭焼入れ時の熱処理歪
の発生を極力抑制するものである。
As described above, the present inventors have conducted various studies on the effects of the cast structure on the heat treatment distortion of the steel for machine structural use from various angles. The present inventors have found that there is a large correlation, and conceived the present invention. In the present invention, in the cross section of the rod-shaped rolled material, the equiaxed crystal region (including the branched columnar crystal region) is defined as an area ratio of 3%.
By suppressing the content to 0% or less, the occurrence of heat treatment distortion during carburizing and quenching is suppressed as much as possible.

【0012】図2に示す様に、鋳造初期には柱状晶1が
生成し、鋳造後期には等軸晶2が生成することが知られ
ているが、柱状晶域に対して等軸晶域ではCやCr等の
焼入性向上元素の含有量が多く、その分ミクロ的には上
記焼入性向上元素の成分偏析の程度が大きくなってい
る。このため、等軸晶域では焼入性が部分的に大きく異
なっており、この焼入性のバラツキが浸炭焼入れ時の歪
の原因となっているものと考えられる。従って、本発明
ではミクロ的な成分偏析が大きく焼入れ性のバラツキの
大きい等軸晶域を減少させて、ミクロ的な成分偏析が小
さく焼入性のバラツキの小さい柱状晶域を増大させるこ
とにより、焼入歪量が非常に小さく制限できるものであ
る。
As shown in FIG. 2, it is known that columnar crystals 1 are formed in the early stage of casting and equiaxed crystals 2 are formed in the later stage of casting. In this case, the content of the hardenability improving elements such as C and Cr is large, and the degree of segregation of the components of the hardenability improving elements is increased microscopically. For this reason, the hardenability partially differs greatly in the equiaxed crystal region, and it is considered that this variation in hardenability causes distortion during carburizing and quenching. Therefore, in the present invention, by reducing the equiaxed crystal region where the micro component segregation is large and the hardenability variation is large, and increasing the columnar crystal region where the micro component segregation is small and the hardenability variation is small, The amount of quenching distortion can be limited to a very small value.

【0013】また鋳造最終段階の凝固時に中心部付近に
生成する中心偏析帯はその周囲よりもCやCr等の焼入
性向上元素がかなり高くなっていることから、中心偏析
帯は周囲よりも焼入性が高い。この中心偏析帯が鋼材の
中心より離れた位置に存在する場合、浸炭焼入れ時に中
心偏析帯においては周囲に比べマルテンサイトが生成し
易く、且つ変態膨張量も大きくなり、片側に偏った歪が
発生してしまう。一方、中心偏析帯が中心付近に存在す
る場合は、全円周方向または厚み方向に対して均一に変
形が発生する。従って、図2に示す様に、棒状圧延材の
横断面における中心偏析帯の中心と前記横断面の中心と
の距離をa、圧延材の直径をDとする時、a/Dの値を
0.05以下とすることが、浸炭焼入れ時の熱処理歪を
低減させる上で望ましい。
Further, since the center segregation zone formed near the center during solidification in the final stage of casting has considerably higher hardenability improving elements such as C and Cr than its surroundings, the center segregation zone is higher than the surroundings. High hardenability. If this central segregation zone exists at a position away from the center of the steel material, martensite is more likely to be generated in the central segregation zone than in the surroundings during carburizing and quenching, and the amount of transformation expansion increases, resulting in a strain on one side. Resulting in. On the other hand, when the center segregation zone exists near the center, deformation occurs uniformly in the entire circumferential direction or the thickness direction. Therefore, as shown in FIG. 2, when the distance between the center of the central segregation zone in the cross section of the rod-shaped rolled material and the center of the cross-section is a and the diameter of the rolled material is D, the value of a / D is 0. 0.05 or less is desirable in order to reduce heat treatment distortion during carburizing and quenching.

【0014】更に、凝固最終段階で凝固する等軸晶域
は、先に凝固する柱状晶域に比べてCやCr等の焼入性
向上元素のミクロ的な偏析が大きい。このため、等軸晶
域では焼入性のバラツキが大きく、このバラツキが浸炭
焼入れ時の歪の原因となっている。この焼入れ性のバラ
ツキの大きい等軸晶域が、中心よりもずれた位置に存在
した場合、片側で等軸晶領域が大きくなり、浸炭焼入れ
時に、片側に偏った歪が発生してしまう。これに対し
て、等軸晶の中心が圧延材の中心付近に存在する場合
は、全円周方向に対して均一に変形するため、全周に均
一に変形が発生する。従って、図2に示す様に、棒状圧
延材の横断面における等軸晶域の中心と前記横断面の中
心との距離をb、圧延材の直径をDとする時、b/Dの
値を0.05以下とすることが、浸炭焼入れ時の熱処理
歪を低減させる上で推奨される。
Further, in the equiaxed crystal region solidified in the final solidification stage, micro segregation of hardenability improving elements such as C and Cr is larger than in the columnar crystal region solidified first. For this reason, in the equiaxed crystal region, variation in hardenability is large, and this variation causes distortion during carburizing and quenching. If the equiaxed crystal region having a large variation in hardenability is located at a position deviated from the center, the equiaxed crystal region becomes large on one side, and one-sided strain occurs during carburizing and quenching. On the other hand, when the center of the equiaxed crystal exists near the center of the rolled material, the deformation occurs uniformly in the entire circumferential direction, and thus the deformation occurs uniformly in the entire circumference. Therefore, as shown in FIG. 2, when the distance between the center of the equiaxed crystal region in the cross section of the rod-shaped rolled material and the center of the cross section is b and the diameter of the rolled material is D, the value of b / D is It is recommended to be 0.05 or less in order to reduce heat treatment distortion during carburizing and quenching.

