JPH10280508A - Slowly soluble solid aromatic detergent - Google Patents

Abstract

PROBLEM TO BE SOLVED: To prevent clogging in a drain inlet by forming a plane section easily fixed onto a base in a tank to the periphery of a slowly soluble solid aromatic detergent charged into water in a fixed quantity in the tank and used and adjusting specific gravity so as to exceed a specific value. SOLUTION: The slowly soluble solid aromatic detergent 1, which has a rectangular parallelopiped shape and in which specific gravity is adjusted so as to exceed 1 and each surface is formed in plane sections 2, is molded, and fixed onto a base in a tank when it is charged into the tank because each surface has the plane sections 2. A cover for the tank of a water storage type flush toilet is opened and the slowly soluble solid detergent 1 is charged into the tank at the time of usage, the surface of the solid detergent 1 is melted and the solid detergent 1 has a sticking tendency, and one surface of the plane sections 2 is fixed onto the base in the tank. In the cube-shaped slowly soluble solid detergent 1, a layer A, in which the content of a pigment is not added or added in a trace quantity, is used as an external layer, and a layer B, in which the pigment at a normal level is contained, is formed as an internal layer. Accordingly, a hand is not stained by the pigment while a color shading is prevented.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a slowly dissolving solid agent which is used by being charged into a water storage tank of a flush toilet.

[0002]

2. Description of the Related Art Conventionally, a so-called in-tank type cleaner has been known as an aromatic detergent for a flush type flush toilet, which is used by hanging it in a tank of the toilet as it is, or wrapped in a water-soluble film. A throw-in type solid detergent has been known.

[0003]

In the above-mentioned conventional in-tank type cleaner, the hanging type of the former is very troublesome to mount and remove, and the water-soluble film of the throw-in type is the latter. Because of the problem of solubility, such as a semi-dissolved state, and the semi-dissolved substance comes out as it is, it took a long time to color. In addition, since this cleaner has a small specific gravity and has only one flat portion, there is a problem that the cleaner is moved by the water flow in the tank and clogs a drain port in the tank. An object of the present invention is to provide a gradually soluble solid agent that is fixed in the tank, does not move by a water flow, and has no fear of clogging a drain port in the tank, in order to eliminate the conventional problems. Things.

[0004]

The present invention has solved the above-mentioned problems by the following means. (1) In a gradually dissolving solid agent to be used by being introduced into a certain amount of water in a tank, the slowly dissolving solid agent has at least one flat portion around the periphery thereof which can be easily fixed to the bottom surface in the tank, A slowly dissolving solid agent having a solid form adjusted to have a specific gravity of 1 or more. (2) The slowly dissolving solid agent according to the above (1), wherein a layer substantially not containing a dye is at least a surface layer, and the inside contains a dye. (3) The slowly dissolving solid agent according to the above (1), wherein the interior is melt-filled and solidified in a container having a smooth interior.

[0005]

BEST MODE FOR CARRYING OUT THE INVENTION In the present invention, a slowly soluble solid agent is optional as long as it gradually dissolves in water and exerts an effect according to the contained components. Typically, the solid agent may be a single agent or a combination of an aromatic agent, a detergent, a bactericide, a rust inhibitor, a bleaching agent, a deodorant, and the like. When the solidifying agent is a detergent, its components include various surfactants such as polyoxyethylene stearate (nonionic surfactant), polyoxyethylene alkyl ether (nonionic surfactant), and fragrance (fragrance). Components, deodorant components), pigments (dyes), rust inhibitors, enzymes, bleaching agents, disinfectants such as TBZ and PCMX, and dissolution rate regulators such as polyethylene glycol. These components may have a specific gravity as large as possible so that the specific gravity becomes large. In addition to the above, sodium sulfate, talc, or the like may be added to make the specific gravity 1 or more. Among them, sodium sulfate which is easily soluble in water is preferable.

