JPH10295942A - Partially dyed hair for doll and dyeing method therefor - Google Patents

Partially dyed hair for doll and dyeing method therefor

Info

Publication number
JPH10295942A
JPH10295942A JP12162197A JP12162197A JPH10295942A JP H10295942 A JPH10295942 A JP H10295942A JP 12162197 A JP12162197 A JP 12162197A JP 12162197 A JP12162197 A JP 12162197A JP H10295942 A JPH10295942 A JP H10295942A
Authority
JP
Grant status
Application
Patent type
Prior art keywords
dyeing
doll
fiber
fibers
hair
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP12162197A
Other languages
Japanese (ja)
Inventor
Yoshiaki Ono
義明 小野
Original Assignee
Pilot Ink Co Ltd
パイロットインキ株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date

Links

Abstract

PROBLEM TO BE SOLVED: To provide partially dyed hair for a doll presenting a specific aspect, and variously commercialize it by partially dyeing a large number of adjacent fibers, and forming the partially dyed hair of a doll so that a coloring pattern can be visually sensed.
SOLUTION: Fiber to be used is formed of synthetic fiber such as a polyamide type such as nylon, a vinyl chloride type and a vinylidene chloride type, natural fiber such as cotton, flax, wool and silk, regenerated fiber such as rayon, polynosic and cuprammonium rayon, semisynthetic fiber such as acetate and triacetate or the like normally used as fiber for doll hair 1, and is dyed by dyes. When a dyeing liquid is stuck to this fiber, dyeing work is performed on fiber put in a condition of being implanted in a doll head part or fiber already put in a work condition as a wig and false hair or fiber on which at least one end is put in a fixed condition. In this case, a coloring pattern 3 is formed by crossing a large number of adjacent fibers, or the coloring pattern is formed in plural places so as to become patterns mutually different in a color tone.
COPYRIGHT: (C)1998,JPO

Description

【発明の詳細な説明】 DETAILED DESCRIPTION OF THE INVENTION

【0001】 [0001]

【発明の属する技術分野】本発明は人形用部分染色毛髪及びその染色方法に関する。 The present invention relates to relates to a part dyeing hair and the dyeing process for the doll. 更に詳細には、隣接する繊維の多数本が部分的に染色されて、着色模様を視覚させるよう構成した人形用部分染色毛髪及び前記毛髪の効果的な染色方法に関する。 More particularly, a number of adjacent fibers present is partially stained, on Effective staining methods doll partial dyeing the hair and the hair was configured so as to visually colored pattern.

【0002】 [0002]

【従来の技術】従来、人形玩具等において部分的に着色した毛髪を構成するために、色種の異なる繊維の適宜本数を部分的に集合させて基端部を頭部に植毛する手段が一般的に採用されている。 Conventionally, partly colored hair to configure the means for an appropriate number of color types of different fibers partially assembled to flocking the base end portion to the head generally in dolls toys It has been adopted in manner. この手段によるものは、長手方向の整列状態にあっては色違いによる効果を視覚させることができるとしても、末端の自由端が横方向にズレると、隣接の他色の繊維と混ざり合い、所期の色違い効果を視覚させ難くなり、見栄えも悪くなる等の不具合があった。 By this means, in the longitudinal direction of alignment as it is possible to visually the effect of different colors, deviated the free end of the end in the horizontal direction, mixes with fibers of other colors adjacent where it becomes difficult to visualize a different color effect of the period, there was a problem such as appearance also becomes worse.

【0003】一方、予め部分的に適宜長さにわたって着色した多数の繊維を隣接集合状態に植毛して横方向に拡がる部分的な着色模様を視覚させる試みは、前記した不具合を解消できるとしても、前記部分着色の繊維を適正配置に植毛することは、煩雑かつ手間を要し、生産性を満足させず実用化でき難い。 On the other hand, even if the attempt to visually partial color patterning extending laterally flocking a number of fibers that are colored over previously partially appropriate length neighbor set state can be eliminated the problem that described above, that flocked fibers of the portion colored in proper placement, cumbersome and takes time, hardly be put to practical use without satisfying productivity.

【0004】前記した状況に鑑み、人形の頭部等に植毛状態にある毛髪表面の適所に着色塗料を部分的に吹き付ける手段が一般的に採用されているが、この種の手段によるものは、個々の繊維への付着量が偏在しがちであり、更には再現性のある模様が形成され難いという問題があった。 [0004] In view of the circumstances described above, but means for blowing place the colored coating of the hair surface in a planted state on the head like a doll partially are commonly employed, due to this kind of means, tend localized adhesion amount of the individual fibers, further has a problem that pattern reproducible is hardly formed. 又、塗料中の樹脂分により着色剤が固着されるので繊維の触感や光沢性を低下させ、人形毛髪としての商品性を損なっていた。 In addition, since the colorant is fixed by the resin component in the coating reduces the touch and luster of the fibers had impaired marketability as doll hair. 又、着色液の固着手段として、溶剤分の乾燥或いは高温下での熱処理等を要し、人形の頭部等に毛髪を植毛状態にあっては、頭部を構成するプラスチック材の熱変形や熱劣化等を起こす危険があり、実施し難い。 Further, as the fixing means of the colored liquid, requires a heat treatment in a dry or high temperature of the solvent fraction, in the hair to flocked state on the head like a doll, Ya thermal deformation of the plastic material forming the head There is a risk of causing thermal deterioration, difficult to practice.

【0005】 [0005]

【発明が解決しようとする課題】本発明は、前記した従来の不具合を一挙に解消し、繊維の光沢感、風合い等を損なうことなく、繊維表面に部分着色模様を形成し、特異な様相を呈する人形用部分染色毛髪及びその染色方法を提供しようとするものである。 SUMMARY OF THE INVENTION It is an object of the present invention is to solve at once a problem of the conventional described above, gloss of the fibers, without compromising the texture or the like, to form a portion colored pattern on the fiber surface, a unique appearance doll partial dyeing hair and the dyeing process exhibit is intended to provide.

