JPH10263535A - Water purifying device - Google Patents

Water purifying device

Info

Publication number
JPH10263535A
JPH10263535A JP9068568A JP6856897A JPH10263535A JP H10263535 A JPH10263535 A JP H10263535A JP 9068568 A JP9068568 A JP 9068568A JP 6856897 A JP6856897 A JP 6856897A JP H10263535 A JPH10263535 A JP H10263535A
Authority
JP
Japan
Prior art keywords
light
water
water purification
thin film
light source
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9068568A
Other languages
Japanese (ja)
Inventor
Machiko Yukitani
まち子 行谷
Toru Kubota
亨 久保田
Toru Yamaguchi
徹 山口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Toshiba AVE Co Ltd
Original Assignee
Toshiba Corp
Toshiba AVE Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp, Toshiba AVE Co Ltd filed Critical Toshiba Corp
Priority to JP9068568A priority Critical patent/JPH10263535A/en
Publication of JPH10263535A publication Critical patent/JPH10263535A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Abstract

PROBLEM TO BE SOLVED: To maintain stable high water purifying performance over a long period. SOLUTION: This water purifying device is provided with a light source 4 for emitting light containing ultraviolet ray, a light transmissive member 5 formed so as to cover the light source 4 and transmitting light from the light source 4 and a light excitation thin film 6, which is formed on the outer surface of the light transmitting member 5 in contact with a water-bearing liquid to be purified and is excited by the light from the light source 4 to purify the water-bearing liquid to be purified by a chemical reaction.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、光触媒を用いた浄
水装置に関する。
[0001] The present invention relates to a water purification device using a photocatalyst.

【0002】[0002]

【従来の技術】これまで、水の浄化は、活性炭、フィル
タによるものが一般的であった。しかし、最近では、触
媒により、水中の有害物質を化学的に分解して浄化する
技術が発達してきた。通常、触媒は活性化されないとそ
の効果を発揮しない。この触媒を活性化させる手段とし
て熱エネルギーが最も一般的である。しかし搭載される
部位によっては、加熱が不可能な場合もあり、熱による
活性化触媒は制約が多かった。ところが、蛍光灯のよう
な弱い光でも活性化する光触媒が開発され、光が照射さ
れるところであれば、どこでも効果を発揮させることが
可能となった。光触媒は半導体であり、紫外線が照射さ
れると正孔が生成される。この正孔が水と反応してOH
ラジカルを生成し、水中の有機物を分解するというしく
みで浄水を行う。つまり、紫外線は不可欠ということで
ある。図8は、このような光触媒を用いた従来の浄水装
置を示している。紫外線ランプ21が光透過性部材22
で完全に覆われ、この光透過性部材22から適宜間隔を
おいて光触媒を担持したセラミックスハニカム23が配
設されている。24は処理液の入口、25は出口であ
る。処理液はセラミックスハニカム23に担持された光
触媒に接したところから浄化される。また、浄水の分野
では、紫外線によって有機物の分解や殺菌などに応用す
る技術が古くから検討されている。
2. Description of the Related Art Heretofore, water has generally been purified by activated carbon and a filter. However, recently, a technology for purifying by chemically decomposing harmful substances in water using a catalyst has been developed. Usually, the catalyst does not exert its effect unless activated. Thermal energy is the most common means of activating this catalyst. However, heating may not be possible depending on the portion to be mounted, and the catalyst activated by heat has many restrictions. However, photocatalysts, such as fluorescent lamps, that can be activated by weak light have been developed, and the effect can be exerted wherever light is irradiated. The photocatalyst is a semiconductor and generates holes when irradiated with ultraviolet light. These holes react with water to form OH
Water is purified by generating radicals and decomposing organic substances in water. That is, ultraviolet rays are indispensable. FIG. 8 shows a conventional water purification device using such a photocatalyst. UV lamp 21 is a light transmitting member 22
A ceramic honeycomb 23 carrying a photocatalyst is provided at an appropriate distance from the light transmitting member 22. Reference numeral 24 denotes an inlet for the processing liquid, and reference numeral 25 denotes an outlet. The treatment liquid is purified from the part in contact with the photocatalyst supported on the ceramic honeycomb 23. In the field of water purification, technology applied to decomposition and sterilization of organic substances by ultraviolet rays has been studied for a long time.

【0003】一方、生活の多様化、清潔志向の高まりな
どから1日に数回入浴したり、いつでも入浴したいとい
うニーズが高まってきている。さらに、風呂掃除をしな
くてもよいという利便性から、循環式風呂水浄化装置
(一般的には24時間風呂と呼ばれている)が普及して
いる。この循環式風呂水浄化装置は比較的大きなゴミを
除去するフィルタと微生物によってその他の汚れを分解
する浄化槽、及び保温用ヒータ、ポンプで形成され、常
時湯を循環して浄化するものである。
On the other hand, diversification of daily life and growing desire for cleanliness have increased the need to take a bath several times a day or to take a bath at any time. Furthermore, a circulating bath water purifier (generally referred to as a 24-hour bath) has become widespread because of the convenience of not having to clean the bath. The circulating bath water purifier is formed by a filter for removing relatively large dust, a purifying tank for decomposing other dirt by microorganisms, a heater for keeping heat, and a pump, and circulates and purifies hot water constantly.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、従来の
浄水装置では、紫外線ランプを覆っている光透過性部材
は、処理液が接すると水中の汚れが徐々に付着する。長
期的に使用を続けると、この汚れに細菌が付着するおそ
れがある上に、紫外線の透過を妨害するため、セラミッ
クスハニカムに担持された光触媒に十分に紫外線エネル
ギーが行き渡らなくなる。その結果、浄水能力が徐々に
低下してくるという問題点があった。
However, in the conventional water purifier, when the processing liquid comes into contact with the light-transmitting member covering the ultraviolet lamp, dirt in the water gradually adheres. If used for a long period of time, bacteria may adhere to the dirt, and furthermore, the transmission of ultraviolet light is hindered, so that the ultraviolet energy is not sufficiently distributed to the photocatalyst supported on the ceramic honeycomb. As a result, there was a problem that the water purification capacity gradually decreased.

【0005】また、従来の循環式風呂水浄化装置におけ
る浄化方法では、微生物による浄化が、循環条件に左右
されるので、その浄化能力が不安定になりやすく、さら
に浄化菌等の細菌類が浴槽に流出するおそれがある。対
策として、光触媒による浄化機能が付与されたもの、オ
ゾンや紫外線による殺菌機能を付与されたものがある。
しかし、先に述べたように水中で紫外線ランプを長時間
使用する場合は、紫外線ランプや保護管に水中の汚れが
付着し、紫外線出力が低下する。その結果、十分に浄水
及び殺菌することが不可能になるという問題点があっ
た。
[0005] In the purification method of the conventional circulating bath water purification apparatus, purification by microorganisms depends on circulation conditions, so that the purification ability tends to be unstable, and bacteria such as purification bacteria are liable to bathtub. May be leaked. As a countermeasure, there is one provided with a purification function using a photocatalyst, and one provided with a sterilization function using ozone or ultraviolet rays.
However, when the ultraviolet lamp is used for a long time in water as described above, dirt in the water adheres to the ultraviolet lamp and the protection tube, and the ultraviolet output decreases. As a result, there is a problem that it becomes impossible to sufficiently purify and sterilize water.