It is desirable that the above-mentioned solidifying agent has two or more layers. However, when the surface layer contains a dye, the content of the dye is smaller than that of the other layers, so that the surface layer is hardly stained even when touched by hand.
The surface layer does not need to be provided on the entire surface of the solidifying agent, and another layer containing the dye may be partially exposed. The solid agent has a specific gravity of 1 or more, preferably 1.1 or more, and most preferably 1.12 or more, and can quickly sink in water and quickly adhere to the inner bottom surface of the tank. Since the present invention has the above-described configuration, after being charged into the tank, it can be efficiently and quickly fixed to the bottom surface of the tank. The flow never goes away. In addition, hands are not stained during handling, have good sticking properties during use, and eliminate color unevenness.

[0007]

The present invention will be described below in detail with reference to examples. However, the present invention is not limited to only these examples.

Example 1 FIG. 1 shows a perspective view of one example of a slowly soluble solid agent of the present invention. The slowly soluble solid agent 1 has a rectangular parallelepiped shape, and each surface has a flat portion 2.
Is formed. In this case, since it is a rectangular parallelepiped, each surface has the flat portion 2, so that when it is put into the tank, it is guaranteed that any one of the flat portions will adhere to the bottom surface in the tank. At the time of use, the lid of the tank of the flush toilet is opened, and the gradually soluble solid agent 1 is put into the tank, thereby reaching the bottom of the tank. At this time, the surface of the solid agent 1 is melted. The solid agent 1 is fixed to the inner bottom surface of the tank on one surface of the flat portion 2 of the solid agent 1 as a result. Example 2 FIG. 2 shows a perspective view of another example of the slowly soluble solid agent of the present invention. It is substantially the same as that of FIG. 1 except that the solidifying agent 1 has a truncated pyramid shape. In this case, since the solid agent 1 has a truncated pyramid shape, when the solid agent is accommodated in a container of the same type, there is an advantage that the container is tapered to facilitate removal.

Example 3 As shown in a longitudinal sectional view of FIG.
Layer A, which is cubic and has no or very little dye content, is an outer layer, and the inner layer is a layer B containing a normal level of dye.
Are formed. In this case, since the layer A covers the layer B containing a large amount of pigment, there is an advantage that the pigment is not stained on the hands when the toner is put into the tank, and there is no uneven color.

Example 4 As shown in a vertical sectional view of FIG.
It is substantially the same as that of FIG. 3 except that a layer A containing no dye covers the outside of two layers B and C composed of three layers and different colors of the dye. In this case, since there are layers B and C of different kinds of dyes, two kinds of color tones can be enjoyed during one use period. The pigments may be the same and have different scents and medicinal effects. The layer B is
Since it has a surface that is in direct contact with water, it is preferable to use a fluorescent dye as a coloring matter and adjust so as to eliminate the difference in visual density.

Example 5 This slowly soluble solid agent 1 was prepared as shown in the longitudinal sectional view of FIG.
It is substantially the same as that shown in FIGS. 1 and 2 except that the rectangular parallelepiped has a through hole 3 substantially at the center thereof. In this case, since the through-hole 3 is provided, there is an advantage that the solidifying agent 1 is quickly fixed to the inner bottom surface of the tank. Example 6 This slowly soluble solid agent 1 has a cubic shape, and as shown in the vertical sectional view of FIG. It is embedded in the layer A not containing. In this case, since the columnar layer B is buried, there is an advantage that there is no color unevenness and that many components other than the dye can be used together.

Example 7 This slowly soluble solid agent 1 has a truncated regular pyramid shape, and as shown in a longitudinal sectional view of FIG. 7, a container in which the solid agent 1 is the same type of a thin material having a smooth inner surface. 4 and is substantially the same as that of each embodiment except that a seal 5 is provided on the opening surface of the container 4. In this case, since the solidifying agent 1 is contained in the container 4 having a thin inner surface and having a smooth inner surface, the solidifying agent 1 can be easily released from the mold by pressing the top surface 4a of the container 4 and denting it downward. After releasing the mold, the seal 5 is peeled off, and only the solidifying agent 1 can be efficiently introduced into the tank.

