JPH10235163A - Membrane module - Google Patents

Membrane module

Info

Publication number
JPH10235163A
JPH10235163A JP9039606A JP3960697A JPH10235163A JP H10235163 A JPH10235163 A JP H10235163A JP 9039606 A JP9039606 A JP 9039606A JP 3960697 A JP3960697 A JP 3960697A JP H10235163 A JPH10235163 A JP H10235163A
Authority
JP
Japan
Prior art keywords
header
ceramic
guide plate
membrane module
ceramic film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP9039606A
Other languages
Japanese (ja)
Other versions
JP3340340B2 (en
Inventor
Katsuro Ishihara
勝郎 石原
Yoshihisa Narukami
善久 鳴上
Takeshi Yoshizaki
健 吉崎
Toshiya Ozaki
俊也 尾崎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kubota Corp
Original Assignee
Kubota Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kubota Corp filed Critical Kubota Corp
Priority to JP03960697A priority Critical patent/JP3340340B2/en
Publication of JPH10235163A publication Critical patent/JPH10235163A/en
Application granted granted Critical
Publication of JP3340340B2 publication Critical patent/JP3340340B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/131Reverse-osmosis

Landscapes

  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

PROBLEM TO BE SOLVED: To absorb the tensile stress acting on a ceramic membrane even when expansion and contraction difference is generated between a guide plate and the ceramic membrane by a change in the circumferential temp. SOLUTION: This membrane module is constituted so that a header 3 supporting the end parts of ceramic membranes 1 and the other end parts of the guide plates 10, 10 opposed to the side surface thereof are bonded by an elastic adhesive 11 and the other end parts of the guide plates 10, 10 and the header 3 are made freely displaceable each other along the longitudinal direction of the ceramic membranes 1 by the elastic deformation of the elastic adhesive 11. By this constitution, the guide plates 10 and the ceramic membranes 1 are mutually freely expanded and contracted.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、被処理液中に浸漬
して設けられる外圧型の膜モジュールに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an external pressure type membrane module provided immersed in a liquid to be treated.

【0002】[0002]

【従来の技術】し尿・生活排水・産業廃水の処理や海水
淡水化処理などにおいて、被処理液中に浸漬して設けら
れる外圧型の膜モジュールとして、図4および図5に示
したような、複数本のチューブ状セラミック膜1を、ヘ
ッダ2,3で支持して互いに間隔をおいて平行に配列し
たものがある。
2. Description of the Related Art In the treatment of night soil, domestic wastewater, industrial wastewater, seawater desalination, and the like, an external pressure type membrane module provided by immersion in a liquid to be treated, as shown in FIGS. There are a plurality of tubular ceramic films 1 supported by headers 2 and 3 and arranged in parallel at intervals.

【0003】一方のヘッダ2には、面板4により吸引室
5が形成されるとともに、吸引室5を外部と連通させる
ための吸引口6が設けられており、ヘッダ2に支持され
るセラミック膜1の一端部は、面板4に貫設された孔7
に挿通されて吸引室5の内部に開口し、接着剤8により
面板4に固定されている。セラミック膜1の他端部は、
断面コ字形のヘッダ3の内底面に突き当てられ、接着剤
9により固定されている。
The header 2 has a suction chamber 5 formed by a face plate 4 and a suction port 6 for communicating the suction chamber 5 with the outside. One end of the hole is formed with a hole 7
And is opened to the inside of the suction chamber 5, and is fixed to the face plate 4 by the adhesive 8. The other end of the ceramic film 1
It is abutted against the inner bottom surface of the header 3 having a U-shaped cross section, and is fixed by an adhesive 9.