【0006】 [0006]

【課題を解決するための手段】本発明は、隣接する繊維の多数本が部分的に染色されて、着色模様を視覚させるよう構成した人形用部分染色毛髪を要件とする。 The present invention SUMMARY OF], the large number of adjacent fibers is partially stained, and configured requirements doll partial dyeing hair so as to visually colored pattern. 更には、着色模様は隣接する多数の繊維を横断して形成されてなること、着色模様は複数個所に設けられてなること、着色模様は相異なる色調の模様であること等を要件とする。 Furthermore, the colored pattern is to become formed across a number of adjacent fibers, color patterning may be provided at a plurality of locations, the colored pattern is a requirement such that it appears in different shades. 更には、集合状態に配置した多数本の繊維に、 Furthermore, the large number of fibers arranged in the set state,
水性媒体の染色液を部分的に付着させ、該染色液が未乾燥状態にあるうちに、高周波電界による誘電加熱処理を行なうことにより染色液の付着した部位を染色することを要件とする。 A staining liquid aqueous medium partially attached to, while the 該染 Iroeki is in undried, is required for the staining the adherent sites staining solution by performing the dielectric heating process by the high-frequency electric field. 更には、多数本の繊維は、一端が集束固定状態にあること、集束固定状態は、人形頭部に植毛状態にあること、染色液の付着手段が染色液を含浸させた多孔体を集合状態にある繊維の所望染色部位の繊維表面に接触配置することにより、染色液を繊維間に浸透させること等を要件とするものである。 Furthermore, a large number of fibers, that one end is in focusing a fixed state, focusing stationary state, that is in the planted state doll head, porous aggregate state attachment means is impregnated with stain solution staining solution by arranged in contact with the desired site stained surface of the fibers of the fiber in, it is an requirement like that infiltrate staining solution between the fibers.

【0007】前記において、繊維は人形毛髪用繊維として通常使用されているナイロン等のポリアミド系、塩化ビニル系、塩化ビニリデン系、アクリロニトリル−塩化ビニル共重合体、アクリロニトリル−塩化ビニリデン共重合体等のアクリル系、ポリエステル系、ポリエチレン系、ポリプロピレン系、ビニロン、ポリウレタン等の合成繊維、木綿、麻、羊毛、絹等の天然繊維、レーヨン、 [0007] In the above, the fibers polyamide such as nylon, which is usually used as a fiber for doll hair, vinyl chloride, vinylidene chloride, acrylonitrile - vinyl chloride copolymer, acrylonitrile - acrylic vinylidene chloride copolymer systems, polyester, polyethylene, polypropylene, vinylon, synthetic fibers such as polyurethane, cotton, hemp, wool, natural fibers silk, etc., rayon,
ポリノジック、キュプラ等の再生繊維、アセテート、トリアセテート等の半合成繊維、各種熱可塑性樹脂のフィラメント、複数の熱可塑性樹脂が溶融ブレンドされたフィラメント、複数の異なる繊維を複合させた、芯−鞘構造その他の形態の複合繊維等が挙げられ、染料により染色可能な繊維であればよい。 Polynosic, regenerated fibers such as cupra, acetate, semisynthetic fibers triacetate, filaments filaments of various thermoplastic resins, a plurality of thermoplastic resins are melt-blended, complexed with a plurality of different fibers, a core - sheath structure Other mentioned composite fibers in the form of, it may be a dyeable fibers by dye.

【0008】更には、前記のような繊維形態ではなく、 Furthermore, rather than fiber form, such as described above,
プラスチックシート等を細幅に裁断し、繊維状としたものであってもよい。 The plastic sheet was cut into a narrow, or may be set to fibrous. 又、前記繊維に公知の染料や紫外線発光型色素、蛍光増白剤、顔料、蛍光顔料、蓄光顔料、 Also, known dyes or ultraviolet light-emitting dye to the fibers, optical brighteners, pigments, fluorescent pigments, phosphorescent pigments,
夜光顔料、メタリック光沢顔料、体質顔料、熱変色性着色剤、フォトクロミック着色剤等によって予め着色された状態のものを用いてもよい。 Luminous pigments, metallic luster pigments, extender pigments, thermochromic colorant, may also be used in a state of being previously colored by photochromic coloring agent. この場合には、前記着色効果と本発明の部分染色効果との複合的色彩効果が得られる。 In this case, combined color effect of the partial dyeing effect of the coloring effect and the present invention is obtained.

【0009】次に、染色液について説明する。 [0009] Next, a description will be given of staining solution. 本発明においては、従来より繊維の染色に適用されている染色液を構成する染料が総て有効に用いられる。 In the present invention, the dye constituting the dye solution is applied to the dyeing of conventionally fibers all be effectively used. 具体的に例示すれば、アクリル系繊維に対してはカチオン染料、塩基性染料、分散染料等、ナイロン繊維に対しては酸性染料、分散染料等、ポリエステル繊維に対しては分散染料等を好適に用いることができる。 If specifically exemplified, cationic dyes for acrylic fibers, basic dyes, disperse dyes, acid dyes for nylon fibers, disperse dyes, etc., preferably a disperse dye or the like for polyester fibers it can be used. 本発明に使用する染色液には、染料、水以外に通常の染色に用いられる染色液と同様に、促染剤、緩染剤、均染剤、pH調整剤、湿潤剤、染料溶解助剤等を必要に応じて添加できる。 Dyeing solution used in the present invention, a dye, similarly to the staining solution to be used in conventional dyeing besides water, accelerants, retarding agents, leveling agents, pH modifiers, wetting agents, dye dissolving aid It can be added as required and the like.

【0010】次に繊維への染色液の付着手段について説明する。 [0010] will be described attachment means of staining solution to the fiber. 人形頭部に植毛された状態或いは、かつらや付け毛として既に加工状態にある繊維、或いは少なくとも一端が固定状態にある繊維について染色加工を施す。 State flocked doll head or fibers already in the machining state as a wig or attached hair, or at least one end subjected to dyeing for fibers in a fixed state. 前記固定状態にある繊維の、染色所望位置の繊維表面に染色液を吸蔵させた多孔体を接触、適宜に押圧するパッディング手段により染色液を繊維間に浸透、付着させる。 Said stationary with some fiber, dyeing a desired position contacting the porous body stain solution was occluded in the fiber surface, penetrate the stain solution between the fibers by padding means for pressing the appropriate deposit.
ここで、繊維相互が密接状態に集束されていれば、繊維間の毛細管力により染色液が効果的に下層に位置する繊維まで浸透し、各々の繊維表面に付着する。 Here, if it is focused on the fibers mutually close contact, stain by capillary force between fibers effectively penetrate the fibers located in the lower layer, which adheres to each of the fiber surface.