【0015】尚、等軸晶域を面積率で30%以下に制御
するにあたっては、比較的大きな速度で冷却を施しなが
ら連続鋳造を行うことが望ましく、鋳造開始から約80
0℃までを4℃/min以上の速度で冷却することが好
ましい。また連続鋳造の際に、電磁撹拌を行うと等軸晶
域が大きくなり易いので、電磁撹拌は極力制限すること
が推奨される。
In controlling the equiaxed crystal area to an area ratio of 30% or less, continuous casting is desirably performed while cooling at a relatively high speed.
It is preferable to cool to 0 ° C. at a rate of 4 ° C./min or more. In addition, in the case of continuous casting, when electromagnetic stirring is performed, the equiaxed crystal region is likely to be large. Therefore, it is recommended to limit the electromagnetic stirring as much as possible.

【0016】さらに中心偏析帯は、例えば鋳片の片側側
面だけから冷却を施した場合に圧延材中心からずれるの
で、できるだけ鋳片の全周から均一に冷却を施すことが
望ましい。また等軸晶域の中心は、冷却速度が遅く、或
いは鋳片の片側だけを冷却するような不均一冷却の場合
に、圧延材中心からずれて前記b/Dの値が0.05を
超えるので、冷却速度を比較的速くし、且つ鋳片の全周
から均一に冷却を施すことが望ましい。
Furthermore, since the center segregation zone is shifted from the center of the rolled material when cooling is performed only from one side surface of the slab, it is desirable to cool the slab as uniformly as possible from the entire circumference. In the case of a slow cooling rate or non-uniform cooling in which only one side of the slab is cooled, the value of the b / D exceeds 0.05 at the center of the equiaxed crystal region because of the deviation from the center of the rolled material. Therefore, it is desirable that the cooling rate be relatively high and that the casting be uniformly cooled from the entire circumference.

【0017】また化学成分に関しては、少なくとも
C,Si,Mn,Al,Nを以下の範囲で含有させ、残
部をFe及び不可避的不純物とすることが望ましい。
Regarding the chemical components, it is desirable that at least C, Si, Mn, Al, and N are contained in the following ranges, and the balance is Fe and inevitable impurities.

【0018】C:0.01〜0.50% Cは、強化元素として浸炭焼入れ時に芯部硬さを付与
し、必要な有効硬化層深さを得るのに効果的な元素であ
ることから0.01%以上含有させることが必要であ
り、0.10%以上であると望ましい。但し、多過ぎる
と焼入れ時の芯部の変態膨張量が大きくなって熱処理歪
が大きくなり、また被削性や靱性が劣化するので上限は
0.50%とすることが必要であり、0.25%以下で
あると望ましい。
C: 0.01 to 0.50% C is an effective element for imparting core hardness during carburizing and quenching as a strengthening element and for obtaining a required effective hardened layer depth. It is necessary to contain at least 0.01%, and desirably at least 0.10%. However, if it is too large, the amount of transformation expansion of the core during quenching increases and the heat treatment strain increases, and the machinability and toughness deteriorate. Therefore, the upper limit must be 0.50%. It is desirable that it is 25% or less.

【0019】Si:2.0%以下(0%を含まない) Siは、溶製時に脱酸材として有効に作用する他、強化
元素として芯部硬さの向上に寄与するが、多過ぎると浸
炭性を阻害すると共に粒界酸化を助長して曲げ疲労特性
にも悪影響を及ぼすので上限を2.0%とした。より好
ましくは0.8%以下である。
Si: 2.0% or less (excluding 0%) Si not only functions effectively as a deoxidizer at the time of melting but also contributes to the improvement of core hardness as a strengthening element. The upper limit is set to 2.0% because it inhibits carburization and promotes grain boundary oxidation, adversely affecting bending fatigue properties. More preferably, it is 0.8% or less.

【0020】Mn:0.20〜2.5% Mnは、脱酸材として有効に作用する他、焼入性を高め
て表層及び芯部硬さを高め、疲労強度の向上に寄与する
元素である。それらの作用を有効に発揮するには0.2
0%以上含有させなければならない。より好ましくは
0.3%以上である。一方、多過ぎると素材が硬くなり
過ぎて冷圧性や被削性が悪くなると共に、焼入れ時の芯
部の変態膨張量が大きくなって熱処理歪が大きくなるの
で上限を2.5%とした。好ましくは1.6%以下であ
る。
Mn: 0.20 to 2.5% Mn is an element that effectively acts as a deoxidizing material, and also enhances hardenability, increases the hardness of the surface layer and the core, and contributes to the improvement of fatigue strength. is there. In order to exert those effects effectively, 0.2
Must be contained at 0% or more. It is more preferably at least 0.3%. On the other hand, if the content is too large, the material becomes too hard to deteriorate the cold pressure property and machinability, and the amount of transformation expansion of the core at the time of quenching increases and the heat treatment distortion increases, so the upper limit was set to 2.5%. Preferably it is 1.6% or less.

