JPH1045516A - Herbicide composition - Google Patents

Herbicide composition

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Publication number
JPH1045516A
JPH1045516A JP8198787A JP19878796A JPH1045516A JP H1045516 A JPH1045516 A JP H1045516A JP 8198787 A JP8198787 A JP 8198787A JP 19878796 A JP19878796 A JP 19878796A JP H1045516 A JPH1045516 A JP H1045516A
Authority
JP
Japan
Prior art keywords
component
parts
weeds
composition
salts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP8198787A
Other languages
Japanese (ja)
Other versions
JP3799669B2 (en
Inventor
Tsutomu Nawamaki
勤 縄巻
Chiaki Kawaguchi
千秋 川口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissan Chemical Corp
Original Assignee
Nissan Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Chemical Corp filed Critical Nissan Chemical Corp
Priority to JP19878796A priority Critical patent/JP3799669B2/en
Publication of JPH1045516A publication Critical patent/JPH1045516A/en
Application granted granted Critical
Publication of JP3799669B2 publication Critical patent/JP3799669B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To obtain a herbicide composition exhibiting synergistic effect to control weeds at a low rate of application by mixing two specific kinds of known active herbicide components. SOLUTION: (A) carfentrazone is used in combination with (B) glyphosate. The component B includes various salts such as metal salts and amine salts. The amount of the component B is preferably about 0.1-1,000 pts.wt., especially 1-100 pts.wt. based on 1 pt.wt. of the component A. The application rate of the active component is about 0.1-1,000g/ha, preferably 10-100g/ha for the component A and about 10-10,000g/ha, preferably 100-1,000g/ha for the component B. The component A promotes the development of the herbicidal effect of the component B. The composition can be applied for the control of various weeds on non-crop land such as orchard, vacant land and forest and exhibits remarkable economic effect for the control of weeds. In the case of culturing various crops such as soybean, the composition is scattered before sowing to kill the existing grown weeds.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は2種類の公知の除草
剤活性成分を混合することにより各種の有害な雑草を効
率的に防除する除草剤組成物に関するものである。
TECHNICAL FIELD The present invention relates to a herbicide composition for efficiently controlling various harmful weeds by mixing two kinds of known herbicide active ingredients.

【0002】[0002]

【従来の技術及び課題】長年にわたる除草剤の研究開発
の中から多種多様な薬剤が実用化され、これら除草剤は
雑草防除作業の省力化や農園芸作物の生産性向上に寄与
してきた。今日においても、より優れた除草特性を有す
る新規薬剤の開発が要望され、特に農園芸用除草剤とし
ては、栽培作物に薬害を及ぼすことなく、対象雑草のみ
を選択的にかつ低薬量で防除しうることが望ましいが、
既存の薬剤は必ずしもこの要求を満たすものではない。
2. Description of the Related Art A wide variety of chemicals have been put into practical use from the research and development of herbicides over many years, and these herbicides have contributed to labor saving in weed control work and improvement in productivity of agricultural and horticultural crops. Even today, there is a demand for the development of new chemicals having better herbicidal properties. In particular, as an agricultural and horticultural herbicide, it is possible to control only the target weed selectively and at a low dose without damaging the cultivated crop. It is desirable to be able to
Existing drugs do not always meet this need.

【0003】カルフェントラゾン(一般名)は従来の除
草剤に比して茎葉処理においては各種広葉雑草に低薬量
で優れた除草効果を有するが成育が進んだイネ科雑草に
は十分な効果が得られない場合がある。一方、グリホサ
ート(一般名)は、各種塩類の形で実用場面ですでに使
用されており、優れた茎葉処理効果を有することが特徴
である。ただし、茎葉処理においては高い薬量が必要で
ある。
[0003] Carfentrazone (generic name) has an excellent herbicidal effect at a low dose on various broadleaf weeds in foliar treatment compared to conventional herbicides, but is sufficient for growing grass weeds. The effect may not be obtained. On the other hand, glyphosate (common name) has already been used in practical use in the form of various salts, and is characterized by having an excellent foliage treatment effect. However, a high dose is required in the foliage treatment.