【0011】集束繊維の一方の側から、前記したパッディング手段により染色液を付着させることができるが、 [0011] From one side of the focusing fiber, but may be attached to stain the aforementioned padding means,
繊維量が多い場合には、表裏両側からのパッディング処理を行なうことにより、内部に位置する繊維表面に対して均等に染色液を付着させることができる。 If the amount of fiber is large, by performing padding processing from the front and back sides, it can be deposited evenly staining solution to the fiber surfaces located therein. 又、繊維束を扇状に拡げて繊維束の厚みを適宜に調整することもできる。 It is also possible to appropriately adjust the thickness of the fiber bundle is spread fiber bundle in a fan shape.

【0012】複数の染色部を配設する系にあっては、当該所望染色部に個別にパッディング処理することもできるが、処理操作に時間差を生じ、毛細管作用による染色液の移動の度合いが異なり、色むらを生じて染色されがちとなるため、所望染色部の各部に染色液を吸蔵させた多孔体を同時に押圧してパッディングすることが望ましい。 [0012] In the system of disposing a plurality of the dyeing unit, can also be padded processed individually to the desired dyeing unit, resulting time difference in processing operation, the degree of movement of the staining solution by capillary action Unlike, since the likely stained occurs color irregularity, it is desirable to padding simultaneously pressing the desired staining section each part porous body stain solution was occluded in the.

【0013】染色液を吸蔵させる多孔体の形状、大きさを適宜選択することにより、多様な部分着色模様を形成できるが、多孔体の配置の調整により、非染色部とのバランスの調整や、混色、或いは階調模様を形成することもできる。 [0013] The shape of the porous body to absorb stain by selecting the size appropriate, can form a variety of parts colored patterns, by adjusting the arrangement of the porous body, adjustment of the balance between the unstained portion, mixed, or formed gradation pattern.

【0014】多孔体は、染色液を吸蔵可能な連続気孔体、例えば、フェルトや繊維の樹脂加工乃至融着加工体、連続気孔を有するプラスチック成形体等を挙げることができる。 [0014] porous body, storable continuous pores bodies stain for example, resin processing or fusion process of felt or fiber, and a plastic molded body or the like having continuous pores. その他、適度に染色液を吸蔵、放出させる材料であれば全て用いられる。 Other moderately occlude stain all used as long as the material is discharged.

【0015】次に、染色手段について説明する。 [0015] Next, a description will be given of staining means. 従来の工業的な染色手段、例えば、染料を含む染浴中に繊維を一定時間浸して染色を行う浸染では、繊維と染料との組合わせや染色条件によっても異なるが、通常、1時間前後の加熱処理を要し、合成繊維の系では、加熱温度も8 Conventional industrial dyeing means, for example, in the dyeing of performing dyeing by immersing a predetermined time fibers in the dye bath containing a dye, varies depending combinations and dyeing conditions the fibers and the dye, usually, 1 hour before and after It requires heat treatment, in a system of synthetic fibers, also the heating temperature 8
0〜130℃までの昇温を要し、染色浴比(被染色物重量:染色液重量)は1:20乃至1:60に設定されるのが通例であり、この種の染色手段を人形用毛髪の染色加工に適用することは実質的に不可能である。 It requires heating up to 0 to 130 ° C., dye bath ratio (the dyeing Weight: staining solution by weight) is usually that is set 1:20 to 1:60 doll staining means of this kind it is substantially impossible to apply the dyeing of use hair. 即ち、人形毛髪用繊維の部分的な個所にのみ染色液を付着させ難いし、付着できたとしても繊維に対する染色液の割合が大であり、染色液が繊維表面に適正に保持されず、移動しがちである。 That is, to difficult to adhere the only stain partial locations doll hair fibers, the ratio of dyeing solution for the fiber even be deposited is large, not properly held staining solution within the fiber surface, moving it is prone to. 更には長時間の高温加熱処理を要するので、人形毛髪に植毛状態の繊維に対して染色加工を行なうと、繊維以外の人形部品も同時に加熱され、熱変形や熱劣化を起こすので不可能である。 Further, since it takes a long time high-temperature heat treatment, performing a dyeing the fiber flocked state doll hair, doll parts other than fibers may be heated simultaneously, it is impossible because it causes thermal deformation or thermal deterioration .

【0016】本発明染色手段は、前記した不具合を発生させることなく、人形本体に植毛された状態或いは、かつらや付け毛のように製品への加工過程にある人形毛髪用繊維に対して染色加工を可能となすものであり、集合状態の人形毛髪用繊維に対して少なくとも一色以上の染色液を部分的に含浸させた状態で高周波電界の誘電加熱により染色液の加熱を行い染色液含浸部分の染色を行う。 [0016] The present invention staining means, without causing a problem that the, or condition being flocked surface of the doll, dyeing respect doll hair fibers in the course of processing into products like wig or hair extension the are those which form capable of dielectric heating by performing heat staining solution stained impregnation portion of the high frequency electric field in a state of partially impregnated with at least one color or stain respect doll hair fibers of the set state the dyeing is carried out.

【0017】次に本発明に適用の誘電加熱手段について説明する。 [0017] Next will be described dielectric heating means applied to the present invention. 誘電加熱では、高周波電界内においた被加熱物中の水等の誘電体分子の電界中での分極状態が高周波電界の交番により逆転し、分子が衝突,摩擦することにより熱が発生し、被加熱物自体が発熱体となって物質内部から加熱が行われる。 In dielectric heating, the polarization state in a field of dielectric molecules, such as water of the heated object in which was placed in a high frequency electric field is reversed by the alternating high frequency electric field, heat is generated by the molecules colliding, friction, the heated itself heated material inside is carried out a heating element. 損失係数(物質の比誘電率×誘電体損失角)の大きい物質程加熱されやすく、水は損失係数が他の物質に較べて非常に大きいため、誘電加熱によって染色液含浸部分を選択的に加熱することができる。 Loss factor tends to be heated larger material (material dielectric constant × dielectric loss angle), since the water loss factor is very large compared to other materials, selectively heating the dyeing liquid impregnated portion by dielectric heating can do.