[0013]

As described above, the present invention has a flat portion around its periphery which can be fixed to the bottom surface of the tank, and has a specific gravity of 1 or more. , The surface is made stable by being supported by the surface, and the surface of the flat portion starts to be melted by water, so that it can be fixed to the bottom surface in the tank very efficiently and speedily. Does not move due to the water flow, so that the solidifying agent does not clog the drain port on the bottom surface in the tank. In addition, by making the outer layer of the solidifying agent a layer containing little or no pigment, hands are not stained at the time of handling, and excellent effects such as better fixation and no color unevenness during use are exhibited. In addition, by providing the solid agent in two or more layers, it is possible to impart a concentration gradient to the detergent, the fragrance, and the dye, and the elution concentration of each component can be made more stable. Furthermore, by using two or more layers, different scents, medicinal properties, and colors of the same component can be arbitrarily combined, so that a plurality of scents, medicinal properties, colors, and the like can be enjoyed in one use period.

[Brief description of the drawings]

FIG. 1 is a perspective view of a cuboid slow-dissolving solid agent as an example of the present invention.

FIG. 2 is a perspective view of a truncated pyramid-shaped gradually soluble solid agent as another example of the present invention.

FIG. 3 shows a longitudinal sectional view of a slowly soluble solid agent which is an example of the present invention.

FIG. 4 is a longitudinal sectional view of a three-layer type slowly soluble solid agent which is an example of the present invention.

FIG. 5 is a longitudinal sectional view of a slowly soluble solid agent having a through hole in the center, which is an example of the present invention.

FIG. 6 is a longitudinal sectional view of a slowly soluble solid agent having a columnar portion at the center, which is an example of the present invention.

FIG. 7 is a vertical cross-sectional view of an example of the present invention in which a gradually soluble solid agent having a truncated pyramid shape is accommodated in a container 4 of a thin material of the same shape and having a smooth inner surface.

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 1 Slowly soluble solid agent 2 Flat part 3 Through-hole 4 Container 4a Top surface 5 Seal A layer B layer C layer

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[Procedure amendment]

[Submission date] April 24, 1998

[Procedure amendment 1]

[Document name to be amended] Statement

[Correction target item name] Full text

[Correction method] Change

[Correction contents]

[Document Name] Statement

[Title of the Invention] Slowly soluble solid aroma cleaner

[Claims]

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a slowly dissolving solid-type aroma cleaning agent which is used by being charged into a water storage tank of a flush flush toilet. In particular, put it into the storage tank of a flush toilet
When used as a
Slowly soluble solid type that does not clog the drain port inside the tank
It relates to an aromatic detergent.

[0002]

2. Description of the Related Art Conventionally, a so-called in-tank type cleaner has been known as an aromatic detergent for a flush type flush toilet, which is used by hanging it in a tank of the toilet as it is, or wrapped in a water-soluble film. A throw-in type solid detergent has been known. Throw-in type solid washing
As one of the cleaning agents, tablet-type solid cleaning agents are known.
(Japanese Patent Laid-Open No. 54-13060)
Tablet mixture at high pressure to form a tablet
Because it is shaped, it is in the form of a tablet that is hard to break
is there.

[0003]

In the above-mentioned conventional in-tank type cleaner, the hanging type of the former is very troublesome to mount and remove, and the water-soluble film of the throw-in type is the latter. Because of the problem of solubility, such as a semi-dissolved state, and the semi-dissolved substance comes out as it is, it took a long time to color. In addition, since this cleaner has a small specific gravity and has only one flat portion, there is a problem that the cleaner is moved by the water flow in the tank and clogs a drain port in the tank. Especially in the case of Japanese flush toilets,
There is a storage tank with a drain at the bottom of the tank
Cause the problem of clogging the drain
No. The present invention is used in order to eliminate the above-mentioned conventional problems by being fixedly attached to a bottom surface in the tank and not moving due to a water flow generated when the water is flown, so that there is no fear of clogging a drain port in the tank. An object of the present invention is to obtain a soluble solid aromatic detergent .

[0004]

The present invention provides the following means.
The above problem has been solved. (1) Slow solubility used in a certain amount of water in a tank
SolidAromatic cleaningThe slowly soluble solid formAromatic cleaningAgent
There are few flat areas around it that can be easily fixed to the bottom of the tank.
Have at least one,The flat part is fixed to the bottom of the tank
use,Specific gravity is 1Cross overSolid form adjusted
Characterized by the fact thatAromatic cleaningAgent. (2) At least a surface layer containing substantially no dye
And wherein the inside contains a dye
Slowly soluble solid according to (1)Aromatic cleaningAgent. (3) The inside of the container must be melt-filled and solidified in a smooth container.
The slowly soluble solid according to (1) above,Aromatic cleaning
Agent.