【0021】Al:0.01〜1.0% Alは、浸炭加熱時におけるオーステナイト結晶粒の成
長を抑えることにより歪を抑制するのに有効な元素であ
り、0.01%以上の添加が必要である。但し、1.0
%を超えて添加してもこの効果は飽和するため上限を
1.0%とした。好ましくは0.04%以下である。
Al: 0.01 to 1.0% Al is an element effective for suppressing the distortion by suppressing the growth of austenite crystal grains during carburizing heating, and it is necessary to add 0.01% or more. It is. However, 1.0
%, The effect is saturated, so the upper limit was made 1.0%. Preferably it is 0.04% or less.

【0022】N:0.003〜0.03% Nは、Alと結合してAlNを生成しオーステナイト結
晶粒の成長を抑制する元素である。この効果を発揮する
ためには0.003%以上の添加が必要である。しか
し、0.03%を超えて過多に含有させると鍛造時や熱
間加工時に割れを起こし易くなるため、上限を0.03
%とした。好ましくは0.02%以下である。
N: 0.003 to 0.03% N is an element that combines with Al to form AlN and suppresses the growth of austenite crystal grains. In order to exhibit this effect, 0.003% or more must be added. However, if the content is excessively larger than 0.03%, cracks are likely to occur during forging or hot working.
%. Preferably it is 0.02% or less.

【0023】また焼入性の一層の向上を目的として、
上記成分に加えてBを含有させてもよく、その場合に
は、N含有量を更に制限した上で、Tiを併用すること
が望ましい。
For the purpose of further improving hardenability,
B may be contained in addition to the above components. In this case, it is desirable to further limit the N content and then use Ti in combination.

【0024】B:0.01%以下(0%を含まない) Bは、少量の添加で焼入性を高めると共に、粒界強度を
向上させるのに有用な元素である。但し、多過ぎてもそ
の効果は飽和するので、上限を0.01%とした。
B: 0.01% or less (excluding 0%) B is an element useful for improving hardenability and improving grain boundary strength by adding a small amount. However, the effect is saturated even if it is too much, so the upper limit was made 0.01%.

【0025】Ti:0.005〜0.3% Tiは鋼の脱酸、脱窒に有効に作用する他、結晶粒の微
細化に有効であるから、B含有の有無に限らず含有させ
ることが望ましいが、Bと併用する場合には、特に鋼中
のNを固定してBを有効に働かせる効果も発揮する。こ
の様なTiの添加効果を発揮するためには0.005%
以上の添加が必要である。但し、多過ぎると粗大なTi
N等の硬質介在物が多量生成して曲げ疲労特性や転動疲
労特性を劣化させるので0.3%以下とする。好ましく
は0.1%以下であり、0.05%以下であるとより好
ましい。
Ti: 0.005 to 0.3% Ti is effective not only for deoxidation and denitrification of steel but also for refining crystal grains. However, when it is used in combination with B, the effect of fixing N in steel and making B work effectively is also exhibited. In order to exhibit such an effect of adding Ti, 0.005%
The above addition is necessary. However, if too much, coarse Ti
Since a large amount of hard inclusions such as N are generated to deteriorate the bending fatigue characteristics and the rolling fatigue characteristics, the content is set to 0.3% or less. It is preferably at most 0.1%, more preferably at most 0.05%.

【0026】N:0.002〜0.01% Bと共に添加する場合に、Nが多過ぎるとBと結びつい
てBNとなりBの焼入性向上効果を阻害するので、Nは
少なめに添加することが望ましく、下限を0.002%
として上限を0.01%とすることが望ましい。
N: 0.002 to 0.01% When B is added together with B, if N is too large, it is combined with B and becomes BN, impairing the effect of improving the hardenability of B. Therefore, N should be added in a small amount. Is desirable, and the lower limit is 0.002%
It is desirable to set the upper limit to 0.01%.

【0027】更に焼入性の向上を目的として、Ni,
Cr,Mo,Cuを以下の範囲で添加しても良い。
In order to further improve hardenability, Ni,
Cr, Mo, and Cu may be added in the following ranges.

【0028】Ni:0.2〜4.5% Niは、表面硬化部の焼入性を確保して不完全焼入組織
の生成を抑えると共に靱性の向上に有効な元素であり、
このためには0.2%以上の添加が必要である。但し、
多過ぎても芯部硬さが高くなりすぎ、かえって焼入歪を
増大させるので上限を4.5%とした。より好ましくは
2.0%以下である。
Ni: 0.2 to 4.5% Ni is an element effective for securing hardenability of the surface hardened portion to suppress generation of an incompletely hardened structure and improving toughness.
For this purpose, it is necessary to add 0.2% or more. However,
Even if it is too large, the core hardness becomes too high, and the quenching strain is rather increased. Therefore, the upper limit is set to 4.5%. It is more preferably at most 2.0%.