【0018】誘電加熱には、2枚の電極板の間に被加熱物を挿入し、6〜80MHzの高周波電圧を加えることにより、発生する高周波電界により被加熱物を発熱させる高周波誘電加熱と被加熱物に特定波長のマイクロ波を照射することにより、被加熱物を発熱させるマイクロ波誘電加熱がある。 [0018] dielectric heating, insert the object to be heated in the two electrode plates, by applying a high frequency voltage of 6~80MHz, high-frequency dielectric heating and the heated object to heat the object to be heated by a high frequency electric field generated by applying a microwave of a specific wavelength, there is a microwave induction heating to heat the object to be heated. その使用周波数は工業加熱用として、 The frequency used as industrial heating,
ISM(Industrial Scientific ISM (Industrial Scientific
and Medical Use)周波数帯域が定められており、高周波誘電加熱では13.56MHz帯、 and Medical the Use) frequency band are determined in, 13.56 MHz band high-frequency dielectric heating,
27.12MHz帯、および40.68MHz帯が国際的に認められている。 27.12MHz band, and 40.68MHz band is internationally recognized.

【0019】マイクロ波誘電加熱では、ISM周波数帯として915MHz帯および2450MHz帯が国際的に広く用いられおり、国内では、電波法によって245 [0019] In microwave dielectric heating, 915 MHz band and 2450MHz band as ISM frequency band are used internationally widespread, in Japan, the Radio Law 245
0MHz帯の使用が許可されているが、915MHz帯についても定められた基準内で使用が可能である。 Using 0MHz band is permitted, but can be used in the criteria also defined for 915MHz band. これらの高周波電界による誘電加熱手段を本発明は適用するものであり、通常の外部加熱による手段に対し、熱伝導性が要求されず、染色液を付着させた繊維の部位が内部発熱し、外面に位置する繊維に限らず、内部に位置する部位を同時に一様に加熱し、熱効率にも優れている。 The present invention dielectric heating means by these high-frequency electric field is intended to be applied, to means by conventional external heating, the thermal conductivity is not required, part of the fiber adhered with dyeing liquid is internal heating, the outer surface not limited to fibers located, and at the same time uniformly heat the site located inside, it is excellent in thermal efficiency.

【0020】更には、電極板を用いる高周波誘電加熱に比較して、マイクロ波誘電加熱は被加熱物に対して電磁波の一種であるマイクロ波を照射して加熱を行うため、 Furthermore, compared to the high-frequency dielectric heating using an electrode plate, since the microwave dielectric heating of heating by microwave irradiation, which is a kind of electromagnetic wave with respect to the object to be heated,
本発明の頭部に植毛状態にある繊維等の複雑な形状の被加熱物の加熱にあっても、比較的均一に加熱できるので、より一層好適である。 Even in the heating of the heated object of complicated shape of the fiber or the like in the head portion flocked condition of the present invention, since relatively uniform heating, it is even more preferred.

【0021】前記した如く、マイクロ波誘電加熱は人形本体に組付け状態にあっても、繊維の染色液含浸部分のみを選択的に加熱することができ、他の人形部品が熱劣化する危険性がない。 [0021] As described above, even in a state assembled with the microwave dielectric heating of the doll, it is possible to selectively heat only the stain-impregnated portion of the fibers, the risk of other doll parts are thermally degraded there is no. 更には、加熱が急速、効率的であり、短時間で染色を完了させることができるため、繊維重量に対して染色液の重量比率が小さい系にあっても所期の染色性を得ることができる。 Furthermore, heating is rapid, efficient, since it is possible to complete the dyeing in a short time, that even in the weight ratio is less based stain to the fiber weight obtain the desired dyeability it can.

【0022】次に、染色工程における染色浴比、処理方法について説明する。 Next, a dye bath ratio in the dyeing process, the processing method will be described. 人形毛髪用繊維の毛細管作用によって染色液が繊維間に含浸、保持されるため、繊維束が保持できる染色液量には制限があり、又、繊維の材質、 Since the dyeing solution by the capillary action of the doll hair fibers are impregnated between fibers are maintained, there is a limit to the stain amount fiber bundles can be held, also, the textile material,
外径、断面形状等、繊維の種類や染色の対象とする繊維量等により異なるが、本発明における染色浴比(被染色個所の繊維重量:染色液重量)は概ね1:1〜1:0. Outer diameter, cross sectional shape, etc., varies depending on the amount of fibers such that the fiber type and staining of the subject, dye bath ratio in the present invention (of the dyeing point fiber weight: staining solution by weight) is approximately 1: 1 to 1: 0 .
2の範囲が好ましく、被染色個所の繊維重量に対して、 2 ranges are preferred, with respect to the fiber weight of the dyeing point,
染色液重量が上回る比率の染色浴比の系にあっては、加熱処理において染色液の体積膨張や沸騰等のため染色液の移動による染色部分の拡大、他の染色部分との混合、 In the system of the ratio of dyebath ratio dyeing solution weight is above, expansion of movement by staining part of the staining solution for volume expansion and boiling like stain in the heat treatment, mixing with the other areas stained,
他の人形部分を汚染する場合があり好ましくない。 Unfavorable might contaminate the other doll parts. 又、 or,
染色液重量が被染色個所の繊維重量1重量部に対し0. 0 staining solution weight relative to the fiber weight 1 part by weight of the dyeing point.
2未満の系では、所望の染色部分全体を均一に染色することが困難となり、また、全体を染色できたとしても染色濃度が薄くなる場合がある。 In less than 2 system, it is difficult to uniformly stain the entire desired areas stained, also, in some cases even staining concentration becomes thin as could stain the whole. 人形毛髪用繊維に染色液の含浸処理を施したままの状態で高周波電界による誘電加熱処理を行っても染色は可能であるが、より染色効果を高めるため、染色部分を耐熱性プラスチックフィルムで覆う等の水分蒸発防止手段を施すことが好ましい。 Although even if the dielectric heating by the high frequency electric field in a state subjected to impregnation stain doll hair fibers are possible staining, to increase more dyeing effect, covering the areas stained with a heat-resistant plastic film it is preferably subjected to water evaporation preventing means equal.
尚、染色液を吸蔵させた多孔体の押圧手段に代えて、染色液をスプレー等により吹き付け、未乾燥状態において前記高周波電界による誘電加熱処理を行なうことにより染色させることもできる。 Instead of the pressing means of the porous body was occluded Staining staining solution sprayed by a spray or the like, it can also be dyed by the undried performing dielectric heating process by the high frequency electric field.