【0004】[0004]

【課題を解決するための手段】本発明は、カルフェント
ラゾン(A)とグリホサート(B)を有効成分として含
有する除草剤組成物(以下、本発明組成物という)であ
る。
Means for Solving the Problems The present invention is a herbicide composition containing carfentrazone (A) and glyphosate (B) as active ingredients (hereinafter referred to as the composition of the present invention).

【0005】[0005]

【発明の実施の形態】(B)は各種塩類、例えば、金属
塩、アミン塩の形を含む。金属塩としては、ナトリウム
塩及びカリウム塩等があげられ、アミン塩としては、ア
ンモニウム塩、イソプロピルアミン塩及びトリメシウム
塩があげられる。本発明組成物は、(A)1重量部当た
り、(B)を0.1〜1000重量部を含む。好ましく
は、(A)1重量部当たり、(B)を1〜100重量部
を含む。
BEST MODE FOR CARRYING OUT THE INVENTION (B) includes various salts such as metal salts and amine salts. Examples of metal salts include sodium salts and potassium salts, and examples of amine salts include ammonium salts, isopropylamine salts, and trimesium salts. The composition of the present invention contains 0.1 to 1000 parts by weight of (B) per 1 part by weight of (A). Preferably, (B) is contained in an amount of 1 to 100 parts by weight per 1 part by weight of (A).

【0006】本発明組成物の処理薬量は、生育を阻止す
べき特定の対象植物の種類などにより左右されるが、有
効成分として、(A)が0.1〜1000g/ha、好
ましくは10〜100g/haであり、(B)が10〜
10000g/ha、好ましくは100〜1000g/
haである。本発明組成物は、本発明組成物中に含まれ
る(A)と(B)のそれぞれの除草効果が単に相加的に
得られるだけでなく、相乗的な作用を有し、それぞれの
使用薬量を低減できる。
[0006] The amount of the treated drug of the composition of the present invention depends on the type of the specific target plant to be inhibited from growing. -100 g / ha, and (B) is 10
10,000 g / ha, preferably 100 to 1000 g / ha
ha. The composition of the present invention has not only a herbicidal effect of each of (A) and (B) contained in the composition of the present invention additively obtained, but also has a synergistic action, and The amount can be reduced.

【0007】また、同時に(A)は(B)の除草効果の
発現を早める作用を有する。本発明組成物は、果樹園な
どの農園芸分野及び運動場、空き地、林地、タンクヤー
ド、線路端などの非農耕地における各種雑草の防除に適
用でき、雑草防除にあたって大きな経済的効果を示す。
また、本発明組成物は、耕起を行わずに、ダイズ、トウ
モロコシ等の各種作物を栽培する場合には、播種前に散
布することにより、既に発生している雑草を防除するこ
とができる。
At the same time, (A) has the effect of accelerating the onset of the herbicidal effect of (B). INDUSTRIAL APPLICABILITY The composition of the present invention can be applied to the control of various weeds in agricultural and horticultural fields such as orchards and non-cultivated lands such as playgrounds, vacant lots, forest lands, tank yards, track ends, and the like, and has a significant economic effect in controlling weeds.
When cultivating various crops such as soybean and corn without plowing, the composition of the present invention can control weeds that have already occurred by spraying before sowing.