【0004】配列されたセラミック膜1の外側には、セ
ラミック膜1の保護と整流効果を目的として、両ヘッダ
2,3間に渡して互いに対向する一対のプラスチック製
ガイド板10,10が配置されている。ガイド板10,
10の一端は、接着剤などによりヘッダ2に固定され、
ガイド板10,10の他端は、ヘッダ3との間に適当間
隔をおいてセラミック膜1の長手方向に設けられた外枠
11に固定されている。
A pair of plastic guide plates 10, 10 facing each other across the two headers 2, 3 are arranged outside the arranged ceramic films 1 for the purpose of protecting and rectifying the ceramic films 1. ing. Guide plate 10,
One end of 10 is fixed to the header 2 with an adhesive or the like,
The other ends of the guide plates 10, 10 are fixed to an outer frame 11 provided in the longitudinal direction of the ceramic film 1 at an appropriate distance from the header 3.

【0005】このような膜モジュールにより濾過を行う
際は、膜モジュールを汚泥汚泥混合液などの被処理液中
に浸漬した状態において、被処理液を流動させてセラミ
ック膜1の間を通過させるとともに、吸引口6を通じて
セラミック膜1の内部に吸引圧を作用させることにより
(あるいは被処理液の自然水頭により)、セラミック膜
1において被処理液を濾過し、セラミック膜1を透過し
た清澄水を吸引室5,吸引口6を経て外部へ取り出す。
[0005] When filtration is performed by such a membrane module, while the membrane module is immersed in a liquid to be treated such as a mixture of sludge and sludge, the liquid to be treated is caused to flow and pass between the ceramic membranes 1. By applying a suction pressure to the inside of the ceramic membrane 1 through the suction port 6 (or by the natural head of the liquid to be treated), the liquid to be treated is filtered in the ceramic membrane 1 and the clear water permeating through the ceramic membrane 1 is sucked. It is taken out through the chamber 5 and the suction port 6.

【0006】このとき被処理液によっては処理中にたと
えば60℃程度に昇温することがあり、その場合、プラ
スチック製のガイド板10,10とセラミック膜1とは
熱膨張率の差により伸縮差が生じるが、ガイド板10,
10が固定された外枠11とセラミック膜1が固定され
たヘッダ3とが互いに摺動自在なので、セラミック膜1
とガイド板10とは互いに自由に伸縮することになり、
セラミック膜1には引張応力は生じにくく、破損は生じ
にくい。
At this time, depending on the liquid to be treated, the temperature may rise to, for example, about 60 ° C. during the treatment. Occurs, but the guide plate 10,
The outer frame 11 to which the ceramic film 1 is fixed and the header 3 to which the ceramic film 1 is fixed are slidable with respect to each other.
And the guide plate 10 will freely expand and contract with each other,
Tensile stress is hardly generated in the ceramic film 1 and breakage is hardly generated.

【0007】[0007]

【発明が解決しようとする課題】しかしながら、上記し
た従来の膜モジュールでは、ヘッダ3と外枠11との隙
間に汚泥などが入り込んで閉塞し、ヘッダ3,外枠11
が互いに摺動不能となる場合があった。
However, in the above-mentioned conventional membrane module, sludge or the like enters the gap between the header 3 and the outer frame 11 and is closed, so that the header 3 and the outer frame 11 are closed.
May not slide with each other.

【0008】本発明は上記問題を解決するもので、周囲
温度の変化によってガイド板とセラミック膜との間に伸
縮差が生じた時も、セラミック膜に働く引張応力を吸収
できる膜モジュールを提供することを目的とするもので
ある。
The present invention solves the above problem, and provides a membrane module that can absorb the tensile stress acting on the ceramic film even when a difference in expansion and contraction occurs between the guide plate and the ceramic film due to a change in ambient temperature. The purpose is to do so.

【0009】[0009]