[0005]

BEST MODE FOR CARRYING OUT THE INVENTION In the present invention, a slowly soluble solid aroma is used.
The detergent (hereinafter sometimes simply referred to as "solidifying agent") is optional as long as it can be gradually dissolved in water and exert an effect corresponding to the contained components. Typically, examples of the solid aromatic detergent include those in which a bactericide, a rust inhibitor, a bleaching agent, a deodorant, and the like are used alone or in combination in addition to the fragrance and the detergent. In the solid agent, the components of the cleaning agent, polyoxyethylene stearate (nonionic surfactant), various surfactants such as polyoxyethylene alkyl ether (nonionic surfactant), with the other, Perfume (fragrance component, deodorant component), pigment (dye), rust inhibitor, enzyme, bleach, TB
Z, disinfectants such as PCMX, dissolution rate regulators such as polyethylene glycol, and the like. These components may have a specific gravity as large as possible so that the specific gravity becomes large. In addition to the above, sodium sulfate, talc, or the like may be added to make the specific gravity exceed 1. Among them, sodium sulfate which is easily soluble in water is preferable.

It is desirable that the above-mentioned solidifying agent has two or more layers. However, when the surface layer contains a dye, the content of the dye is smaller than that of the other layers, so that the surface layer is hardly stained even when touched by hand.
The surface layer does not need to be provided on the entire surface of the solidifying agent, and another layer containing the dye may be partially exposed. The solid agent specific gravity greater than 1, preferably 1.1 or more, and most preferably may not less 1.12 or more, sink quickly in water, it can be fixed quickly to the inner bottom surface of the tank. Since the present invention has the above-described configuration, after being charged into the tank, it can be efficiently and quickly fixed to the bottom surface of the tank. The flow never goes away. In addition, hands are not stained during handling, have good sticking properties during use, and eliminate color unevenness.

[0007]

The present invention will be described below in detail with reference to examples. However, the present invention is not limited to only these examples.

Example 1 FIG. 1 is a perspective view showing one example of a slowly dissolving solid-type aroma detergent of the present invention. Slowly soluble solid aromatic detergent (hereinafter also referred to as "solid agent")
In the drawings, simply referred to as “slow-solubilizing solid agent”) 1 has a rectangular parallelepiped shape, and each surface forms a plane portion 2. In this case, since it is a rectangular parallelepiped, each surface has the flat portion 2, so that when it is put into the tank, it is guaranteed that any one of the flat portions will adhere to the bottom surface in the tank. Before use, open the tank lid of the flush flush toilet and put the slowly soluble solid agent 1 in the tank.
, The solid agent 1 reaches the bottom surface of the tank, and at this time, the surface of the solid agent 1 is melted and thus has a fixed property. As a result, the solid agent 1 is placed on the bottom surface of the tank. Plane part 2 of
Stick on one side. Example 2 FIG. 2 shows a perspective view of another example of the slowly soluble solid agent of the present invention. Except that solid agents 1 has a prismatic shape Ru substantially identical der as in FIG.

Example 3 As shown in a longitudinal sectional view of FIG.
Layer A, which is cubic and has no or very little dye content, is an outer layer, and the inner layer is a layer B containing a normal level of dye.
Are formed. In this case, since the layer A covers the layer B containing a large amount of pigment, there is an advantage that the pigment is not stained on the hands when the toner is put into the tank, and there is no uneven color.

Example 4 As shown in a vertical sectional view of FIG.
It is substantially the same as that of FIG. 3 except that a layer A containing no dye covers the outside of two layers B and C composed of three layers and different colors of the dye. In this case, since there are layers B and C of different kinds of dyes, two kinds of color tones can be enjoyed during one use period. The pigments may be the same and have different scents and medicinal effects. The layer B is
Since it has a surface that is in direct contact with water, it is preferable to use a fluorescent dye as a coloring matter and adjust so as to eliminate the difference in visual density.