【0008】本発明組成物は、通常固体または液体希釈
液からなる担体と混合した製剤の形態で使用するが、界
面活性剤を更に混合した製剤の形態での使用が好まし
い。担体として、例えば、クレー、タルク、ベントナイ
ト、珪藻土及びホワイトカーボン等の固体担体、並びに
水、アルコール類(イソプロパノール、ブタノール、ベ
ンジルアルコール、フルフリルアルコール等)、芳香族
炭化水素類(トルエン、キシレン等)、塩素化炭化水素
類(クロロベンゼン等)、エーテル類(アニソール
等)、ケトン類(シクロヘキサノン、イソホロン等)、
エステル類(酢酸ブチル等)及び酸アミド類(N−メチ
ルピロリドン等)等の液体担体があげられる。
[0008] The composition of the present invention is usually used in the form of a preparation mixed with a carrier comprising a solid or liquid diluent, but is preferably used in the form of a preparation further mixed with a surfactant. As the carrier, for example, solid carriers such as clay, talc, bentonite, diatomaceous earth, and white carbon, as well as water, alcohols (such as isopropanol, butanol, benzyl alcohol, and furfuryl alcohol), and aromatic hydrocarbons (such as toluene and xylene) , Chlorinated hydrocarbons (such as chlorobenzene), ethers (such as anisole), ketones (such as cyclohexanone, isophorone),
Liquid carriers such as esters (such as butyl acetate) and acid amides (such as N-methylpyrrolidone) are exemplified.

【0009】界面活性剤として、例えば、アルキルアリ
ールスルホン酸ナトリウム、アルキルナフタレンスルホ
ン酸ナトリウム、ジアルキル琥珀酸ナトリウム、ポリオ
キシエチレンアルキルアリールエーテルサルフェート、
アルキル型燐酸エステル及びアルキルフェノール型燐酸
エステル等のアニオン系界面活性剤、ポリオキシエチレ
ンアルキルエーテル、ポリオキシエチレンアルキルアリ
ールエーテル、ポリオキシエチレン(プロピレン)脂肪
酸エステル、ソルビタンモノオレート及びポリオキシエ
チレンソルビタンモノラウレート等のノニオン系界面活
性剤並びにポリオキシエチレン硬化ヒマシ油のような植
物誘導体があげられる。
Examples of the surfactant include sodium alkylaryl sulfonate, sodium alkylnaphthalene sulfonate, sodium dialkyl succinate, polyoxyethylene alkyl aryl ether sulfate,
Anionic surfactants such as alkyl phosphates and alkylphenol phosphates, polyoxyethylene alkyl ethers, polyoxyethylene alkyl aryl ethers, polyoxyethylene (propylene) fatty acid esters, sorbitan monooleate and polyoxyethylene sorbitan monolaurate And plant derivatives such as polyoxyethylene hydrogenated castor oil.

【0010】本発明組成物は、所望により乳化剤、湿潤
剤、分散剤、結合剤、浸透剤、展着剤、安定剤及び崩壊
剤等を添加し、乳剤、液剤、水和剤、粉剤、粒剤、顆粒
剤、懸濁剤又はゲル剤等任意の剤型にて実用に供するこ
とができる。この際、同時に複数の公知農薬との混合使
用も可能である。次に本発明化合物を用いる場合の製剤
の配合例を示す。但し本発明の配合例は、これらのみに
限定されるものではない。なお、以下の配合例において
「部」は重量部を意味する。 〔水和剤〕 (A)+(B) 5〜80部 固体担体 10〜85部 界面活性剤 1〜10部 その他 0〜5部 その他として、例えば、固結防止剤などがあげられる。 〔乳 剤〕 (A)+(B) 1〜30部 液体担体 30〜95部 界面活性剤 1〜15部 その他 0〜10部 その他として、例えば安定剤などがあげられる。 〔フロアブル剤〕 (A)+(B) 5〜70部 液体担体 15〜65部 界面活性剤 0.1〜12部 その他 0.1〜30部 その他として、例えば、凍結防止剤、増粘剤等があげら
れる。 〔粒状水和剤(ドライフロアブル剤)〕 (A)+(B) 20〜90部 固体担体 9〜60部 界面活性剤 1〜20部 その他 0〜40部 その他として、例えば崩壊剤等があげられる。
The composition of the present invention may optionally contain an emulsifier, a wetting agent, a dispersing agent, a binder, a penetrant, a spreading agent, a stabilizer, a disintegrating agent, and the like, and then prepare emulsions, solutions, wettable powders, powders, granules It can be put to practical use in any dosage form such as a drug, granule, suspension or gel. At this time, a mixture with a plurality of known agricultural chemicals can be used at the same time. Next, a formulation example of a preparation when the compound of the present invention is used is shown. However, the composition examples of the present invention are not limited to these. In the following formulation examples, "parts" means parts by weight. [Wettable powder] (A) + (B) 5 to 80 parts Solid carrier 10 to 85 parts Surfactant 1 to 10 parts Others 0 to 5 parts Others include, for example, an anti-caking agent. [Emulsion] (A) + (B) 1-30 parts Liquid carrier 30-95 parts Surfactant 1-15 parts Others 0-10 parts Others include, for example, stabilizers. [Floable agent] (A) + (B) 5 to 70 parts Liquid carrier 15 to 65 parts Surfactant 0.1 to 12 parts Others 0.1 to 30 parts Others include, for example, an antifreezing agent and a thickener. Is raised. [Granular wettable powder (dry flowable)] (A) + (B) 20 to 90 parts Solid carrier 9 to 60 parts Surfactant 1 to 20 parts Others 0 to 40 parts Others include, for example, disintegrants and the like. .