【0023】本発明の染色方法は、動物形象玩具を含む人形用擬毛、殊に人形用頭髪に適用されるものであるが、例えば、擬毛、付け毛、服飾、各種装飾材等へ適用することも可能である。 [0023] The dyeing method of the present invention are, for the doll, including the zoomorphism toy false hair, but is especially intended to be applied to the doll for hair applied, for example, false hair, put hair, clothing and accessories, to a variety of decorative materials, etc. it is also possible to.

【0024】 [0024]

【発明の実施の形態】本発明は部分染色による着色模様を少なくとも一箇所以上に配設した人形毛髪用繊維及び前記毛髪の染色方法を要件とするものであり、以下に実施例を記載する。 DETAILED DESCRIPTION OF THE INVENTION The present invention has been made to a method of dyeing doll hair fibers, and the hair coloring pattern by partial staining is disposed above at least one place a requirement, the following examples are set forth. 尚、本発明は実施例に限定されない。 The present invention is not limited to the examples.
以下の実施例中の部は重量部を示す。 Parts in the following examples means parts by weight.

【0025】実施例1 染色液の調製 染色液A(青色) カチオン染料〔Aizen Cathilon Pur [0025] Preparation dyeing solution A (blue) of Example 1 staining solution cationic dyes [Aizen Cathilon Pur
e Blue 5GH200%(C.I.No.Bas e Blue 5GH200% (C.I.No.Bas
ic Blue 3),保土谷化学工業株式会社製) ic Blue 3), manufactured by Hodogaya Chemical Co., Ltd.)
0.5部,酢酸2.5部,酢酸ナトリウム0.5部,エチレングリコール10部,水86.5部を混合溶解して得た。 0.5 parts, 2.5 parts of acetic acid, 0.5 part of sodium acetate, 10 parts of ethylene glycol was obtained by mixing and dissolving the water 86.5 parts. 染色液B(緑色) 染色液Aの染料をAizen Cathilon Pu The dye stain B (green) staining solution A Aizen Cathilon Pu
re Blue 5GH 200%0.2部およびAi re Blue 5GH 200% 0.2 parts of Ai
zen Cathilon Yellow 7GLH zen Cathilon Yellow 7GLH
(C.I.No.Basic Yellow 21,保土谷化学工業株式会社製)0.8部とした以外は染色液Aと同一の処方により得た。 Except that the (C.I.No.Basic Yellow 21, manufactured by Hodogaya Chemical Co., Ltd.) 0.8 parts was obtained by the same prescription and staining solution A. 染色液C(黄色) 染色液Aの染料をAizen Cathilon Ye The dye stain C (yellow) staining solution A Aizen Cathilon Ye
llow 7GLH1.8部とした以外は、染色液Aと同一の処方により得た。 Except that the llow 7GLH1.8 parts was obtained by the same prescription and staining solution A. 染色液D(橙色) 染色液Aの染料をAizen Cathilon Or The dye stain D (orange) staining solution A Aizen Cathilon Or
ange GLH 200% (C.I.No.Bas ange GLH 200% (C.I.No.Bas
ic Orange 21,保土谷化学工業株式会社製)0.6部とした以外は、染色液Aと同一の処方により得た。 ics Orange 21, except for using manufactured by Hodogaya Chemical Co., Ltd.) 0.6 parts was obtained by the same prescription and staining solution A. 染色液E(赤色) 染色液Aの染料をAizen Cathilon Re The dye stain E (red) staining solution A Aizen Cathilon Re
d T−BLH(C.I.No.Basic Red d T-BLH (C.I.No.Basic Red
46,保土谷化学工業株式会社製)0.8部とした以外は、染色液Aと同一の処方により得た。 46, except for using manufactured by Hodogaya Chemical Co., Ltd.) 0.8 parts was obtained by the same prescription and staining solution A. 染色液F(桃色) 染色液Aの染料をAizen Cathilon Pi The dye stain F (pink) staining solution A Aizen Cathilon Pi
nk FGH(C.I.No.Basic Red 1 nk FGH (C.I.No.Basic Red 1
3,保土谷化学工業株式会社製)1.0部とした以外は、染色液Aと同一の処方により得た。 3, except for using manufactured by Hodogaya Chemical Co., Ltd.) 1.0 parts was obtained by the same prescription and staining solution A. 染色液G(藍色) 染色液Aの染料をAizen Cathilon Bl The dye stain G (indigo blue) staining solution A Aizen Cathilon Bl
ue CD−F2RLH(C.I.No.Basic ue CD-F2RLH (C.I.No.Basic
Blue 129、保土谷化学工業株式会社製)1.0 Blue 129, manufactured by Hodogaya Chemical Co., Ltd.) 1.0
部とした以外は、染色液Aと同一の処方により得た。 Except that the parts were obtained by the same prescription and staining solution A.

【0026】毛髪用繊維の用意 ポリ塩化ビニル製の人形頭部にブロンド色に着色されたモダアクリルフィラメント(アクリロニトル−塩化ビニル共重合体:720デニール/36フィラメント)を約30cmの長さで多数、植毛して毛髪部を形成した。 [0026] the hair fibers prepared Polyvinyl doll head chloride colored in blond was Moda acrylic filaments (acrylonitrile - copolymer vinyl chloride polymer: 720 denier / 36 filament) number a length of about 30cm and, They flocked to the formation of the hair part. この毛髪部の毛髪全体を束状に集合させた時の単位長さあたりの繊維重量は0.8g/cmであった。 Fiber weight per unit length of time this has the entire hair of the hair portion is set in a bundle was 0.8 g / cm.

【0027】毛髪用繊維への染色液の付着 前記の染色液A、B、C、D、E、F、Gを図8及び9 The deposition the staining solution A staining solution to hair fibers, B, C, D, 8 and 9 E, F, and G
に示したように、多孔体4として羊毛フエルト製の染色液吸蔵体4a、4b、4c、4d、4e、4f、4gにそれぞれ吸蔵させた後、固定部6として人形頭部に固定された繊維2からなる毛髪の後端から20cmの部分に、毛髪繊維束の両面から染色液吸蔵体を押圧し、7色合計8.8gの染色液を含浸させた(染色浴比=被染色個所の繊維重量:染色液重量=1:0.55)。 As shown in, wool felt made of staining solution storing member 4a as a porous body 4, 4b, 4c, 4d, 4e, 4f, after each was occluded in 4g, fibers fixed to the doll head as a fixed part 6 the rear end from 20cm portion of hair consisting of two presses the stain occlusions from both of the hair fiber bundle, a staining liquid 7 colors total 8.8g impregnated (dyeing bath ratio = of the dyeing point fibers weight: staining solution weight = 1: 0.55).