Example 5 This slowly soluble solid agent 1 was prepared as shown in the longitudinal sectional view of FIG.
It is substantially the same as that shown in FIGS. 1 and 2 except that the rectangular parallelepiped has a through hole 3 substantially at the center thereof. In this case, since the through-hole 3 is provided, there is an advantage that the solidifying agent 1 is quickly fixed to the inner bottom surface of the tank. Example 6 This slowly soluble solid agent 1 has a cubic shape, and as shown in the vertical sectional view of FIG. It is embedded in the layer A not containing. In this case, since the columnar layer B is buried, there is an advantage that there is no color unevenness and that many components other than the dye can be used together.

Example 7 This slowly soluble solid agent 1 has a truncated regular pyramid shape, and as shown in a longitudinal sectional view of FIG. 7, a container in which the solid agent 1 is the same type of a thin material having a smooth inner surface. 4 and is substantially the same as that of each embodiment except that a seal 5 is provided on the opening surface of the container 4. In this case the thin material of the inner surface is the solid agent 1 is housed in a smooth container 4, by recessing downward by pressing the top surface 4a of the container 4, thereby easily releasing the solid agent 1 There is an advantage that after release, the seal 5
It can be introduced efficiently only the solid dosage 1 to peeling to the tank.

[0013]

According to the present invention, as described above, it has a planar portion which can be fixed to the tank bottom to its periphery, a specific gravity greater than 1
Since those that, in contact with the immediately tank bottom plane portion when the charged into the tank, the support by the surface is held are in stably made, and by the surface of the planar portion begins to melt with water, Since the solidifying agent can be fixed very efficiently and quickly to the bottom surface in the tank, the solidifying agent does not move due to the water flow, and thus the solidifying agent does not clog the drain port on the bottom surface in the tank. In addition, by making the outer layer of the solidifying agent a layer containing little or no pigment, hands are not stained at the time of handling, and excellent effects such as better fixation and no color unevenness during use are exhibited. In addition, by providing the solid agent in two or more layers, it is possible to impart a concentration gradient to the detergent, the fragrance, and the dye, and the elution concentration of each component can be made more stable. Furthermore, 2
By having more than one layer, the same ingredients have different scents, medicinal properties,
Since the colors can be arbitrarily combined, a plurality of scents, medicinal effects, colors, and the like can be enjoyed in one use period.

[Brief description of the drawings]

FIG. 1 is a perspective view of a cuboid slow-dissolving solid agent as an example of the present invention.

FIG. 2 is a perspective view of a prismatic slowly soluble solid agent as another example of the present invention.

FIG. 3 shows a longitudinal sectional view of a slowly soluble solid agent which is an example of the present invention.

FIG. 4 is a longitudinal sectional view of a three-layer type slowly soluble solid agent which is an example of the present invention.

FIG. 5 is a longitudinal sectional view of a slowly soluble solid agent having a through hole in the center, which is an example of the present invention.

FIG. 6 is a longitudinal sectional view of a slowly soluble solid agent having a columnar portion at the center, which is an example of the present invention.

FIG. 7 is a vertical cross-sectional view of an example of the present invention in which a gradually soluble solid agent having a truncated pyramid shape is accommodated in a container 4 of a thin material of the same shape and having a smooth inner surface.

[Explanation of Signs] 1 Slowly dissolving solid agent 2 Flat part 3 Through hole 4 Container 4a Top surface 5 Seal A layer B layer C layer

 ──────────────────────────────────────────────────続 き Continuation of the front page (72) Inventor Junichiro Mezaki 3-1-2 Nakahamacho, Ako City, Hyogo Prefecture (72) Inventor Akira Nishimura 9-14 Matsubaracho, Ako City, Hyogo Prefecture

Claims (3)

[Claims] 1. A slowly dissolving solid agent which is used by being poured into a certain amount of water in a tank, wherein the slowly dissolving solid agent has at least one flat portion around which the solid solution can be easily fixed to the bottom surface of the tank. And a solid-solubilized solid agent in a solid form adjusted to have a specific gravity of 1 or more. 2. The slowly dissolving solid agent according to claim 1, wherein a layer substantially not containing a dye is at least a surface layer, and the inside contains a dye. 3. The slowly dissolving solid agent according to claim 1, wherein the inside of the container is melt-filled and solidified in a smooth container.