【0011】[0011]

【実施例】以下本発明組成物を実施例によりさらに具体
的に説明するが、本発明における化合物、製造量、剤型
等は実施例のみに限定されるものではない。なお、
「部」は全て重量部を意味する。 〔配合実施例1〕 フロアブル 化合物(A) 2部 グリホサート 30部 アグリゾール S−711 8部 (非イオン性界面活性剤:花王(株)商品名) ルノックス 1000C 0.5部 (アニオン性界面活性剤:東邦化学工業(株)商品名) 1%ロドポール水 20部 (増粘剤:ローンプーラン社商品名) エチレングリコール 8部 (凍結防止剤) 水 31.5部 以上を均一に混合して、フロアブル剤とする。
The composition of the present invention will be more specifically described below with reference to examples, but the compounds, production amounts, dosage forms, etc. in the present invention are not limited to the examples. In addition,
“Parts” all mean parts by weight. [Formulation Example 1] 2 parts of flowable compound (A) 30 parts of glyphosate 8 parts of agrisol S-711 8 parts (nonionic surfactant: trade name of Kao Corporation) Lunox 1000C 0.5 part (anionic surfactant: Toho Chemical Industry Co., Ltd. 1% Rhodopol water 20 parts (Thickener: Lone Poulin Co., Ltd.) Ethylene glycol 8 parts (Anti-freezing agent) Water 31.5 parts And

【0012】〔配合実施例2〕 粒状水和剤 化合物(A) 3部 グリホサート 72部 イソバンNo.1 10部 (アニオン性界面活性剤:クラレイソプレンケミカル
(株)商品名) バニレックスN 5部 (アニオン性界面活性剤:山陽国策パルプ(株)商品
名) カープレックス#80 10部 以上を均一に混合微粉砕して、粒状水和剤とする。
Formulation Example 2 Granular wettable powder compound (A) 3 parts Glyphosate 72 parts Isoban No. 1 10 parts (anionic surfactant: Kuraray Isoprene Chemical Co., Ltd.) Vanirex N 5 parts (anionic surfactant: Sanyo Kokusaku Pulp Co., Ltd.) Carplex # 80 10 parts Finely pulverized to a granular wettable powder.