【0006】本発明は、上記に鑑みてなされたもので、
安定した高い浄水能力を長期的に維持し続けることがで
きる浄水装置を提供することを目的とする。
[0006] The present invention has been made in view of the above,
An object of the present invention is to provide a water purification device that can maintain a stable and high water purification capacity for a long period of time.

【0007】[0007]

【課題を解決するための手段】上記課題を解決するため
に、請求項1記載の発明は、紫外線を含む光を発する光
源と、該光源を覆うように形成され当該光源からの光を
透過する光透過性部材と、被浄化処理含水液体が接触す
る前記光透過性部材の外表面に形成され前記光源からの
光で励起されて化学反応により前記被浄化処理含水液体
を浄化する光励起薄膜とを有することを要旨とする。こ
の構成により、光励起薄膜の化学反応によって接触した
被浄化処理含水液体の浄化と同時に光透過性部材の外表
面の汚れが分解されて付着が防止される。
According to a first aspect of the present invention, there is provided a light source for emitting light including ultraviolet light, and a light source formed to cover the light source and transmitting light from the light source. A light-transmitting member, and a light-excited thin film formed on an outer surface of the light-transmitting member, which is in contact with the water-containing liquid to be purified, and excited by light from the light source to purify the water-containing liquid to be purified by a chemical reaction. It is the gist to have. With this configuration, the dirt on the outer surface of the light-transmitting member is decomposed and the adhesion is prevented at the same time as the water-containing liquid to be purified is contacted by the chemical reaction of the photoexcited thin film.

【0008】請求項2記載の発明は、紫外線を含む光を
発する光源と、該光源を覆うように形成され当該光源か
らの光を透過する光透過性部材及び家庭用上水が接触す
る前記光透過性部材の外表面に形成され前記光源からの
光で励起されて化学反応により前記家庭用上水を浄化す
る光励起薄膜を備えた光浄水部を、前記家庭用上水を一
時的に貯留するタンクに取り付けてなることを要旨とす
る。この構成により、多量の家庭用上水が的確に浄化処
理される。
According to a second aspect of the present invention, there is provided a light source which emits light including ultraviolet light, the light transmitting member which is formed to cover the light source and transmits light from the light source, and the light which is in contact with domestic tap water. The optical water purification unit, which is formed on the outer surface of the transparent member and is provided with a photo-excitation thin film that is excited by light from the light source and purifies the household water by a chemical reaction, temporarily stores the household water. The point is to attach to the tank. With this configuration, a large amount of domestic water is properly purified.

【0009】請求項3記載の発明は、上記請求項2記載
の浄水装置において、前記家庭用上水は浴槽水であり、
前記光浄水部で浄化した水を循環使用するように構成し
てなることを要旨とする。この構成により、循環使用さ
れる浴槽水が的確に且つ安定して浄化処理される。
According to a third aspect of the present invention, in the water purification apparatus according to the second aspect, the domestic tap water is bathtub water,
The gist is that the water purified by the light water purification section is configured to be circulated and used. With this configuration, the bathtub water to be circulated is purified accurately and stably.

【0010】請求項4記載の発明は、上記請求項2記載
の浄水装置において、セラミックス等の担持体に微生物
を担持させ前記家庭用上水を浄化する微生物浄水部を有
し、前記光浄水部は前記微生物浄水部の下流側に配置し
てなることを要旨とする。この構成により、家庭用上水
中の生物処理不可能な物質の浄化が可能になるとともに
光浄水部は殺菌効果も持つため、微生物浄水部から流出
した浄化菌の殺菌が可能となる。
According to a fourth aspect of the present invention, there is provided the water purification device according to the second aspect, further comprising a microorganism water purification unit for purifying the domestic water by supporting microorganisms on a carrier such as ceramics. The gist is that it is arranged downstream of the microorganism purification section. With this configuration, it is possible to purify substances that cannot be biologically treated in domestic water, and since the optical water purification section also has a bactericidal effect, it is possible to sterilize purified bacteria flowing out of the microorganism water purification section.

【0011】請求項5記載の発明は、上記請求項2又は
3記載の浄水装置において、フィルタを含む物理濾過部
を有し、前記光浄水部は前記物理濾過部の下流側に配置
してなることを要旨とする。この構成により、物理濾過
部の微粒子除去作用によって光浄水部では紫外線透過率
が高まり、浄水力が向上する。
According to a fifth aspect of the present invention, there is provided the water purification apparatus according to the second or third aspect, further comprising a physical filtration unit including a filter, wherein the optical water purification unit is disposed downstream of the physical filtration unit. That is the gist. With this configuration, the ultraviolet light transmittance in the light water purification unit is increased by the action of removing fine particles of the physical filtration unit, and the water purification power is improved.

【0012】請求項6記載の発明は、上記請求項3記載
の浄水装置において、前記光浄水部と前記タンクとの間
に、前記家庭用上水を常時循環させる駆動部と、前記家
庭用上水を最適浄化温度に維持する加熱部と、これらを
接続する配管とを有することを要旨とする。この構成に
より、家庭用上水が微生物処理等に最適な温度に維持さ
れて効率のよい浄水が可能となる。
According to a sixth aspect of the present invention, in the water purification apparatus according to the third aspect, a driving unit for constantly circulating the domestic water supply between the optical water purification unit and the tank; The gist of the present invention is to have a heating section for maintaining water at an optimum purification temperature and a pipe for connecting these. With this configuration, domestic tap water is maintained at an optimum temperature for microbial treatment and the like, and efficient water purification becomes possible.

【0013】請求項7記載の発明は、上記請求項2,
3,4,5又は6記載の浄水装置において、処理される
前記家庭用上水は気泡を含有していることを要旨とす
る。この構成により、溶存酸素量が高まり、光励起薄膜
の化学反応が促進されて浄化効果が向上する。
[0013] The invention according to claim 7 is the invention according to claim 2,
7. The water purifier according to 3, 4, 5 or 6, wherein the domestic water to be treated contains air bubbles. With this configuration, the amount of dissolved oxygen increases, and the chemical reaction of the photoexcited thin film is promoted, thereby improving the purification effect.

【0014】請求項8記載の発明は、上記請求項2,
3,4,5,6又は7記載の浄水装置において、前記タ
ンクへの排出部は、気泡を含有する機能が付与されてい
ることを要旨とする。この構成により、上記請求項7記
載の発明の作用と同様の作用に加えてさらに、家庭用上
水が浴槽水であるときには、入浴者へのマッサージ効果
が得られる。
[0014] The invention described in claim 8 is the second invention.
The gist of the water purifier according to any one of 3, 4, 5, 6 and 7, wherein the discharge portion to the tank has a function of containing bubbles. According to this configuration, in addition to the same effect as the above-described seventh aspect of the invention, when the domestic tap water is bathtub water, a massage effect for the bather can be obtained.