【0028】染色方法 次いで、毛髪部の染色液含浸部分をポリエステルシートで上下より覆い、発振周波数2450MHz、出力50 The dyeing process is then stained impregnation portion of the hair portion is covered from above and below with a polyester sheet, the oscillation frequency 2450 MHz, output 50
0Wの箱型マイクロ波照射装置を用いて40秒間のマイクロ波照射を行なった後、染色部を水洗した結果、図1、2に示すような毛髪の頭部側より青色、緑色、黄色、橙色、赤色、桃色、藍色の順に連続的に染色された着色模様3、31を有する人形用部分染色毛髪1が得られた。 After performing the microwave irradiation for 40 seconds by using a box-type microwave irradiation apparatus 0 W, the result was washed with water staining section, blue than the head side of the hair, as shown in FIGS. 1 and 2, green, yellow, orange , red, pink, dolls partial dyeing hair 1 having a colored pattern 3,31 which are continuously dyed in the order of indigo were obtained.

【0029】前記の染色部の各色の境界部分には、図4 [0029] Each color boundary portion of the dyeing unit, FIG. 4
に示すように色調の階調変化による階調模様32が認められ、毛髪部の毛髪を鮮やかなレインボー調に染色することができた。 Gradation patterns 32 by the gradation change in color tone as shown in recognized, it was possible to stain the hair of the hair portion bright rainbow tone. また、マイクロ波照射後において、染色部分以外の毛髪部には、熱処理による劣化は認められなかった。 Further, after the microwave irradiation, the hair portion other than the stained part, degradation due to heat treatment was observed.

【0030】実施例2 染色液H(黄色) 酸性染料(Kayanol Milling Yell [0030] Example 2 staining solution H (yellow) acid dye (Kayanol Milling Yell
ow O、C. ow O, C. I. I. No. No. Acid yellow Acid yellow
38、日本化薬株式会社製)2部、酢酸アンモニウム1 38, manufactured by Nippon Kayaku Co., Ltd.) 2 parts of ammonium acetate 1
部、エチレングリコール10部、水87部を混合溶解して得た。 Parts, 10 parts of ethylene glycol was obtained by mixing and dissolving 87 parts of water. 染色液I(黄緑色) 染色液Hの染料をKayanol Milling Y The dye stain I (yellow-green) staining solution H Kayanol Milling Y
ellow O 1.5部,Kayanol Mill ellow O 1.5 parts, Kayanol Mill
ing Green GW(C.I.No.Acid ing Green GW (C.I.No.Acid
Green27,日本化薬株式会社製)0.5部とした以外は、染色液Hと同一の処方で得た。 Green27, except for using Nippon Kayaku Co., Ltd.) 0.5 parts were obtained in the same prescription and staining solution H. 染色液J(緑色) 染色液Hの染料をKayanol Milling G The dye stain J (green) staining solution H Kayanol Milling G
reen GW 2部とした以外は、染色液Hと同一の処方で得た。 Except that the reen GW 2 parts were obtained in the same prescription and staining solution H. 染色試料 ハイインパクトスチロール樹脂製の馬に尾として白色に着色されたナイロンフィラメント(1200デニール/ Stained specimen high impact styrene resin nylon filaments colored in white as tail horses (1200 denier /
24フィラメント)を約12cmの長さで取り付けた。 Fitted with a 24 filament) with a length of about 12cm.
この尾の部分の繊維を束状に集合させたときの単位長さあたりの繊維重量は0.4g/cmであった。 Fiber weight per unit length of time obtained by aggregating fibers of this tail portion in a bundle was 0.4 g / cm.

【0031】染色方法 前記の染色液H、I、Jを図6、7に示したように、プラスチックシート5に固定した多孔体4として示される羊毛フェルト製の染色液吸蔵体にそれぞれ吸蔵させ、固定部6で示される馬の尾部より9cmの部分に毛髪繊維束の片面から染色液吸蔵体を押圧し、3色合計1.6g The dyeing method wherein dyeing liquors H, as indicated I, a J in FIGS. 6 and 7, is respectively inserted in the dyeing liquid absorbing body made wool felt, shown as a porous body 4 fixed to the plastic sheet 5, pressing the staining solution occlusion bodies 9cm portion of the tail portion of the horse represented by the fixed portion 6 from one side of the hair fiber bundle 3 colors total 1.6g
の染色液を含浸させた(染色浴比=被染色個所の繊維重量:染色液重量=1:0.44)。 Staining solution impregnated with the (dyeing bath ratio = of the dyeing point fiber weight: staining solution by weight = 1: 0.44). 次いで、尾の染色液含浸部分をポリエステルシートで上下より覆い、実施例1と同一の条件でマイクロ波照射を行なった後、染色部を水洗した結果、尾の部分が胴体側より、白色、黄色、 Then, a stain impregnated portion of the tail cover from the top and bottom with a polyester sheet, after performing the microwave irradiation under the same conditions as in Example 1, the result was washed with water and stained portion, the tail portions than the fuselage side, white, yellow ,
黄緑、緑色に色調が階調変化する染色物が得られた。 Yellowish green, dyeings color changes gradation green was obtained.
又、マイクロ波照射後において染色部分以外の部分には、熱処理による劣化は認められなかった。 Further, in the portion other than the areas stained after microwave irradiation, deterioration due to heat treatment was observed.

【0032】実施例3 染色液K 分散染料 Diacelliton Fast Pin [0032] Example 3 staining solution K disperse dyes Diacelliton Fast Pin
k R(C.I.Disperse Red 4、三菱化成工業株式会社製)2部、エチレングリコール10 k R (C.I.Disperse Red 4, manufactured by Mitsubishi Kasei Kogyo Co., Ltd.) 2 parts Ethylene glycol 10
部、水88部を均一混合し、分散液を調製した。 Parts, 88 parts of water were uniformly mixed to prepare a dispersion. 染色試料 ブロンド色に着色されたポリエステルフィラメント(8 Colored stained sample blond polyester filaments (8
00デニール/36フィラメント)をベルクロ部分に約25cmの長さで植毛し、中央部分をリボンで固定して人形用の付け毛を作製した。 00 denier / 36 filament) was planted in the length of about 25cm to Velcro part, were prepared with hair for the doll to secure the central part in the ribbon.