【課題を解決するための手段】上記問題を解決するため
に、本発明の膜モジュールは、複数本のチューブ状セラ
ミック膜の両端部に、各セラミック膜を互いに間隔をお
いて平行に支持する一対のヘッダを設け、前記複数本の
セラミック膜の外側に、各セラミック膜を保護するとと
もに被処理液の流れを案内するガイド板を両ヘッダ間に
渡して互いに対向して設けた外圧型の膜モジュールにお
いて、前記ガイド板の一端部は一方のヘッダに固定し、
前記ガイド板の他端部は、弾性接着剤により他方のヘッ
ダに接着して、このガイド板の他端部と他方のヘッダと
を、弾性接着剤の弾性変形により、セラミック膜の長手
方向に沿って互いに変位自在に構成したものである。
In order to solve the above-mentioned problems, a membrane module according to the present invention comprises a pair of tubular ceramic membranes which are supported at both ends by a pair of ceramic membranes which are supported in parallel at a distance from each other. An external pressure type membrane module in which a header is provided, and a guide plate for protecting each ceramic membrane and guiding the flow of the liquid to be treated is provided between the two headers and opposed to each other outside the plurality of ceramic membranes. In, one end of the guide plate is fixed to one header,
The other end of the guide plate is adhered to the other header with an elastic adhesive, and the other end of the guide plate and the other header are moved along the longitudinal direction of the ceramic film by elastic deformation of the elastic adhesive. Are configured to be mutually displaceable.

【0010】好ましくは、他方のヘッダは内側面に凹部
を有して断面がコ字形をなす形状に形成し、各セラミッ
ク膜の一端部を前記凹部内に配置し、凹部内に充填した
弾性接着剤により支持する。
Preferably, the other header has a concave portion on the inner surface and has a U-shaped cross section, one end of each ceramic film is disposed in the concave portion, and the elastic adhesive filled in the concave portion is provided. Supported by the agent.

【0011】より好ましくは、各セラミック膜の端面と
他方のヘッダの凹部内底面との間に所定の間隙を設け
る。上記構成によれば、ガイド板の他端部とセラミック
膜の一方の端部を支持する他方のヘッダとが、弾性接着
剤の弾性変形によりセラミック膜の長手方向に沿って互
いに変位自在なので、ガイド板とセラミック膜との間に
熱膨張率差がある場合も、ガイド板とセラミック膜とが
互いに自由に伸縮することになり、セラミック膜にその
破壊の原因となる大きな引張応力が働くことが防止され
る。
More preferably, a predetermined gap is provided between the end face of each ceramic film and the bottom face in the recess of the other header. According to the above configuration, the other end of the guide plate and the other header supporting one end of the ceramic film can be displaced from each other along the longitudinal direction of the ceramic film due to the elastic deformation of the elastic adhesive. Even if there is a difference in the coefficient of thermal expansion between the plate and the ceramic film, the guide plate and the ceramic film can freely expand and contract with each other, preventing the ceramic film from being subjected to a large tensile stress that causes its destruction. Is done.

【0012】またガイド板の他端部と他方のヘッダとの
間隙は弾性接着剤により閉塞されているので、ガイド板
と他方のヘッダとが一体となり、チューブ状の膜はその
両端において十分に支持されるため、長さ方向と直交す
る方向に水流が通過するような場合も十分な強度が得ら
れる。
Since the gap between the other end of the guide plate and the other header is closed by an elastic adhesive, the guide plate and the other header are integrated, and the tubular film is sufficiently supported at both ends. Therefore, sufficient strength can be obtained even when the water flow passes in a direction orthogonal to the length direction.

【0013】各セラミック膜の一端部を他方のヘッダの
凹部内において弾性接着剤により支持する場合は、この
弾性接着剤の弾性変形によって、ガイド板とセラミック
膜との伸縮差によりセラミック膜に負荷される引張応力
や水流による曲げ応力を吸収できる。この作用は、各セ
ラミック膜の端面と他方のヘッダの凹部内底面との間に
所定の間隙を設けた場合に、より大きい。
When one end of each ceramic film is supported by an elastic adhesive in the recess of the other header, a load is applied to the ceramic film due to the difference in expansion and contraction between the guide plate and the ceramic film due to the elastic deformation of the elastic adhesive. It can absorb tensile stress and bending stress caused by water flow. This effect is greater when a predetermined gap is provided between the end surface of each ceramic film and the bottom surface in the recess of the other header.