【0029】Cr:0.2〜6.0% Crは、焼入性を向上させ、浸炭焼入れ時の有効硬化層
深さや芯部硬さを確保するのに有効な元素である。その
ためには0.2%以上の添加が必要であり、0.3%以
上であれば望ましい。一方、多過ぎると浸炭性を阻害す
るばかりでなく、芯部硬さが増大しすぎて、歪が大きく
なるため、上限を6.0%とした。好ましくは2.0%
以下である。
Cr: 0.2 to 6.0% Cr is an element effective for improving hardenability and ensuring the effective hardened layer depth and core hardness during carburizing and quenching. For that purpose, addition of 0.2% or more is necessary, and 0.3% or more is desirable. On the other hand, if the content is too large, not only does the carburizing property be impaired, but the core hardness also increases too much and the strain increases, so the upper limit was made 6.0%. Preferably 2.0%
It is as follows.

【0030】Mo:0.05〜1.0% Moは、表面硬化部の焼入性を確保して不完全焼入れ層
の生成を抑制したり、有効硬化層深さを深くして芯部硬
さを高め、さらにはオーステナイト結晶粒を微細化して
曲げ疲労強度や靱性の向上に有用な元素であることか
ら、0.05%以上含有させることが望ましい。但し、
多くなり過ぎると芯部硬さが高くなりすぎて歪を増大さ
せると共に被削性の低下も招くので1.0%以下とする
ことが望ましく、0.5%以下であるとより好ましい。
Mo: 0.05 to 1.0% Mo secures the hardenability of the hardened surface to suppress the formation of an incompletely hardened layer, or increases the effective hardened layer depth to harden the core. It is an element useful for improving flexural fatigue strength and toughness by increasing the austenitic crystal grain by further improving the austenitic crystal grain, and therefore, it is desirable to contain 0.05% or more. However,
If it is too large, the core hardness becomes too high, which increases the strain and lowers the machinability. Therefore, the content is preferably 1.0% or less, more preferably 0.5% or less.

【0031】Cu:0.2〜1.0% Cuは、焼入性を高めると共に靱性の向上に有効な元素
であり、且つ耐食性の向上にも有効である。この効果を
十分に発揮させるには0.2%以上含有することが望ま
しい。但し、多過ぎると熱間割れを生じ易くなって熱間
加工性を阻害するので上限は1.0%とすることが望ま
しく、0.6%以下とすることがより好ましい。
Cu: 0.2 to 1.0% Cu is an element that is effective in improving hardenability and improving toughness, and is also effective in improving corrosion resistance. In order to sufficiently exhibit this effect, it is desirable to contain 0.2% or more. However, if the content is too large, hot cracking is likely to occur and hot workability is impaired. Therefore, the upper limit is preferably set to 1.0%, more preferably 0.6% or less.

【0032】またV及びNbは、Tiと同様に結晶粒
の微細化に有効であり靭性の向上に効果的であるので以
下の範囲で含有させることが望ましい。
V and Nb, like Ti, are effective in refining crystal grains and effective in improving toughness. Therefore, V and Nb are desirably contained in the following ranges.

【0033】V:0.03〜1.5% Vは、炭化物を生成して結晶粒を微細化させるのに有効
であり、また炭化物の安定性を高め、軟化抵抗を高める
ことにより転動疲労強度を向上させるのに効果的である
ので0.03%含有させることが好ましく、0.20%
以上であればより好ましい。但し、多過ぎると芯部のA
3 ,A1 変態点が大幅に低下し、芯部のオーステナイト
化が不十分となり焼入れによって焼きが入らず、硬さが
低くなるので、上限は1.5%とすべきであり、1.0
%以下とすることがより好ましい。
V: 0.03 to 1.5% V is effective for forming carbides to refine crystal grains, and also enhances the stability of the carbides and the rolling resistance by increasing the softening resistance. Since it is effective to improve the strength, it is preferable to contain 0.03%, and 0.20%
The above is more preferable. However, if too much, A
3 , the A 1 transformation point is greatly reduced, the austenitization of the core is insufficient, the quenching does not cause quenching, and the hardness is low. Therefore, the upper limit should be 1.5%, and the upper limit should be 1.0%.
% Is more preferable.

【0034】Nb:0.005〜1.5% Nbは結晶粒の微細化に効果があるので、0.005%
以上含有させることが望ましく、0.01%以上含有さ
せればより望ましい。但し、過度に添加しても効果は飽
和するので、1.5%以下の添加量でよく1.0%以下
がより好ましい。
Nb: 0.005 to 1.5% Since Nb is effective in refining crystal grains, 0.005%
More preferably, the content is more preferably 0.01% or more. However, the effect is saturated even if it is added excessively, so the addition amount may be 1.5% or less, more preferably 1.0% or less.

【0035】S,Ca,Pb,Te,Zrはいずれも
被削性向上元素であり、夫々以下の範囲で添加すること
が推奨される。
S, Ca, Pb, Te, and Zr are all machinability improving elements, and it is recommended to add each of them in the following ranges.

【0036】S :0.02〜0.3% Sは、被削性向上元素であり、0.02%以上含有させ
ることが望ましいが、多量に含有させ過ぎるとMnSが
多く生成し、横目(圧延方向と垂直な方向)の疲労特性
や衝撃特性に悪影響を与えるので上限は0.3%とする
ことが好ましい。
S: 0.02 to 0.3% S is an element for improving machinability, and is desirably contained in an amount of 0.02% or more. The upper limit is preferably set to 0.3%, since it has an adverse effect on the fatigue characteristics and impact characteristics in the direction perpendicular to the rolling direction).