【0015】請求項9記載の発明は、上記請求項1乃至
8の何れかに記載の浄水装置において、前記光源と前記
光透過性部材との間は、気体もしくは真空状態であるこ
とを要旨とする。この構成により、紫外線透過率が高ま
って浄水効率が向上する。
According to a ninth aspect of the present invention, in the water purifier according to any one of the first to eighth aspects, a gas or a vacuum is provided between the light source and the light transmitting member. I do. With this configuration, the ultraviolet ray transmittance increases, and the water purification efficiency improves.

【0016】請求項10記載の発明は、上記請求項1乃
至8の何れかに記載の浄水装置において、前記光透過性
部材は透水性であることを要旨とする。この構成によ
り、被浄化処理液が光源に直接接触して紫外線による殺
菌等の作用が高まる。
According to a tenth aspect of the present invention, in the water purifier according to any one of the first to eighth aspects, the light-transmitting member is water-permeable. With this configuration, the liquid to be purified is in direct contact with the light source, and the action such as sterilization by ultraviolet rays is enhanced.

【0017】請求項11記載の発明は、上記請求項10
記載の浄水装置において、前記光透過性部材の内表面と
前記光源の壁面に前記光励起薄膜を形成してなることを
要旨とする。この構成により、上記請求項10記載の発
明の作用と同様の作用に加えてさらに、被浄化処理液と
光励起薄膜の接触面積が増大して、より高い浄水効果が
得られる。
The invention according to claim 11 is the invention according to claim 10.
In the water purification apparatus described above, the gist is that the light excitation thin film is formed on an inner surface of the light transmitting member and a wall surface of the light source. According to this configuration, in addition to the same function as the above-described function of the tenth aspect, the contact area between the liquid to be purified and the photoexcitation thin film is further increased, so that a higher water purification effect can be obtained.

【0018】請求項12記載の発明は、上記請求項1乃
至11の何れかに記載の浄水装置において、前記光透過
性部材は石英ガラスで形成してなることを要旨とする。
この構成により、紫外線透過率が高まり、浄水効率が向
上する。
According to a twelfth aspect of the present invention, in the water purifier according to any one of the first to eleventh aspects, the light transmitting member is formed of quartz glass.
With this configuration, the ultraviolet transmittance is increased, and the water purification efficiency is improved.

【0019】請求項13記載の発明は、上記請求項1乃
至12の何れかに記載の浄水装置において、前記光励起
薄膜は、酸化チタンを主成分としたゾルゲル法によって
形成してなることを要旨とする。この構成により、光透
過性の高い光励起薄膜が光透過性部材の内外表面や光源
の壁面に適切に形成される。
According to a thirteenth aspect of the present invention, in the water purifier according to any one of the first to twelfth aspects, the photoexcited thin film is formed by a sol-gel method containing titanium oxide as a main component. I do. With this configuration, the light-exciting thin film having high light transmittance is appropriately formed on the inner and outer surfaces of the light-transmitting member and the wall surface of the light source.

【0020】請求項14記載の発明は、上記請求項1乃
至13の何れかに記載の浄水装置において、前記光励起
薄膜を形成した透過性部材を間に挟んで対向する位置
に、前記光源からの少なくとも紫外線を反射する反射面
を形成してなることを要旨とする。この構成により、紫
外線が有効に活用されて浄水効率が向上する。
According to a fourteenth aspect of the present invention, there is provided the water purification apparatus according to any one of the first to thirteenth aspects, wherein the light source from the light source is located at a position facing the light-excited thin film-formed transparent member. The gist of the invention is to form at least a reflection surface that reflects ultraviolet light. With this configuration, the ultraviolet light is effectively used, and the water purification efficiency is improved.

【0021】請求項15記載の発明は、上記請求項14
記載の浄水装置において、前記反射面には、前記光励起
薄膜を形成してなることを要旨とする。この構成によ
り、反射面への汚れ付着が防止されて、常時高い反射作
用が得られる。
According to a fifteenth aspect of the present invention, the above-mentioned fourteenth aspect
In the water purification device described above, the light excitation thin film is formed on the reflection surface. With this configuration, it is possible to prevent dirt from adhering to the reflection surface, and to always obtain a high reflection action.

【0022】請求項16記載の発明は、上記請求項1乃
至15の何れかに記載の浄水装置において、前記光励起
薄膜を形成した面に、前記被浄化処理含水液体の流れに
乱流を起こさせる障害部材を形成してなることを要旨と
する。この構成により、光励起薄膜と被浄化処理液の接
触頻度が高まって、より高い浄水効果が得られる。
According to a sixteenth aspect of the present invention, in the water purification apparatus according to any one of the first to fifteenth aspects, a turbulent flow is caused in the flow of the water-containing liquid to be purified on the surface on which the photoexcitation thin film is formed. The gist is to form an obstacle member. With this configuration, the frequency of contact between the photoexcitation thin film and the liquid to be purified increases, and a higher water purification effect can be obtained.

【0023】請求項17記載の発明は、上記請求項16
記載の浄水装置において、前記障害部材は、前記光励起
薄膜を形成した面に凹凸を付けたものであることを要旨
とする。この構成により、装置内への障害部材の容易形
成性が得られる。
The invention according to claim 17 is the invention according to claim 16.
In the water purification device described above, the obstacle is that the surface on which the photoexcitation thin film is formed has irregularities. With this configuration, it is possible to easily form the obstacle member in the apparatus.

【0024】[0024]

【発明の実施の形態】以下、本発明の実施の形態を図面
に基づいて説明する。
Embodiments of the present invention will be described below with reference to the drawings.

【0025】図1は、本発明の第1の実施の形態を示す
図である。まず光浄水部10Aの構成を説明すると、光
源としての紫外線ランプ4が光透過性部材5で完全に覆
われている。紫外線ランプ4と光透過性部材5の間は気
体が存在していてもよいが紫外線透過率の高い真空状態
の方が好ましい。光透過性部材5は紫外線透過率の高い
石英ガラスで形成され、処理裡液と接する外表面に光励
起薄膜6が形成されている。また、光透過性部材5を間
に挟んで光浄水部本体の対向する内壁面は、少なくとも
紫外線を反射するとともに被浄化処理含水液体の流れに
乱流を起こさせる障害部材としての凹凸の付いた凹凸付
き反射面7で形成され、この凹凸付き反射面7にも光励
起薄膜6が形成されている。2は光浄水部入口、3は光
浄水部出口である。光励起薄膜6は、酸化チタンを主成
分とした酸化チタンゾルを塗布、乾燥を数回繰り返し、
焼成して固定する方法、即ちゾルゲル法で作製され、厚
さは0.1μm程度に形成されている。これにより、従
来の酸化チタン微粒子懸濁液を塗布する方法とは異な
り、光透過性の高い触媒層が得られ、直接紫外線ランプ
や保護管、壁面などに形成することが可能となってい
る。
FIG. 1 is a diagram showing a first embodiment of the present invention. First, the configuration of the light purification unit 10A will be described. The ultraviolet lamp 4 as a light source is completely covered with the light transmitting member 5. A gas may be present between the ultraviolet lamp 4 and the light transmitting member 5, but a vacuum state having a high ultraviolet transmittance is preferable. The light transmissive member 5 is formed of quartz glass having a high ultraviolet transmittance, and a light excitation thin film 6 is formed on an outer surface in contact with the treated liquid. The opposite inner wall surface of the optical water purification unit main body with the light transmitting member 5 interposed therebetween has irregularities as an obstacle member that reflects at least ultraviolet rays and causes turbulence in the flow of the water-containing liquid to be purified. The light-excitation thin film 6 is also formed on the uneven reflection surface 7. Reference numeral 2 denotes an entrance of the light purification unit, and reference numeral 3 denotes an exit of the light purification unit. The photoexcitation thin film 6 is formed by applying and drying a titanium oxide sol containing titanium oxide as a main component several times,
It is manufactured by a method of firing and fixing, that is, a sol-gel method, and has a thickness of about 0.1 μm. Thereby, unlike the conventional method of applying a suspension of titanium oxide fine particles, a catalyst layer having high light transmittance is obtained and can be directly formed on an ultraviolet lamp, a protective tube, a wall surface, or the like.