【0033】染色方法 前記の染色液を多孔体4としてハート型の羊毛フェルト製染色液吸蔵体に吸蔵させ、付け毛のベルクロ部分とリボンの間の部分に繊維の片面より、染色液吸蔵体を押圧し、ハート型の染色液含浸部を形成した(図3、図5参照)。 [0033] is inserted in the dyeing process the dyeing liquid wool felt made stain occlusions of heart-shaped as a porous material 4, from one side of the fiber portion between the attaching hair Velcro portion and a ribbon, the staining solution occlusion body pressed to form a staining solution impregnation of the heart-shaped (see FIGS. 3 and 5). 次いで、染色液含浸部分をポリエステルシートで上下より覆い、実施例1と同一の条件でマイクロ波照射を行なった後、染色部を水洗した結果、桃色のハート型の染色部を有する付け毛が得られた。 Then, a staining liquid impregnated portion covered from the upper and lower with a polyester sheet, after performing the microwave irradiation under the same conditions as in Example 1, the result was washed with water and stained section, obtained with hairs having a heart-shaped dyeing of pink obtained. また、マイクロ波照射後において染色部分以外の部分には、熱処理による劣化は認められなかった。 Further, in the portion other than the areas stained after microwave irradiation, deterioration due to heat treatment was observed.

【0034】 [0034]

【発明の効果】本発明人形用部分染色毛髪は、隣接する繊維の多数本が横断的に部分着色されて、模様として視覚されるよう構成されており、前記模様は繊維の開放端部が横方向に移動したとしても模様に与える影響が少なく、所期の模様を視覚させることができる。 The present invention doll portion dyeing hair according to the present invention, in a large number of adjacent fibers are transversely parts colored, is configured to be visualized as a pattern, said pattern has the open end portion of the fiber transverse less impact on the pattern even when moved in the direction, it is possible to visually desired pattern. 更には、前記着色模様は染色により形成されているので、光沢感、 Further, since the colored pattern is formed by dyeing, gloss,
風合い等が非着色部に対して実質的に変わっていないので異質感を与えない。 It does not give a different texture because it is not changed substantially with respect to texture, such as a non-colored portion. 又、水洗いや擦過等により色落ちすることもない。 In addition, nor does it fall color by washing and scraping, or the like. 前記部分着色模様の形成手段が、適用の繊維に適性を有する水性媒体の染色液を目的の箇所に付着させ、未乾燥の状態で高周波電界による誘電加熱処理により、短時間で処理できるので生産性を満たす。 Forming means of the parts colored pattern, it is deposited on part of the purpose of stain of an aqueous medium having a suitability to the fibers of the application, the dielectric heating process by the high-frequency electric field in an undried state, productivity since it treated in a short time meet. 更には、前記染色液の付着手段が、染色液を含浸させた多孔体を染色部位に軽く押圧し、それにより集束状態の繊維間に染色液を毛細管作用により浸透、保持させることができるので接触部に位置する繊維のみでなく内部に位置する繊維まで付着させることができる。 Furthermore contact attachment means of the staining solution is a porous material impregnated with dyeing liquor lightly pressed onto the stained site, whereby penetration by capillary action the staining solution between the fibers of the focusing state, can be held until the fibers located inside not only fibers located part can be attached. 又、模様の形状、大きさ等は、多孔体の形状、大きさにより設定できるので模様の形成も効率的に行われる。 The shape of the pattern, size and the like, the shape of the porous body, the formation of patterns can be set according to the size are also efficient. 尚、前記多孔体は目的に応じて、複数個を配備することができ、間隔等を適宜調節することにより、界面での混色や、階調模様等も自在に形成できる。 Incidentally, the porous body in accordance with the purpose, a plurality can be deployed, by adjusting the distance or the like as appropriate, and mixing at the interface, the gradation pattern or the like can be freely formed. 本発明染色方法では、毛髪に植毛状態にあっても部分染色が可能であるので、簡易生産性を満たし、多品種小ロットによる多様な商品化を可能となす。 In the present invention dyeing method, since even the flocking conditions the hair is possible moiety staining meets simple productivity, makes it possible a variety of commercialized by various kinds in small lots.

【図面の簡単な説明】 BRIEF DESCRIPTION OF THE DRAWINGS

【図1】本発明人形用毛髪を植毛した人形の頭部外観図である。 FIG. 1 is a head external view of a doll who flocked to the present invention doll for hair.

【図2】図1の毛髪の矢視部の拡大説明図である。 2 is an enlarged illustration of the arrow portion of the hair of FIG.

【図3】本発明毛髪の他の実施例の要部拡大説明図である。 3 is an enlarged explanatory view of another embodiment of the present invention the hair.

【図4】本発明毛髪の他の実施例の要部拡大説明図である。 4 is an enlarged explanatory view of another embodiment of the present invention the hair.

【図5】図3の模様を形成するための装置の説明図である。 5 is an explanatory view of an apparatus for forming a pattern in FIG.

【図6】図2の模様を形成するための装置の説明図である。 6 is an explanatory view of an apparatus for forming a pattern in FIG.

【図7】染色液を含浸させる工程の一実施例の縦断説明図である。 7 is a longitudinal sectional view of an embodiment of a step of impregnating the dyeing liquor.

【図8】染色液を含浸させる工程の他の実施例の縦断説明図である。 8 is a longitudinal sectional view of another embodiment of a step of impregnating the dyeing liquor.