【0014】[0014]

【発明の実施の形態】以下、本発明の実施形態を図面を
参照しながら説明する。図1において、本発明の一実施
形態における膜モジュールは図4,図5を用いて説明し
た従来のものとほぼ同様の構成を有しているので、同様
の作用を有する部材に図4,5と同一符号を付して詳し
い説明を省略する。
Embodiments of the present invention will be described below with reference to the drawings. In FIG. 1, the membrane module according to one embodiment of the present invention has substantially the same configuration as the conventional one described with reference to FIGS. The same reference numerals are given and the detailed description is omitted.

【0015】この膜モジュールでは、従来のものと同様
に、複数本のチューブ状セラミック膜1が、ヘッダ2,
3で支持して互いに間隔をおいて平行に配列されてお
り、両ヘッダ2,3間に渡して、互いに対向するガイド
板10,10が設けられている。
In this membrane module, a plurality of tubular ceramic membranes 1 are provided with a header 2,
Guide plates 10, 10 are supported by 3, are arranged in parallel at a distance from each other, and face each other between both headers 2, 3.

【0016】ガイド板10,10の一端部はヘッダ2に
固定され、ガイド板10,10の他端部は、ヘッダ3の
外側に適当間隔をおいてセラミック膜1の長手方向に沿
って設けられた外枠11に固定されている。各セラミッ
ク膜1の一端部は、ヘッダ2の面板4に貫設された孔7
に挿通されて吸引室5の内部に開口し、接着剤8により
面板4に固定されている。
One end of each of the guide plates 10, 10 is fixed to the header 2, and the other end of each of the guide plates 10, 10 is provided outside the header 3 at an appropriate interval along the longitudinal direction of the ceramic film 1. Fixed to the outer frame 11. One end of each ceramic film 1 is provided with a hole 7 formed through the face plate 4 of the header 2.
And is opened to the inside of the suction chamber 5, and is fixed to the face plate 4 by the adhesive 8.

【0017】この膜モジュールが従来のものと異なるの
は、外枠11とヘッダ3とをその間に充填した弾性接着
剤12により接着した点である。また、各セラミック膜
1の他端部を、断面がコ字形をなすヘッダ3の凹部内で
内底面3aとの間に所定の間隙をおいて配置し、凹部内
に充填した弾性接着剤13により接着した点である。
The difference between this membrane module and the conventional one is that the outer frame 11 and the header 3 are bonded by an elastic adhesive 12 filled between them. Further, the other end of each ceramic film 1 is arranged at a predetermined gap between the inner bottom surface 3a and the concave portion of the header 3 having a U-shaped cross section, and the elastic adhesive 13 filled in the concave portion. It is the point where they adhered.

【0018】上記構成によれば、ガイド板10の他端部
とセラミック膜1の他端部を支持するヘッダ3とが、弾
性接着剤12の弾性変形によりセラミック膜1の長手方
向に沿って互いに変位自在なので、ガイド板10とセラ
ミック膜1との間に熱膨張率差がある場合も、ガイド板
10とセラミック膜1とが互いに自由に伸縮することに
なり、セラミック膜1に大きな引張応力が働くことはな
く、その破壊は防止される。
According to the above configuration, the other end of the guide plate 10 and the header 3 supporting the other end of the ceramic film 1 are mutually moved along the longitudinal direction of the ceramic film 1 by the elastic deformation of the elastic adhesive 12. Since the guide plate 10 and the ceramic film 1 can be freely displaced, the guide plate 10 and the ceramic film 1 can freely expand and contract with each other even when there is a difference in the coefficient of thermal expansion between the guide plate 10 and the ceramic film 1. It does not work and its destruction is prevented.

【0019】またガイド板10の他端部とヘッダ3との
間隙が弾性接着剤12により閉塞され、ガイド板10と
ヘッダ3とが一体とされているため、チューブ状のセラ
ミック膜1はその両端において十分に支持されており、
長さ方向と直交する方向に通過する水流に対しても十分
な強度を有する。
Since the gap between the other end of the guide plate 10 and the header 3 is closed by the elastic adhesive 12 and the guide plate 10 and the header 3 are integrated, the tubular ceramic film 1 has both ends. Is well supported by
It has sufficient strength against water flowing in a direction perpendicular to the length direction.