【0026】上記のように構成された光浄水部10Aの
作用を説明する。被浄化処理含水液体である処理液は光
浄水部入口2より入り、光浄水部10A内で浄化されて
光浄水部出口3より排出される。光浄水部10A内で
は、紫外線ランプ4の光によって光励起薄膜6が活性化
され、化学反応により処理液が浄化される。このとき、
光浄水部本体の内壁面は反射面で構成されているため紫
外線が光浄水部10A内で反射し、有効に活用される。
また、内壁面には、光励起薄膜6が形成されている上に
凹凸を有するため、内部で乱流が起こり、処理液と光励
起薄膜6の接触回数が増し、浄水効果が上がる。以上の
ように、光励起薄膜6が形成されている面では化学反応
によって処理液中の有機物を分解するため、浄水と同時
に処理液が接する面の汚れを分解して付着を防止する。
その結果、衛生的かつ、紫外線エネルギー透過の妨害防
止効果がある。よって、長期的に使用しても、常に紫外
線エネルギーが光励起薄膜6に十分に行き渡り、光励起
薄膜6の高い浄化効果が得られる。
The operation of the optical water purification unit 10A configured as described above will be described. The treatment liquid, which is the water-containing liquid to be purified, enters through the light purification unit inlet 2, is purified in the light purification unit 10 </ b> A, and is discharged from the light purification unit outlet 3. In the light purification unit 10A, the light from the ultraviolet lamp 4 activates the photoexcited thin film 6, and the treatment liquid is purified by a chemical reaction. At this time,
Since the inner wall surface of the optical water purification unit main body is formed of a reflection surface, ultraviolet rays are reflected in the optical water purification unit 10A and are effectively used.
In addition, since the photoexcitation thin film 6 is formed on the inner wall surface and has irregularities, turbulence occurs inside, and the number of contacts between the treatment liquid and the photoexcitation thin film 6 increases, and the water purification effect increases. As described above, since the organic matter in the processing liquid is decomposed by the chemical reaction on the surface on which the photoexcitation thin film 6 is formed, dirt on the surface in contact with the processing liquid is decomposed at the same time as water purification to prevent adhesion.
As a result, there is a hygienic effect of preventing transmission of ultraviolet energy. Therefore, even when used for a long period of time, ultraviolet energy is always sufficiently distributed to the photoexcited thin film 6, and a high purification effect of the photoexcited thin film 6 is obtained.

【0027】図2には、本発明の第2の実施の形態を示
す。本実施の形態の光浄水部10Bでは、石英ガラスか
らなる光透過性部材5aは透水性を有し、紫外線ランプ
4と処理液が直接接触する構造になっている。そして、
この透水性の光透過性部材5aの外表面だけでなく、内
表面と紫外線ランプ4自体にも光励起薄膜6が形成され
ている。この構造によれば、透水性の光透過性部材5a
外表面の光励起薄膜6で浄化された処理液がさらに光透
過性部材5a内表面や紫外線ランプ4表面の光励起薄膜
6で浄化されるため、一層浄水効果が上がる。また、装
置全体の光励起薄膜6の面積が多くなるため、より高い
浄水効果が期待できる。
FIG. 2 shows a second embodiment of the present invention. In the light water purification section 10B of the present embodiment, the light transmissive member 5a made of quartz glass has water permeability, and has a structure in which the ultraviolet lamp 4 and the treatment liquid are in direct contact. And
The photoexcitation thin film 6 is formed not only on the outer surface of the water-permeable light-transmitting member 5a but also on the inner surface and the ultraviolet lamp 4 itself. According to this structure, the water-permeable light-transmitting member 5a
The treatment liquid purified by the photoexcitation thin film 6 on the outer surface is further purified by the photoexcitation thin film 6 on the inner surface of the light transmitting member 5a and the surface of the ultraviolet lamp 4, so that the water purification effect is further improved. In addition, since the area of the photoexcitation thin film 6 of the entire apparatus increases, a higher water purification effect can be expected.

【0028】図3には、本発明の第3の実施の形態を示
す。本実施の形態の光浄水部10Cでは、紫外線ランプ
4が、直接処理液と接する構造になっており、紫外線ラ
ンプ4表面には光励起薄膜6が形成されている。この場
合、紫外線ランプ4は直管よりもU字管の方が光励起薄
膜6の面積が増すため、U字管の方が好ましい。
FIG. 3 shows a third embodiment of the present invention. In the water purification section 10C of the present embodiment, the ultraviolet lamp 4 has a structure in direct contact with the treatment liquid, and the photoexcitation thin film 6 is formed on the surface of the ultraviolet lamp 4. In this case, the U-shaped tube of the ultraviolet lamp 4 is preferable because the area of the photoexcitation thin film 6 is larger in the U-shaped tube than in the straight tube.

【0029】以上の第1〜第3の実施の形態の光浄水部
10A,10B,10Cを用い、前記図8の従来の光浄
水部を比較例として浄水性能を調べた。各々の光浄水部
に、有機物10mg/Lを含む処理液を流速20L/m
inで通水し、残存している有機物量を測定した。結果
を図4に示す。この結果、以下のことがわかる。従来の
光浄水部はセラミックハニカムに光励起薄膜を担持して
いるため、紫外線ランプから遠い部分ほど紫外線が行き
渡らず、光励起薄膜の浄化効果が乏しい。それに対し、
本実施の形態の光浄水部10A,10B,10Cでは光
励起薄膜6に十分な紫外線が照射されるため、浄化効果
が高くなる。中でも第2の実施の形態の光浄水部10B
は、光透過性部材5aの内外面及び紫外線ランプ4表面
に光励起薄膜6が形成されているため、最も浄化面積が
大きく、その効果が高い。次いで、第1の実施の形態の
光浄水部10A、第3の実施の形態の光浄水部10Cの
順に光励起薄膜6の面積が小さくなるため、浄化能力も
少しずつ、低下する。
Using the optical water purifiers 10A, 10B, and 10C of the first to third embodiments described above, water purification performance was examined using the conventional optical water purifier of FIG. 8 as a comparative example. A treatment liquid containing 10 mg / L of an organic substance is supplied to each light purification section at a flow rate of 20 L / m.
Water was passed in, and the amount of remaining organic matter was measured. FIG. 4 shows the results. As a result, the following can be understood. In the conventional light purifying section, since the photoexcitation thin film is carried on the ceramic honeycomb, the farther from the ultraviolet lamp, ultraviolet rays do not spread, and the purification effect of the photoexcitation thin film is poor. For it,
In the optical water purifiers 10A, 10B, and 10C of the present embodiment, the photoexcitation thin film 6 is irradiated with sufficient ultraviolet rays, so that the purification effect is enhanced. Among them, the optical water purification unit 10B of the second embodiment
Since the light excitation thin film 6 is formed on the inner and outer surfaces of the light transmitting member 5a and the surface of the ultraviolet lamp 4, the cleaning area is the largest and the effect is high. Next, since the area of the photoexcitation thin film 6 becomes smaller in the order of the optical water purification unit 10A of the first embodiment and the optical water purification unit 10C of the third embodiment, the purification ability also decreases gradually.