【0037】Ca:0.0003〜0.01% Caは、MnSと硫化物系介在物を形成することによ
り、介在物を球状化して異方性を改善し靱性および曲げ
疲労強度を劣化させずに被削性を向上させることができ
るので0.0003%以上添加することが望ましく、
0.0008%以上がより望ましい。一方、0.01%
を超えると粗大な複合介在物が多数生成して、曲げ疲労
特性、転動疲労特性が劣化するので、上限は0.01%
とすべきであり、0.005%以下の含有量が望まし
い。
Ca: 0.0003 to 0.01% Ca forms sulfide-based inclusions with MnS, thereby spheroidizing the inclusions to improve anisotropy and not deteriorating toughness and bending fatigue strength. Therefore, it is desirable to add 0.0003% or more because machinability can be improved.
0.0008% or more is more desirable. On the other hand, 0.01%
If more than, a large number of coarse composite inclusions are formed and the bending fatigue characteristics and the rolling fatigue characteristics deteriorate, so the upper limit is 0.01%.
And a content of 0.005% or less is desirable.

【0038】Pb:0.3%以下(0%を含まない) Pbも被削性向上元素であるが、0.3%を超えて添加
すると曲げ疲労強度や転動疲労寿命が大幅に低下するた
め上限を0.3%とした。より好ましくは0.1%以下
である。
Pb: 0.3% or less (excluding 0%) Pb is also an element for improving machinability, but when added in excess of 0.3%, bending fatigue strength and rolling fatigue life are significantly reduced. Therefore, the upper limit is set to 0.3%. It is more preferably at most 0.1%.

【0039】Te:0.1%以下(0%を含まない) TeはMn−Teを形成してMnSの周辺に共存し、熱
間圧延時にMnSの変形を抑制してMnSの球状化に寄
与することによって、横目の靱性および曲げ疲労強度を
劣化させずに被削性を向上させる。但し、0.1%を超
えると非金属介在物の増大により曲げ疲労強度を劣化さ
せるので上限を0.1%とした。
Te: 0.1% or less (excluding 0%) Te forms Mn-Te and coexists around MnS, suppresses deformation of MnS during hot rolling and contributes to spheroidization of MnS. By doing so, the machinability is improved without deteriorating the toughness of the grain and the bending fatigue strength. However, if it exceeds 0.1%, the bending fatigue strength is degraded due to an increase in nonmetallic inclusions, so the upper limit was made 0.1%.

【0040】Zr:0.1%以下(0%を含まない) Zrは熱間圧延時にMnSの変形を抑制してMnSの球
状化に寄与することによって、異方性を改善し、靱性お
よび曲げ疲労強度を劣化させずに被削性を向上させる。
但し、0.1%を超えるとZrO2 等の非金属介在物が
多く生成し、曲げ疲労強度を劣化させるので上限を0.
1%とした。
Zr: 0.1% or less (excluding 0%) Zr suppresses deformation of MnS during hot rolling and contributes to spheroidization of MnS, thereby improving anisotropy, and improving toughness and bending. Improves machinability without deteriorating fatigue strength.
However, if it exceeds 0.1%, a large amount of non-metallic inclusions such as ZrO 2 are generated and the bending fatigue strength is deteriorated.
1%.

【0041】なお、本発明の肌焼鋼を部品に適用する場
合には、部品に加工した後、通常の方法により浸炭焼入
れを行えばよいが、ガス,真空,プラズマ等による浸炭
処理または浸炭窒化処理を行うか、もしくは軟窒化処理
を行い、或いは浸炭後に高周波焼入れ処理を行い、必要
によりショットピーニング加工を行って表面を強化して
もよい。
When the case hardening steel of the present invention is applied to a part, it may be processed into a part and then carburized and quenched by a usual method. The surface may be strengthened by performing a treatment, performing a soft nitriding treatment, or performing an induction hardening treatment after carburizing, and performing a shot peening process as necessary.

【0042】以下、本発明を実施例によって更に詳細に
説明するが、下記実施例は本発明を限定する性質のもの
ではなく、前・後記の主旨に徴して設計変更することは
いずれも本発明の技術的範囲に含まれるものである。
Hereinafter, the present invention will be described in more detail with reference to Examples. However, the following Examples are not intended to limit the present invention. It is included in the technical range of.