【0020】また各セラミック膜1の他端部をヘッダ3
の凹部内で、内底面3aとの間に所定の間隙をおいて弾
性接着剤13により接着しているので、弾性接着剤13
の弾性変形によって、ガイド板10とセラミック膜1の
伸縮差によりセラミック膜1に負荷される引張応力や水
流による曲げ応力を吸収できる。
The other end of each ceramic film 1 is connected to a header 3
Of the elastic adhesive 13 with a predetermined gap between the inner surface 3a and the inner bottom surface 3a.
Elastic deformation of the guide plate 10 and the ceramic film 1 can absorb the tensile stress applied to the ceramic film 1 due to the expansion and contraction and the bending stress due to the water flow.

【0021】弾性接着剤12,13としては、例えばシ
リコン系弾性接着剤を使用できる。なお、各セラミック
膜1は他端部の端面がヘッダ3の内底面3aに当接する
状態に配置してもよい。また外枠11は必ずしも必要で
はないが、外枠11によってガイド板10とヘッダ3と
の間隙を調節できるので、ヘッダ3を精度よく形成する
必要がなく、製作が容易になる。
As the elastic adhesives 12, 13, for example, a silicon-based elastic adhesive can be used. Note that each ceramic film 1 may be arranged such that the end face of the other end abuts on the inner bottom face 3 a of the header 3. Although the outer frame 11 is not always necessary, the gap between the guide plate 10 and the header 3 can be adjusted by the outer frame 11, so that it is not necessary to form the header 3 with high accuracy, and the manufacture becomes easy.

【0022】[0022]

【発明の効果】以上のように本発明によれば、セラミッ
ク膜の端部を支持するヘッダとその側面に対向するガイ
ド板の端部とを弾性接着剤により接着して、セラミック
膜の長手方向に沿って互いに変位自在とすることによ
り、周囲温度が変化した時にセラミック膜とガイド板と
を互いに自由に伸縮させることができ、セラミック膜の
破壊の原因となる大きな引張応力の発生を防止できる。
As described above, according to the present invention, the header supporting the end portion of the ceramic film and the end portion of the guide plate facing the side surface thereof are adhered to each other by an elastic adhesive so that the longitudinal direction of the ceramic film can be improved. The ceramic film and the guide plate can freely expand and contract with each other when the ambient temperature changes, thereby preventing the occurrence of a large tensile stress that causes the ceramic film to break.

【0023】また上記セラミック膜の端部をヘッダによ
り支持する際に、ヘッダの凹部内において弾性接着剤に
より接着することにより、セラミック膜に負荷される引
張応力や水流による曲げ応力を吸収できる。
Further, when the end of the ceramic film is supported by the header, the tensile stress applied to the ceramic film and the bending stress due to the water flow can be absorbed by bonding the elastic film in the recess of the header.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の一実施形態における膜モジュールの全
体構成を示した縦断面図である。
FIG. 1 is a longitudinal sectional view showing an overall configuration of a membrane module according to an embodiment of the present invention.

【図2】図1の膜モジュールにおけるヘッダとガイド板
との接着状態を示した拡大断面図である。
FIG. 2 is an enlarged cross-sectional view showing a bonding state between a header and a guide plate in the membrane module of FIG.

【図3】図1の膜モジュールにおけるヘッダとセラミッ
ク膜との接着状態を示した拡大断面図である。
FIG. 3 is an enlarged cross-sectional view showing a bonding state between a header and a ceramic film in the film module of FIG. 1;

【図4】従来の膜モジュールの全体構成を示した縦断面
図である。
FIG. 4 is a longitudinal sectional view showing the entire configuration of a conventional membrane module.

【図5】図4の膜モジュールのII−II断面図であ
る。
FIG. 5 is a sectional view of the membrane module of FIG. 4 taken along the line II-II.