【図9】図8の平面説明図である。 Is a plan view of FIG. 8;

【符号の説明】 DESCRIPTION OF SYMBOLS

1 人形用部分染色毛髪 2 繊維 3 着色模様 31 部分着色模様 32 階調模様 4 多孔体 5 プラスチックシート 6 固定部 1 doll partial dyeing hair 2 fibers 3 color patterning 31 parts colored pattern 32 gradation pattern 4 porous 5 plastic sheet 6 fixed part

Claims (8)

    【特許請求の範囲】 [The claims]
  1. 【請求項1】 隣接する繊維の多数本が部分的に染色されて、着色模様を視覚させるよう構成した人形用部分染色毛髪。 1. A is a number the partially staining of adjacent fibers, dolls partial dyeing hair configured so as to visually colored pattern.
  2. 【請求項2】 着色模様は隣接する多数の繊維を横断して形成されてなる請求項1記載の人形用部分染色毛髪。 2. A color patterning doll partial dyeing hair according to claim 1, wherein comprising formed across a number of adjacent fibers.
  3. 【請求項3】 着色模様は複数個所に設けられてなる請求項2記載の人形用部分染色毛髪。 3. A doll partial dyeing hair color patterning is provided at a plurality of locations according to claim 2.
  4. 【請求項4】 着色模様は相異なる色調の模様である請求項3記載の人形用部分染色毛髪。 4. A color patterning is pattern different shades claim 3 dolls partial dyeing hair according.
  5. 【請求項5】 集合状態に配置した多数本の繊維に、水性媒体の染色液を部分的に付着させ、該染色液が未乾燥状態にあるうちに、高周波電界による誘電加熱処理を行なうことにより染色液の付着した部位を染色することを特徴とする人形用部分染色毛髪の染色方法。 5. A large number of fibers arranged in the set state, a staining liquid aqueous medium partially attached to, while the 該染 Iroeki is in undried, by performing dielectric heating by the high frequency electric field the method of dyeing doll portion dyeing hair, which comprises dyeing the adhered site of the staining solution.
  6. 【請求項6】 多数本の繊維は、一端が集束固定状態にある請求項5記載の人形用部分染色毛髪の染色方法。 6. A large number of fibers, a method of dyeing doll portion dyeing hair according to claim 5, wherein one end is in focusing a fixed state.
  7. 【請求項7】 前記集束固定状態は、人形頭部に植毛状態にある請求項6記載の人形用部分染色毛髪の染色方法。 Wherein said converging fixed state, a method of dyeing doll portion dyeing hair according to claim 6, wherein in the planted state doll head.
  8. 【請求項8】 染色液の付着手段が、染色液を含浸させた多孔体を集合状態にある繊維の所望染色位置の繊維表面に接触配置することにより、染色液を繊維間に浸透させることを特徴とする請求項5乃至7記載のいずれかの人形用部分染色毛髪の染色方法。 8. staining liquid deposition means by contacting placed in the desired dyeing position of the fiber surface of the fibers in the porous body impregnated with dyeing liquor to a set state, that infiltrate staining solution between the fibers the method of any of dyeing doll portion dyeing hair according to claim 5 to 7, wherein.
JP12162197A 1997-04-23 1997-04-23 Partially dyed hair for doll and dyeing method therefor Pending JPH10295942A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12162197A JPH10295942A (en) 1997-04-23 1997-04-23 Partially dyed hair for doll and dyeing method therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12162197A JPH10295942A (en) 1997-04-23 1997-04-23 Partially dyed hair for doll and dyeing method therefor

Publications (1)

Publication Number Publication Date
JPH10295942A true true JPH10295942A (en) 1998-11-10

Family

ID=14815798

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12162197A Pending JPH10295942A (en) 1997-04-23 1997-04-23 Partially dyed hair for doll and dyeing method therefor

Country Status (1)

Country Link
JP (1) JPH10295942A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2006004A3 (en) * 2007-05-22 2009-01-07 The Pilot Ink Co., Ltd. Hair for toys
US8511320B2 (en) 2006-07-18 2013-08-20 Kaneka Corporation Fiber bundle for artificial hair, process for producing fiber bundle for artificial hair, and head decoration product
CN104695048A (en) * 2013-12-07 2015-06-10 招远鲁娃婴幼儿用品有限公司 Fiber for toll hair

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8511320B2 (en) 2006-07-18 2013-08-20 Kaneka Corporation Fiber bundle for artificial hair, process for producing fiber bundle for artificial hair, and head decoration product
EP2006004A3 (en) * 2007-05-22 2009-01-07 The Pilot Ink Co., Ltd. Hair for toys
CN104695048A (en) * 2013-12-07 2015-06-10 招远鲁娃婴幼儿用品有限公司 Fiber for toll hair

Similar Documents

Publication Publication Date Title
US3663262A (en) Fugitive coloration of solid materials with dyes
US5861044A (en) Method to selectively carve textile fabrics
US4740214A (en) Process for pattern dyeing of textile materials
EP0605730A1 (en) Printed cloth and method of manufacturing the same
US6350504B1 (en) Printed flocked pile fabric and method for making same
US20060029767A1 (en) Process for continuous production of a flocked and dyed cloth backing
US3906757A (en) Apparatus for continuous dyeing of yarns
US4586934A (en) Process and apparatus for coloring textile yarns
US4557972A (en) Ultrafine sheath-core composite fibers and composite sheets made thereof
US6387488B1 (en) Color-developing composite short fibers and color-developing structures employing the same
US4316924A (en) Synthetic fur and process for preparation thereof
US4361609A (en) Fiber structures of split multicomponent fibers and process therefor
US5925149A (en) Method for dyeing nylon fabrics in multiple colors
JP2002248423A (en) Colored three-dimensional pattern forming apparatus, method and article made by the same
US6497936B1 (en) Method and apparatus for dyeing and treating yarns
US5354342A (en) Stain resistant multicolor textured cut pile carpet
US3649400A (en) Method of manufacturing nonwoven fabric with pattern formed thereon
US6859983B2 (en) Camouflage material
US4525169A (en) Artificial grain leather having different color spot groups
CN101922059A (en) Production process of colored flat acrylic fiber and production line thereof
JPH06240587A (en) Multilayer dyeing of formed article of dyeable synthetic resin
US4604320A (en) Ultrafine sheath-core composite fibers and composite sheets made thereof
US20080155762A1 (en) Process for dyeing a textile web
US3961882A (en) Sculptured printing of nylon carpet
EP0127851A2 (en) Nonwoven fabric and process for producing thereof

Legal Events

Date Code Title Description
A977 Report on retrieval

Effective date: 20051017

Free format text: JAPANESE INTERMEDIATE CODE: A971007

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20051108

A521 Written amendment

Effective date: 20051227

Free format text: JAPANESE INTERMEDIATE CODE: A523

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20060207