【0030】図4には、本発明の第4の実施の形態を示
す。本実施の形態は、浄水システムとしてシステム化さ
れたものである。光浄水部は家庭用上水を処理の対象水
とし、一時的に貯留するタンクなどに設置するものであ
る。貯留するタンクは専用の貯水槽もしくは浴槽14な
どである。浴槽14に貯水されている場合、処理液1は
循環用ポンプ9の動力により、まずフィルタを含む物理
濾過部8で粒子を除去する。これにより光浄水部10で
は光の透過率がよくなり、光励起薄膜に十分な紫外線エ
ネルギーが与えられる。よって、物理濾過部8は光浄水
部10より前段に設置される必要がある。次に、処理液
1は加熱部11で適温に保持されながら、微生物浄水部
12で処理される。微生物処理では、微生物が活発に活
動する最適温度があるが、この温度が約40℃前後であ
るため、加熱部11では処理液1をこの温度に保持す
る。よって、加熱部11は微生物浄水部12より前段に
位置する必要がある。さらに処理液1は光浄水部10で
浄化され、排出口13より細かい気泡とともに排出され
る。微生物浄水部12では浄化に有効な細菌が繁殖して
いるが、この細菌は僅かながら、流出する可能性があ
る。一方、光浄水部10は殺菌効果も有しているため、
流出した浄化菌を殺菌することができる。また、微生物
が不得意とする界面活性剤などを有効に処理するため
に、光浄水部10は微生物浄水部12の下流に位置する
ことが望ましい。また、気泡を含んだ処理液1は入浴者
へのマッサージ効果があるだけでなく、溶存酸素が高い
ため、微生物に対しても有効である。また、光励起薄膜
は紫外線エネルギーによって正孔と電子を形成し、この
正孔によるラジカル反応で有機物の分解、殺菌の効果が
得られる。水中の溶存酸素は電子を消費して、電子と正
孔の再結合を防止する効果があり、ラジカル反応が効率
よく行われる。
FIG. 4 shows a fourth embodiment of the present invention. In the present embodiment, a water purification system is systemized. The light water purification section is intended to treat domestic tap water for treatment, and is installed in a temporary storage tank or the like. The tank for storing is a dedicated water tank or a bathtub 14 or the like. When the processing liquid 1 is stored in the bath 14, particles of the processing liquid 1 are first removed by the physical filtration unit 8 including a filter by the power of the circulation pump 9. As a result, the light transmittance of the light purification section 10 is improved, and sufficient ultraviolet energy is given to the photoexcitation thin film. Therefore, the physical filtration unit 8 needs to be installed at a stage before the optical water purification unit 10. Next, the treatment liquid 1 is treated in the microorganism purification section 12 while being kept at an appropriate temperature in the heating section 11. In the microbial treatment, there is an optimum temperature at which the microorganisms are actively activated. However, since this temperature is about 40 ° C., the heating unit 11 holds the treatment liquid 1 at this temperature. Therefore, it is necessary that the heating unit 11 be located before the microorganism purification unit 12. Further, the treatment liquid 1 is purified in the optical water purification section 10 and discharged together with fine bubbles from the discharge port 13. Bacteria effective for purification are breeding in the microbial water purification unit 12, but there is a possibility that these bacteria may flow out, albeit slightly. On the other hand, since the light purification unit 10 also has a sterilizing effect,
The spilled purification bacteria can be sterilized. In addition, in order to effectively treat a surfactant or the like that microorganisms are not good at, it is desirable that the light water purification unit 10 be located downstream of the microorganism water purification unit 12. In addition, the treatment liquid 1 containing bubbles not only has a massage effect for bathers, but also has high dissolved oxygen, and thus is effective against microorganisms. In addition, the photoexcited thin film forms holes and electrons by the energy of ultraviolet rays, and the radical reaction by the holes has the effect of decomposing and sterilizing organic substances. Dissolved oxygen in water has an effect of consuming electrons and preventing recombination of electrons and holes, and a radical reaction is efficiently performed.

【0031】以上の浄水システムを用いて浄水性能を調
べた。前記第2の実施の形態の光浄水部10Bと、比較
例として前記図8の従来の光浄水部を図5の浄水システ
ムに組み込み、有機物10mg/Lを含む処理液を流速
20L/minで通水し、開始後1時間の有機物量を測
定した。測定終了後も装置の運転を継続した。翌日装置
の運転を中止し、10mg/Lの有機物を添加してから
運転を再開し測定した。この操作を連続して1ケ月間実
施した。図6には浄化開始1時間後の有機物量を示す。
この結果、本実施の形態の光浄水部10Bを設置した浄
水装置は、初期の浄水効果が高いだけでなく、処理液の
接する部分に汚れが付着しないため、長期にわたって光
励起薄膜に十分紫外線エネルギーが到達し、有機物の分
解が有効に行われる。これに対し、従来の光浄水部で
は、紫外線ランプを覆うガラス管に汚れが付着し、紫外
線透過率が低下するため、光励起薄膜の効果も低下す
る。図7には、初期と30日後の浄化開始後1時間の有
機物量の経時変化を示す。この結果から、本実施の形態
の光浄水部10Bを設置した浄水装置は、30日経って
も1時間で十分浄化されている。一方、従来の光浄水部
では、前日の有機物が浄化されずに残存しているため、
初期は12mg/Lの有機物を含有していた。また、浄
化を開始しても光浄水部の効果が乏しいため、1時間で
は十分に浄化されなかった。
The water purification performance was examined using the above-mentioned water purification system. The optical water purification unit 10B of the second embodiment and the conventional optical water purification unit of FIG. 8 as a comparative example are incorporated in the water purification system of FIG. 5, and a treatment liquid containing 10 mg / L of organic matter is passed at a flow rate of 20 L / min. Water was added, and the amount of organic matter for one hour after the start was measured. After the measurement was completed, the operation of the apparatus was continued. On the next day, the operation of the apparatus was stopped, and after adding 10 mg / L of an organic substance, the operation was restarted and measured. This operation was continuously performed for one month. FIG. 6 shows the amount of organic matter one hour after the start of purification.
As a result, the water purification device provided with the optical water purification unit 10B of the present embodiment not only has a high initial water purification effect, but also does not cause dirt to adhere to the portion in contact with the treatment liquid. And organic matter is effectively decomposed. On the other hand, in the conventional optical water purification section, dirt adheres to the glass tube covering the ultraviolet lamp, and the ultraviolet transmittance is reduced, so that the effect of the photoexcited thin film is also reduced. FIG. 7 shows the change over time in the amount of organic matter in the initial stage and one hour after the start of purification 30 days later. From this result, the water purification device provided with the optical water purification unit 10B of the present embodiment is sufficiently purified in one hour even after 30 days. On the other hand, in the conventional light water purification section, since the organic matter of the previous day remains without being purified,
Initially, it contained 12 mg / L of organic matter. Further, even when the purification was started, the effect of the light purification section was poor, so that the purification was not sufficient in one hour.