【符号の説明】[Explanation of symbols]

1 セラミック膜 2,3 ヘッダ 3a 内底面 10 ガイド板 12 弾性接着剤 13 弾性接着剤 DESCRIPTION OF SYMBOLS 1 Ceramic film 2, 3 Header 3a Inner bottom surface 10 Guide plate 12 Elastic adhesive 13 Elastic adhesive

───────────────────────────────────────────────────── フロントページの続き (72)発明者 尾崎 俊也 大阪府大阪市西淀川区西島2丁目1番地6 号 株式会社クボタ新淀川工場内 ──────────────────────────────────────────────────の Continued on the front page (72) Inventor Toshiya Ozaki 2-1-1, Nishijima, Nishiyodogawa-ku, Osaka-shi, Osaka Inside Kubota Shin-Yodogawa Plant

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 複数本のチューブ状セラミック膜の両端
部に、各セラミック膜を互いに間隔をおいて平行に支持
する一対のヘッダを設け、前記複数本のセラミック膜の
外側に、各セラミック膜を保護するとともに被処理液の
流れを案内するガイド板を両ヘッダ間に渡して互いに対
向して設けた外圧型の膜モジュールにおいて、前記ガイ
ド板の一端部は一方のヘッダに固定し、前記ガイド板の
他端部は、弾性接着剤により他方のヘッダに接着して、
このガイド板の他端部と他方のヘッダとを、弾性接着剤
の弾性変形により、セラミック膜の長手方向に沿って互
いに変位自在に構成したことを特徴とする膜モジュー
ル。
A pair of headers are provided at both ends of a plurality of tubular ceramic films to support the respective ceramic films in parallel at a distance from each other, and the respective ceramic films are provided outside the plurality of ceramic films. In an external pressure type membrane module in which a guide plate for protecting and guiding the flow of the liquid to be treated is provided between two headers and opposed to each other, one end of the guide plate is fixed to one header, and the guide plate is The other end is bonded to the other header with an elastic adhesive,
A membrane module wherein the other end of the guide plate and the other header are configured to be mutually displaceable along the longitudinal direction of the ceramic film by elastic deformation of an elastic adhesive.
【請求項2】 他方のヘッダは内側面に凹部を有して断
面がコ字形をなす形状に形成し、各セラミック膜の一端
部を前記凹部内に配置し、凹部内に充填した弾性接着剤
により支持したことを特徴とする請求項1記載の膜モジ
ュール。
2. The other header has a concave portion on its inner surface and has a U-shaped cross section. One end of each ceramic film is disposed in the concave portion, and the elastic adhesive filled in the concave portion. The membrane module according to claim 1, wherein the membrane module is supported by:
【請求項3】 各セラミック膜の端面と他方のヘッダの
凹部内底面との間に所定の間隙を設けたことを特徴とす
る請求項2記載の膜モジュール。
3. The membrane module according to claim 2, wherein a predetermined gap is provided between the end face of each ceramic membrane and the bottom face in the recess of the other header.
JP03960697A 1997-02-25 1997-02-25 Membrane module Expired - Lifetime JP3340340B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP03960697A JP3340340B2 (en) 1997-02-25 1997-02-25 Membrane module

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP03960697A JP3340340B2 (en) 1997-02-25 1997-02-25 Membrane module

Publications (2)

Publication Number Publication Date
JPH10235163A true JPH10235163A (en) 1998-09-08
JP3340340B2 JP3340340B2 (en) 2002-11-05

Family

ID=12557784

Family Applications (1)

Application Number Title Priority Date Filing Date
JP03960697A Expired - Lifetime JP3340340B2 (en) 1997-02-25 1997-02-25 Membrane module

Country Status (1)

Country Link
JP (1) JP3340340B2 (en)

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JP2002346343A (en) * 2001-05-22 2002-12-03 Mitsubishi Rayon Co Ltd Water collection header and membrane module unit
JP4716599B2 (en) * 2001-05-22 2011-07-06 三菱レイヨン株式会社 Catchment header and membrane module unit
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JP2016155094A (en) * 2015-02-25 2016-09-01 三菱化学株式会社 Separation membrane module
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