【0013】次に、(A)と(B)を混合した場合に、
単剤どうしの効果から期待される効果を上回る効果を示
した試験例を示す。除草剤混合物の相乗的除草効果につ
いては、次のように説明することができる。即ち、個々
の活性化合物は、その除草活性にそれぞれ欠点を示す場
合が多くあるが、その場合2種の活性化合物を組み合わ
せた除草活性が、その2種の化合物の各々の活性の単純
な合計(期待される活性)よりも大きくなる場合にこれ
を相乗作用という。2種の除草剤の特定組み合わせによ
り期待される活性は、次のように計算することができ
る。(コルビー(Colby S.R.)、除草剤の組
み合わせの相乗および拮抗作用反応の計算、ウィード
(Weed)、第15巻、20〜22頁(1967年)
を参照)
Next, when (A) and (B) are mixed,
The test example which showed the effect exceeding the effect expected from the effect of a single agent is shown. The synergistic herbicidal effect of the herbicide mixture can be explained as follows. That is, the individual active compounds often exhibit disadvantages in their herbicidal activities, respectively, in which case the herbicidal activity of the combination of the two active compounds is simply the sum of the activities of each of the two compounds ( This is referred to as synergism when it is greater than the expected activity). The expected activity of a particular combination of two herbicides can be calculated as follows. (Colby SR, Calculation of synergistic and antagonistic responses of herbicide combinations, Weed, Vol. 15, 20-22 (1967)).
See

【0014】C=α+B−(α・β/100) α:除草剤Aをakg/haの量で処理した時の抑制率 β:除草剤Bをbkg/haの量で処理した時の抑制率 C:除草剤Aをakg/ha、除草剤Bをbkg/ha
の量で処理した場合に期待される抑制率 即ち、実際の抑制率が上記計算より大きいならば組み合
わせによる活性は相乗効果を示すということができる。
C = α + B− (α · β / 100) α: Inhibition rate when the herbicide A is treated at the amount of akg / ha β: Inhibition rate when the herbicide B is treated at the amount of bkg / ha C: Herbicide A akg / ha, Herbicide B bkg / ha
Inhibition rate expected when the treatment is performed with the amount of (i.e., if the actual inhibition rate is larger than the above calculation), it can be said that the activity by the combination shows a synergistic effect.

【0015】〔試験例1〕 生育期処理による除草効果
試験 プラスチック製4寸鉢に化学肥料、堆肥を混合した殺菌
畑地土壌を入れ、これにノビエもしくはハキダメギクを
播種した。温室内で20日間生育させ、草丈8〜15c
mの時期に試験を供した。(A)は適宜調製された水和
剤を、(B)(一般名グリホサート)は市販の各水溶剤
を用いて、所定濃度に希釈混合を行い、さらに展着剤と
してニッポールを0.05%となるように混合した。散
布にはスプレーガンを用い、5リットル/haの散布水
量で処理を入った。薬剤散布2週間後に各雑草の地上部
生体重を測定し、次の式で抑制率(%)を求めた。
[Test Example 1] Test of herbicidal effect by growing treatment A sterilized upland field mixed with a chemical fertilizer and a compost was put into a plastic four-size bowl, and seedlings of nobies or oaks were sown. Grow in a greenhouse for 20 days, plant height 8-15c
The test was performed at the time of m. (A) is an appropriately prepared wettable powder, and (B) (generic name glyphosate) is diluted and mixed to a predetermined concentration using a commercially available water solvent. Further, 0.05% of Nippole is used as a spreading agent. Were mixed so that The spraying was performed using a spray gun at a spraying water amount of 5 liters / ha. Two weeks after spraying the chemical, the above-ground live weight of each weed was measured, and the inhibition rate (%) was determined by the following equation.

【0016】抑制率(%)=(1−処理区の生体重/無
処理区の生体重)×100 第1表に(A)と(B)の単剤の除草効果を示した。第
2表に(A)と(B)の混合した場合の除草効果を示し
た。(表中、Eは実測値、Cは期待値を表し、期待値は
前記コルビーの式より求めた値を示す。) なお、表中の記号は以下を示す。
Inhibition rate (%) = (1−live weight of treated section / live weight of untreated section) × 100 Table 1 shows the herbicidal effects of the single agents (A) and (B). Table 2 shows the herbicidal effect when (A) and (B) were mixed. (In the table, E indicates an actual measurement value, C indicates an expected value, and the expected value indicates a value obtained from the Colby's formula.) The symbols in the table indicate the following.