【0043】[0043]

【実施例】表1に示す化学組成の鋼材を溶製し、鋳造時
の等軸晶の割合を変化させるために、鋳造開始から80
0℃までの冷却速度を次の様に、鋼材により夫々変えて
鋳造した。即ち、鋼No.1〜21は10℃/minで冷
却し、No.22は7℃/minで冷却し、No.23
〜25は、冷却速度2℃/minで鋳造を行った。尚、
No.21,22とNo.24,25は、中心偏析帯及
び等軸晶域の中心が圧延材中心からずれて形成されてい
ることの影響を調べるため、鋳片の片方のみを水冷し
た。また、No.23以外は、曲げ連鋳で鋳造を行い、
No.23は造塊法で鋳造し、次いでφ80mmの丸棒
に圧延した。
EXAMPLE In order to change the ratio of equiaxed crystals at the time of casting a steel material having the chemical composition shown in Table 1 and to change the ratio of the equiaxed crystal at the time of casting, 80% of the steel was used.
Casting was performed by changing the cooling rate to 0 ° C depending on the steel material as follows. That is, steel Nos. 1 to 21 were cooled at 10 ° C./min. No. 22 was cooled at 7 ° C./min. 23
No. 25 to 25 were cast at a cooling rate of 2 ° C./min. still,
No. Nos. 21 and 22 and Nos. In Nos. 24 and 25, only one of the cast slabs was water-cooled in order to investigate the influence of the center segregation zone and the center of the equiaxed crystal region being shifted from the center of the rolled material. In addition, No. Except 23, cast by bending continuous casting,
No. No. 23 was cast by an ingot-making method, and then rolled into a φ80 mm round bar.

【0044】その後、各圧延材の横断面にてマクロ試験
を行い、圧延材横断面中の等軸晶の占める割合を面積率
で示した。等軸晶域の測定は、JIS G 0553に
規定された鋼のマクロ組織試験方法に準じて、約20%
HCl液中で約30〜40秒間腐食し、等軸晶と柱状晶
に分離し、等軸晶域の面積率を測定し、更に中心偏析帯
および等軸晶域の中心と横断面の中心との距離を測定し
た。なお、等軸晶と柱状晶が混在している領域(分岐柱
状晶域)はすべて等軸晶域に分類した。測定結果は表2
に示す。
Thereafter, a macro test was performed on the cross section of each rolled material, and the proportion of the equiaxed crystals in the cross section of the rolled material was indicated by the area ratio. The measurement of the equiaxed crystal area is performed by about 20% according to the macrostructure test method for steel specified in JIS G 0553.
Corroded for about 30 to 40 seconds in HCl solution, separated into equiaxed crystals and columnar crystals, measured the area ratio of the equiaxed crystal region, and further determined the center of the center segregation zone and the center of the equiaxed crystal region and the center of the cross section. Was measured. All the regions where the equiaxed crystals and the columnar crystals are mixed (branched columnar crystal regions) were all classified into the equiaxed crystal regions. Table 2 shows the measurement results.
Shown in

【0045】これらの鋼材をそれぞれ200mmの長さ
に切断した後、熱間鍛造にて高さ28mmの円板に据込
み加工し、加熱(900℃×1Hr)→空冷の焼ならし
処理を行った。その後、図3に示す様なリング型試験片
を切り出し、図4に示す様にカーボンポテンシャル0.
8%で浸炭処理(920℃×2Hr+850℃×0.5
Hr)を施した後、130℃のオイル中で焼入れを行
い、続いて170℃×2Hrの焼戻しを行った。その
後、図3に示す位置において端面の平坦度及び外径真円
度を測定した。
After cutting each of these steel materials to a length of 200 mm, they were hot-forged into a 28 mm-high disc and heated (900 ° C. × 1 hr) → air-cooled normalizing treatment. Was. Thereafter, a ring-shaped test piece as shown in FIG. 3 was cut out, and as shown in FIG.
Carburizing treatment at 8% (920 ° C × 2Hr + 850 ° C × 0.5
After performing (Hr), quenching was performed in oil at 130 ° C., followed by tempering at 170 ° C. × 2 hours. Thereafter, the flatness of the end face and the roundness of the outer diameter were measured at the positions shown in FIG.

【0046】また、上記圧延材をφ30mmに鍛造後、
加熱(900℃×1Hr)→空冷の焼ならし処理を行っ
た後、図5に示すφ20mm×200mmの軸型試験片
に加工した。さらに、図4に示す前記浸炭処理及び焼入
れ・焼戻し処理を行い、その後、図5に示す位置におい
て軸の曲がりを測定した。測定結果は表2に併記する。
After forging the rolled material to φ30 mm,
After performing a normalization process of heating (900 ° C. × 1 hr) → air cooling, it was processed into a φ20 mm × 200 mm shaft type test piece shown in FIG. Further, the carburizing treatment and the quenching / tempering treatment shown in FIG. 4 were performed, and thereafter, the bending of the shaft was measured at the position shown in FIG. The measurement results are also shown in Table 2.

【0047】[0047]

【表1】 [Table 1]

【0048】[0048]

【表2】 [Table 2]

【0049】No.1〜22は、等軸晶の面積率が30
%以下である本発明鋼であり、等軸晶面積率が30%を
超える比較鋼No.23〜25と比較して、端面の平坦
度及び外径真円度が高く、また軸の曲がりも少なかっ
た。尚、比較鋼No.24,25は、等軸晶の面積率が
高いだけでなく、中心偏析帯及び等軸晶中心のズレも大
きく、特に外形真円度が悪かった。
No. 1 to 22 have an equiaxed crystal area ratio of 30.
% Of the present invention steel having an equiaxed crystal area ratio of more than 30%. As compared with 23 to 25, the flatness of the end face and the roundness of the outer diameter were higher, and the bending of the shaft was less. In addition, comparative steel No. In Nos. 24 and 25, not only the area ratio of the equiaxed crystal was high, but also the deviation of the center segregation zone and the center of the equiaxed crystal was large, and particularly the outer roundness was poor.