【0032】以上のように、本実施の形態の光浄水部に
よれば、水中の光励起薄膜による浄水が有効にかつ、長
期的にも安定した能力を維持し続けることが可能であ
る。
As described above, according to the optical water purification section of the present embodiment, it is possible to effectively purify the water using the photoexcited thin film in the water and to maintain the stable ability for a long time.

【0033】[0033]

【発明の効果】以上説明したように、請求項1記載の発
明によれば、紫外線を含む光を発する光源と、該光源を
覆うように形成され当該光源からの光を透過する光透過
性部材と、被浄化処理含水液体が接触する前記光透過性
部材の外表面に形成され前記光源からの光で励起されて
化学反応により前記被浄化処理含水液体を浄化する光励
起薄膜とを具備させたため、光励起薄膜の化学反応で光
透過性部材の外表面の汚れが分解されて付着が防止され
るので、長期的に安定した浄水能力を維持し続けること
ができる。
As described above, according to the first aspect of the present invention, a light source that emits light including ultraviolet light, and a light transmissive member that is formed to cover the light source and transmits light from the light source. And a light-excited thin film formed on the outer surface of the light-transmissive member that is to be contacted by the water-containing liquid to be purified and excited by light from the light source to purify the water-containing liquid to be purified by a chemical reaction. Dirt on the outer surface of the light-transmitting member is decomposed by the chemical reaction of the light-excited thin film and adhesion is prevented, so that stable water purification ability can be maintained for a long time.

【0034】請求項2記載の発明によれば、紫外線を含
む光を発する光源と、該光源を覆うように形成され当該
光源からの光を透過する光透過性部材及び家庭用上水が
接触する前記光透過性部材の外表面に形成され前記光源
からの光で励起されて化学反応により前記家庭用上水を
浄化する光励起薄膜を備えた光浄水部を、前記家庭用上
水を一時的に貯留するタンクに取り付けたため、多量の
家庭用上水を常時的確に浄化処理することができる。
According to the second aspect of the present invention, the light source that emits light including ultraviolet light, the light-transmitting member formed so as to cover the light source and transmitting the light from the light source, and household water are in contact with each other. An optical water purification section having a light excitation thin film formed on the outer surface of the light transmitting member and being excited by light from the light source and purifying the household water by a chemical reaction, temporarily cleans the household water. Since it is attached to the storage tank, a large amount of domestic water can always be purified accurately.

【0035】請求項3記載の発明によれば、前記家庭用
上水は浴槽水であり、前記光浄水部で浄化した水を循環
使用するように構成したため、循環使用される浴槽水を
常時的確に且つ安定して浄化処理することができる。
According to the third aspect of the present invention, the domestic tap water is bathtub water, and the water purified by the light purification section is circulated and used. The purification treatment can be performed quickly and stably.

【0036】請求項4記載の発明によれば、セラミック
ス等の担持体に微生物を担持させ前記家庭用上水を浄化
する微生物浄水部を有し、前記光浄水部は前記微生物浄
水部の下流側に配置したため、家庭用上水中の生物処理
不可能な物質の浄化を長期にわたって安定して行うこと
ができるとともに光浄水部は殺菌効果も持つため、微生
物浄水部から流出した浄化菌の殺菌を常時的確に行うこ
とができる。
According to the fourth aspect of the present invention, there is provided a microorganism purifying section for purifying the domestic water by supporting microorganisms on a carrier such as ceramics, and the light purifying section is located downstream of the microorganism purifying section. The water purification unit can stably purify substances that can not be treated in living water for a long period of time, and the light purification unit also has a bactericidal effect. Can be performed accurately.

【0037】請求項5記載の発明によれば、フィルタを
含む物理濾過部を有し、前記光浄水部は前記物理濾過部
の下流側に配置したため、物理濾過部の微粒子除去作用
によって光浄水部では紫外線透過率が高まり、高い浄水
力を長期にわたって維持することができる。
According to the fifth aspect of the present invention, there is provided a physical purification unit including a filter, and the optical water purification unit is disposed downstream of the physical filtration unit. In this case, the ultraviolet transmittance is increased, and high water purification power can be maintained for a long period of time.

【0038】請求項6記載の発明によれば、前記光浄水
部と前記タンクとの間に、前記家庭用上水を常時循環さ
せる駆動部と、前記家庭用上水を最適浄化温度に維持す
る加熱部と、これらを接続する配管とを具備させたた
め、家庭用上水が微生物処理等に最適な温度に維持され
て一層効率のよい浄水力を長期にわたって維持すること
ができる。
According to the invention of claim 6, a drive section for constantly circulating the domestic water supply between the light purification section and the tank, and maintaining the household water at an optimum purification temperature. Since the heating unit and the piping connecting these are provided, domestic water can be maintained at an optimum temperature for microbial treatment and the like, and more efficient water purification can be maintained for a long time.

【0039】請求項7記載の発明によれば、処理される
前記家庭用上水に気泡を含有させたため、溶存酸素量が
高まり、光励起薄膜の化学反応が促進されて、一層高い
浄水力を長期にわたって維持することができる。
According to the seventh aspect of the present invention, since the household water to be treated contains bubbles, the amount of dissolved oxygen is increased, the chemical reaction of the photoexcited thin film is promoted, and a higher water purification power is obtained for a long time. Can be maintained over time.

【0040】請求項8記載の発明によれば、前記タンク
への排出部に、気泡を含有する機能を付与させたため、
上記請求項7記載の発明の効果と同様の効果に加えてさ
らに、家庭用上水が浴槽水であるときには、入浴者への
マッサージ効果を得ることができる。
According to the eighth aspect of the present invention, since the function of containing air bubbles is imparted to the discharge section to the tank,
In addition to the effect similar to the effect of the invention described in claim 7, when the domestic tap water is bathtub water, a massage effect for a bather can be obtained.

【0041】請求項9記載の発明によれば、前記光源と
前記光透過性部材との間は、気体もしくは真空状態とし
たため、紫外線透過率が高まって、高い浄水効率を長期
にわたって維持することができる。
According to the ninth aspect of the present invention, since the space between the light source and the light-transmitting member is in a gas or vacuum state, the transmittance of ultraviolet rays is increased, and high water purification efficiency can be maintained for a long time. it can.