【0017】N:ノビエ、H:ハキダメギクN: Nobie, H: Hawk-meadow

【0018】[0018]

【表1】 第1表 単剤の除草効果(抑制率%) ───────────────────────────────── 化合物 有効成分の処理量(g/ha) N H ───────────────────────────────── A 2.5 2 65 10 26 90 ───────────────────────────────── B 100 36 56 400 89 89 ───────────────────────────────── [Table 1] Table 1 Herbicidal effect of single agent (suppression rate%) Compound Treatment amount of active ingredient (g / ha) NH HA2.5 265 10 26 90 ───────────────────────────────── B 100 36 56 400 89 89 ───── ────────────────────────────

【0019】[0019]

【表2】 第2表 混合剤の除草効果(抑制率%) ───────────────────────────────── 各有効成分 N H の処理薬量 (g/ha) (E) (C) (E) (C) ───────────────────────────────── 2.5+100 80 37 100 85 2.5+400 100 89 100 96 10 +100 88 53 100 96 10 +400 100 92 100 99 ───────────────────────────────── [Table 2] Table 2 Herbicidal effect of mixture (suppression rate%) Treatment amount of each active ingredient NH (g / ha) (E) (C) (E) (C) ──────────────────────── {2.5 + 100 80 37 100 85 2.5 + 400 100 89 100 96 10 10 + 100 88 53 53 100 96 10 + 400 100 92 100 99} ──────────────────

【0020】以上の結果から明らかな様に、(A)と
(B)とを混合した場合のそれぞれの合計の除草効果に
とどまらず、相乗的な効果を有しており、低薬量で対象
雑草を防除することができる。
As is clear from the above results, when (A) and (B) are mixed, they have not only the total herbicidal effect but also a synergistic effect when they are mixed. Weeds can be controlled.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 カルフェントラゾンとグリホサートを有
効成分として含有する除草剤組成物。
1. A herbicidal composition comprising carfentrazone and glyphosate as active ingredients.
JP19878796A 1996-07-29 1996-07-29 Herbicidal composition Expired - Lifetime JP3799669B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP19878796A JP3799669B2 (en) 1996-07-29 1996-07-29 Herbicidal composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP19878796A JP3799669B2 (en) 1996-07-29 1996-07-29 Herbicidal composition

Publications (2)

Publication Number Publication Date
JPH1045516A true JPH1045516A (en) 1998-02-17
JP3799669B2 JP3799669B2 (en) 2006-07-19

Family

ID=16396909

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2769176A1 (en) * 1997-10-07 1999-04-09 Sumitomo Chemical Co Synergistic herbicidal formulations containing carfentrazone ethyl and glyphosate
WO1999051099A1 (en) * 1998-04-03 1999-10-14 Monsanto Company Combination of glyphosate and a triazolinone herbicide
WO2000064256A1 (en) * 1999-04-23 2000-11-02 Monsanto Technology Llc Enhanced herbicide compositions
US6245713B1 (en) 1996-10-25 2001-06-12 Monsanto Company Plant treatment compositions having enhanced biological effectiveness
JP2001328907A (en) * 2000-03-14 2001-11-27 Sumitomo Chem Co Ltd Water-based herbicidal composition
JP2002522458A (en) * 1998-08-13 2002-07-23 アベンティス・クロップサイエンス・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング Herbicidal composition for resistant or resistant corn crops
JP2002522457A (en) * 1998-08-13 2002-07-23 アベンティス・クロップサイエンス・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング Herbicide composition for resistant or resistant rice crops
EP1189511A4 (en) * 1999-06-22 2002-11-13 Fmc Corp Liquid herbicide composition
WO2002063955A3 (en) * 2001-02-14 2003-03-20 Monsanto Technology Llc Coformulation of carfentrazone-ethyl and glyphosate
WO2003055310A1 (en) * 2001-12-25 2003-07-10 Nihon Nohyaku Co., Ltd. Herbicidal compositions and method of using the same
US6689719B2 (en) 1999-08-11 2004-02-10 Monsanto Technology Llc Coformulation of carfentrazone-ethyl and glyphasate
US6713433B2 (en) 1999-08-11 2004-03-30 Monsanto Technology, Llc Coformulation of an oil-soluble herbicide and a water-soluble herbicide
US6774087B1 (en) 1999-06-22 2004-08-10 Fmc Corporation Liquid herbicide composition
CN106417356A (en) * 2016-09-13 2017-02-22 张先文 Method for quickly and effectively eradicating refractory plants in economic forest
CN108651480A (en) * 2018-05-04 2018-10-16 广西田园生化股份有限公司 A kind of application of ternary built herbicidal composition and its China fir forest land weeds control
CN114052031A (en) * 2021-12-08 2022-02-18 山东坤牛植物保护有限公司 Preparation method of synergistic weeding pesticide composition