【0050】またNo.16〜20は、等軸晶の面積率
は30%以下であり、中心偏析帯及び等軸晶中心のズレ
も少ないが、C,Si,Mn,Al,Nの含有量が多過
ぎるか、少な過ぎる場合の本発明例であり、No.16
〜18は夫々C,Si,Mnの含有量が多いため焼入れ
性が高くNo.1〜15の本発明鋼に比較すると熱処理
歪が大きくなっている。No.19,20は夫々Al,
Nの含有量が少なく、浸炭焼入れ時にオーステナイト結
晶粒が粗大となり、No.1〜15の本発明鋼に比較す
ると熱処理歪が大きくなっている。
No. In Nos. 16 to 20, the area ratio of the equiaxed crystal is 30% or less, and the deviation of the center segregation zone and the center of the equiaxed crystal is small, but the content of C, Si, Mn, Al, N is too large or small. This is an example of the present invention when it is too long. 16
Nos. 18 to 18 have high hardenability due to high contents of C, Si and Mn, respectively. The heat treatment strain is larger than those of the steels of Nos. 1 to 15 of the present invention. No. 19 and 20 are Al,
N content is small, and austenite crystal grains become coarse during carburizing and quenching. The heat treatment strain is larger than those of the steels of Nos. 1 to 15 of the present invention.

【0051】No.21,22は、等軸晶の面積率が3
0%以下である本発明鋼であり、比較鋼と比較すると熱
処理歪は非常に少ないが、いずれも中心偏析帯が鋳片中
心よりずれており、No.22は等軸晶中心のズレも大
きく、No.1〜15の本発明鋼に比較すると軸の曲が
りが大きくなっている。
No. 21 and 22 have an equiaxed crystal area ratio of 3
The steel of the present invention is 0% or less, and the heat treatment strain is very small as compared with the comparative steel, but the center segregation zone is shifted from the center of the slab in any case. In No. 22, the deviation of the center of the equiaxed crystal was large. Compared with the inventive steels Nos. 1 to 15, the bending of the shaft is large.

【0052】[0052]

【発明の効果】本発明は以上の様に構成されており、鋼
材鋳造時の等軸晶域の面積率を制御することにより、望
ましくは更に中心偏析帯及び等軸晶中心の位置と成分組
成を制御することにより、浸炭焼入れ時に部品の拘束を
行ったり、浸炭焼入れ後に形状の修正を行う等しなくて
も熱処理歪を少なくできる肌焼鋼であって、しかも焼入
時に特定の焼入剤等を必要としない肌焼鋼が提供できる
こととなった。
The present invention is constituted as described above. By controlling the area ratio of the equiaxed crystal zone at the time of casting a steel material, it is desirable to further position the center segregation zone and the center of the equiaxed crystal and to improve the composition of the component. Is a case hardening steel that can reduce heat treatment distortion without restraining parts during carburizing and quenching and without modifying the shape after carburizing and quenching. It is possible to provide case hardening steel that does not require the above.

【図面の簡単な説明】[Brief description of the drawings]

【図1】等軸晶の面積率と熱処理歪(端面の平坦度)の
関係を示すグラフである。
FIG. 1 is a graph showing the relationship between the area ratio of equiaxed crystals and heat treatment strain (flatness of end faces).

【図2】鋼材の断面の状態を示す説明図である。FIG. 2 is an explanatory view showing a state of a cross section of a steel material.

【図3】実施例で用いたリング型試験片の形状と熱処理
歪の測定位置を示す説明図である。
FIG. 3 is an explanatory diagram showing a shape of a ring-shaped test piece used in an example and a measurement position of a heat treatment strain.

【図4】実施例で採用した浸炭処理及び焼入れ・焼戻し
処理の条件を示す説明図である。
FIG. 4 is an explanatory diagram showing conditions of a carburizing process and a quenching / tempering process adopted in an example.

【図5】実施例で用いた軸型試験片の形状と熱処理歪の
測定位置を示す説明図である。
FIG. 5 is an explanatory diagram showing the shape of a shaft-type test piece used in an example and a measurement position of a heat treatment strain.

【符号の説明】[Explanation of symbols]

1 柱状晶 2 等軸晶 1 columnar crystal 2 equiaxed crystal

───────────────────────────────────────────────────── フロントページの続き (72)発明者 近藤 直哉 神戸市灘区灘浜東町2番地 株式会社神戸 製鋼所神戸製鉄所内 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Naoya Kondo 2 Nadahama-Higashi-cho, Nada-ku, Kobe Kobe Steel, Ltd. Inside Kobe Works

Claims (9)