【0042】請求項10記載の発明によれば、前記光透
過性部材は透水性としたため、被浄化処理液が光源に直
接接触して紫外線による殺菌等の作用が高まって、高い
浄水力を長期にわたって維持することができる。
According to the tenth aspect of the present invention, since the light-transmitting member is made of water-permeable material, the liquid to be purified comes into direct contact with the light source, and the action of sterilization by ultraviolet rays is enhanced, and a high water-purifying power is obtained for a long time. Can be maintained over time.

【0043】請求項11記載の発明によれば、前記光透
過性部材の内表面と前記光源の壁面に前記光励起薄膜を
形成したため、被浄化処理液と光励起薄膜の接触面積が
増大して、より高い浄水力を長期的に安定して維持し続
けることができる。
According to the eleventh aspect of the present invention, since the photoexcitation thin film is formed on the inner surface of the light transmissive member and the wall surface of the light source, the contact area between the liquid to be purified and the photoexcitation thin film increases. High water purification power can be maintained stably for a long time.

【0044】請求項12記載の発明によれば、前記光透
過性部材は石英ガラスで形成したため、紫外線透過率が
高まり、高い浄水効率を長期にわたって維持することが
できる。
According to the twelfth aspect of the present invention, since the light-transmitting member is formed of quartz glass, the transmittance of ultraviolet rays is increased, and high water purification efficiency can be maintained for a long time.

【0045】請求項13記載の発明によれば、前記光励
起薄膜は、酸化チタンを主成分としたゾルゲル法によっ
て形成したため、光透過性の高い光励起薄膜が光透過性
部材の内外表面や光源の壁面に適切に形成されて、高い
浄水力を長期的に安定して維持し続けることができる。
According to the thirteenth aspect of the present invention, since the photoexcitation thin film is formed by a sol-gel method containing titanium oxide as a main component, the photoexcitation thin film having high light transmittance is formed on the inner and outer surfaces of the light transmission member and the wall surface of the light source. It can be formed properly and can maintain high water purification power stably for a long time.

【0046】請求項14記載の発明によれば、前記光励
起薄膜を形成した透過性部材を間に挟んで対向する位置
に、前記光源からの少なくとも紫外線を反射する反射面
を形成したため、紫外線が有効に活用されて、高い浄水
効率を長期にわたって維持することができる。
According to the fourteenth aspect of the present invention, a reflecting surface for reflecting at least ultraviolet light from the light source is formed at a position facing the light-exciting thin film formed transmissive member therebetween, so that ultraviolet light is effective. High water purification efficiency can be maintained over a long period of time.

【0047】請求項15記載の発明によれば、前記反射
面には、前記光励起薄膜を形成したため、反射面への汚
れ付着が防止され、常時高い反射作用が得られて、高い
浄水効率を一層長期にわたって維持することができる。
According to the fifteenth aspect of the present invention, since the photoexcitation thin film is formed on the reflection surface, adhesion of dirt to the reflection surface is prevented, a high reflection action is always obtained, and a high water purification efficiency is further improved. Can be maintained for a long time.

【0048】請求項16記載の発明によれば、前記光励
起薄膜を形成した面に、前記被浄化処理含水液体の流れ
に乱流を起こさせる障害部材を形成したため、光励起薄
膜と被浄化処理液の接触頻度が高まって、より高い浄水
効率を長期にわたって維持することができる。
According to the sixteenth aspect of the present invention, since the obstruction member that causes turbulence in the flow of the water-containing liquid to be purified is formed on the surface on which the light-excited thin film is formed. The frequency of contact increases, and higher water purification efficiency can be maintained for a long time.

【0049】請求項17記載の発明によれば、前記障害
部材は、前記光励起薄膜を形成した面に凹凸を付けたも
ので構成したため、装置内への障害部材の容易形成性が
得られて、上記請求項16記載の発明の効果と同様の効
果を容易に得ることができる。
According to the seventeenth aspect of the present invention, since the obstacle member is formed by forming irregularities on the surface on which the photoexcited thin film is formed, it is possible to easily form the obstacle member in the apparatus. The same effect as the effect of the invention described in claim 16 can be easily obtained.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明に係る浄水装置の第1の実施の形態を示
す構成図である。
FIG. 1 is a configuration diagram showing a first embodiment of a water purification device according to the present invention.

【図2】本発明の第2の実施の形態を示す構成図であ
る。
FIG. 2 is a configuration diagram showing a second embodiment of the present invention.

【図3】本発明の第3の実施の形態を示す構成図であ
る。
FIG. 3 is a configuration diagram showing a third embodiment of the present invention.

【図4】上記第1〜第3の実施の形態の浄水性能を比較
例とともに示す図である。
FIG. 4 is a diagram showing the water purification performance of the first to third embodiments together with a comparative example.

【図5】本発明の第4の実施の形態を示すブロック図で
ある。
FIG. 5 is a block diagram showing a fourth embodiment of the present invention.

【図6】上記第4の実施の形態の浄水性能(1)を比較
例とともに示す図である。
FIG. 6 is a diagram showing water purification performance (1) of the fourth embodiment together with a comparative example.

【図7】上記第4の実施の形態の浄水性能(2)を比較
例とともに示す図である。
FIG. 7 is a diagram showing water purification performance (2) of the fourth embodiment together with a comparative example.

【図8】従来の浄水装置の構成図である。FIG. 8 is a configuration diagram of a conventional water purification device.

【符号の説明】[Explanation of symbols]

1 処理液(被浄化処理含水液体) 4 紫外線ランプ(光源) 5,5a 光透過性部材 6 光励起薄膜 7 凹凸付き反射面 8 物理濾過部 9 循環用ポンプ 10,10A,10B,10C 光浄水部 11 加熱部 12 微生物浄水部 13 排出口 REFERENCE SIGNS LIST 1 treatment liquid (purified water-containing liquid) 4 ultraviolet lamp (light source) 5, 5a light-transmitting member 6 light-exciting thin film 7 reflection surface with irregularities 8 physical filtration unit 9 circulation pump 10, 10A, 10B, 10C light purification unit 11 Heating section 12 Microbial water purification section 13 Outlet

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 FI C02F 3/06 ZAB F24H 9/00 W F24H 9/00 B01D 35/02 J (72)発明者 山口 徹 東京都港区新橋3丁目3番9号 東芝エ ー・ブイ・イー株式会社内──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 6 Identification code FI C02F 3/06 ZAB F24H 9/00 W F24H 9/00 B01D 35/02 J (72) Inventor Tohru Yamaguchi 3 Shimbashi, Minato-ku, Tokyo Chome 3-9 Toshiba Ebu E Co., Ltd.