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6245713B1 (en) 1996-10-25 2001-06-12 Monsanto Company Plant treatment compositions having enhanced biological effectiveness
FR2769176A1 (en) * 1997-10-07 1999-04-09 Sumitomo Chemical Co Synergistic herbicidal formulations containing carfentrazone ethyl and glyphosate
JP2002510605A (en) * 1998-04-03 2002-04-09 モンサント カンパニー Glyphosate and triazolinone herbicide combinations
WO1999051099A1 (en) * 1998-04-03 1999-10-14 Monsanto Company Combination of glyphosate and a triazolinone herbicide
US6127318A (en) * 1998-04-03 2000-10-03 Monsanto Company Combination of glyphosate and a triazolinone herbicide
AU2003231699B2 (en) * 1998-04-03 2006-02-23 Monsanto Technology Llc Combination of glyphosate and a triazolinone herbicide
JP2002522457A (en) * 1998-08-13 2002-07-23 アベンティス・クロップサイエンス・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング Herbicide composition for resistant or resistant rice crops
JP2002522458A (en) * 1998-08-13 2002-07-23 アベンティス・クロップサイエンス・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング Herbicidal composition for resistant or resistant corn crops
WO2000064256A1 (en) * 1999-04-23 2000-11-02 Monsanto Technology Llc Enhanced herbicide compositions
EP1189511A4 (en) * 1999-06-22 2002-11-13 Fmc Corp Liquid herbicide composition
US6774087B1 (en) 1999-06-22 2004-08-10 Fmc Corporation Liquid herbicide composition
US6689719B2 (en) 1999-08-11 2004-02-10 Monsanto Technology Llc Coformulation of carfentrazone-ethyl and glyphasate
US6713433B2 (en) 1999-08-11 2004-03-30 Monsanto Technology, Llc Coformulation of an oil-soluble herbicide and a water-soluble herbicide
JP2001328907A (en) * 2000-03-14 2001-11-27 Sumitomo Chem Co Ltd Water-based herbicidal composition
WO2002063955A3 (en) * 2001-02-14 2003-03-20 Monsanto Technology Llc Coformulation of carfentrazone-ethyl and glyphosate
WO2003055310A1 (en) * 2001-12-25 2003-07-10 Nihon Nohyaku Co., Ltd. Herbicidal compositions and method of using the same
CN106417356A (en) * 2016-09-13 2017-02-22 张先文 Method for quickly and effectively eradicating refractory plants in economic forest
CN108651480A (en) * 2018-05-04 2018-10-16 广西田园生化股份有限公司 A kind of application of ternary built herbicidal composition and its China fir forest land weeds control
CN114052031A (en) * 2021-12-08 2022-02-18 山东坤牛植物保护有限公司 Preparation method of synergistic weeding pesticide composition

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