【特許請求の範囲】[Claims] 【請求項1】 棒状圧延材の横断面において等軸晶の占
める領域が面積率で30%以下であることを特徴とする
熱処理歪の少ない肌焼鋼。
1. A case hardening steel having a small heat treatment strain, wherein the area occupied by equiaxed crystals in the cross section of the rod-shaped rolled material is 30% or less in terms of area ratio.
【請求項2】 棒状圧延材の横断面における中心偏析帯
の中心と前記横断面の中心との距離をa、圧延材の直径
をDとする時、a/Dの値が0.05以下である請求項
1に記載の肌焼鋼。
2. When the distance between the center of the central segregation zone in the cross section of the rod-shaped rolled material and the center of the cross-section is a and the diameter of the rolled material is D, the value of a / D is 0.05 or less. The case hardened steel according to claim 1.
【請求項3】 棒状圧延材の横断面における等軸晶域の
中心と前記横断面の中心との距離をb、圧延材の直径を
Dとする時、b/Dの値が0.05以下である請求項1
または2に記載の肌焼鋼。
3. When the distance between the center of the equiaxed crystal region and the center of the cross section in the cross section of the rod-shaped rolled material is b and the diameter of the rolled material is D, the value of b / D is 0.05 or less. Claim 1
Or the case hardened steel according to 2.
【請求項4】C :0.01〜0.50%(質量%の意
味、以下同じ) Si:2.0%以下(0%を含まない)、 Mn:0.20〜2.5%、 Al:0.01〜1.0%、 N :0.003〜0.03% を含有し、残部Feおよび不可避的不純物からなる請求
項1〜3のいずれかに記載の肌焼鋼。
4. C: 0.01 to 0.50% (meaning of mass%, the same applies hereinafter) Si: 2.0% or less (excluding 0%), Mn: 0.20 to 2.5%, The case hardening steel according to any one of claims 1 to 3, which contains 0.01 to 1.0% of Al and 0.003 to 0.03% of N and the balance is Fe and unavoidable impurities.
【請求項5】 さらに他の元素として Ti:0.005〜0.3% を含有するものである請求項4に記載の肌焼鋼。5. The case hardened steel according to claim 4, further comprising Ti: 0.005 to 0.3% as another element. 【請求項6】C :0.01〜0.30%、 Si:2.0%以下(0%を含まない)、 Mn:0.20〜2.5%、 Al:0.01〜1.0%、 B :0.01%以下(0%を含まない)、 Ti:0.005〜0.3%、 N :0.002〜0.01% を含有し、残部Feおよび不可避的不純物からなる請求
項1〜3のいずれかに記載の肌焼鋼。
6. C: 0.01 to 0.30%, Si: 2.0% or less (excluding 0%), Mn: 0.20 to 2.5%, Al: 0.01 to 1. 0%, B: 0.01% or less (excluding 0%), Ti: 0.005 to 0.3%, N: 0.002 to 0.01%, with the balance being Fe and inevitable impurities The case hardened steel according to any one of claims 1 to 3.
【請求項7】 さらに他の元素として Ni:0.2〜4.5%、 Cr:0.2〜6.0%、 Mo:0.05〜1.0%、 Cu:0.2〜1.0% よりなる群から選択される1種以上を含有するものであ
る請求項4〜6のいずれかに記載の肌焼鋼。
7. Still other elements: Ni: 0.2 to 4.5%, Cr: 0.2 to 6.0%, Mo: 0.05 to 1.0%, Cu: 0.2 to 1 The case hardening steel according to any one of claims 4 to 6, comprising one or more selected from the group consisting of 0.0%.
【請求項8】 さらに他の元素として V :0.03〜1.5%、 Nb:0.005〜1.5% よりなる群から選択される1種以上を含有するものであ
る請求項4〜7のいずれかに記載の肌焼鋼。
8. The composition according to claim 4, further comprising at least one element selected from the group consisting of V: 0.03 to 1.5% and Nb: 0.005 to 1.5%. 8. The case hardened steel according to any one of items 1 to 7.
【請求項9】 さらに他の元素として S :0.02〜0.3%、 Ca:0.0003〜0.01%、 Pb:0.3%以下(0%を含まない)、 Te:0.1%以下(0%を含まない)、 Zr:0.1%以下(0%を含まない) よりなる群から選択される1種以上を含有するものであ
る請求項4〜8のいずれかに記載の肌焼鋼。
9. Other elements: S: 0.02 to 0.3%, Ca: 0.0003 to 0.01%, Pb: 0.3% or less (excluding 0%), Te: 0 10. 1% or less (excluding 0%), Zr: 0.1% or less (excluding 0%) It contains one or more selected from the group consisting of: Case hardening steel according to the above.
JP29137997A 1997-10-23 1997-10-23 Case hardened steel with little heat treatment distortion Expired - Lifetime JP3409275B2 (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
JP29137997A JP3409275B2 (en) 1997-10-23 1997-10-23 Case hardened steel with little heat treatment distortion

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Publication Number Publication Date
JPH11131184A true JPH11131184A (en) 1999-05-18
JP3409275B2 JP3409275B2 (en) 2003-05-26

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Country Link
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Cited By (10)

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Publication number Priority date Publication date Assignee Title
WO2010082481A1 (en) * 2009-01-16 2010-07-22 新日本製鐵株式会社 Case hardening steel, carburized component, and method for producing case hardening steel
JP4709944B2 (en) * 2009-01-16 2011-06-29 新日本製鐵株式会社 Case-hardened steel, carburized parts, and method for producing case-hardened steel
US8980022B2 (en) 2009-01-16 2015-03-17 Nippon Steel & Sumitomo Metal Corporation Case hardening steel, carburized component, and manufacturing method of case hardening steel
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