Claims (17)

【特許請求の範囲】[Claims] 【請求項1】 紫外線を含む光を発する光源と、該光源
を覆うように形成され当該光源からの光を透過する光透
過性部材と、被浄化処理含水液体が接触する前記光透過
性部材の外表面に形成され前記光源からの光で励起され
て化学反応により前記被浄化処理含水液体を浄化する光
励起薄膜とを有することを特徴とする浄水装置。
1. A light source that emits light including ultraviolet light, a light-transmitting member formed so as to cover the light source and transmitting light from the light source, and a light-transmitting member that is in contact with the water-containing liquid to be purified. A water-excited thin film formed on an outer surface and excited by light from the light source to purify the water-containing liquid to be purified by a chemical reaction.
【請求項2】 紫外線を含む光を発する光源と、該光源
を覆うように形成され当該光源からの光を透過する光透
過性部材及び家庭用上水が接触する前記光透過性部材の
外表面に形成され前記光源からの光で励起されて化学反
応により前記家庭用上水を浄化する光励起薄膜を備えた
光浄水部を、前記家庭用上水を一時的に貯留するタンク
に取り付けてなることを特徴とする浄水装置。
2. A light source that emits light including ultraviolet light, an outer surface of the light transmissive member formed so as to cover the light source, and a light transmissive member that transmits the light from the light source and a household water supply. A water purification section provided with a photo-excitation thin film that is formed in the water and is excited by light from the light source to purify the household water by a chemical reaction, attached to a tank that temporarily stores the household water. A water purification device characterized by the following.
【請求項3】 前記家庭用上水は浴槽水であり、前記光
浄水部で浄化した水を循環使用するように構成してなる
ことを特徴とする請求項2記載の浄水装置。
3. The water purification device according to claim 2, wherein the domestic tap water is bathtub water, and the purified water in the optical water purification unit is circulated and used.
【請求項4】 セラミックス等の担持体に微生物を担持
させ前記家庭用上水を浄化する微生物浄水部を有し、前
記光浄水部は前記微生物浄水部の下流側に配置してなる
ことを特徴とする請求項2記載の浄水装置。
4. A microbial water purification unit for purifying the domestic water by supporting microorganisms on a carrier such as ceramics, and wherein the light water purification unit is disposed downstream of the microorganism water purification unit. The water purification device according to claim 2, wherein
【請求項5】 フィルタを含む物理濾過部を有し、前記
光浄水部は前記物理濾過部の下流側に配置してなること
を特徴とする請求項2又は3記載の浄水装置。
5. The water purification device according to claim 2, further comprising a physical filtration unit including a filter, wherein the optical water purification unit is disposed downstream of the physical filtration unit.
【請求項6】 前記光浄水部と前記タンクとの間に、前
記家庭用上水を常時循環させる駆動部と、前記家庭用上
水を最適浄化温度に維持する加熱部と、これらを接続す
る配管とを有することを特徴とする請求項3記載の浄水
装置。
6. A drive section for constantly circulating the domestic tap water, a heating section for maintaining the domestic tap water at an optimum purification temperature, and a connection between the light purifying section and the tank. The water purification device according to claim 3, further comprising a pipe.
【請求項7】 処理される前記家庭用上水は気泡を含有
していることを特徴とする請求項2,3,4,5又は6
記載の浄水装置。
7. The domestic tap water to be treated contains air bubbles.
The described water purification device.
【請求項8】 前記タンクへの排出部は、気泡を含有す
る機能が付与されていることを特徴とする請求項2,
3,4,5,6又は7記載の浄水装置。
8. The discharge section to the tank is provided with a function of containing air bubbles.
The water purifier according to 3, 4, 5, 6 or 7.
【請求項9】 前記光源と前記光透過性部材との間は、
気体もしくは真空状態であることを特徴とする請求項1
乃至8の何れかに記載の浄水装置。
9. Between the light source and the light transmitting member,
2. A gas or vacuum state.
9. The water purification device according to any one of claims 1 to 8.
【請求項10】 前記光透過性部材は透水性であること
を特徴とする請求項1乃至8の何れかに記載の浄水装
置。
10. The water purification device according to claim 1, wherein the light-transmitting member is water-permeable.
【請求項11】 前記光透過性部材の内表面と前記光源
の壁面に前記光励起薄膜を形成してなることを特徴とす
る請求項10記載の浄水装置。
11. The water purification device according to claim 10, wherein the light excitation thin film is formed on an inner surface of the light transmitting member and a wall surface of the light source.
【請求項12】 前記光透過性部材は石英ガラスで形成
してなることを特徴とする請求項1乃至11の何れかに
記載の浄水装置。
12. The water purification device according to claim 1, wherein the light transmitting member is formed of quartz glass.
【請求項13】 前記光励起薄膜は、酸化チタンを主成
分としたゾルゲル法によって形成してなることを特徴と
する請求項1乃至12の何れかに記載の浄水装置。
13. The water purification device according to claim 1, wherein the photoexcited thin film is formed by a sol-gel method containing titanium oxide as a main component.
【請求項14】 前記光励起薄膜を形成した透過性部材
を間に挟んで対向する位置に、前記光源からの少なくと
も紫外線を反射する反射面を形成してなることを特徴と
する請求項1乃至13の何れかに記載の浄水装置。
14. A reflection surface for reflecting at least ultraviolet light from the light source is formed at a position facing the light-exciting thin film-formed transmissive member therebetween. The water purification device according to any one of the above.
【請求項15】 前記反射面には、前記光励起薄膜を形
成してなることを特徴とする請求項14記載の浄水装
置。
15. The water purification apparatus according to claim 14, wherein the light excitation thin film is formed on the reflection surface.
【請求項16】 前記光励起薄膜を形成した面に、前記
被浄化処理含水液体の流れに乱流を起こさせる障害部材
を形成してなることを特徴とする請求項1乃至15の何
れかに記載の浄水装置。
16. The method according to claim 1, wherein an obstruction member that causes a turbulent flow in the flow of the water-containing liquid to be purified is formed on the surface on which the photoexcitation thin film is formed. Water purification equipment.
【請求項17】 前記障害部材は、前記光励起薄膜を形
成した面に凹凸を付けたものであることを特徴とする請
求項16記載の浄水装置。
17. The water purification apparatus according to claim 16, wherein the obstacle member has a surface on which the light-excited thin film is formed with irregularities.
JP9068568A 1997-03-21 1997-03-21 Water purifying device Pending JPH10263535A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9068568A JPH10263535A (en) 1997-03-21 1997-03-21 Water purifying device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9068568A JPH10263535A (en) 1997-03-21 1997-03-21 Water purifying device

Publications (1)

Publication Number Publication Date
JPH10263535A true JPH10263535A (en) 1998-10-06

Family

ID=13377512

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9068568A Pending JPH10263535A (en) 1997-03-21 1997-03-21 Water purifying device

Country Status (1)

Country Link
JP (1) JPH10263535A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1714691A1 (en) * 2005-04-15 2006-10-25 Nipro Corporation Method of removing carbon monoxide from an oxygen carrier such as hemoglobin

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1714691A1 (en) * 2005-04-15 2006-10-25 Nipro Corporation Method of removing carbon monoxide from an oxygen carrier such as hemoglobin
US7601201B2 (en) 2005-04-15 2009-10-13 Nipro Corporation Method of removing carbon monoxide from an oxygen carrier and apparatus for removing carbon monoxide

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